Karanović, Ljiljana

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orcid::0000-0001-9534-1315
  • Karanović, Ljiljana (29)
Projects

Author's Bibliography

Investigation of Bi2O3-rich part of Bi2O3-PbO phase diagram

Dapčević, Aleksandra; Poleti, Dejan; Karanović, Ljiljana; Miladinović, Jelena

(Srpsko hemijsko društvo, Beograd, 2017)

TY  - JOUR
AU  - Dapčević, Aleksandra
AU  - Poleti, Dejan
AU  - Karanović, Ljiljana
AU  - Miladinović, Jelena
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3642
AB  - A new Bi-rich part of Bi2O3-PbO phase diagram was determined using differential thermal analysis and X-ray powder diffraction techniques. Four solid solutions, alpha-Bi2O3, gamma-Bi2O3, d-Bi2O3 and ss(ss)-Bi8Pb5O17, can be distinguished below 37.5 mol % of PbO and one compound, ss(2)-Bi8Pb5O17. Two of them, d-Bi2O3 and ss(ss)-Bi8Pb5O17 are high-temperature phases. The large field of gamma-Bi2O3 stability was implemented making the crucial difference comparing to phase diagrams from the Bi2O3-PbO system published so far.
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - Investigation of Bi2O3-rich part of Bi2O3-PbO phase diagram
EP  - 1444
IS  - 12
SP  - 1433
VL  - 82
DO  - 10.2298/JSC170711111D
ER  - 
@article{
author = "Dapčević, Aleksandra and Poleti, Dejan and Karanović, Ljiljana and Miladinović, Jelena",
year = "2017",
abstract = "A new Bi-rich part of Bi2O3-PbO phase diagram was determined using differential thermal analysis and X-ray powder diffraction techniques. Four solid solutions, alpha-Bi2O3, gamma-Bi2O3, d-Bi2O3 and ss(ss)-Bi8Pb5O17, can be distinguished below 37.5 mol % of PbO and one compound, ss(2)-Bi8Pb5O17. Two of them, d-Bi2O3 and ss(ss)-Bi8Pb5O17 are high-temperature phases. The large field of gamma-Bi2O3 stability was implemented making the crucial difference comparing to phase diagrams from the Bi2O3-PbO system published so far.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Investigation of Bi2O3-rich part of Bi2O3-PbO phase diagram",
pages = "1444-1433",
number = "12",
volume = "82",
doi = "10.2298/JSC170711111D"
}
Dapčević, A., Poleti, D., Karanović, L.,& Miladinović, J.. (2017). Investigation of Bi2O3-rich part of Bi2O3-PbO phase diagram. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 82(12), 1433-1444.
https://doi.org/10.2298/JSC170711111D
Dapčević A, Poleti D, Karanović L, Miladinović J. Investigation of Bi2O3-rich part of Bi2O3-PbO phase diagram. in Journal of the Serbian Chemical Society. 2017;82(12):1433-1444.
doi:10.2298/JSC170711111D .
Dapčević, Aleksandra, Poleti, Dejan, Karanović, Ljiljana, Miladinović, Jelena, "Investigation of Bi2O3-rich part of Bi2O3-PbO phase diagram" in Journal of the Serbian Chemical Society, 82, no. 12 (2017):1433-1444,
https://doi.org/10.2298/JSC170711111D . .
5
2
4

Modification of mechanical and thermal properties of fly ash-based geopolymer by the incorporation of steel slag

Niklioc, I.; Marković, Smilja; Janković-Častvan, Ivona; Radmilović, Vuk; Karanović, Ljiljana; Babić, Biljana M.; Radmilović, Velimir R.

(Elsevier Science Bv, Amsterdam, 2016)

TY  - JOUR
AU  - Niklioc, I.
AU  - Marković, Smilja
AU  - Janković-Častvan, Ivona
AU  - Radmilović, Vuk
AU  - Karanović, Ljiljana
AU  - Babić, Biljana M.
AU  - Radmilović, Velimir R.
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3238
AB  - Geopolymeric binders (GB) were produced using fly ash (FA) and electric arc furnace slag (EAFS). The slag has been added in the range of 0-40%. The effects of slag content on the strength, microstructure and thermal resistance were evaluated. It was found that the amount of EAFS up to 30% positively affects the strength evolution of GB. The main reaction product of FA/EAFS blends was amorphous N-
PB  - Elsevier Science Bv, Amsterdam
T2  - Materials Letters
T1  - Modification of mechanical and thermal properties of fly ash-based geopolymer by the incorporation of steel slag
EP  - 305
SP  - 301
VL  - 176
DO  - 10.1016/j.matlet.2016.04.121
ER  - 
@article{
author = "Niklioc, I. and Marković, Smilja and Janković-Častvan, Ivona and Radmilović, Vuk and Karanović, Ljiljana and Babić, Biljana M. and Radmilović, Velimir R.",
year = "2016",
abstract = "Geopolymeric binders (GB) were produced using fly ash (FA) and electric arc furnace slag (EAFS). The slag has been added in the range of 0-40%. The effects of slag content on the strength, microstructure and thermal resistance were evaluated. It was found that the amount of EAFS up to 30% positively affects the strength evolution of GB. The main reaction product of FA/EAFS blends was amorphous N-",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Materials Letters",
title = "Modification of mechanical and thermal properties of fly ash-based geopolymer by the incorporation of steel slag",
pages = "305-301",
volume = "176",
doi = "10.1016/j.matlet.2016.04.121"
}
Niklioc, I., Marković, S., Janković-Častvan, I., Radmilović, V., Karanović, L., Babić, B. M.,& Radmilović, V. R.. (2016). Modification of mechanical and thermal properties of fly ash-based geopolymer by the incorporation of steel slag. in Materials Letters
Elsevier Science Bv, Amsterdam., 176, 301-305.
https://doi.org/10.1016/j.matlet.2016.04.121
Niklioc I, Marković S, Janković-Častvan I, Radmilović V, Karanović L, Babić BM, Radmilović VR. Modification of mechanical and thermal properties of fly ash-based geopolymer by the incorporation of steel slag. in Materials Letters. 2016;176:301-305.
doi:10.1016/j.matlet.2016.04.121 .
Niklioc, I., Marković, Smilja, Janković-Častvan, Ivona, Radmilović, Vuk, Karanović, Ljiljana, Babić, Biljana M., Radmilović, Velimir R., "Modification of mechanical and thermal properties of fly ash-based geopolymer by the incorporation of steel slag" in Materials Letters, 176 (2016):301-305,
https://doi.org/10.1016/j.matlet.2016.04.121 . .
56
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54

Kinetics of electric arc furnace slag leaching in alkaline solutions

Nikolić, Irena; Drincić, Ana; Đurović, Dijana; Karanović, Ljiljana; Radmilović, Vuk; Radmilović, Velimir R.

(Elsevier Sci Ltd, Oxford, 2016)

TY  - JOUR
AU  - Nikolić, Irena
AU  - Drincić, Ana
AU  - Đurović, Dijana
AU  - Karanović, Ljiljana
AU  - Radmilović, Vuk
AU  - Radmilović, Velimir R.
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3463
AB  - The dissolution of electric arc furnace steel slag (EAFSS) in highly alkaline MOH solution (M = alkali metal Na or K) has been investigated with emphases on the influence of the initial alkali concentration, solid to liquid (S/L) ratio and temperature on the kinetics of Si and Al dissolution from EAFSS. The shrinking core model (SCM) was used to analyze experimental data and the results have shown that the Si and Al dissolution from EAFSS was greatly influenced by MOH concentration, alkaline ion type and temperature. The dissolution process was controlled by the bulk diffusion through the product layer crystals. The activation energy for Si and Al dissolution was 55.27 kJ/mol and 48.05 kJ/mol in NaOH solution and 90.68 kJ/mol and 33.62 kJ/mol in KOH solution, respectively.
PB  - Elsevier Sci Ltd, Oxford
T2  - Construction and Building Materials
T1  - Kinetics of electric arc furnace slag leaching in alkaline solutions
EP  - 9
SP  - 1
VL  - 108
DO  - 10.1016/j.conbuildmat.2016.01.038
ER  - 
@article{
author = "Nikolić, Irena and Drincić, Ana and Đurović, Dijana and Karanović, Ljiljana and Radmilović, Vuk and Radmilović, Velimir R.",
year = "2016",
abstract = "The dissolution of electric arc furnace steel slag (EAFSS) in highly alkaline MOH solution (M = alkali metal Na or K) has been investigated with emphases on the influence of the initial alkali concentration, solid to liquid (S/L) ratio and temperature on the kinetics of Si and Al dissolution from EAFSS. The shrinking core model (SCM) was used to analyze experimental data and the results have shown that the Si and Al dissolution from EAFSS was greatly influenced by MOH concentration, alkaline ion type and temperature. The dissolution process was controlled by the bulk diffusion through the product layer crystals. The activation energy for Si and Al dissolution was 55.27 kJ/mol and 48.05 kJ/mol in NaOH solution and 90.68 kJ/mol and 33.62 kJ/mol in KOH solution, respectively.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Construction and Building Materials",
title = "Kinetics of electric arc furnace slag leaching in alkaline solutions",
pages = "9-1",
volume = "108",
doi = "10.1016/j.conbuildmat.2016.01.038"
}
Nikolić, I., Drincić, A., Đurović, D., Karanović, L., Radmilović, V.,& Radmilović, V. R.. (2016). Kinetics of electric arc furnace slag leaching in alkaline solutions. in Construction and Building Materials
Elsevier Sci Ltd, Oxford., 108, 1-9.
https://doi.org/10.1016/j.conbuildmat.2016.01.038
Nikolić I, Drincić A, Đurović D, Karanović L, Radmilović V, Radmilović VR. Kinetics of electric arc furnace slag leaching in alkaline solutions. in Construction and Building Materials. 2016;108:1-9.
doi:10.1016/j.conbuildmat.2016.01.038 .
Nikolić, Irena, Drincić, Ana, Đurović, Dijana, Karanović, Ljiljana, Radmilović, Vuk, Radmilović, Velimir R., "Kinetics of electric arc furnace slag leaching in alkaline solutions" in Construction and Building Materials, 108 (2016):1-9,
https://doi.org/10.1016/j.conbuildmat.2016.01.038 . .
40
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41

Thermal Resistance of Alkali Activated Binders Synthesized Using the Fly Ash and Steel Slag

Nikolić, Irena; Marković, Smilja; Karanović, Ljiljana; Radmilović, Vuk; Radmilović, Velimir R.

