Приказ основних података о документу
Solar-driven thermo-photocatalytic CO2 methanation over a structured RuO2:TiO2/SBA-15 nanocomposite at low temperature
dc.creator | Paulista, Larissa O. | |
dc.creator | Ferreira, Alexandre F. P. | |
dc.creator | Castanheira, Bruna | |
dc.creator | Đolić, Maja B. | |
dc.creator | Martins, Ramiro J. E. | |
dc.creator | Boaventura, Rui A. R. | |
dc.creator | Vilar, Vítor J. P. | |
dc.creator | Silva, Tânia F. C. V. | |
dc.date.accessioned | 2023-09-20T07:34:45Z | |
dc.date.available | 2023-09-20T07:34:45Z | |
dc.date.issued | 2024 | |
dc.identifier.issn | 0926-3373 | |
dc.identifier.uri | http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6622 | |
dc.description.abstract | A new hybrid catalyst composed of mesostructured silica SBA-15 functionalized with TiO2 and further loaded with RuO2 was developed to efficiently promote thermo-photocatalytic CO2 hydrogenation into methane at low temperatures. The catalytic activity was assessed with respect to TiO2:RuO2 loading, catalyst dosage, illumination source (polychromatic sunlight and monochromatic LEDs) and power, [H2]:[CO2] molar ratio, temperature, and catalyst reusability. The best methanation yields were attained for the RuO2(6.4%):TiO2(16.9%)/SBA-15 nanocomposite at 150 ºC, under simulated sunlight (0.21 W) and stoichiometric [H2]:[CO2] molar ratio, reaching: a specific CH4 production rate of 13.6 mmol gcat-1 h-1; 99.8 % selectivity; 96.8 % CO2 conversion (110-min; 40 mL); and apparent photonic efficiency/quantum yield of 39.5 %/42.1 %. Considering only the active RuO2:TiO2 photocatalyst mass (23.3 %), the CH4 production rate increased to 58.6 mmol gactive_cat-1 h-1. Besides, this highly-active photocatalyst featured excellent UV-Vis-IR light absorbance, high surface area, and stability for reuse when moist gas was removed between cycles. | sr |
dc.language.iso | en | sr |
dc.publisher | Elsevier B.V. | sr |
dc.relation | LA/P/0045/2020 (ALiCE), UIDB/50020/2020 and UIDP/50020/2020 (LSRE-LCM), funded by national funds through Fundaçao para a Ciencia e a Tecnologia (FCT), and Ministerio da Ciencia, Tecnologia e Ensino Superior (MCTES), Portugal, under Programa de Investimento e Despesas de Desenvolvimento da Administraçao Central (PIDDAC) | sr |
dc.relation | Project HyGreen&LowEmissions (NORTE-01-0145-FEDER-000077), supported by Norte Portugal Regional Operational Programme (NORTE 2020), under the PORTUGAL 2020 Partnership Agreement, through the European Regional Development Fund (ERDF) | sr |
dc.relation | Project CO2-to-CH4 (2022.01176. PTDC), supported by national funds through the FCT/MCTES (PIDDAC). Larissa O. Paulista acknowledges the Ph.D. fellowship supported by FCT (reference SFRH/BD/137639/2018 and COVID/BD/152922/2022) | sr |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200135/RS// | sr |
dc.relation | FCT Individual Call to Scientific Employment Stimulus 2017 (CEECIND/ 01386/2017) | sr |
dc.rights | restrictedAccess | sr |
dc.source | Applied Catalysis B: Environmental | sr |
dc.subject | Outstanding UV-Vis-IR light response | sr |
dc.subject | Renewable methane production | sr |
dc.subject | RuO2:TiO2-functionalized SBA | sr |
dc.subject | Solar-assisted CO2 hydrogenation | sr |
dc.subject | Thermo-photocatalysis | sr |
dc.title | Solar-driven thermo-photocatalytic CO2 methanation over a structured RuO2:TiO2/SBA-15 nanocomposite at low temperature | sr |
dc.type | article | sr |
dc.rights.license | ARR | sr |
dc.citation.rank | aM21 | |
dc.citation.spage | 123232 | |
dc.citation.volume | 340 | |
dc.identifier.doi | 10.1016/j.apcatb.2023.123232 | |
dc.identifier.scopus | 2-s2.0-85170086440 | |
dc.type.version | publishedVersion | sr |