(C4H12N2)[Zn-2(PO4)(HPO4)(H2PO4)], a layered zinc phosphate with intercalated N-methylpropane-1,3-diaminium cations
2005
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Authors
Zabukovec-Logar, NatašaRajić, Nevenka
Stojaković, D.
Sajić, Sanja
Golobić, Amalija
Kaučič, Venčeslav
Article (Published version)
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The title compound, catena-poly[[N-methylpropane-1,3diaminium [mu-phosphato-(mu-hydrogen phosphato)(mu-dihydrogen phosphato) dizincate(II)]], {(C4H14N2)[Zn-2(PO4)(HPO4)(H2PO4)]}(n), consists of macroanionic [Zn-2(PO4)(HPO4)(H2PO4)](2-) layers and intercalated (C4H12N2)(2+) cations. The layers are built up from ZnO4 and PO4/HPO4/H2PO4 tetrahedra that result in small channels of approximate diameter 3.7 angstrom within the layers. Framework-to-framework O - H center dot center dot center dot O and template-to-framework N - H center dot center dot center dot O hydrogen bonds are important in stabilizing the structure.
Source:
Acta Crystallographica Section E-Crystallographic Communications, 2005, 61, M1354-M1356Publisher:
- Int Union Crystallography, Chester
DOI: 10.1107/S1600536805018908
ISSN: 2056-9890
WoS: 000230167400041
Scopus: 2-s2.0-32244448022
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Zabukovec-Logar, Nataša AU - Rajić, Nevenka AU - Stojaković, D. AU - Sajić, Sanja AU - Golobić, Amalija AU - Kaučič, Venčeslav PY - 2005 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/784 AB - The title compound, catena-poly[[N-methylpropane-1,3diaminium [mu-phosphato-(mu-hydrogen phosphato)(mu-dihydrogen phosphato) dizincate(II)]], {(C4H14N2)[Zn-2(PO4)(HPO4)(H2PO4)]}(n), consists of macroanionic [Zn-2(PO4)(HPO4)(H2PO4)](2-) layers and intercalated (C4H12N2)(2+) cations. The layers are built up from ZnO4 and PO4/HPO4/H2PO4 tetrahedra that result in small channels of approximate diameter 3.7 angstrom within the layers. Framework-to-framework O - H center dot center dot center dot O and template-to-framework N - H center dot center dot center dot O hydrogen bonds are important in stabilizing the structure. PB - Int Union Crystallography, Chester T2 - Acta Crystallographica Section E-Crystallographic Communications T1 - (C4H12N2)[Zn-2(PO4)(HPO4)(H2PO4)], a layered zinc phosphate with intercalated N-methylpropane-1,3-diaminium cations EP - M1356 SP - M1354 VL - 61 DO - 10.1107/S1600536805018908 ER -
@article{ author = "Zabukovec-Logar, Nataša and Rajić, Nevenka and Stojaković, D. and Sajić, Sanja and Golobić, Amalija and Kaučič, Venčeslav", year = "2005", abstract = "The title compound, catena-poly[[N-methylpropane-1,3diaminium [mu-phosphato-(mu-hydrogen phosphato)(mu-dihydrogen phosphato) dizincate(II)]], {(C4H14N2)[Zn-2(PO4)(HPO4)(H2PO4)]}(n), consists of macroanionic [Zn-2(PO4)(HPO4)(H2PO4)](2-) layers and intercalated (C4H12N2)(2+) cations. The layers are built up from ZnO4 and PO4/HPO4/H2PO4 tetrahedra that result in small channels of approximate diameter 3.7 angstrom within the layers. Framework-to-framework O - H center dot center dot center dot O and template-to-framework N - H center dot center dot center dot O hydrogen bonds are important in stabilizing the structure.", publisher = "Int Union Crystallography, Chester", journal = "Acta Crystallographica Section E-Crystallographic Communications", title = "(C4H12N2)[Zn-2(PO4)(HPO4)(H2PO4)], a layered zinc phosphate with intercalated N-methylpropane-1,3-diaminium cations", pages = "M1356-M1354", volume = "61", doi = "10.1107/S1600536805018908" }
Zabukovec-Logar, N., Rajić, N., Stojaković, D., Sajić, S., Golobić, A.,& Kaučič, V.. (2005). (C4H12N2)[Zn-2(PO4)(HPO4)(H2PO4)], a layered zinc phosphate with intercalated N-methylpropane-1,3-diaminium cations. in Acta Crystallographica Section E-Crystallographic Communications Int Union Crystallography, Chester., 61, M1354-M1356. https://doi.org/10.1107/S1600536805018908
Zabukovec-Logar N, Rajić N, Stojaković D, Sajić S, Golobić A, Kaučič V. (C4H12N2)[Zn-2(PO4)(HPO4)(H2PO4)], a layered zinc phosphate with intercalated N-methylpropane-1,3-diaminium cations. in Acta Crystallographica Section E-Crystallographic Communications. 2005;61:M1354-M1356. doi:10.1107/S1600536805018908 .
Zabukovec-Logar, Nataša, Rajić, Nevenka, Stojaković, D., Sajić, Sanja, Golobić, Amalija, Kaučič, Venčeslav, "(C4H12N2)[Zn-2(PO4)(HPO4)(H2PO4)], a layered zinc phosphate with intercalated N-methylpropane-1,3-diaminium cations" in Acta Crystallographica Section E-Crystallographic Communications, 61 (2005):M1354-M1356, https://doi.org/10.1107/S1600536805018908 . .