Synthesis and single-crystal structure analysis of a new layered zinc phosphate
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2005
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A new 2D zinc phosphate [H3NCH(CH3)CH 2NH3]2+0.75[COOH(CH 2)COOH]0.25 (Zn3P3O 11OH)2-* 0.5NH4+ consists of zinc phosphate layers, which are intercalated by diprotonated 1,2-diaminopropane, malonic acid, and NH4+ ions. The inorganic layers are composed of alternating ZnO4 and PO4 (PO3OH) tetrahedra that form 8-membered ring apertures. The intercalated species strongly interact with the zinc phosphate layers through hydrogen bonds, which is a key factor in stabilizing the structure. Crystal data: monoclinic, P21/a, a = 8.3457(1) Å, b = 16.8953(3) Å, c = 10.1817(2) Å, β = 95.3121(8)°, Z = 4, R = 0.0423.
Ključne reči:
Layered / Low-dimensional / Open framework / Zinc phosphate / ZPAMIzvor:
Pure and Applied Chemistry, 2005, 77, 10, 1707-1717Finansiranje / projekti:
- We are thankful for the support by the Slovenian Ministry of Education, Science and Sport through the research program P0-0516-0104 and by the Ministry of Science and Technology of Serbia (Project No: OI 1603).
DOI: 10.1351/pac200577101707
ISSN: 0033-4545
PubMed:
WoS: 000232991500005
Scopus: 2-s2.0-27644469066
Institucija/grupa
Tehnološko-metalurški fakultetTY - JOUR AU - Zabukovec-Logar, Nataša AU - Rajić, Nevenka AU - Stojaković, D. AU - Golobić, Amalija AU - Kaučič, Venčeslav PY - 2005 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/726 AB - A new 2D zinc phosphate [H3NCH(CH3)CH 2NH3]2+0.75[COOH(CH 2)COOH]0.25 (Zn3P3O 11OH)2-* 0.5NH4+ consists of zinc phosphate layers, which are intercalated by diprotonated 1,2-diaminopropane, malonic acid, and NH4+ ions. The inorganic layers are composed of alternating ZnO4 and PO4 (PO3OH) tetrahedra that form 8-membered ring apertures. The intercalated species strongly interact with the zinc phosphate layers through hydrogen bonds, which is a key factor in stabilizing the structure. Crystal data: monoclinic, P21/a, a = 8.3457(1) Å, b = 16.8953(3) Å, c = 10.1817(2) Å, β = 95.3121(8)°, Z = 4, R = 0.0423. T2 - Pure and Applied Chemistry T1 - Synthesis and single-crystal structure analysis of a new layered zinc phosphate EP - 1717 IS - 10 SP - 1707 VL - 77 DO - 10.1351/pac200577101707 ER -
@article{ author = "Zabukovec-Logar, Nataša and Rajić, Nevenka and Stojaković, D. and Golobić, Amalija and Kaučič, Venčeslav", year = "2005", abstract = "A new 2D zinc phosphate [H3NCH(CH3)CH 2NH3]2+0.75[COOH(CH 2)COOH]0.25 (Zn3P3O 11OH)2-* 0.5NH4+ consists of zinc phosphate layers, which are intercalated by diprotonated 1,2-diaminopropane, malonic acid, and NH4+ ions. The inorganic layers are composed of alternating ZnO4 and PO4 (PO3OH) tetrahedra that form 8-membered ring apertures. The intercalated species strongly interact with the zinc phosphate layers through hydrogen bonds, which is a key factor in stabilizing the structure. Crystal data: monoclinic, P21/a, a = 8.3457(1) Å, b = 16.8953(3) Å, c = 10.1817(2) Å, β = 95.3121(8)°, Z = 4, R = 0.0423.", journal = "Pure and Applied Chemistry", title = "Synthesis and single-crystal structure analysis of a new layered zinc phosphate", pages = "1717-1707", number = "10", volume = "77", doi = "10.1351/pac200577101707" }
Zabukovec-Logar, N., Rajić, N., Stojaković, D., Golobić, A.,& Kaučič, V.. (2005). Synthesis and single-crystal structure analysis of a new layered zinc phosphate. in Pure and Applied Chemistry, 77(10), 1707-1717. https://doi.org/10.1351/pac200577101707
Zabukovec-Logar N, Rajić N, Stojaković D, Golobić A, Kaučič V. Synthesis and single-crystal structure analysis of a new layered zinc phosphate. in Pure and Applied Chemistry. 2005;77(10):1707-1717. doi:10.1351/pac200577101707 .
Zabukovec-Logar, Nataša, Rajić, Nevenka, Stojaković, D., Golobić, Amalija, Kaučič, Venčeslav, "Synthesis and single-crystal structure analysis of a new layered zinc phosphate" in Pure and Applied Chemistry, 77, no. 10 (2005):1707-1717, https://doi.org/10.1351/pac200577101707 . .