Приказ основних података о документу

dc.creatorRajić, Nevenka
dc.creatorStojaković, D.
dc.creatorZabukovec-Logar, Nataša
dc.creatorKaučič, Venčeslav
dc.date.accessioned2021-03-10T10:33:01Z
dc.date.available2021-03-10T10:33:01Z
dc.date.issued2006
dc.identifier.issn1380-2224
dc.identifier.urihttp://TechnoRep.tmf.bg.ac.rs/handle/123456789/931
dc.description.abstractA 3-D open-framework and a chain-structured zinc terephthalate are obtained by hydrothermal crystallization under microwave heating at 180 degrees C. The study shows that these structures have rather similar principal building units, which facilitates the structure transformation from the low-dimensional to the open-framework one during crystallization. The transformation involves the formation of new coordinative bonds between a Zn atom in a chain and two terephthalate groups from two different chains: one from the same stack and the other from the neighboring stack. Also, one water molecule coordinated to the Zn atom in the chain-like structure is lost and the zinc atom expands its coordination number to five. A considerable shift of the chains as well as bond twisting in them are necessary to occur prior to the formation of the network.en
dc.publisherSpringer, Dordrecht
dc.rightsrestrictedAccess
dc.sourceJournal of Porous Materials
dc.subjectzinc terephthalateen
dc.subjectopen-frameworken
dc.subjectinorganic-organic hybriden
dc.subjecthydrothermal crystallizationen
dc.subjecthydrogen storageen
dc.titleAn evidence for a chain to network transformation during the microwave hydrothermal crystallization of an open-framework zinc terephthalateen
dc.typearticle
dc.rights.licenseARR
dc.citation.epage156
dc.citation.issue2
dc.citation.other13(2): 153-156
dc.citation.rankM22
dc.citation.spage153
dc.citation.volume13
dc.identifier.doi10.1007/s10934-006-7022-9
dc.identifier.scopus2-s2.0-33645933300
dc.identifier.wos000236842400008
dc.type.versionpublishedVersion


Документи

Thumbnail

Овај документ се појављује у следећим колекцијама

Приказ основних података о документу