Investigation of the interfacial bonding in composite propellants. 1,3,5-trisubstituted isocyanurates as universal bonding agents
Proučavanje međusobnih veza komponenata u kompozitnim gorivima. 1,3,5-trisupstituisani izocijanurati kao univerzalni vezivni agensi
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
A series of 1,3,5-trisubstituted isocyanurates (substituents: CH2CH2OH CH2CH=CH2 and CH2CH2COOH) was synthesized according to a modified literature procedure. Experimental investigations included modification of the synthetic procedure in terms of the starting materials, solvents, temperature isolation techniques, as well as purification and identification of the products. All the synthesized isocyanurates were identified by their melting point and FTIR, 1H NMR and UV spectroscopic data. Fourier transform infrared spectrophotometry was also used to study the interaction between ammonium perchlorate, hydroxyl terminated poly(butadiene), carboxyl terminated poly(butadiene), poly(butadiene-co-acrylonitrile), poly(propylene ether) cyclotrimethylenetrinitramine and the compounds synthesized in this work which can serve as bonding agents. The results show that tris(2-hydroxyethyl)isocyanurate is a universal bonding agent for the ammonium perchlorate/carboxyl terminated poly(butadiene)/cyclot...rimethylenetrinitramine composite propellant system.
1,3,5-Trisupstituisani izocijanurati (supstituenti: CH2CH2OH, CH2CH=CH2 i CH2CH2COOH) su sintetizovani koristeći modifikovane literaturne postupke. Pri tome su menjani reaktanti, rastvarači, temperatura, način izolovanja kao i način prečišćavanja proizvoda. Svi dobijeni izocijanurati su okarakterisani temperaturama topljenja, FTIR, 1H NMR i UV podacima. FTIR je takođe korišćen za proučavanje interakcija između amonijumperhlorata, poli(butadiena) sa hidroksi i karboksi krajnjim grupama, poli(butadien-ko-akrilonitrila) poli(propilenetra), ciklotrimetilennitramina i jedinjenja sintetizovanih u ovom radu koji mogu poslužiti kao vezivni agensi.
Ključne reči:
isocyanurates / binder / bonding agent / interactions / composite material / hydrogen bonding / FTIRIzvor:
Journal of the Serbian Chemical Society, 2006, 71, 5, 445-458Izdavač:
- Serbian Chemical Society, Belgrade
Finansiranje / projekti:
- Proučavanje sinteze, strukture i aktivnosti organskih jedinjenja prirodnog i sintetskog porekla (RS-MESTD-MPN2006-2010-142063)
Institucija/grupa
Tehnološko-metalurški fakultetTY - JOUR AU - Ušćumlić, Gordana AU - Zreigh, Mohamed M. AU - Mijin, Dušan PY - 2006 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/997 AB - A series of 1,3,5-trisubstituted isocyanurates (substituents: CH2CH2OH CH2CH=CH2 and CH2CH2COOH) was synthesized according to a modified literature procedure. Experimental investigations included modification of the synthetic procedure in terms of the starting materials, solvents, temperature isolation techniques, as well as purification and identification of the products. All the synthesized isocyanurates were identified by their melting point and FTIR, 1H NMR and UV spectroscopic data. Fourier transform infrared spectrophotometry was also used to study the interaction between ammonium perchlorate, hydroxyl terminated poly(butadiene), carboxyl terminated poly(butadiene), poly(butadiene-co-acrylonitrile), poly(propylene ether) cyclotrimethylenetrinitramine and the compounds synthesized in this work which can serve as bonding agents. The results show that tris(2-hydroxyethyl)isocyanurate is a universal bonding agent for the ammonium perchlorate/carboxyl terminated poly(butadiene)/cyclotrimethylenetrinitramine composite propellant system. AB - 1,3,5-Trisupstituisani izocijanurati (supstituenti: CH2CH2OH, CH2CH=CH2 i CH2CH2COOH) su sintetizovani koristeći modifikovane literaturne postupke. Pri tome su menjani reaktanti, rastvarači, temperatura, način izolovanja kao i način prečišćavanja proizvoda. Svi dobijeni izocijanurati su okarakterisani temperaturama topljenja, FTIR, 1H NMR i UV podacima. FTIR je takođe korišćen za proučavanje interakcija između amonijumperhlorata, poli(butadiena) sa hidroksi i karboksi krajnjim grupama, poli(butadien-ko-akrilonitrila) poli(propilenetra), ciklotrimetilennitramina i jedinjenja sintetizovanih u ovom radu koji mogu poslužiti kao vezivni agensi. PB - Serbian Chemical Society, Belgrade T2 - Journal of the Serbian Chemical Society T1 - Investigation of the interfacial bonding in composite propellants. 