(Belgrade : Materials Research Society of Serbia, 2015)

TY  - CONF
AU  - Nikolić, Irena
AU  - Marković, Smilja
AU  - Karanović, Ljiljana
AU  - Radmilović, Vuk
AU  - Radmilović, Velimir R.
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2882
AB  - The thermal resistance of alkali-activated binders based on fly ash (FA), electric arc furnace slag (EAFS) and their FA/EAFS blends was assessed. Compressive strengths of samples before and after firing were measured. The samples were characterized by X-ray powder diffraction (XRPD), scanning electron microscopy (SEM), energydispersive X-ray spectra (EDS), thermal (TG/DTA) analysis. Besides, the sintering shrinkage were recorded by thermomechanical analyzer (TMA) during non-isothermal sintering up to 900 ºC with heating rate of 15 º/min, in an air atmosphere. The main reaction products in FA and EAFS based alkali activated binders are the sodiumalumino-silicate-hydrate (N–A–S–H) and calcium-alumino-silicate-hydrate (C-A-S-H) type gels, respectively. FA/EAFS based binders are characterized by the presence of N-A-S-H gel with the high content of Ca. The EAFS based binders exhibited superior performances in terms of compressive strength than FA based binders. Thermal resistance of FA based binders was improved by the slag addition. This research was supported by a Ministry of Science of Montenegro under the contract No. 01-460.
PB  - Belgrade : Materials Research Society of Serbia
C3  - Programme and The Book of Abstracts / Seventeenth Annual Conference YUCOMAT 205, Herceg Novi, August
T1  - Thermal Resistance of Alkali Activated Binders Synthesized Using the Fly Ash and Steel Slag
EP  - 24
SP  - 24
UR  - https://hdl.handle.net/21.15107/rcub_technorep_2882
ER  - 
@conference{
author = "Nikolić, Irena and Marković, Smilja and Karanović, Ljiljana and Radmilović, Vuk and Radmilović, Velimir R.",
year = "2015",
abstract = "The thermal resistance of alkali-activated binders based on fly ash (FA), electric arc furnace slag (EAFS) and their FA/EAFS blends was assessed. Compressive strengths of samples before and after firing were measured. The samples were characterized by X-ray powder diffraction (XRPD), scanning electron microscopy (SEM), energydispersive X-ray spectra (EDS), thermal (TG/DTA) analysis. Besides, the sintering shrinkage were recorded by thermomechanical analyzer (TMA) during non-isothermal sintering up to 900 ºC with heating rate of 15 º/min, in an air atmosphere. The main reaction products in FA and EAFS based alkali activated binders are the sodiumalumino-silicate-hydrate (N–A–S–H) and calcium-alumino-silicate-hydrate (C-A-S-H) type gels, respectively. FA/EAFS based binders are characterized by the presence of N-A-S-H gel with the high content of Ca. The EAFS based binders exhibited superior performances in terms of compressive strength than FA based binders. Thermal resistance of FA based binders was improved by the slag addition. This research was supported by a Ministry of Science of Montenegro under the contract No. 01-460.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Programme and The Book of Abstracts / Seventeenth Annual Conference YUCOMAT 205, Herceg Novi, August",
title = "Thermal Resistance of Alkali Activated Binders Synthesized Using the Fly Ash and Steel Slag",
pages = "24-24",
url = "https://hdl.handle.net/21.15107/rcub_technorep_2882"
}
Nikolić, I., Marković, S., Karanović, L., Radmilović, V.,& Radmilović, V. R.. (2015). Thermal Resistance of Alkali Activated Binders Synthesized Using the Fly Ash and Steel Slag. in Programme and The Book of Abstracts / Seventeenth Annual Conference YUCOMAT 205, Herceg Novi, August
Belgrade : Materials Research Society of Serbia., 24-24.
https://hdl.handle.net/21.15107/rcub_technorep_2882
Nikolić I, Marković S, Karanović L, Radmilović V, Radmilović VR. Thermal Resistance of Alkali Activated Binders Synthesized Using the Fly Ash and Steel Slag. in Programme and The Book of Abstracts / Seventeenth Annual Conference YUCOMAT 205, Herceg Novi, August. 2015;:24-24.
https://hdl.handle.net/21.15107/rcub_technorep_2882 .
Nikolić, Irena, Marković, Smilja, Karanović, Ljiljana, Radmilović, Vuk, Radmilović, Velimir R., "Thermal Resistance of Alkali Activated Binders Synthesized Using the Fly Ash and Steel Slag" in Programme and The Book of Abstracts / Seventeenth Annual Conference YUCOMAT 205, Herceg Novi, August (2015):24-24,
https://hdl.handle.net/21.15107/rcub_technorep_2882 .

Improved compressive strength of alkali activated slag upon heating

Nikolić, Irena; Karanović, Ljiljana; Janković-Častvan, Ivona; Radmilović, Vuk; Mentus, Slavko; Radmilović, Velimir R.

(Elsevier Science Bv, Amsterdam, 2014)

TY  - JOUR
AU  - Nikolić, Irena
AU  - Karanović, Ljiljana
AU  - Janković-Častvan, Ivona
AU  - Radmilović, Vuk
AU  - Mentus, Slavko
AU  - Radmilović, Velimir R.
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2661
AB  - This paper presents a study on thermal stability of alkali activated slag (AAS) prepared from electric arc furnace slag (EAFS) using a mixture of alkaline sodium hydroxide and sodium silicate solutions. The samples were investigated by means of XRD, SEM, TG/DTA and porosity analysis. Compressive strengths of MS samples before and after exposure to elevated temperatures ranging from 600 degrees C to 1000 degrees C were determined. The significant microstructural modifications highlighted by changes in porosity due to the sintering process are responsible for the strengthening of MS sample after heating at 600,800 and 1000 degrees C. Moreover, in MS sample after heating to and above 600 degrees C wustite transforms to spinel.
PB  - Elsevier Science Bv, Amsterdam
T2  - Materials Letters
T1  - Improved compressive strength of alkali activated slag upon heating
EP  - 254
SP  - 251
VL  - 133
DO  - 10.1016/j.matlet.2014.07.021
ER  - 
@article{
author = "Nikolić, Irena and Karanović, Ljiljana and Janković-Častvan, Ivona and Radmilović, Vuk and Mentus, Slavko and Radmilović, Velimir R.",
year = "2014",
abstract = "This paper presents a study on thermal stability of alkali activated slag (AAS) prepared from electric arc furnace slag (EAFS) using a mixture of alkaline sodium hydroxide and sodium silicate solutions. The samples were investigated by means of XRD, SEM, TG/DTA and porosity analysis. Compressive strengths of MS samples before and after exposure to elevated temperatures ranging from 600 degrees C to 1000 degrees C were determined. The significant microstructural modifications highlighted by changes in porosity due to the sintering process are responsible for the strengthening of MS sample after heating at 600,800 and 1000 degrees C. Moreover, in MS sample after heating to and above 600 degrees C wustite transforms to spinel.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Materials Letters",
title = "Improved compressive strength of alkali activated slag upon heating",
pages = "254-251",
volume = "133",
doi = "10.1016/j.matlet.2014.07.021"
}
Nikolić, I., Karanović, L., Janković-Častvan, I., Radmilović, V., Mentus, S.,& Radmilović, V. R.. (2014). Improved compressive strength of alkali activated slag upon heating. in Materials Letters
Elsevier Science Bv, Amsterdam., 133, 251-254.
https://doi.org/10.1016/j.matlet.2014.07.021
Nikolić I, Karanović L, Janković-Častvan I, Radmilović V, Mentus S, Radmilović VR. Improved compressive strength of alkali activated slag upon heating. in Materials Letters. 2014;133:251-254.
doi:10.1016/j.matlet.2014.07.021 .
Nikolić, Irena, Karanović, Ljiljana, Janković-Častvan, Ivona, Radmilović, Vuk, Mentus, Slavko, Radmilović, Velimir R., "Improved compressive strength of alkali activated slag upon heating" in Materials Letters, 133 (2014):251-254,
https://doi.org/10.1016/j.matlet.2014.07.021 . .
17
12
19

Geopolymer materials based on the electric arc furnace slag

Nikolić, Irena; Janković-Častvan, Ivona; Radmilović, Vuk; Karanović, Ljiljana; Marković, Smilja; Mentus, Slavko; Radmilović, Velimir R.

