Osmotic coefficient of K2SO4(aq) in supersaturated solution at T=298.15 K
Само за регистроване кориснике
2005
Аутори
Ninković, RozalijaMiladinović, Jelena
Todorović, Milica D.
Rumyantsev, AV
Božović, Branislava R.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The Zdanovskii rule, in simple and modified form, was used for the estimation of supersaturated K2SO4-(aq) osmotic coefficients at T = 298.15 K by treatment of the isopiestic data of the mixed electrolyte solutions. The results were compared with the predictions of the Akerlof-Thomas rule and of weighted averages. Estimated values by the Zdanovskii rule together with the K2SO4(aq) osmotic coefficient experimental data in unsaturated solution were used in fitting the data to the extended Pitzer equation. The reliability of the Zdanovskii rule estimation was tested on the prediction of the osmotic coefficients in several mixed electrolyte solutions containing K2SO4 and having an ionic strength much greater than the ionic strength of saturated K2SO4(aq) and on the osmotic coefficient estimation for supersaturated Na2SO4(aq) at T = 298.15 K.
Извор:
Journal of Chemical and Engineering Data, 2005, 50, 3, 735-741Издавач:
- Amer Chemical Soc, Washington
DOI: 10.1021/je049632h
ISSN: 0021-9568
WoS: 000229128300001
Scopus: 2-s2.0-19544367131
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Ninković, Rozalija AU - Miladinović, Jelena AU - Todorović, Milica D. AU - Rumyantsev, AV AU - Božović, Branislava R. PY - 2005 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/817 AB - The Zdanovskii rule, in simple and modified form, was used for the estimation of supersaturated K2SO4-(aq) osmotic coefficients at T = 298.15 K by treatment of the isopiestic data of the mixed electrolyte solutions. The results were compared with the predictions of the Akerlof-Thomas rule and of weighted averages. Estimated values by the Zdanovskii rule together with the K2SO4(aq) osmotic coefficient experimental data in unsaturated solution were used in fitting the data to the extended Pitzer equation. The reliability of the Zdanovskii rule estimation was tested on the prediction of the osmotic coefficients in several mixed electrolyte solutions containing K2SO4 and having an ionic strength much greater than the ionic strength of saturated K2SO4(aq) and on the osmotic coefficient estimation for supersaturated Na2SO4(aq) at T = 298.15 K. PB - Amer Chemical Soc, Washington T2 - Journal of Chemical and Engineering Data T1 - Osmotic coefficient of K2SO4(aq) in supersaturated solution at T=298.15 K EP - 741 IS - 3 SP - 735 VL - 50 DO - 10.1021/je049632h ER -
@article{ author = "Ninković, Rozalija and Miladinović, Jelena and Todorović, Milica D. and Rumyantsev, AV and Božović, Branislava R.", year = "2005", abstract = "The Zdanovskii rule, in simple and modified form, was used for the estimation of supersaturated K2SO4-(aq) osmotic coefficients at T = 298.15 K by treatment of the isopiestic data of the mixed electrolyte solutions. The results were compared with the predictions of the Akerlof-Thomas rule and of weighted averages. Estimated values by the Zdanovskii rule together with the K2SO4(aq) osmotic coefficient experimental data in unsaturated solution were used in fitting the data to the extended Pitzer equation. The reliability of the Zdanovskii rule estimation was tested on the prediction of the osmotic coefficients in several mixed electrolyte solutions containing K2SO4 and having an ionic strength much greater than the ionic strength of saturated K2SO4(aq) and on the osmotic coefficient estimation for supersaturated Na2SO4(aq) at T = 298.15 K.", publisher = "Amer Chemical Soc, Washington", journal = "Journal of Chemical and Engineering Data", title = "Osmotic coefficient of K2SO4(aq) in supersaturated solution at T=298.15 K", pages = "741-735", number = "3", volume = "50", doi = "10.1021/je049632h" }
Ninković, R., Miladinović, J., Todorović, M. D., Rumyantsev, A.,& Božović, B. R.. (2005). Osmotic coefficient of K2SO4(aq) in supersaturated solution at T=298.15 K. in Journal of Chemical and Engineering Data Amer Chemical Soc, Washington., 50(3), 735-741. https://doi.org/10.1021/je049632h
Ninković R, Miladinović J, Todorović MD, Rumyantsev A, Božović BR. Osmotic coefficient of K2SO4(aq) in supersaturated solution at T=298.15 K. in Journal of Chemical and Engineering Data. 2005;50(3):735-741. doi:10.1021/je049632h .
Ninković, Rozalija, Miladinović, Jelena, Todorović, Milica D., Rumyantsev, AV, Božović, Branislava R., "Osmotic coefficient of K2SO4(aq) in supersaturated solution at T=298.15 K" in Journal of Chemical and Engineering Data, 50, no. 3 (2005):735-741, https://doi.org/10.1021/je049632h . .