Effect of temperature on the excess molar volumes of some alcohol plus aromatic mixtures and modelling by cubic EOS mixing rules
Само за регистроване кориснике
2006
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Densities of the (methanol + benzene), (ethanol + benzene), (methanol + chlorobenzene) and (ethanol + chlorobenzene) mixtures have been measured at six temperatures (288.15, 293.15, 298.15, 303.15, 308.15 and 313.15 K) and 101.33 kPa. Excess molar volumes 19 were determined and fitted by the Redlich-Kister equation. It was observed that in all cases V-E increases with rising of temperature. The values of limiting excess partial molar volumes have been calculated, as well. The obtained results have been analysed in terms of specific molecular interactions present in these mixtures taking into considerations effect of temperature on them. The correlation of V-E binary data was performed with the Peng-Robinson-Stryjek-Vera cubic equation of state (PRSV CEOS) coupled with the van der Waals (vdWI) and CEOS/G(E) mixing rule introduced by Twu, Coon, Bluck and Tilton (TCBT). The experimental values of V-E were compared with those estimated by both mixing rules at the temperature range and on e...ach temperature, separately.
Кључне речи:
alcohols / aromatics / experiments / excess molar volume / cubic EOS mixing rulesИзвор:
Fluid Phase Equilibria, 2006, 239, 1, 69-82Издавач:
- Elsevier
Напомена:
DOI: 10.1016/j.fluid.2005.10.022
ISSN: 0378-3812
WoS: 000234611200011
Scopus: 2-s2.0-29244491200
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Šerbanović, Slobodan P. AU - Kijevčanin, Mirjana AU - Radović, Ivona AU - Đorđević, Bojan D. PY - 2006 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/967 AB - Densities of the (methanol + benzene), (ethanol + benzene), (methanol + chlorobenzene) and (ethanol + chlorobenzene) mixtures have been measured at six temperatures (288.15, 293.15, 298.15, 303.15, 308.15 and 313.15 K) and 101.33 kPa. Excess molar volumes 19 were determined and fitted by the Redlich-Kister equation. It was observed that in all cases V-E increases with rising of temperature. The values of limiting excess partial molar volumes have been calculated, as well. The obtained results have been analysed in terms of specific molecular interactions present in these mixtures taking into considerations effect of temperature on them. The correlation of V-E binary data was performed with the Peng-Robinson-Stryjek-Vera cubic equation of state (PRSV CEOS) coupled with the van der Waals (vdWI) and CEOS/G(E) mixing rule introduced by Twu, Coon, Bluck and Tilton (TCBT). The experimental values of V-E were compared with those estimated by both mixing rules at the temperature range and on each temperature, separately. PB - Elsevier T2 - Fluid Phase Equilibria T1 - Effect of temperature on the excess molar volumes of some alcohol plus aromatic mixtures and modelling by cubic EOS mixing rules EP - 82 IS - 1 SP - 69 VL - 239 DO - 10.1016/j.fluid.2005.10.022 ER -
@article{ author = "Šerbanović, Slobodan P. and Kijevčanin, Mirjana and Radović, Ivona and Đorđević, Bojan D.", year = "2006", abstract = "Densities of the (methanol + benzene), (ethanol + benzene), (methanol + chlorobenzene) and (ethanol + chlorobenzene) mixtures have been measured at six temperatures (288.15, 293.15, 298.15, 303.15, 308.15 and 313.15 K) and 101.33 kPa. Excess molar volumes 19 were determined and fitted by the Redlich-Kister equation. It was observed that in all cases V-E increases with rising of temperature. The values of limiting excess partial molar volumes have been calculated, as well. The obtained results have been analysed in terms of specific molecular interactions present in these mixtures taking into considerations effect of temperature on them. The correlation of V-E binary data was performed with the Peng-Robinson-Stryjek-Vera cubic equation of state (PRSV CEOS) coupled with the van der Waals (vdWI) and CEOS/G(E) mixing rule introduced by Twu, Coon, Bluck and Tilton (TCBT). The experimental values of V-E were compared with those estimated by both mixing rules at the temperature range and on each temperature, separately.", publisher = "Elsevier", journal = "Fluid Phase Equilibria", title = "Effect of temperature on the excess molar volumes of some alcohol plus aromatic mixtures and modelling by cubic EOS mixing rules", pages = "82-69", number = "1", volume = "239", doi = "10.1016/j.fluid.2005.10.022" }
Šerbanović, S. P., Kijevčanin, M., Radović, I.,& Đorđević, B. D.. (2006). Effect of temperature on the excess molar volumes of some alcohol plus aromatic mixtures and modelling by cubic EOS mixing rules. in Fluid Phase Equilibria Elsevier., 239(1), 69-82. https://doi.org/10.1016/j.fluid.2005.10.022
Šerbanović SP, Kijevčanin M, Radović I, Đorđević BD. Effect of temperature on the excess molar volumes of some alcohol plus aromatic mixtures and modelling by cubic EOS mixing rules. in Fluid Phase Equilibria. 2006;239(1):69-82. doi:10.1016/j.fluid.2005.10.022 .
Šerbanović, Slobodan P., Kijevčanin, Mirjana, Radović, Ivona, Đorđević, Bojan D., "Effect of temperature on the excess molar volumes of some alcohol plus aromatic mixtures and modelling by cubic EOS mixing rules" in Fluid Phase Equilibria, 239, no. 1 (2006):69-82, https://doi.org/10.1016/j.fluid.2005.10.022 . .