(Belgrade : Materials Research Society of Serbia, 2013)

TY  - CONF
AU  - Nikolić, Irena
AU  - Janković-Častvan, Ivona
AU  - Radmilović, Vuk
AU  - Karanović, Ljiljana
AU  - Marković, Smilja
AU  - Mentus, Slavko
AU  - Radmilović, Velimir R.
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2289
AB  - The remelting of iron and steel scrap in the electric arc furnaces generates the non-hazardous waste – electric arc furnace slag (EAFS), which can be disposed of to appropriate landfills. Currently, this slag found its application in conventional concrete production to improve its mechanical, chemical and physical properties, as an additive to asphalt base mixture and in cement production. In this study we have investigated the effect of alkaline dosage on the strength and thermal resistance of EAFS based geopolymers. The results have shown that these materials are mainly amorphous with some crystal phases remained from the undisolved EAFS such as larnite, gehlenite, wuestite, monticellite, calcite. Compressive strength of these materials is strongly influenced by the alkaline dosage. An increase of NaOH concentration in the interval of 7-10 M leads to the increase of geopolymer’s strength. The maximal compressive strength of EAFS based geopolymer was obtained using the 10 M NaOH. Further increase of alkaline dosage to the value of 13 M NaOH results in the slight decrease of the geopolymer strength. Additionally, depending on the synthesis parameters, EAFS based geopolymers exhibit improved durability in high temperature environments in comparison with conventional cement based materials. All investigated samples exhibit a shrinkage which is attributed to the change of porosity. The mass loss due to the loss of water was also observed. This research was supported by a Ministry of Science of Montenegro under the contract No 01-460.
PB  - Belgrade : Materials Research Society of Serbia
C3  - The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts
T1  - Geopolymer materials based on the electric arc furnace slag
EP  - 47
SP  - 47
UR  - https://hdl.handle.net/21.15107/rcub_technorep_2289
ER  - 
@conference{
author = "Nikolić, Irena and Janković-Častvan, Ivona and Radmilović, Vuk and Karanović, Ljiljana and Marković, Smilja and Mentus, Slavko and Radmilović, Velimir R.",
year = "2013",
abstract = "The remelting of iron and steel scrap in the electric arc furnaces generates the non-hazardous waste – electric arc furnace slag (EAFS), which can be disposed of to appropriate landfills. Currently, this slag found its application in conventional concrete production to improve its mechanical, chemical and physical properties, as an additive to asphalt base mixture and in cement production. In this study we have investigated the effect of alkaline dosage on the strength and thermal resistance of EAFS based geopolymers. The results have shown that these materials are mainly amorphous with some crystal phases remained from the undisolved EAFS such as larnite, gehlenite, wuestite, monticellite, calcite. Compressive strength of these materials is strongly influenced by the alkaline dosage. An increase of NaOH concentration in the interval of 7-10 M leads to the increase of geopolymer’s strength. The maximal compressive strength of EAFS based geopolymer was obtained using the 10 M NaOH. Further increase of alkaline dosage to the value of 13 M NaOH results in the slight decrease of the geopolymer strength. Additionally, depending on the synthesis parameters, EAFS based geopolymers exhibit improved durability in high temperature environments in comparison with conventional cement based materials. All investigated samples exhibit a shrinkage which is attributed to the change of porosity. The mass loss due to the loss of water was also observed. This research was supported by a Ministry of Science of Montenegro under the contract No 01-460.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts",
title = "Geopolymer materials based on the electric arc furnace slag",
pages = "47-47",
url = "https://hdl.handle.net/21.15107/rcub_technorep_2289"
}
Nikolić, I., Janković-Častvan, I., Radmilović, V., Karanović, L., Marković, S., Mentus, S.,& Radmilović, V. R.. (2013). Geopolymer materials based on the electric arc furnace slag. in The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts
Belgrade : Materials Research Society of Serbia., 47-47.
https://hdl.handle.net/21.15107/rcub_technorep_2289
Nikolić I, Janković-Častvan I, Radmilović V, Karanović L, Marković S, Mentus S, Radmilović VR. Geopolymer materials based on the electric arc furnace slag. in The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts. 2013;:47-47.
https://hdl.handle.net/21.15107/rcub_technorep_2289 .
Nikolić, Irena, Janković-Častvan, Ivona, Radmilović, Vuk, Karanović, Ljiljana, Marković, Smilja, Mentus, Slavko, Radmilović, Velimir R., "Geopolymer materials based on the electric arc furnace slag" in The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts (2013):47-47,
https://hdl.handle.net/21.15107/rcub_technorep_2289 .

Coexistence of several sillenite-like phases in pseudo-binary and pseudo-ternary systems based on Bi2O3

Dapčević, Aleksandra; Poleti, Dejan; Karanović, Ljiljana; Rogan, Jelena; Dražić, Goran

(Elsevier, Amsterdam, 2013)

TY  - JOUR
AU  - Dapčević, Aleksandra
AU  - Poleti, Dejan
AU  - Karanović, Ljiljana
AU  - Rogan, Jelena
AU  - Dražić, Goran
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2441
AB  - A series of polycrystalline samples containing sillenite-like (doped gamma-Bi2O3) phases were prepared by high-temperature reactions from alpha-Bi2O3 powder and different oxides in six pseudo-binary Bi2O3-MxOy (M = Mn, Ti, V) and six pseudo-ternary Bi2O3-M1(x)O(y)-M2(x)O(y) (M1 = Pb, Zn, Ti and M2 = Zn, Ti, Si) systems. The products were characterized by XRD, SEM/EDX, HRTEM, SAED and DTA techniques. It is shown that for pseudo-binary systems, the phase composition of specimens depends on dopant content, while, for pseudo-ternary systems, depends on dopants radii, as well. In pseudo-binary systems, singlephase sillenites are obtained if the dopant content is in accordance with formula Bi12M4+O20, for M = Mn and Ti, and Bi-12(M-0.8(5+))O-20, for M = V. However, two coexisting sillenite-like phases, doped compound and nominally undoped solid solution, are found if a half of that dopant quantity is applied. In pseudoternary systems, the phase-pure double-doped sillenite specimens are identified if ionic radii of dopants differ less than 40%. Otherwise, two coexisting sillenites were obtained. The possibility to prepare the undoped gamma-Bi2O3 phase was also discussed.
PB  - Elsevier, Amsterdam
T2  - Solid State Sciences
T1  - Coexistence of several sillenite-like phases in pseudo-binary and pseudo-ternary systems based on Bi2O3
EP  - 102
SP  - 93
VL  - 25
DO  - 10.1016/j.solidstatesciences.2013.08.010
ER  - 
@article{
author = "Dapčević, Aleksandra and Poleti, Dejan and Karanović, Ljiljana and Rogan, Jelena and Dražić, Goran",
year = "2013",
abstract = "A series of polycrystalline samples containing sillenite-like (doped gamma-Bi2O3) phases were prepared by high-temperature reactions from alpha-Bi2O3 powder and different oxides in six pseudo-binary Bi2O3-MxOy (M = Mn, Ti, V) and six pseudo-ternary Bi2O3-M1(x)O(y)-M2(x)O(y) (M1 = Pb, Zn, Ti and M2 = Zn, Ti, Si) systems. The products were characterized by XRD, SEM/EDX, HRTEM, SAED and DTA techniques. It is shown that for pseudo-binary systems, the phase composition of specimens depends on dopant content, while, for pseudo-ternary systems, depends on dopants radii, as well. In pseudo-binary systems, singlephase sillenites are obtained if the dopant content is in accordance with formula Bi12M4+O20, for M = Mn and Ti, and Bi-12(M-0.8(5+))O-20, for M = V. However, two coexisting sillenite-like phases, doped compound and nominally undoped solid solution, are found if a half of that dopant quantity is applied. In pseudoternary systems, the phase-pure double-doped sillenite specimens are identified if ionic radii of dopants differ less than 40%. Otherwise, two coexisting sillenites were obtained. The possibility to prepare the undoped gamma-Bi2O3 phase was also discussed.",
publisher = "Elsevier, Amsterdam",
journal = "Solid State Sciences",
title = "Coexistence of several sillenite-like phases in pseudo-binary and pseudo-ternary systems based on Bi2O3",
pages = "102-93",
volume = "25",
doi = "10.1016/j.solidstatesciences.2013.08.010"
}
Dapčević, A., Poleti, D., Karanović, L., Rogan, J.,& Dražić, G.. (2013). Coexistence of several sillenite-like phases in pseudo-binary and pseudo-ternary systems based on Bi2O3. in Solid State Sciences
Elsevier, Amsterdam., 25, 93-102.
https://doi.org/10.1016/j.solidstatesciences.2013.08.010
Dapčević A, Poleti D, Karanović L, Rogan J, Dražić G. Coexistence of several sillenite-like phases in pseudo-binary and pseudo-ternary systems based on Bi2O3. in Solid State Sciences. 2013;25:93-102.
doi:10.1016/j.solidstatesciences.2013.08.010 .
Dapčević, Aleksandra, Poleti, Dejan, Karanović, Ljiljana, Rogan, Jelena, Dražić, Goran, "Coexistence of several sillenite-like phases in pseudo-binary and pseudo-ternary systems based on Bi2O3" in Solid State Sciences, 25 (2013):93-102,
https://doi.org/10.1016/j.solidstatesciences.2013.08.010 . .
4
5
5

Influence of Alkali Cation on the Mechanical Properties and Durability of Fly Ash Based Geopolymers

Nikolić, Irena; Zejak, Radomir; Janković-Častvan, Ivona; Karanović, Ljiljana; Radmilović, Vuk; Radmilović, Velimir R.

