Surface characterization of macroporous glycidyl methacrylate based copolymers by inverse gas chromatography
Samo za registrovane korisnike
2005
Članak u časopisu (Objavljena verzija)

Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Two samples of macroporous crosslinked poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate), PGME, with different porosity parameters were synthesized by suspension copolymerization and modified by ring-opening reaction of the pendant epoxy groups with ethylene diamine, EDA. Inverse gas chromatography at infinite dilution was used for the determination of adsorption properties of PGME, and copolymer modified with ethylene diamine, PGME-en. Thermodynamic parameters of adsorption, dispersive components of the surface free energies, and the S, acid/base constants for the copolymer samples were calculated. The calculated dispersive surface energy values, gamma(d)(S), for PGME and PGME-en are comparable with the literature data for nonconductive polymers.
Ključne reči:
thermodynamic parameters / adsorption / inverse gas chromatography / glycidyl methacrylate based copolymersIzvor:
European Polymer Journal, 2005, 41, 6, 1234-1242Izdavač:
- Pergamon-Elsevier Science Ltd, Oxford
DOI: 10.1016/j.eurpolymj.2004.12.020
ISSN: 0014-3057
WoS: 000229139800009
Scopus: 2-s2.0-17444412672
Institucija/grupa
Tehnološko-metalurški fakultetTY - JOUR AU - Nastasović, Aleksandra AU - Onjia, Antonije AU - Milonjić, Slobodan K. AU - Jovanović, SM PY - 2005 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/818 AB - Two samples of macroporous crosslinked poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate), PGME, with different porosity parameters were synthesized by suspension copolymerization and modified by ring-opening reaction of the pendant epoxy groups with ethylene diamine, EDA. Inverse gas chromatography at infinite dilution was used for the determination of adsorption properties of PGME, and copolymer modified with ethylene diamine, PGME-en. Thermodynamic parameters of adsorption, dispersive components of the surface free energies, and the S, acid/base constants for the copolymer samples were calculated. The calculated dispersive surface energy values, gamma(d)(S), for PGME and PGME-en are comparable with the literature data for nonconductive polymers. PB - Pergamon-Elsevier Science Ltd, Oxford T2 - European Polymer Journal T1 - Surface characterization of macroporous glycidyl methacrylate based copolymers by inverse gas chromatography EP - 1242 IS - 6 SP - 1234 VL - 41 DO - 10.1016/j.eurpolymj.2004.12.020 ER -
@article{ author = "Nastasović, Aleksandra and Onjia, Antonije and Milonjić, Slobodan K. and Jovanović, SM", year = "2005", abstract = "Two samples of macroporous crosslinked poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate), PGME, with different porosity parameters were synthesized by suspension copolymerization and modified by ring-opening reaction of the pendant epoxy groups with ethylene diamine, EDA. Inverse gas chromatography at infinite dilution was used for the determination of adsorption properties of PGME, and copolymer modified with ethylene diamine, PGME-en. Thermodynamic parameters of adsorption, dispersive components of the surface free energies, and the S, acid/base constants for the copolymer samples were calculated. The calculated dispersive surface energy values, gamma(d)(S), for PGME and PGME-en are comparable with the literature data for nonconductive polymers.", publisher = "Pergamon-Elsevier Science Ltd, Oxford", journal = "European Polymer Journal", title = "Surface characterization of macroporous glycidyl methacrylate based copolymers by inverse gas chromatography", pages = "1242-1234", number = "6", volume = "41", doi = "10.1016/j.eurpolymj.2004.12.020" }
Nastasović, A., Onjia, A., Milonjić, S. K.,& Jovanović, S.. (2005). Surface characterization of macroporous glycidyl methacrylate based copolymers by inverse gas chromatography. in European Polymer Journal Pergamon-Elsevier Science Ltd, Oxford., 41(6), 1234-1242. https://doi.org/10.1016/j.eurpolymj.2004.12.020
Nastasović A, Onjia A, Milonjić SK, Jovanović S. Surface characterization of macroporous glycidyl methacrylate based copolymers by inverse gas chromatography. in European Polymer Journal. 2005;41(6):1234-1242. doi:10.1016/j.eurpolymj.2004.12.020 .
Nastasović, Aleksandra, Onjia, Antonije, Milonjić, Slobodan K., Jovanović, SM, "Surface characterization of macroporous glycidyl methacrylate based copolymers by inverse gas chromatography" in European Polymer Journal, 41, no. 6 (2005):1234-1242, https://doi.org/10.1016/j.eurpolymj.2004.12.020 . .