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An evidence for a chain to network transformation during the microwave hydrothermal crystallization of an open-framework zinc terephthalate
dc.creator | Rajić, Nevenka | |
dc.creator | Stojaković, D. | |
dc.creator | Zabukovec-Logar, Nataša | |
dc.creator | Kaučič, Venčeslav | |
dc.date.accessioned | 2021-03-10T10:33:01Z | |
dc.date.available | 2021-03-10T10:33:01Z | |
dc.date.issued | 2006 | |
dc.identifier.issn | 1380-2224 | |
dc.identifier.uri | http://TechnoRep.tmf.bg.ac.rs/handle/123456789/931 | |
dc.description.abstract | A 3-D open-framework and a chain-structured zinc terephthalate are obtained by hydrothermal crystallization under microwave heating at 180 degrees C. The study shows that these structures have rather similar principal building units, which facilitates the structure transformation from the low-dimensional to the open-framework one during crystallization. The transformation involves the formation of new coordinative bonds between a Zn atom in a chain and two terephthalate groups from two different chains: one from the same stack and the other from the neighboring stack. Also, one water molecule coordinated to the Zn atom in the chain-like structure is lost and the zinc atom expands its coordination number to five. A considerable shift of the chains as well as bond twisting in them are necessary to occur prior to the formation of the network. | en |
dc.publisher | Springer, Dordrecht | |
dc.rights | restrictedAccess | |
dc.source | Journal of Porous Materials | |
dc.subject | zinc terephthalate | en |
dc.subject | open-framework | en |
dc.subject | inorganic-organic hybrid | en |
dc.subject | hydrothermal crystallization | en |
dc.subject | hydrogen storage | en |
dc.title | An evidence for a chain to network transformation during the microwave hydrothermal crystallization of an open-framework zinc terephthalate | en |
dc.type | article | |
dc.rights.license | ARR | |
dc.citation.epage | 156 | |
dc.citation.issue | 2 | |
dc.citation.other | 13(2): 153-156 | |
dc.citation.rank | M22 | |
dc.citation.spage | 153 | |
dc.citation.volume | 13 | |
dc.identifier.doi | 10.1007/s10934-006-7022-9 | |
dc.identifier.scopus | 2-s2.0-33645933300 | |
dc.identifier.wos | 000236842400008 | |
dc.type.version | publishedVersion |