(Slovenian Chemical Society, 2013)

TY  - JOUR
AU  - Nikolić, Irena
AU  - Zejak, Radomir
AU  - Janković-Častvan, Ivona
AU  - Karanović, Ljiljana
AU  - Radmilović, Vuk
AU  - Radmilović, Velimir R.
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2273
AB  - This research has provided information about the influence of alkali cations (Na+ and K+) on the mechanical properties and durability of fly ash based geopolymers. The results have shown that alkali cations have a strong influence on the mechanical properties of fly ash based geopolymers. K-geopolymers generally reach a higher value of compressive strength in comparison to Na- geopolymers. On the other hand, microstructure and phase composition of fly ash based geopolymers are not influenced by the nature of alkali cations. The ratio of main gel structure forming elements is practically not affected by the nature of alkali cations. Durability of fly ash based geopolymers in different aquatic environments is greatly dependent on the choice of alkali cations. Na-geopolymers are generally more resistant in water and aggressive environments than the K-geopolymers. The best durability of fly ash based geopolymers was observed in sea water.
PB  - Slovenian Chemical Society
T2  - Acta Chimica Slovenica
T1  - Influence of Alkali Cation on the Mechanical Properties and Durability of Fly Ash Based Geopolymers
EP  - 643
IS  - 3
SP  - 636
VL  - 60
UR  - https://hdl.handle.net/21.15107/rcub_technorep_2273
ER  - 
@article{
author = "Nikolić, Irena and Zejak, Radomir and Janković-Častvan, Ivona and Karanović, Ljiljana and Radmilović, Vuk and Radmilović, Velimir R.",
year = "2013",
abstract = "This research has provided information about the influence of alkali cations (Na+ and K+) on the mechanical properties and durability of fly ash based geopolymers. The results have shown that alkali cations have a strong influence on the mechanical properties of fly ash based geopolymers. K-geopolymers generally reach a higher value of compressive strength in comparison to Na- geopolymers. On the other hand, microstructure and phase composition of fly ash based geopolymers are not influenced by the nature of alkali cations. The ratio of main gel structure forming elements is practically not affected by the nature of alkali cations. Durability of fly ash based geopolymers in different aquatic environments is greatly dependent on the choice of alkali cations. Na-geopolymers are generally more resistant in water and aggressive environments than the K-geopolymers. The best durability of fly ash based geopolymers was observed in sea water.",
publisher = "Slovenian Chemical Society",
journal = "Acta Chimica Slovenica",
title = "Influence of Alkali Cation on the Mechanical Properties and Durability of Fly Ash Based Geopolymers",
pages = "643-636",
number = "3",
volume = "60",
url = "https://hdl.handle.net/21.15107/rcub_technorep_2273"
}
Nikolić, I., Zejak, R., Janković-Častvan, I., Karanović, L., Radmilović, V.,& Radmilović, V. R.. (2013). Influence of Alkali Cation on the Mechanical Properties and Durability of Fly Ash Based Geopolymers. in Acta Chimica Slovenica
Slovenian Chemical Society., 60(3), 636-643.
https://hdl.handle.net/21.15107/rcub_technorep_2273
Nikolić I, Zejak R, Janković-Častvan I, Karanović L, Radmilović V, Radmilović VR. Influence of Alkali Cation on the Mechanical Properties and Durability of Fly Ash Based Geopolymers. in Acta Chimica Slovenica. 2013;60(3):636-643.
https://hdl.handle.net/21.15107/rcub_technorep_2273 .
Nikolić, Irena, Zejak, Radomir, Janković-Častvan, Ivona, Karanović, Ljiljana, Radmilović, Vuk, Radmilović, Velimir R., "Influence of Alkali Cation on the Mechanical Properties and Durability of Fly Ash Based Geopolymers" in Acta Chimica Slovenica, 60, no. 3 (2013):636-643,
https://hdl.handle.net/21.15107/rcub_technorep_2273 .
4
6

Improved structural model of Pb-doped gamma-Bi2O3: (Bi23.68Pb0.32)(Bi1.28Pb0.72)O-38.48

Dapčević, Aleksandra; Poleti, Dejan; Karanović, Ljiljana

(J C P D S-Int Centre Diffraction Data, Newtown Sq, 2012)

TY  - JOUR
AU  - Dapčević, Aleksandra
AU  - Poleti, Dejan
AU  - Karanović, Ljiljana
PY  - 2012
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2159
AB  - A polycrystalline single-phase sample with nominal composition Bi24PbO37 was synthesized from Bi2O3 and PbO by a high-temperature solid state reaction at 690 degrees C for 1.5 h. The compound adopts Bi12SiO20-type structure [cubic, space group I23 (No. 197); a = 10.24957(3) angstrom] and was refined to R-p = 7.96%, R-wp = 10.4%, R-exp = 8.43%, R-B = 3.06%, and S = 1.23. The distributions of Pb2+ and Bi3+ over cationic sites based on the X-ray powder diffraction data were determined using a combination of the Rietveld refinement and bond valence calculations. The results showed that the asymmetric unit contains two mixed cation sites: the fully occupied 24f site and the partly occupied 8c site, with the unit-cell content (Bi23.68Pb0.32)(Bi1.28Pb0.72)O-38.48. The structural constraints favor a preference of Pb2+ ion for the 8c site, i.e. only 1.3% of Bi3+ is substituted by Pb2+ at the 24f site and 36% at the 8c site. At the 24f site, the cations are surrounded by 5 + 2 or in a very small amount by 5 + 1 + 2 oxide ions, forming a base bicapped square pyramid or a bicapped highly deformed octahedron, respectively. At the 8c site, the cations with three oxide ions form a trigonal pyramid with the cations at the apex.
PB  - J C P D S-Int Centre Diffraction Data, Newtown Sq
T2  - Powder Diffraction
T1  - Improved structural model of Pb-doped gamma-Bi2O3: (Bi23.68Pb0.32)(Bi1.28Pb0.72)O-38.48
EP  - 7
IS  - 1
SP  - 2
VL  - 27
DO  - 10.1017/S0885715612000073
ER  - 
@article{
author = "Dapčević, Aleksandra and Poleti, Dejan and Karanović, Ljiljana",
year = "2012",
abstract = "A polycrystalline single-phase sample with nominal composition Bi24PbO37 was synthesized from Bi2O3 and PbO by a high-temperature solid state reaction at 690 degrees C for 1.5 h. The compound adopts Bi12SiO20-type structure [cubic, space group I23 (No. 197); a = 10.24957(3) angstrom] and was refined to R-p = 7.96%, R-wp = 10.4%, R-exp = 8.43%, R-B = 3.06%, and S = 1.23. The distributions of Pb2+ and Bi3+ over cationic sites based on the X-ray powder diffraction data were determined using a combination of the Rietveld refinement and bond valence calculations. The results showed that the asymmetric unit contains two mixed cation sites: the fully occupied 24f site and the partly occupied 8c site, with the unit-cell content (Bi23.68Pb0.32)(Bi1.28Pb0.72)O-38.48. The structural constraints favor a preference of Pb2+ ion for the 8c site, i.e. only 1.3% of Bi3+ is substituted by Pb2+ at the 24f site and 36% at the 8c site. At the 24f site, the cations are surrounded by 5 + 2 or in a very small amount by 5 + 1 + 2 oxide ions, forming a base bicapped square pyramid or a bicapped highly deformed octahedron, respectively. At the 8c site, the cations with three oxide ions form a trigonal pyramid with the cations at the apex.",
publisher = "J C P D S-Int Centre Diffraction Data, Newtown Sq",
journal = "Powder Diffraction",
title = "Improved structural model of Pb-doped gamma-Bi2O3: (Bi23.68Pb0.32)(Bi1.28Pb0.72)O-38.48",
pages = "7-2",
number = "1",
volume = "27",
doi = "10.1017/S0885715612000073"
}
Dapčević, A., Poleti, D.,& Karanović, L.. (2012). Improved structural model of Pb-doped gamma-Bi2O3: (Bi23.68Pb0.32)(Bi1.28Pb0.72)O-38.48. in Powder Diffraction
J C P D S-Int Centre Diffraction Data, Newtown Sq., 27(1), 2-7.
https://doi.org/10.1017/S0885715612000073
Dapčević A, Poleti D, Karanović L. Improved structural model of Pb-doped gamma-Bi2O3: (Bi23.68Pb0.32)(Bi1.28Pb0.72)O-38.48. in Powder Diffraction. 2012;27(1):2-7.
doi:10.1017/S0885715612000073 .
Dapčević, Aleksandra, Poleti, Dejan, Karanović, Ljiljana, "Improved structural model of Pb-doped gamma-Bi2O3: (Bi23.68Pb0.32)(Bi1.28Pb0.72)O-38.48" in Powder Diffraction, 27, no. 1 (2012):2-7,
https://doi.org/10.1017/S0885715612000073 . .
3
4
4

Synthesis, magnetic, thermal and structural properties of Co(II), Ni(II) and Cu(II) complexes containing isophthalato ligands

Rogan, Jelena; Poleti, Dejan; Karanović, Ljiljana; Jaglicić, Zvonko

(Elsevier, Amsterdam, 2011)

