Densities of the (methanol + benzene), (ethanol + benzene), (methanol + chlorobenzene) and (ethanol + chlorobenzene) mixtures have been measured at six temperatures (288.15, 293.15, 298.15, 303.15, 308.15 and 313.15 K) and 101.33 kPa. Excess molar volumes 19 were determined and fitted by the Redlich-Kister equation. It was observed that in all cases V-E increases with rising of temperature. The values of limiting excess partial molar volumes have been calculated, as well. The obtained results have been analysed in terms of specific molecular interactions present in these mixtures taking into considerations effect of temperature on them. The correlation of V-E binary data was performed with the Peng-Robinson-Stryjek-Vera cubic equation of state (PRSV CEOS) coupled with the van der Waals (vdWI) and CEOS/G(E) mixing rule introduced by Twu, Coon, Bluck and Tilton (TCBT). The experimental values of V-E were compared with those estimated by both mixing rules at the temperature range and on e...ach temperature, separately.
TY - JOUR
AU - Šerbanović, Slobodan P.
AU - Kijevčanin, Mirjana
AU - Radović, Ivona
AU - Đorđević, Bojan D.
PY - 2006
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/967
AB - Densities of the (methanol + benzene), (ethanol + benzene), (methanol + chlorobenzene) and (ethanol + chlorobenzene) mixtures have been measured at six temperatures (288.15, 293.15, 298.15, 303.15, 308.15 and 313.15 K) and 101.33 kPa. Excess molar volumes 19 were determined and fitted by the Redlich-Kister equation. It was observed that in all cases V-E increases with rising of temperature. The values of limiting excess partial molar volumes have been calculated, as well. The obtained results have been analysed in terms of specific molecular interactions present in these mixtures taking into considerations effect of temperature on them. The correlation of V-E binary data was performed with the Peng-Robinson-Stryjek-Vera cubic equation of state (PRSV CEOS) coupled with the van der Waals (vdWI) and CEOS/G(E) mixing rule introduced by Twu, Coon, Bluck and Tilton (TCBT). The experimental values of V-E were compared with those estimated by both mixing rules at the temperature range and on each temperature, separately.
PB - Elsevier Science Bv, Amsterdam
T2 - Fluid Phase Equilibria
T1 - Effect of temperature on the excess molar volumes of some alcohol plus aromatic mixtures and modelling by cubic EOS mixing rules
EP - 82
IS - 1
SP - 69
VL - 239
DO - 10.1016/j.fluid.2005.10.022
ER -
@article{
author = "Šerbanović, Slobodan P. and Kijevčanin, Mirjana and Radović, Ivona and Đorđević, Bojan D.",
year = "2006",
abstract = "Densities of the (methanol + benzene), (ethanol + benzene), (methanol + chlorobenzene) and (ethanol + chlorobenzene) mixtures have been measured at six temperatures (288.15, 293.15, 298.15, 303.15, 308.15 and 313.15 K) and 101.33 kPa. Excess molar volumes 19 were determined and fitted by the Redlich-Kister equation. It was observed that in all cases V-E increases with rising of temperature. The values of limiting excess partial molar volumes have been calculated, as well. The obtained results have been analysed in terms of specific molecular interactions present in these mixtures taking into considerations effect of temperature on them. The correlation of V-E binary data was performed with the Peng-Robinson-Stryjek-Vera cubic equation of state (PRSV CEOS) coupled with the van der Waals (vdWI) and CEOS/G(E) mixing rule introduced by Twu, Coon, Bluck and Tilton (TCBT). The experimental values of V-E were compared with those estimated by both mixing rules at the temperature range and on each temperature, separately.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Fluid Phase Equilibria",
title = "Effect of temperature on the excess molar volumes of some alcohol plus aromatic mixtures and modelling by cubic EOS mixing rules",
pages = "82-69",
number = "1",
volume = "239",
doi = "10.1016/j.fluid.2005.10.022"
}
Šerbanović, S. P., Kijevčanin, M., Radović, I.,& Đorđević, B. D.. (2006). Effect of temperature on the excess molar volumes of some alcohol plus aromatic mixtures and modelling by cubic EOS mixing rules. in Fluid Phase Equilibria
Elsevier Science Bv, Amsterdam., 239(1), 69-82.
https://doi.org/10.1016/j.fluid.2005.10.022
Šerbanović SP, Kijevčanin M, Radović I, Đorđević BD. Effect of temperature on the excess molar volumes of some alcohol plus aromatic mixtures and modelling by cubic EOS mixing rules. in Fluid Phase Equilibria. 2006;239(1):69-82.
doi:10.1016/j.fluid.2005.10.022 .
Šerbanović, Slobodan P., Kijevčanin, Mirjana, Radović, Ivona, Đorđević, Bojan D., "Effect of temperature on the excess molar volumes of some alcohol plus aromatic mixtures and modelling by cubic EOS mixing rules" in Fluid Phase Equilibria, 239, no. 1 (2006):69-82,
https://doi.org/10.1016/j.fluid.2005.10.022 . .
