The oxidative and non-oxidative degradation of poly(di-methoxy-), poly(di-ethoxy-), poly(di-iso-propoxy-) and poly(di-n-butoxyethyl itaconate) were investigated by thermogravimetry. Characteristic degradation temperatures and apparent activation energies of degradation were determined for the non-oxidative degradation of all the investigated polymers. It was not possible to determine these characteristics in the presence of oxygen as the degradation was accompanied by a secondary exothermic reaction. Based on examination of the monomers, it is supposed that the exothermic reaction is a repolymerisation of the monomers released during the earlier stages of polymer degradation.
TY - JOUR
AU - Katsikas, Lynne
AU - Đakov, Tatjana
AU - Filipović, Jovanka M.
AU - Veličković, Jovan S.
AU - Popović, Ivanka
PY - 1996
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/87
AB - The oxidative and non-oxidative degradation of poly(di-methoxy-), poly(di-ethoxy-), poly(di-iso-propoxy-) and poly(di-n-butoxyethyl itaconate) were investigated by thermogravimetry. Characteristic degradation temperatures and apparent activation energies of degradation were determined for the non-oxidative degradation of all the investigated polymers. It was not possible to determine these characteristics in the presence of oxygen as the degradation was accompanied by a secondary exothermic reaction. Based on examination of the monomers, it is supposed that the exothermic reaction is a repolymerisation of the monomers released during the earlier stages of polymer degradation.
PB - John Wiley & Sons Ltd, W Sussex
T2 - Journal of Thermal Analysis
T1 - Poly(dialkoxyethyl itaconates) .2. The thermal degradation of some poly(dialkoxyethyl itaconates)
EP - 1104
IS - 4
SP - 1093
VL - 47
DO - 10.1007/BF01979450
ER -
@article{
author = "Katsikas, Lynne and Đakov, Tatjana and Filipović, Jovanka M. and Veličković, Jovan S. and Popović, Ivanka",
year = "1996",
abstract = "The oxidative and non-oxidative degradation of poly(di-methoxy-), poly(di-ethoxy-), poly(di-iso-propoxy-) and poly(di-n-butoxyethyl itaconate) were investigated by thermogravimetry. Characteristic degradation temperatures and apparent activation energies of degradation were determined for the non-oxidative degradation of all the investigated polymers. It was not possible to determine these characteristics in the presence of oxygen as the degradation was accompanied by a secondary exothermic reaction. Based on examination of the monomers, it is supposed that the exothermic reaction is a repolymerisation of the monomers released during the earlier stages of polymer degradation.",
publisher = "John Wiley & Sons Ltd, W Sussex",
journal = "Journal of Thermal Analysis",
title = "Poly(dialkoxyethyl itaconates) .2. The thermal degradation of some poly(dialkoxyethyl itaconates)",
pages = "1104-1093",
number = "4",
volume = "47",
doi = "10.1007/BF01979450"
}
Katsikas, L., Đakov, T., Filipović, J. M., Veličković, J. S.,& Popović, I.. (1996). Poly(dialkoxyethyl itaconates) .2. The thermal degradation of some poly(dialkoxyethyl itaconates). in Journal of Thermal Analysis
John Wiley & Sons Ltd, W Sussex., 47(4), 1093-1104.
https://doi.org/10.1007/BF01979450
Katsikas L, Đakov T, Filipović JM, Veličković JS, Popović I. Poly(dialkoxyethyl itaconates) .2. The thermal degradation of some poly(dialkoxyethyl itaconates). in Journal of Thermal Analysis. 1996;47(4):1093-1104.
doi:10.1007/BF01979450 .
Katsikas, Lynne, Đakov, Tatjana, Filipović, Jovanka M., Veličković, Jovan S., Popović, Ivanka, "Poly(dialkoxyethyl itaconates) .2. The thermal degradation of some poly(dialkoxyethyl itaconates)" in Journal of Thermal Analysis, 47, no. 4 (1996):1093-1104,
https://doi.org/10.1007/BF01979450 . .