TY  - JOUR
AU  - Rogan, Jelena
AU  - Poleti, Dejan
AU  - Karanović, Ljiljana
AU  - Jaglicić, Zvonko
PY  - 2011
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1922
AB  - A series of novel ternary Co(II), Ni(II) and Cu(II) complexes containing 2,2'-dipyridylamine (dipya), 2,2'-bipyridine (bipy), and 1,10-phenanthroline (phen), as aromatic diamine ligands, and dianion of isophthalic acid (ipht) have been prepared by ligand exchange reactions from diluted H2O/EtOH solutions. The complexes were characterized by elemental analysis, IR spectroscopy, magnetic susceptibility measurements and TG and DSC analysis. Three complexes, Cu(dipya)(ipht)center dot H2O (1), Co(dipya)(ipht)center dot 2H(2)O (2) and Cu(ipht)(phen)center dot 2H(2)O (5) are polymeric with bis-monodentate ipht, while the other two complexes M(bipy)(iPht)center dot 4H(2)O, M=Co(II) (3) and Ni(II) (4), contain ipht as a counter ion. All Co(II) and Ni(II) complexes are (pseudo)octahedral, while Cu(II) complexes have square-pyramidal or distorted octahedral geometry. The variable temperature magnetic susceptibility measurements showed very weak antiferromagnetic behaviour for all complexes. Dehydration processes, decomposition mechanisms and thermal stability of 1-5 are assumed. One complex from the above series, [Ni(bipy)(H2O)(4)](iPht) (4), and one additional complex, [Co(bipy)(iPht)](n) (6), are obtained as single-crystals and their structures are determined from X-ray diffraction data. In both structures M(II) centers are in deformed octahedral environment and they are linked by hemi-ipht ligands (4) and two different bridging ipht ligands (6). Three-dimensional networks in 4 and 6 are governed by strong noncovalent interactions. The cations and ipht anions in 4 are connected by hydrogen bonds building double layers parallel to ab-plane that are further packed by pi-pi interactions. In 6 double chains extending along b-axis are strengthened by interchain pi-pi interactions constructing a three-dimensional framework.
PB  - Elsevier, Amsterdam
T2  - Journal of Molecular Structure
T1  - Synthesis, magnetic, thermal and structural properties of Co(II), Ni(II) and Cu(II) complexes containing isophthalato ligands
EP  - 379
IS  - 2-3
SP  - 371
VL  - 985
DO  - 10.1016/j.molstruc.2010.11.024
ER  - 
@article{
author = "Rogan, Jelena and Poleti, Dejan and Karanović, Ljiljana and Jaglicić, Zvonko",
year = "2011",
abstract = "A series of novel ternary Co(II), Ni(II) and Cu(II) complexes containing 2,2'-dipyridylamine (dipya), 2,2'-bipyridine (bipy), and 1,10-phenanthroline (phen), as aromatic diamine ligands, and dianion of isophthalic acid (ipht) have been prepared by ligand exchange reactions from diluted H2O/EtOH solutions. The complexes were characterized by elemental analysis, IR spectroscopy, magnetic susceptibility measurements and TG and DSC analysis. Three complexes, Cu(dipya)(ipht)center dot H2O (1), Co(dipya)(ipht)center dot 2H(2)O (2) and Cu(ipht)(phen)center dot 2H(2)O (5) are polymeric with bis-monodentate ipht, while the other two complexes M(bipy)(iPht)center dot 4H(2)O, M=Co(II) (3) and Ni(II) (4), contain ipht as a counter ion. All Co(II) and Ni(II) complexes are (pseudo)octahedral, while Cu(II) complexes have square-pyramidal or distorted octahedral geometry. The variable temperature magnetic susceptibility measurements showed very weak antiferromagnetic behaviour for all complexes. Dehydration processes, decomposition mechanisms and thermal stability of 1-5 are assumed. One complex from the above series, [Ni(bipy)(H2O)(4)](iPht) (4), and one additional complex, [Co(bipy)(iPht)](n) (6), are obtained as single-crystals and their structures are determined from X-ray diffraction data. In both structures M(II) centers are in deformed octahedral environment and they are linked by hemi-ipht ligands (4) and two different bridging ipht ligands (6). Three-dimensional networks in 4 and 6 are governed by strong noncovalent interactions. The cations and ipht anions in 4 are connected by hydrogen bonds building double layers parallel to ab-plane that are further packed by pi-pi interactions. In 6 double chains extending along b-axis are strengthened by interchain pi-pi interactions constructing a three-dimensional framework.",
publisher = "Elsevier, Amsterdam",
journal = "Journal of Molecular Structure",
title = "Synthesis, magnetic, thermal and structural properties of Co(II), Ni(II) and Cu(II) complexes containing isophthalato ligands",
pages = "379-371",
number = "2-3",
volume = "985",
doi = "10.1016/j.molstruc.2010.11.024"
}
Rogan, J., Poleti, D., Karanović, L.,& Jaglicić, Z.. (2011). Synthesis, magnetic, thermal and structural properties of Co(II), Ni(II) and Cu(II) complexes containing isophthalato ligands. in Journal of Molecular Structure
Elsevier, Amsterdam., 985(2-3), 371-379.
https://doi.org/10.1016/j.molstruc.2010.11.024
Rogan J, Poleti D, Karanović L, Jaglicić Z. Synthesis, magnetic, thermal and structural properties of Co(II), Ni(II) and Cu(II) complexes containing isophthalato ligands. in Journal of Molecular Structure. 2011;985(2-3):371-379.
doi:10.1016/j.molstruc.2010.11.024 .
Rogan, Jelena, Poleti, Dejan, Karanović, Ljiljana, Jaglicić, Zvonko, "Synthesis, magnetic, thermal and structural properties of Co(II), Ni(II) and Cu(II) complexes containing isophthalato ligands" in Journal of Molecular Structure, 985, no. 2-3 (2011):371-379,
https://doi.org/10.1016/j.molstruc.2010.11.024 . .
9
13
13

catena-Poly[[[(di-2-pyridylamine-kappa N-2(2),N-2 ')copper(II)]-mu-benzene-1,3-dicarboxylato-kappa O-3(1),O-1 ':O-3] monohydrate], a zigzag coordination polymer with strong pi-pi interactions

Rogan, Jelena; Poleti, Dejan; Karanović, Ljiljana

(Wiley-Blackwell, Hoboken, 2011)

TY  - JOUR
AU  - Rogan, Jelena
AU  - Poleti, Dejan
AU  - Karanović, Ljiljana
PY  - 2011
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1914
AB  - The novel title coordination polymer, {[Cu(C8H4O4)-(C10H9N3)]center dot H2O}(n), synthesized by the slow-diffusion method, takes the form of one-dimensional zigzag chains built up of Cu-II cations linked by benzene-1,3-dicarboxylate (ipht) anions. An exceptional characteristic of this structure is that it belongs to a small group of metal-organic polymers where ipht is coordinated as a bridging tridentate ligand with monodentate and chelate coordination of individual carboxylate groups. The Cu-II cation has a highly distorted square-pyramidal geometry formed by three O atoms from two ipht anions and two N atoms from a di-2-pyridylamine (dipya) ligand. The zigzag chains, which run along the b axis, further construct a three-dimensional metal-organic framework via strong face-to-face pi-pi interactions and hydrogen bonds. A solvent water molecule is linked to the different carboxylate groups via hydrogen bonds. Thermogravimetric and differential scanning calorimetric analyses confirm the strong hydrogen bonding.
PB  - Wiley-Blackwell, Hoboken
T2  - Acta Crystallographica Section C-Crystal Structure Communications
T1  - catena-Poly[[[(di-2-pyridylamine-kappa N-2(2),N-2 ')copper(II)]-mu-benzene-1,3-dicarboxylato-kappa O-3(1),O-1 ':O-3] monohydrate], a zigzag coordination polymer with strong pi-pi interactions
EP  - M233
SP  - M230
VL  - 67
DO  - 10.1107/S0108270111022451
ER  - 
@article{
author = "Rogan, Jelena and Poleti, Dejan and Karanović, Ljiljana",
year = "2011",
abstract = "The novel title coordination polymer, {[Cu(C8H4O4)-(C10H9N3)]center dot H2O}(n), synthesized by the slow-diffusion method, takes the form of one-dimensional zigzag chains built up of Cu-II cations linked by benzene-1,3-dicarboxylate (ipht) anions. An exceptional characteristic of this structure is that it belongs to a small group of metal-organic polymers where ipht is coordinated as a bridging tridentate ligand with monodentate and chelate coordination of individual carboxylate groups. The Cu-II cation has a highly distorted square-pyramidal geometry formed by three O atoms from two ipht anions and two N atoms from a di-2-pyridylamine (dipya) ligand. The zigzag chains, which run along the b axis, further construct a three-dimensional metal-organic framework via strong face-to-face pi-pi interactions and hydrogen bonds. A solvent water molecule is linked to the different carboxylate groups via hydrogen bonds. Thermogravimetric and differential scanning calorimetric analyses confirm the strong hydrogen bonding.",
publisher = "Wiley-Blackwell, Hoboken",
journal = "Acta Crystallographica Section C-Crystal Structure Communications",
title = "catena-Poly[[[(di-2-pyridylamine-kappa N-2(2),N-2 ')copper(II)]-mu-benzene-1,3-dicarboxylato-kappa O-3(1),O-1 ':O-3] monohydrate], a zigzag coordination polymer with strong pi-pi interactions",
pages = "M233-M230",
volume = "67",
doi = "10.1107/S0108270111022451"
}
Rogan, J., Poleti, D.,& Karanović, L.. (2011). catena-Poly[[[(di-2-pyridylamine-kappa N-2(2),N-2 ')copper(II)]-mu-benzene-1,3-dicarboxylato-kappa O-3(1),O-1 ':O-3] monohydrate], a zigzag coordination polymer with strong pi-pi interactions. in Acta Crystallographica Section C-Crystal Structure Communications
Wiley-Blackwell, Hoboken., 67, M230-M233.
https://doi.org/10.1107/S0108270111022451
Rogan J, Poleti D, Karanović L. catena-Poly[[[(di-2-pyridylamine-kappa N-2(2),N-2 ')copper(II)]-mu-benzene-1,3-dicarboxylato-kappa O-3(1),O-1 ':O-3] monohydrate], a zigzag coordination polymer with strong pi-pi interactions. in Acta Crystallographica Section C-Crystal Structure Communications. 2011;67:M230-M233.
doi:10.1107/S0108270111022451 .
Rogan, Jelena, Poleti, Dejan, Karanović, Ljiljana, "catena-Poly[[[(di-2-pyridylamine-kappa N-2(2),N-2 ')copper(II)]-mu-benzene-1,3-dicarboxylato-kappa O-3(1),O-1 ':O-3] monohydrate], a zigzag coordination polymer with strong pi-pi interactions" in Acta Crystallographica Section C-Crystal Structure Communications, 67 (2011):M230-M233,
https://doi.org/10.1107/S0108270111022451 . .
2
6
5

