Ion-exchange resins not previously used for this purpose were employed to study the synthesis of glycidyl esters. The reaction was carried out both with free acids and their sodium salts. The model reaction was the synthesis of glycidyl stearate. Crude glycidyl stearate was afforded in yields greater than 90% in a nonaquous, but not anhydrous system with GC purity above 99%. The phase-transfer catalytic (PTC) mechanism is proposed for the investigated reaction.
Keywords:
Glycidyl stearate / Ion-exchange resins / Phase transfer catalysis
Source:
Journal of the Serbian Chemical Society, 1996, 61, 7, 517-522
TY - JOUR
AU - Mijin, Dušan
AU - Ostrić, I.D.
AU - Misić-Vuković, Milica
PY - 1996
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/80
AB - Ion-exchange resins not previously used for this purpose were employed to study the synthesis of glycidyl esters. The reaction was carried out both with free acids and their sodium salts. The model reaction was the synthesis of glycidyl stearate. Crude glycidyl stearate was afforded in yields greater than 90% in a nonaquous, but not anhydrous system with GC purity above 99%. The phase-transfer catalytic (PTC) mechanism is proposed for the investigated reaction.
PB - Serbian Chemical Society, Belgrade
T2 - Journal of the Serbian Chemical Society
T1 - Glycidyl esters synthesis catalysed by ion-exchange resins
EP - 522
IS - 7
SP - 517
VL - 61
UR - https://hdl.handle.net/21.15107/rcub_technorep_80
ER -
@article{
author = "Mijin, Dušan and Ostrić, I.D. and Misić-Vuković, Milica",
year = "1996",
abstract = "Ion-exchange resins not previously used for this purpose were employed to study the synthesis of glycidyl esters. The reaction was carried out both with free acids and their sodium salts. The model reaction was the synthesis of glycidyl stearate. Crude glycidyl stearate was afforded in yields greater than 90% in a nonaquous, but not anhydrous system with GC purity above 99%. The phase-transfer catalytic (PTC) mechanism is proposed for the investigated reaction.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Glycidyl esters synthesis catalysed by ion-exchange resins",
pages = "522-517",
number = "7",
volume = "61",
url = "https://hdl.handle.net/21.15107/rcub_technorep_80"
}
Mijin, D., Ostrić, I.D.,& Misić-Vuković, M.. (1996). Glycidyl esters synthesis catalysed by ion-exchange resins. in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 61(7), 517-522.
https://hdl.handle.net/21.15107/rcub_technorep_80
Mijin D, Ostrić I, Misić-Vuković M. Glycidyl esters synthesis catalysed by ion-exchange resins. in Journal of the Serbian Chemical Society. 1996;61(7):517-522.
https://hdl.handle.net/21.15107/rcub_technorep_80 .
Mijin, Dušan, Ostrić, I.D., Misić-Vuković, Milica, "Glycidyl esters synthesis catalysed by ion-exchange resins" in Journal of the Serbian Chemical Society, 61, no. 7 (1996):517-522,
https://hdl.handle.net/21.15107/rcub_technorep_80 .
