Show simple item record

dc.creatorRadovanović, Dragana
dc.creatorDikić, Jelena
dc.creatorŠtulović, Marija
dc.creatorAnđić, Zoran
dc.creatorKamberović, Željko
dc.creatorJevtić, Sanja
dc.date.accessioned2023-11-21T21:53:52Z
dc.date.available2023-11-21T21:53:52Z
dc.date.issued2023
dc.identifier.issn2217-8961
dc.identifier.urihttp://TechnoRep.tmf.bg.ac.rs/handle/123456789/6872
dc.description.abstractLow-cost and easily available natural zeolite is a promising adsorbent for metal ions removal in wastewater treatment. The possibility of using zeolitic tuff from Serbia in the form of Na-enriched natural zeolite (Na-Z) for the adsorption of Pb2+, Zn2+, Cu2+, and Ni2+ions from wastewater was investigated in the presented paper. The research included Na-Z characterization and determination of adsorption kinetics in individual ion adsorption tests using Weber-Morris intraparticle diffusion model, non-linear pseudo-first-order (PFO), pseudo-second-order (PSO) and mixed-order (MO) kinetic models. The results indicate that the adsorption processes of metal ions on Na-Z are complex processes dominated by multiple rate-limiting mechanisms and best defined by the MO model. The mechanisms of ion diffusion and adsorption to active sites are equally represented in the Pb2+adsorption process. The mechanism of ion adsorption on the active sites is the rate-limiting step in the Zn2+adsorption process, while in the case of the Cu2+and Ni2+adsorption ion diffusion is the rate-limiting kinetic mechanism. Within the MO model, the PFO rate (external/internal diffusion) and the PSO rate (adsorption on active sites) were calculated and results wereapplied to a multicomponent wastewater sample in order to determine and explain the adsorption efficiency in wastewater treatment. The results show that the rate of adsorption of individual metal ions and the efficiency of ion removal from a multicomponent wastewater sample are influenced by several factors including the radius of the hydrated ion and the free energy of hydration. The achieved removal of metal ions by Na-Z is Pb2+(89%) > Cu2+(72%) > Zn2+(61%) > Ni2+(58%) and defines Na-enriched naturalzeolite as an effective adsorbent in wastewater treatment.sr
dc.language.isoensr
dc.publisherThe Netherlands Presssr
dc.relationinfo:eu-repo/grantAgreement/MESTD/inst-2020/200287/RS//sr
dc.relationinfo:eu-repo/grantAgreement/MESTD/inst-2020/200135/RS//sr
dc.relationinfo:eu-repo/grantAgreement/MESTD/inst-2020/200288/RS//sr
dc.rightsopenAccesssr
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.sourceMetallurgical and Materials Engineeringsr
dc.subjectCationssr
dc.subjectMixed-Order Kineticssr
dc.subjectMulticomponent Systemsr
dc.subjectNon-Linear Regressionsr
dc.subjectPseudo-First Order Kineticssr
dc.subjectPseudo-Second Order Kineticssr
dc.titleSorption of Pb2+, Zn2+, Cu2+ and Ni2+ Ions on Na-enriched Natural Zeolite for Wastewater Treatment Process: A Kinetic Approachsr
dc.typearticlesr
dc.rights.licenseBYsr
dc.citation.epage35
dc.citation.issue3
dc.citation.rankM24
dc.citation.spage20
dc.citation.volume29
dc.identifier.doi10.56801/MME1007
dc.identifier.fulltexthttp://TechnoRep.tmf.bg.ac.rs/bitstream/id/18708/Sorption_of_Pb2+_pub_2023.pdf
dc.identifier.scopus2-s2.0-85176410523
dc.type.versionpublishedVersionsr


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record