Mechanochemical synthesis and electrical conductivity of nanocrystalline δ-Bi2O3 stabilized by HfO2 and ZrO2

Zdujić, Miodrag; Poleti, Dejan; Jovalekić, Čedomir; Karanović, Ljiljana

(Belgrade : Serbian Chemical Society, 2009)

TY  - JOUR
AU  - Zdujić, Miodrag
AU  - Poleti, Dejan
AU  - Jovalekić, Čedomir
AU  - Karanović, Ljiljana
PY  - 2009
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5532
AB  - A powder mixture of α-Bi2O3 and HfO2, in the molar ratio 2:3, was mechanochemically treated in a planetary ball mill under air, using zirconium oxide vials and balls as the milling medium. After 50 h of milling, the mechanochemical reaction led to the formation of a nanocrystalline δ-Bi2O3 phase (fluorite-type solid solution Bi0.78Hf0.59Zr0.63O3.61), with a crystallite size of 20 nm. The mechanochemical reaction started at a very beginning of milling accompanied by an accumulation of ZrO2 arising from the milling tools. The samples prepared after various milling times were characterized by X-ray powder diffraction and DSC analysis. The electrical properties of the as-milled and pressed Bi0.78Hf0.59Zr0.63O3.61 powder were studied using impedance spectroscopy in the temperature range from 100 to 700°C under air. The electrical conductivity was determined to be 9.43×10-6 and 0.080 S cm-1 for the temperatures of 300 and 700°C, respectively.
AB  - Smeša prahova α-Bi2O3 i HfO2 u molarnom odnosu 2:3 mehanohemijski je tretirana u planetarnom mlinu u atmosferi vazduha, koristeći cirkonijumske posude i kuglice kao medijum za mlevenje. Posle 50 h mlevenja, mehanohemijska reakcija dovodi do stvaranja nanokristalne δ-Bi2O3 faze (čvrsti rastvor fluoritske strukture Bi0,78Hf0,59Zr0,63O3,61), veličine kristalita 20 nm. Mehanohemijska reakcija otpočinje u samom početku mlevenja i praćena je akumulacijum ZrO2 koji potiče od medijuma za mlevenje. Uzorci dobijeni posle različitih vremena mlevenja karakterisani su rendgenskom strukturnom i termijskom analizom. Električna svojstva mlevenih i presovanih Bi0,78Hf0,59Zr0,63O3,61 prahova ispitivana su impedansnom spektroskopijom u temperaturnom opsegu od 100 do 700°C. Dobijena električna provodnost je 9,43·10-6 i 0,080 S cm-1 za temperaturu 300 i 700°C, redom.
PB  - Belgrade : Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Mechanochemical synthesis and electrical conductivity of nanocrystalline δ-Bi2O3 stabilized by HfO2 and ZrO2
EP  - 1411
IS  - 12
SP  - 1401
VL  - 74
DO  - 10.2298/JSC0912401Z
UR  - https://hdl.handle.net/21.15107/rcub_dais_174
ER  - 
@article{
author = "Zdujić, Miodrag and Poleti, Dejan and Jovalekić, Čedomir and Karanović, Ljiljana",
year = "2009",
abstract = "A powder mixture of α-Bi2O3 and HfO2, in the molar ratio 2:3, was mechanochemically treated in a planetary ball mill under air, using zirconium oxide vials and balls as the milling medium. After 50 h of milling, the mechanochemical reaction led to the formation of a nanocrystalline δ-Bi2O3 phase (fluorite-type solid solution Bi0.78Hf0.59Zr0.63O3.61), with a crystallite size of 20 nm. The mechanochemical reaction started at a very beginning of milling accompanied by an accumulation of ZrO2 arising from the milling tools. The samples prepared after various milling times were characterized by X-ray powder diffraction and DSC analysis. The electrical properties of the as-milled and pressed Bi0.78Hf0.59Zr0.63O3.61 powder were studied using impedance spectroscopy in the temperature range from 100 to 700°C under air. The electrical conductivity was determined to be 9.43×10-6 and 0.080 S cm-1 for the temperatures of 300 and 700°C, respectively., Smeša prahova α-Bi2O3 i HfO2 u molarnom odnosu 2:3 mehanohemijski je tretirana u planetarnom mlinu u atmosferi vazduha, koristeći cirkonijumske posude i kuglice kao medijum za mlevenje. Posle 50 h mlevenja, mehanohemijska reakcija dovodi do stvaranja nanokristalne δ-Bi2O3 faze (čvrsti rastvor fluoritske strukture Bi0,78Hf0,59Zr0,63O3,61), veličine kristalita 20 nm. Mehanohemijska reakcija otpočinje u samom početku mlevenja i praćena je akumulacijum ZrO2 koji potiče od medijuma za mlevenje. Uzorci dobijeni posle različitih vremena mlevenja karakterisani su rendgenskom strukturnom i termijskom analizom. Električna svojstva mlevenih i presovanih Bi0,78Hf0,59Zr0,63O3,61 prahova ispitivana su impedansnom spektroskopijom u temperaturnom opsegu od 100 do 700°C. Dobijena električna provodnost je 9,43·10-6 i 0,080 S cm-1 za temperaturu 300 i 700°C, redom.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Mechanochemical synthesis and electrical conductivity of nanocrystalline δ-Bi2O3 stabilized by HfO2 and ZrO2",
pages = "1411-1401",
number = "12",
volume = "74",
doi = "10.2298/JSC0912401Z",
url = "https://hdl.handle.net/21.15107/rcub_dais_174"
}
Zdujić, M., Poleti, D., Jovalekić, Č.,& Karanović, L.. (2009). Mechanochemical synthesis and electrical conductivity of nanocrystalline δ-Bi2O3 stabilized by HfO2 and ZrO2. in Journal of the Serbian Chemical Society
Belgrade : Serbian Chemical Society., 74(12), 1401-1411.
https://doi.org/10.2298/JSC0912401Z
https://hdl.handle.net/21.15107/rcub_dais_174
Zdujić M, Poleti D, Jovalekić Č, Karanović L. Mechanochemical synthesis and electrical conductivity of nanocrystalline δ-Bi2O3 stabilized by HfO2 and ZrO2. in Journal of the Serbian Chemical Society. 2009;74(12):1401-1411.
doi:10.2298/JSC0912401Z
https://hdl.handle.net/21.15107/rcub_dais_174 .
Zdujić, Miodrag, Poleti, Dejan, Jovalekić, Čedomir, Karanović, Ljiljana, "Mechanochemical synthesis and electrical conductivity of nanocrystalline δ-Bi2O3 stabilized by HfO2 and ZrO2" in Journal of the Serbian Chemical Society, 74, no. 12 (2009):1401-1411,
https://doi.org/10.2298/JSC0912401Z .,
https://hdl.handle.net/21.15107/rcub_dais_174 .
10
12
12

Mechanochemically induced amorphous/crystalline phase transition in the Bi4Ti3O12 compound

Zdujić, Miodrag; Jovalekić, Čedomir; Poleti, Dejan; Veljković, Ivana; Karanović, Ljiljana

(Elsevier, 2009)

TY  - JOUR
AU  - Zdujić, Miodrag
AU  - Jovalekić, Čedomir
AU  - Poleti, Dejan
AU  - Veljković, Ivana
AU  - Karanović, Ljiljana
PY  - 2009
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5533
AB  - Concurrent milling of Bi4Ti3O12 was carried out in a planetary ball mill with hardened-steel 13 or 6 mm diameter balls with a goal to investigate how the system responds to the constrains imposed by milling. Milling intensity for various milling parameters was derived from the electrical power measurement. The reverse amorphous ↔ crystalline phase transition induced by milling is governed by impact energy and frequency. Below a certain threshold value of impact energy crystallization does not occur, whereas a higher impact frequency accelerates amorphization. Mechanochemical reactions are predominantly discrete processes, which occur at the moment of impact. © 2009 Elsevier B.V. All rights reserved.
PB  - Elsevier
T2  - Materials Letters
T1  - Mechanochemically induced amorphous/crystalline phase transition in the Bi4Ti3O12 compound
EP  - 2544
IS  - 29
SP  - 2542
VL  - 63
DO  - 10.1016/j.matlet.2009.08.055
UR  - https://hdl.handle.net/21.15107/rcub_dais_3454
ER  - 
@article{
author = "Zdujić, Miodrag and Jovalekić, Čedomir and Poleti, Dejan and Veljković, Ivana and Karanović, Ljiljana",
year = "2009",
abstract = "Concurrent milling of Bi4Ti3O12 was carried out in a planetary ball mill with hardened-steel 13 or 6 mm diameter balls with a goal to investigate how the system responds to the constrains imposed by milling. Milling intensity for various milling parameters was derived from the electrical power measurement. The reverse amorphous ↔ crystalline phase transition induced by milling is governed by impact energy and frequency. Below a certain threshold value of impact energy crystallization does not occur, whereas a higher impact frequency accelerates amorphization. Mechanochemical reactions are predominantly discrete processes, which occur at the moment of impact. © 2009 Elsevier B.V. All rights reserved.",
publisher = "Elsevier",
journal = "Materials Letters",
title = "Mechanochemically induced amorphous/crystalline phase transition in the Bi4Ti3O12 compound",
pages = "2544-2542",
number = "29",
volume = "63",
doi = "10.1016/j.matlet.2009.08.055",
url = "https://hdl.handle.net/21.15107/rcub_dais_3454"
}
Zdujić, M., Jovalekić, Č., Poleti, D., Veljković, I.,& Karanović, L.. (2009). Mechanochemically induced amorphous/crystalline phase transition in the Bi4Ti3O12 compound. in Materials Letters
Elsevier., 63(29), 2542-2544.
https://doi.org/10.1016/j.matlet.2009.08.055
https://hdl.handle.net/21.15107/rcub_dais_3454
Zdujić M, Jovalekić Č, Poleti D, Veljković I, Karanović L. Mechanochemically induced amorphous/crystalline phase transition in the Bi4Ti3O12 compound. in Materials Letters. 2009;63(29):2542-2544.
doi:10.1016/j.matlet.2009.08.055
https://hdl.handle.net/21.15107/rcub_dais_3454 .
Zdujić, Miodrag, Jovalekić, Čedomir, Poleti, Dejan, Veljković, Ivana, Karanović, Ljiljana, "Mechanochemically induced amorphous/crystalline phase transition in the Bi4Ti3O12 compound" in Materials Letters, 63, no. 29 (2009):2542-2544,
https://doi.org/10.1016/j.matlet.2009.08.055 .,
https://hdl.handle.net/21.15107/rcub_dais_3454 .
3
2
3

