The temperature dependence of the retention index for n-alkyl esters of acetic, propionic, cyclohexanecarboxylic, benzoic and phenylacetic acid on DB-1 and DB-5 capillary columns
Uticaj temperature na retencioni indeks n-alkil-estara sirćetne, propionske, cikloheksankarbonske, benzoeve i fenilsirćetne kiseline na DB-1 i DB-5 kapilarnim kolonama
Апстракт
The temperature dependence of the retention index was studied for n-alkyl esters of acetic, propionic, cyclohexanecarboxylic, benzoic and phenylacetic acid on DB-1 and DB-5 capillary columns. The study was performed over various temperature ranges depending on the volatility of the ester. Two linear equations of the temperature dependence of the retention data on the column temperature and its reciprocal as variables were studied. Agood linearity of the retention index versus column temperature was found.
U radu je prikazana linearna zavisnost retencionog indeksa od temperature korišćenjem linearnih zavisnosti retencionog indeksa u funkciji temperature kolone t, °C ili 1/T, K-1 za n-alkil estre sirćetne, propionske cikloheksankarbonske, benzoeve i fenilsirćetne kiseline na kapilarnim kolonama DB-1 i DB-5.
Кључне речи:
retention indices / alkyl esters / temperature dependenceИзвор:
Journal of the Serbian Chemical Society, 2006, 71, 6, 629-637Издавач:
- Serbian Chemical Society, Belgrade
Финансирање / пројекти:
- Проучавање синтезе, структуре и активности органских једињења природног и синтетског порекла (RS-MESTD-MPN2006-2010-142063)
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Mijin, Dušan AU - Antonović, Dušan PY - 2006 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/996 AB - The temperature dependence of the retention index was studied for n-alkyl esters of acetic, propionic, cyclohexanecarboxylic, benzoic and phenylacetic acid on DB-1 and DB-5 capillary columns. The study was performed over various temperature ranges depending on the volatility of the ester. Two linear equations of the temperature dependence of the retention data on the column temperature and its reciprocal as variables were studied. Agood linearity of the retention index versus column temperature was found. AB - U radu je prikazana linearna zavisnost retencionog indeksa od temperature korišćenjem linearnih zavisnosti retencionog indeksa u funkciji temperature kolone t, °C ili 1/T, K-1 za n-alkil estre sirćetne, propionske cikloheksankarbonske, benzoeve i fenilsirćetne kiseline na kapilarnim kolonama DB-1 i DB-5. PB - Serbian Chemical Society, Belgrade T2 - Journal of the Serbian Chemical Society T1 - The temperature dependence of the retention index for n-alkyl esters of acetic, propionic, cyclohexanecarboxylic, benzoic and phenylacetic acid on DB-1 and DB-5 capillary columns T1 - Uticaj temperature na retencioni indeks n-alkil-estara sirćetne, propionske, cikloheksankarbonske, benzoeve i fenilsirćetne kiseline na DB-1 i DB-5 kapilarnim kolonama EP - 637 IS - 6 SP - 629 VL - 71 UR - https://hdl.handle.net/21.15107/rcub_technorep_996 ER -
@article{ author = "Mijin, Dušan and Antonović, Dušan", year = "2006", abstract = "The temperature dependence of the retention index was studied for n-alkyl esters of acetic, propionic, cyclohexanecarboxylic, benzoic and phenylacetic acid on DB-1 and DB-5 capillary columns. The study was performed over various temperature ranges depending on the volatility of the ester. Two linear equations of the temperature dependence of the retention data on the column temperature and its reciprocal as variables were studied. Agood linearity of the retention index versus column temperature was found., U radu je prikazana linearna zavisnost retencionog indeksa od temperature korišćenjem linearnih zavisnosti retencionog indeksa u funkciji temperature kolone t, °C ili 1/T, K-1 za n-alkil estre sirćetne, propionske cikloheksankarbonske, benzoeve i fenilsirćetne kiseline na kapilarnim kolonama DB-1 i DB-5.", publisher = "Serbian Chemical Society, Belgrade", journal = "Journal of the Serbian Chemical Society", title = "The temperature dependence of the retention index for n-alkyl esters of acetic, propionic, cyclohexanecarboxylic, benzoic and phenylacetic acid on DB-1 and DB-5 capillary columns, Uticaj temperature na retencioni indeks n-alkil-estara sirćetne, propionske, cikloheksankarbonske, benzoeve i fenilsirćetne kiseline na DB-1 i DB-5 kapilarnim kolonama", pages = "637-629", number = "6", volume = "71", url = "https://hdl.handle.net/21.15107/rcub_technorep_996" }
Mijin, D.,& Antonović, D.. (2006). The temperature dependence of the retention index for n-alkyl esters of acetic, propionic, cyclohexanecarboxylic, benzoic and phenylacetic acid on DB-1 and DB-5 capillary columns. in Journal of the Serbian Chemical Society Serbian Chemical Society, Belgrade., 71(6), 629-637. https://hdl.handle.net/21.15107/rcub_technorep_996
Mijin D, Antonović D. The temperature dependence of the retention index for n-alkyl esters of acetic, propionic, cyclohexanecarboxylic, benzoic and phenylacetic acid on DB-1 and DB-5 capillary columns. in Journal of the Serbian Chemical Society. 2006;71(6):629-637. https://hdl.handle.net/21.15107/rcub_technorep_996 .
Mijin, Dušan, Antonović, Dušan, "The temperature dependence of the retention index for n-alkyl esters of acetic, propionic, cyclohexanecarboxylic, benzoic and phenylacetic acid on DB-1 and DB-5 capillary columns" in Journal of the Serbian Chemical Society, 71, no. 6 (2006):629-637, https://hdl.handle.net/21.15107/rcub_technorep_996 .