1,3,5-trisubstituted isocyanurates as universal bonding agents T1 - Proučavanje međusobnih veza komponenata u kompozitnim gorivima. 1,3,5-trisupstituisani izocijanurati kao univerzalni vezivni agensi EP - 458 IS - 5 SP - 445 VL - 71 UR - https://hdl.handle.net/21.15107/rcub_technorep_997 ER -
@article{ author = "Ušćumlić, Gordana and Zreigh, Mohamed M. and Mijin, Dušan", year = "2006", abstract = "A series of 1,3,5-trisubstituted isocyanurates (substituents: CH2CH2OH CH2CH=CH2 and CH2CH2COOH) was synthesized according to a modified literature procedure. Experimental investigations included modification of the synthetic procedure in terms of the starting materials, solvents, temperature isolation techniques, as well as purification and identification of the products. All the synthesized isocyanurates were identified by their melting point and FTIR, 1H NMR and UV spectroscopic data. Fourier transform infrared spectrophotometry was also used to study the interaction between ammonium perchlorate, hydroxyl terminated poly(butadiene), carboxyl terminated poly(butadiene), poly(butadiene-co-acrylonitrile), poly(propylene ether) cyclotrimethylenetrinitramine and the compounds synthesized in this work which can serve as bonding agents. The results show that tris(2-hydroxyethyl)isocyanurate is a universal bonding agent for the ammonium perchlorate/carboxyl terminated poly(butadiene)/cyclotrimethylenetrinitramine composite propellant system., 1,3,5-Trisupstituisani izocijanurati (supstituenti: CH2CH2OH, CH2CH=CH2 i CH2CH2COOH) su sintetizovani koristeći modifikovane literaturne postupke. Pri tome su menjani reaktanti, rastvarači, temperatura, način izolovanja kao i način prečišćavanja proizvoda. Svi dobijeni izocijanurati su okarakterisani temperaturama topljenja, FTIR, 1H NMR i UV podacima. FTIR je takođe korišćen za proučavanje interakcija između amonijumperhlorata, poli(butadiena) sa hidroksi i karboksi krajnjim grupama, poli(butadien-ko-akrilonitrila) poli(propilenetra), ciklotrimetilennitramina i jedinjenja sintetizovanih u ovom radu koji mogu poslužiti kao vezivni agensi.", publisher = "Serbian Chemical Society, Belgrade", journal = "Journal of the Serbian Chemical Society", title = "Investigation of the interfacial bonding in composite propellants. 1,3,5-trisubstituted isocyanurates as universal bonding agents, Proučavanje međusobnih veza komponenata u kompozitnim gorivima. 1,3,5-trisupstituisani izocijanurati kao univerzalni vezivni agensi", pages = "458-445", number = "5", volume = "71", url = "https://hdl.handle.net/21.15107/rcub_technorep_997" }
Ušćumlić, G., Zreigh, M. M.,& Mijin, D.. (2006). Investigation of the interfacial bonding in composite propellants. 1,3,5-trisubstituted isocyanurates as universal bonding agents. in Journal of the Serbian Chemical Society Serbian Chemical Society, Belgrade., 71(5), 445-458. https://hdl.handle.net/21.15107/rcub_technorep_997
Ušćumlić G, Zreigh MM, Mijin D. Investigation of the interfacial bonding in composite propellants. 1,3,5-trisubstituted isocyanurates as universal bonding agents. in Journal of the Serbian Chemical Society. 2006;71(5):445-458. https://hdl.handle.net/21.15107/rcub_technorep_997 .
Ušćumlić, Gordana, Zreigh, Mohamed M., Mijin, Dušan, "Investigation of the interfacial bonding in composite propellants. 1,3,5-trisubstituted isocyanurates as universal bonding agents" in Journal of the Serbian Chemical Society, 71, no. 5 (2006):445-458, https://hdl.handle.net/21.15107/rcub_technorep_997 .