Mechanochemistry of titanium oxides

Veljković, Ivana; Poleti, Dejan; Zdujić, Miodrag; Karanović, Ljiljana

(Belgrade : Association of the Chemical Engineers of Serbia, 2009)

TY  - JOUR
AU  - Veljković, Ivana
AU  - Poleti, Dejan
AU  - Zdujić, Miodrag
AU  - Karanović, Ljiljana
PY  - 2009
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5534
AB  - Mechanochemistry represents an alternative route in synthesis of nanomaterials. Mechanochemical routes are attractive because of their simplicity, flexibility, and ability to prepare materials by solid state reactions at room temperature. The aim of this work is the mechanochemical synthesis of nanostructured titanium oxides of different composition starting from mixtures of Ti and TiO2, TiO and TiO2 or Ti 2O3 and TiO2. Emphasis is on the Magneli phases Ti4O7 and Ti5O9 because their mixture is commercially known as EBONEX material. The materials prepared were characterized by XRPD, TG/DTA analysis, SEM and optical microscopy. Titanium monoxide and several Magneli oxides, Ti4O7, Ti 5O9 and Ti6O11, are successsfully prepared. The results are very interesting because the EBONEX materials were prepared at lower than usual temperature, which would decrease the effective cost of production.
PB  - Belgrade : Association of the Chemical Engineers of Serbia
T2  - Hemijska industrija
T1  - Mechanochemistry of titanium oxides
EP  - 251
IS  - 3
SP  - 247
VL  - 63
DO  - 10.2298/HEMIND0903247V
UR  - https://hdl.handle.net/21.15107/rcub_dais_3458
ER  - 
@article{
author = "Veljković, Ivana and Poleti, Dejan and Zdujić, Miodrag and Karanović, Ljiljana",
year = "2009",
abstract = "Mechanochemistry represents an alternative route in synthesis of nanomaterials. Mechanochemical routes are attractive because of their simplicity, flexibility, and ability to prepare materials by solid state reactions at room temperature. The aim of this work is the mechanochemical synthesis of nanostructured titanium oxides of different composition starting from mixtures of Ti and TiO2, TiO and TiO2 or Ti 2O3 and TiO2. Emphasis is on the Magneli phases Ti4O7 and Ti5O9 because their mixture is commercially known as EBONEX material. The materials prepared were characterized by XRPD, TG/DTA analysis, SEM and optical microscopy. Titanium monoxide and several Magneli oxides, Ti4O7, Ti 5O9 and Ti6O11, are successsfully prepared. The results are very interesting because the EBONEX materials were prepared at lower than usual temperature, which would decrease the effective cost of production.",
publisher = "Belgrade : Association of the Chemical Engineers of Serbia",
journal = "Hemijska industrija",
title = "Mechanochemistry of titanium oxides",
pages = "251-247",
number = "3",
volume = "63",
doi = "10.2298/HEMIND0903247V",
url = "https://hdl.handle.net/21.15107/rcub_dais_3458"
}
Veljković, I., Poleti, D., Zdujić, M.,& Karanović, L.. (2009). Mechanochemistry of titanium oxides. in Hemijska industrija
Belgrade : Association of the Chemical Engineers of Serbia., 63(3), 247-251.
https://doi.org/10.2298/HEMIND0903247V
https://hdl.handle.net/21.15107/rcub_dais_3458
Veljković I, Poleti D, Zdujić M, Karanović L. Mechanochemistry of titanium oxides. in Hemijska industrija. 2009;63(3):247-251.
doi:10.2298/HEMIND0903247V
https://hdl.handle.net/21.15107/rcub_dais_3458 .
Veljković, Ivana, Poleti, Dejan, Zdujić, Miodrag, Karanović, Ljiljana, "Mechanochemistry of titanium oxides" in Hemijska industrija, 63, no. 3 (2009):247-251,
https://doi.org/10.2298/HEMIND0903247V .,
https://hdl.handle.net/21.15107/rcub_dais_3458 .
1
1
1

Reinvestigation of Sr2 [Cu(OH)6]

Šutović, Sabina; Karanović, Ljiljana; Poleti, Dejan

(International Union of Crystallography, 2009)

TY  - JOUR
AU  - Šutović, Sabina
AU  - Karanović, Ljiljana
AU  - Poleti, Dejan
PY  - 2009
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5547
AB  - During an investigation of the SrO-CuO-P2O5-H 2O system, single crystals of distrontium hexa-hydroxido-cuprate(II), Sr2 [Cu(OH) 6], were obtained by the hydro-thermal method. The blue prismatic crystals of Sr2 [Cu(OH) 6] adopt the same structure type as Ba2 [Cu(OH) 6], Sr 2 [Zn(OH) 6] and Ba2 [Zn(OH) 6]. The Cu atoms, located at (0, 0, 1/2 ) (site symmetry ), form /mutually isolated and highly elongated Cu(OH) 6 octa-hedra, which are inter-connected to slightly distorted Sr(OH) 6 trigonal prisms, forming a layered structure. The location of H atoms from difference Fourier maps and their refinement allowed the precise determination of a three-dimensional hydrogen-bonding network in which all hy-drox-ide O atoms are involved. In addition, the hydrogen-bonding topologies in Sr2 [Cu(OH) 6] and other similar hexa-hydroxido-metallates with the general formulae M1[M2(OH) 6], M12 [M2(OH) 6] and M13 [M2(OH) 6] were analysed in detail.
PB  - International Union of Crystallography
T2  - Acta Crystallographica Section C: Crystal Structure Communications
T1  - Reinvestigation of Sr2 [Cu(OH)6]
EP  - i51
IS  - 8
SP  - i48
VL  - 65
DO  - 10.1107/S0108270109021519
ER  - 
@article{
author = "Šutović, Sabina and Karanović, Ljiljana and Poleti, Dejan",
year = "2009",
abstract = "During an investigation of the SrO-CuO-P2O5-H 2O system, single crystals of distrontium hexa-hydroxido-cuprate(II), Sr2 [Cu(OH) 6], were obtained by the hydro-thermal method. The blue prismatic crystals of Sr2 [Cu(OH) 6] adopt the same structure type as Ba2 [Cu(OH) 6], Sr 2 [Zn(OH) 6] and Ba2 [Zn(OH) 6]. The Cu atoms, located at (0, 0, 1/2 ) (site symmetry ), form /mutually isolated and highly elongated Cu(OH) 6 octa-hedra, which are inter-connected to slightly distorted Sr(OH) 6 trigonal prisms, forming a layered structure. The location of H atoms from difference Fourier maps and their refinement allowed the precise determination of a three-dimensional hydrogen-bonding network in which all hy-drox-ide O atoms are involved. In addition, the hydrogen-bonding topologies in Sr2 [Cu(OH) 6] and other similar hexa-hydroxido-metallates with the general formulae M1[M2(OH) 6], M12 [M2(OH) 6] and M13 [M2(OH) 6] were analysed in detail.",
publisher = "International Union of Crystallography",
journal = "Acta Crystallographica Section C: Crystal Structure Communications",
title = "Reinvestigation of Sr2 [Cu(OH)6]",
pages = "i51-i48",
number = "8",
volume = "65",
doi = "10.1107/S0108270109021519"
}
Šutović, S., Karanović, L.,& Poleti, D.. (2009). Reinvestigation of Sr2 [Cu(OH)6]. in Acta Crystallographica Section C: Crystal Structure Communications
International Union of Crystallography., 65(8), i48-i51.
https://doi.org/10.1107/S0108270109021519
Šutović S, Karanović L, Poleti D. Reinvestigation of Sr2 [Cu(OH)6]. in Acta Crystallographica Section C: Crystal Structure Communications. 2009;65(8):i48-i51.
doi:10.1107/S0108270109021519 .
Šutović, Sabina, Karanović, Ljiljana, Poleti, Dejan, "Reinvestigation of Sr2 [Cu(OH)6]" in Acta Crystallographica Section C: Crystal Structure Communications, 65, no. 8 (2009):i48-i51,
https://doi.org/10.1107/S0108270109021519 . .
3
1
2

