Spatial distribution and source apportionment of DTPA-extractable metals in soils surrounding the largest Serbian steel production plant
Authorized Users Only
2023
Authors
Dragović, SnežanaSmičiklas, Ivana
Jović, Mihajlo
Čupić, Aleksandar
Dragović, Ranko
Gajić, Boško
Onjia, Antonije
Article (Published version)
Metadata
Show full item recordAbstract
Despite presenting a practical approach for the characterization of the environmental risk of potentially toxic elements (PTEs) derived from steel production facilities, the analysis of the spatial distribution of bioavailable PTEs concentrations in the soil is frequently overlooked in the management of polluted sites. In this study, the diethylenetriaminepentaacetic acid (DTPA)-extractable forms of PTEs were investigated in soils surrounding the largest Serbian steel production plant. The correlation and geostatistical analysis indicated their pronounced variability suggesting the anthropogenic origin of most investigated elements, apparently from the steel production facility. The detailed visualization of variables and observations derived by self-organizing maps (SOMs) revealed the homologies in PTEs’ distribution patterns, implying the common origin of some elements. These observations were confirmed by principal component analysis (PCA) and positive matrix factorization (PMF). Th...e аpplied approach supports a comprehensive assessment of contaminated sites' ecological and health risks and provides a basis for soil remediation.
Keywords:
Bioavailability / Gis / Multivariate analysis / Potentially toxic elements / Soil pollution / Steel productionSource:
Heliyon, 2023, 9, 5, e16307-Publisher:
- Elsevier Ltd
Funding / projects:
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča) (RS-MESTD-inst-2020-200017)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200116 (University of Belgrade, Faculty of Agriculture) (RS-MESTD-inst-2020-200116)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200124 (Univeristy of Niš, Faculty of Science) (RS-MESTD-inst-2020-200124)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200135 (University of Belgrade, Faculty of Technology and Metallurgy) (RS-MESTD-inst-2020-200135)
DOI: 10.1016/j.heliyon.2023.e16307
ISSN: 2405-8440
PubMed: 37251896
WoS: 001026337300001
Scopus: 2-s2.0-85159325100
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Dragović, Snežana AU - Smičiklas, Ivana AU - Jović, Mihajlo AU - Čupić, Aleksandar AU - Dragović, Ranko AU - Gajić, Boško AU - Onjia, Antonije PY - 2023 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6419 AB - Despite presenting a practical approach for the characterization of the environmental risk of potentially toxic elements (PTEs) derived from steel production facilities, the analysis of the spatial distribution of bioavailable PTEs concentrations in the soil is frequently overlooked in the management of polluted sites. In this study, the diethylenetriaminepentaacetic acid (DTPA)-extractable forms of PTEs were investigated in soils surrounding the largest Serbian steel production plant. The correlation and geostatistical analysis indicated their pronounced variability suggesting the anthropogenic origin of most investigated elements, apparently from the steel production facility. The detailed visualization of variables and observations derived by self-organizing maps (SOMs) revealed the homologies in PTEs’ distribution patterns, implying the common origin of some elements. These observations were confirmed by principal component analysis (PCA) and positive matrix factorization (PMF). The аpplied approach supports a comprehensive assessment of contaminated sites' ecological and health risks and provides a basis for soil remediation. PB - Elsevier Ltd T2 - Heliyon T1 - Spatial distribution and source apportionment of DTPA-extractable metals in soils surrounding the largest Serbian steel production plant IS - 5 SP - e16307 VL - 9 DO - 10.1016/j.heliyon.2023.e16307 ER -
@article{ author = "Dragović, Snežana and Smičiklas, Ivana and Jović, Mihajlo and Čupić, Aleksandar and Dragović, Ranko and Gajić, Boško and Onjia, Antonije", year = "2023", abstract = "Despite presenting a practical approach for the characterization of the environmental risk of potentially toxic elements (PTEs) derived from steel production facilities, the analysis of the spatial distribution of bioavailable PTEs concentrations in the soil is frequently overlooked in the management of polluted sites. In this study, the diethylenetriaminepentaacetic acid (DTPA)-extractable forms of PTEs were investigated in soils surrounding the largest Serbian steel production plant. The correlation and geostatistical analysis indicated their pronounced variability suggesting the anthropogenic origin of most investigated elements, apparently from the steel production facility. The detailed visualization of variables and observations derived by self-organizing maps (SOMs) revealed the homologies in PTEs’ distribution patterns, implying the common origin of some elements. These observations were confirmed by principal component analysis (PCA) and positive matrix factorization (PMF). The аpplied approach supports a comprehensive assessment of contaminated sites' ecological and health risks and provides a basis for soil remediation.", publisher = "Elsevier Ltd", journal = "Heliyon", title = "Spatial distribution and source apportionment of DTPA-extractable metals in soils surrounding the largest Serbian steel production plant", number = "5", pages = "e16307", volume = "9", doi = "10.1016/j.heliyon.2023.e16307" }
Dragović, S., Smičiklas, I., Jović, M., Čupić, A., Dragović, R., Gajić, B.,& Onjia, A.. (2023). Spatial distribution and source apportionment of DTPA-extractable metals in soils surrounding the largest Serbian steel production plant. in Heliyon Elsevier Ltd., 9(5), e16307. https://doi.org/10.1016/j.heliyon.2023.e16307
Dragović S, Smičiklas I, Jović M, Čupić A, Dragović R, Gajić B, Onjia A. Spatial distribution and source apportionment of DTPA-extractable metals in soils surrounding the largest Serbian steel production plant. in Heliyon. 2023;9(5):e16307. doi:10.1016/j.heliyon.2023.e16307 .
Dragović, Snežana, Smičiklas, Ivana, Jović, Mihajlo, Čupić, Aleksandar, Dragović, Ranko, Gajić, Boško, Onjia, Antonije, "Spatial distribution and source apportionment of DTPA-extractable metals in soils surrounding the largest Serbian steel production plant" in Heliyon, 9, no. 5 (2023):e16307, https://doi.org/10.1016/j.heliyon.2023.e16307 . .