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Determination of metal content in some herbal drugs - Empirical and chemometric approach

Authorized Users Only
2005
Authors
Ražić, Slavica
Onjia, Antonije
Dogo, S
Slavković, Latinka J.
Popović, Aleksandar R.
Article (Published version)
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Abstract
The concentrations of Cu, Zn, Mn, Fe, K, Ca, Mg, Al, Ba and B in 26 herbal drugs of special importance in phytopharmacywere studied. Flame atomic absorption and emission spectrometry (FAAS, FAES), as well as inductively coupled plasma atomic emission spectrometry (ICP-AES), were applied in this work. The whole procedure, from sample preparation, via dissolution, to measurements, was validated by using CRM (NIST 1573a-tomato leaves), and the obtained recovery values are in the range from 91 to 102%. Drug samples originated from medicinal plants cultivated in Serbia contained Cu (4.47-14.08 mg kg(-1)), Zn (8.4-54.5 mg kg(-1)), Mn (9-155 mg kg(-1)), Fe (47-546 mg kg(-1)), K (0.20-6.24%), Ca (0.18-1.84%), Mg (0.13-1.09%), Al (16-416 mg kg(-1)), Ba (11.70-84.83 mg kg(-1)) and B (5.1-118.7 mg kg(-1)). In order to get a better insight into the elemental patterns, a common chemometric approach to data evaluation was used. Four significant factors identified by principal component analysis (PCA...) were attributed partly to the significant influential sources and high mobility of some elements thus referring to potential anthropogenic contamination as well.

Keywords:
herbal drugs / trace elements / AAS / AES / chemometrics / PCA
Source:
Talanta, 2005, 67, 1, 233-239
Publisher:
  • Elsevier, Amsterdam

DOI: 10.1016/j.talanta.2005.03.023

ISSN: 0039-9140

PubMed: 18970161

WoS: 000230528500031

Scopus: 2-s2.0-21344461513
[ Google Scholar ]
83
65
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/813
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Ražić, Slavica
AU  - Onjia, Antonije
AU  - Dogo, S
AU  - Slavković, Latinka J.
AU  - Popović, Aleksandar R.
PY  - 2005
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/813
AB  - The concentrations of Cu, Zn, Mn, Fe, K, Ca, Mg, Al, Ba and B in 26 herbal drugs of special importance in phytopharmacywere studied. Flame atomic absorption and emission spectrometry (FAAS, FAES), as well as inductively coupled plasma atomic emission spectrometry (ICP-AES), were applied in this work. The whole procedure, from sample preparation, via dissolution, to measurements, was validated by using CRM (NIST 1573a-tomato leaves), and the obtained recovery values are in the range from 91 to 102%. Drug samples originated from medicinal plants cultivated in Serbia contained Cu (4.47-14.08 mg kg(-1)), Zn (8.4-54.5 mg kg(-1)), Mn (9-155 mg kg(-1)), Fe (47-546 mg kg(-1)), K (0.20-6.24%), Ca (0.18-1.84%), Mg (0.13-1.09%), Al (16-416 mg kg(-1)), Ba (11.70-84.83 mg kg(-1)) and B (5.1-118.7 mg kg(-1)). In order to get a better insight into the elemental patterns, a common chemometric approach to data evaluation was used. Four significant factors identified by principal component analysis (PCA) were attributed partly to the significant influential sources and high mobility of some elements thus referring to potential anthropogenic contamination as well.
PB  - Elsevier, Amsterdam
T2  - Talanta
T1  - Determination of metal content in some herbal drugs - Empirical and chemometric approach
EP  - 239
IS  - 1
SP  - 233
VL  - 67
DO  - 10.1016/j.talanta.2005.03.023
ER  - 
@article{
author = "Ražić, Slavica and Onjia, Antonije and Dogo, S and Slavković, Latinka J. and Popović, Aleksandar R.",
year = "2005",
abstract = "The concentrations of Cu, Zn, Mn, Fe, K, Ca, Mg, Al, Ba and B in 26 herbal drugs of special importance in phytopharmacywere studied. Flame atomic absorption and emission spectrometry (FAAS, FAES), as well as inductively coupled plasma atomic emission spectrometry (ICP-AES), were applied in this work. The whole procedure, from sample preparation, via dissolution, to measurements, was validated by using CRM (NIST 1573a-tomato leaves), and the obtained recovery values are in the range from 91 to 102%. Drug samples originated from medicinal plants cultivated in Serbia contained Cu (4.47-14.08 mg kg(-1)), Zn (8.4-54.5 mg kg(-1)), Mn (9-155 mg kg(-1)), Fe (47-546 mg kg(-1)), K (0.20-6.24%), Ca (0.18-1.84%), Mg (0.13-1.09%), Al (16-416 mg kg(-1)), Ba (11.70-84.83 mg kg(-1)) and B (5.1-118.7 mg kg(-1)). In order to get a better insight into the elemental patterns, a common chemometric approach to data evaluation was used. Four significant factors identified by principal component analysis (PCA) were attributed partly to the significant influential sources and high mobility of some elements thus referring to potential anthropogenic contamination as well.",
publisher = "Elsevier, Amsterdam",
journal = "Talanta",
title = "Determination of metal content in some herbal drugs - Empirical and chemometric approach",
pages = "239-233",
number = "1",
volume = "67",
doi = "10.1016/j.talanta.2005.03.023"
}
Ražić, S., Onjia, A., Dogo, S., Slavković, L. J.,& Popović, A. R.. (2005). Determination of metal content in some herbal drugs - Empirical and chemometric approach. in Talanta
Elsevier, Amsterdam., 67(1), 233-239.
https://doi.org/10.1016/j.talanta.2005.03.023
Ražić S, Onjia A, Dogo S, Slavković LJ, Popović AR. Determination of metal content in some herbal drugs - Empirical and chemometric approach. in Talanta. 2005;67(1):233-239.
doi:10.1016/j.talanta.2005.03.023 .
Ražić, Slavica, Onjia, Antonije, Dogo, S, Slavković, Latinka J., Popović, Aleksandar R., "Determination of metal content in some herbal drugs - Empirical and chemometric approach" in Talanta, 67, no. 1 (2005):233-239,
https://doi.org/10.1016/j.talanta.2005.03.023 . .

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