The UV absorption spectra (200-400 nm) of eleven N-(4-substituted phenyl)-2,3-diphenyl-propanamides 1 have been recorded in fourteen solvents of different polarity. A simple Hammett equation was used to study the effects of substituents on the UV spectra of compounds 1. The effects of solvent polarity and hydrogen bonding on the absorption spectra are interpreted by means of linear solvation energy relationships. The results show that the solvent effect on UV absorption spectra of the investigated amides are very complex and strongly depends on the nature of the substituents of the phenyl ring.
Keywords:
Absorption spectra / Diphenylpropanamide / Linear solvation energy relationship / Simple Hammett equation / Solvent polarity / Substituent effect
TY - JOUR
AU - Valentić, Nataša
AU - Mijin, Dušan
AU - Ušćumlić, Gordana
AU - Marinković, Aleksandar
AU - Petrović, Slobodan
PY - 2006
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/864
AB - The UV absorption spectra (200-400 nm) of eleven N-(4-substituted phenyl)-2,3-diphenyl-propanamides 1 have been recorded in fourteen solvents of different polarity. A simple Hammett equation was used to study the effects of substituents on the UV spectra of compounds 1. The effects of solvent polarity and hydrogen bonding on the absorption spectra are interpreted by means of linear solvation energy relationships. The results show that the solvent effect on UV absorption spectra of the investigated amides are very complex and strongly depends on the nature of the substituents of the phenyl ring.
T2 - Arkivoc
T1 - Solvent and substituent effect on electronic spectra of N-(4-substituted phenyl)-2,3-diphenylpropanamides
EP - 90
IS - 12
SP - 81
VL - 2006
UR - https://hdl.handle.net/21.15107/rcub_technorep_864
ER -
@article{
author = "Valentić, Nataša and Mijin, Dušan and Ušćumlić, Gordana and Marinković, Aleksandar and Petrović, Slobodan",
year = "2006",
abstract = "The UV absorption spectra (200-400 nm) of eleven N-(4-substituted phenyl)-2,3-diphenyl-propanamides 1 have been recorded in fourteen solvents of different polarity. A simple Hammett equation was used to study the effects of substituents on the UV spectra of compounds 1. The effects of solvent polarity and hydrogen bonding on the absorption spectra are interpreted by means of linear solvation energy relationships. The results show that the solvent effect on UV absorption spectra of the investigated amides are very complex and strongly depends on the nature of the substituents of the phenyl ring.",
journal = "Arkivoc",
title = "Solvent and substituent effect on electronic spectra of N-(4-substituted phenyl)-2,3-diphenylpropanamides",
pages = "90-81",
number = "12",
volume = "2006",
url = "https://hdl.handle.net/21.15107/rcub_technorep_864"
}
Valentić, N., Mijin, D., Ušćumlić, G., Marinković, A.,& Petrović, S.. (2006). Solvent and substituent effect on electronic spectra of N-(4-substituted phenyl)-2,3-diphenylpropanamides. in Arkivoc, 2006(12), 81-90.
https://hdl.handle.net/21.15107/rcub_technorep_864
Valentić N, Mijin D, Ušćumlić G, Marinković A, Petrović S. Solvent and substituent effect on electronic spectra of N-(4-substituted phenyl)-2,3-diphenylpropanamides. in Arkivoc. 2006;2006(12):81-90.
https://hdl.handle.net/21.15107/rcub_technorep_864 .
Valentić, Nataša, Mijin, Dušan, Ušćumlić, Gordana, Marinković, Aleksandar, Petrović, Slobodan, "Solvent and substituent effect on electronic spectra of N-(4-substituted phenyl)-2,3-diphenylpropanamides" in Arkivoc, 2006, no. 12 (2006):81-90,
https://hdl.handle.net/21.15107/rcub_technorep_864 .