Crystal structure of picotpaulite, TlFe2S3, from Allchar, FYR Macedonia

Balić-Žunić, Tonči; Karanović, Ljiljana; Poleti, Dejan

(Slovenian Chemical Society, 2008)

TY  - JOUR
AU  - Balić-Žunić, Tonči
AU  - Karanović, Ljiljana
AU  - Poleti, Dejan
PY  - 2008
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5556
AB  - The crystal structure of the mineral picotpaulite, TlFe2S 3, was solved and refined using single-crystal X-ray diffraction data collected at room temperature. The symmetry is orthorhombic, space group Cmcm, with unit-cell parameters: a = 9.083(6), b = 10.754(6), c = 5.412(4) Å, V = 528.6(6) Å3, Z = 4. The structure was refined to the conventional R factor 0.0532 for 226 independent reflections with I > 2σ(I) and 21 variables. Picotpaulite is isostructural with minerals rasvumite (KFe2S3) and pautovite (CsFe2S 3), as well as with a number of synthetic compounds belonging to the CsCu2Cl3 structure type. The structure consists of double chains of FeS4-tetrahedra running along [001] interconnected by TlS10 coordination polyhedra, which form zig-zag chains along the same direction. The Fe-Fe distances between neighbours along the chain direction and perpendicular to it are 2.706(2) and 2.693(6) Å, respectively, indicating strong Fe-Fe interactions. The average oxidation state of Fe is +2.5, achieved by electron transfer over the close Fe sites. Thallium coordination polyhedron can be described as a combination of a square antiprism adjacent to a trigonal prism. The 6s2 electrons of Tl behave as an inert pair and the atom is situated in the centroid of its coordination.
PB  - Slovenian Chemical Society
T2  - Acta Chimica Slovenica
T1  - Crystal structure of picotpaulite, TlFe2S3, from Allchar, FYR Macedonia
EP  - 809
IS  - 4
SP  - 801
VL  - 55
UR  - https://hdl.handle.net/21.15107/rcub_technorep_5556
ER  - 
@article{
author = "Balić-Žunić, Tonči and Karanović, Ljiljana and Poleti, Dejan",
year = "2008",
abstract = "The crystal structure of the mineral picotpaulite, TlFe2S 3, was solved and refined using single-crystal X-ray diffraction data collected at room temperature. The symmetry is orthorhombic, space group Cmcm, with unit-cell parameters: a = 9.083(6), b = 10.754(6), c = 5.412(4) Å, V = 528.6(6) Å3, Z = 4. The structure was refined to the conventional R factor 0.0532 for 226 independent reflections with I > 2σ(I) and 21 variables. Picotpaulite is isostructural with minerals rasvumite (KFe2S3) and pautovite (CsFe2S 3), as well as with a number of synthetic compounds belonging to the CsCu2Cl3 structure type. The structure consists of double chains of FeS4-tetrahedra running along [001] interconnected by TlS10 coordination polyhedra, which form zig-zag chains along the same direction. The Fe-Fe distances between neighbours along the chain direction and perpendicular to it are 2.706(2) and 2.693(6) Å, respectively, indicating strong Fe-Fe interactions. The average oxidation state of Fe is +2.5, achieved by electron transfer over the close Fe sites. Thallium coordination polyhedron can be described as a combination of a square antiprism adjacent to a trigonal prism. The 6s2 electrons of Tl behave as an inert pair and the atom is situated in the centroid of its coordination.",
publisher = "Slovenian Chemical Society",
journal = "Acta Chimica Slovenica",
title = "Crystal structure of picotpaulite, TlFe2S3, from Allchar, FYR Macedonia",
pages = "809-801",
number = "4",
volume = "55",
url = "https://hdl.handle.net/21.15107/rcub_technorep_5556"
}
Balić-Žunić, T., Karanović, L.,& Poleti, D.. (2008). Crystal structure of picotpaulite, TlFe2S3, from Allchar, FYR Macedonia. in Acta Chimica Slovenica
Slovenian Chemical Society., 55(4), 801-809.
https://hdl.handle.net/21.15107/rcub_technorep_5556
Balić-Žunić T, Karanović L, Poleti D. Crystal structure of picotpaulite, TlFe2S3, from Allchar, FYR Macedonia. in Acta Chimica Slovenica. 2008;55(4):801-809.
https://hdl.handle.net/21.15107/rcub_technorep_5556 .
Balić-Žunić, Tonči, Karanović, Ljiljana, Poleti, Dejan, "Crystal structure of picotpaulite, TlFe2S3, from Allchar, FYR Macedonia" in Acta Chimica Slovenica, 55, no. 4 (2008):801-809,
https://hdl.handle.net/21.15107/rcub_technorep_5556 .

Doped gamma-Bi2O3: synthesis of microcrystalline samples and crystal chemical analysis of structural data

Poleti, Dejan; Karanović, Ljiljana; Dapčević, Aleksandra

(Walter de Gruyter Gmbh, Berlin, 2007)

TY  - JOUR
AU  - Poleti, Dejan
AU  - Karanović, Ljiljana
AU  - Dapčević, Aleksandra
PY  - 2007
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1113
AB  - A series of microcrystalline products containing the gamma-Bi2O3 phase doped with Co, Fe, Mn, Pb, Sb, Si, Ti, V and Zn has been prepared by solid state reaction. Based on the heating temperature and heating time, the following order of increasing relative stability of the doped gamma-Bi2O3 phases was established: Sb 51  lt  Co2+ Mn4+  lt  Fe3+ approximate to Si4+  lt  Ti4+  lt  V5+  lt  Zn2+  lt  Ph2+. The unit cell parameters of the prepared samples were compared with available structural data, which were also further analyzed concerning the geometrical parameters and overall reliability. The analysis confirmed the socalled Radaev's model for the doped gamma-Bi2O3 structure, which assumes the presence of Bi2(3+) ions slightly displaced from the tetrahedral M site and corresponding vacancies (resulting from a lone pair on Bi2(3+)) in the coordinating oxygen positions. In addition, the analysis suggested that this model can be further improved. The existence of an approximate linear relationship between the unit cell parameters of the doped gamma-Bi2O3 phases and the ionic radii of the M cations was found.
PB  - Walter de Gruyter Gmbh, Berlin
T2  - Zeitschrift Fur Kristallographie
T1  - Doped gamma-Bi2O3: synthesis of microcrystalline samples and crystal chemical analysis of structural data
EP  - 72
IS  - 2
SP  - 59
VL  - 222
DO  - 10.1524/zkri.2007.222.2.59
ER  - 
@article{
author = "Poleti, Dejan and Karanović, Ljiljana and Dapčević, Aleksandra",
year = "2007",
abstract = "A series of microcrystalline products containing the gamma-Bi2O3 phase doped with Co, Fe, Mn, Pb, Sb, Si, Ti, V and Zn has been prepared by solid state reaction. Based on the heating temperature and heating time, the following order of increasing relative stability of the doped gamma-Bi2O3 phases was established: Sb 51  lt  Co2+ Mn4+  lt  Fe3+ approximate to Si4+  lt  Ti4+  lt  V5+  lt  Zn2+  lt  Ph2+. The unit cell parameters of the prepared samples were compared with available structural data, which were also further analyzed concerning the geometrical parameters and overall reliability. The analysis confirmed the socalled Radaev's model for the doped gamma-Bi2O3 structure, which assumes the presence of Bi2(3+) ions slightly displaced from the tetrahedral M site and corresponding vacancies (resulting from a lone pair on Bi2(3+)) in the coordinating oxygen positions. In addition, the analysis suggested that this model can be further improved. The existence of an approximate linear relationship between the unit cell parameters of the doped gamma-Bi2O3 phases and the ionic radii of the M cations was found.",
publisher = "Walter de Gruyter Gmbh, Berlin",
journal = "Zeitschrift Fur Kristallographie",
title = "Doped gamma-Bi2O3: synthesis of microcrystalline samples and crystal chemical analysis of structural data",
pages = "72-59",
number = "2",
volume = "222",
doi = "10.1524/zkri.2007.222.2.59"
}
Poleti, D., Karanović, L.,& Dapčević, A.. (2007). Doped gamma-Bi2O3: synthesis of microcrystalline samples and crystal chemical analysis of structural data. in Zeitschrift Fur Kristallographie
Walter de Gruyter Gmbh, Berlin., 222(2), 59-72.
https://doi.org/10.1524/zkri.2007.222.2.59
Poleti D, Karanović L, Dapčević A. Doped gamma-Bi2O3: synthesis of microcrystalline samples and crystal chemical analysis of structural data. in Zeitschrift Fur Kristallographie. 2007;222(2):59-72.
doi:10.1524/zkri.2007.222.2.59 .
Poleti, Dejan, Karanović, Ljiljana, Dapčević, Aleksandra, "Doped gamma-Bi2O3: synthesis of microcrystalline samples and crystal chemical analysis of structural data" in Zeitschrift Fur Kristallographie, 222, no. 2 (2007):59-72,
https://doi.org/10.1524/zkri.2007.222.2.59 . .
7
7
7

Crystal structure of potassium lead bismuth oxide hydrate, K-1.09(Bi0.93Pb0.07)O-3 center dot 1/6H(2)O

Poleti, Dejan; Karanović, Ljiljana; Đorđević, Tamara; Dapčević, Aleksandra

(Oldenbourg Verlag, Munich, 2007)

TY  - JOUR
AU  - Poleti, Dejan
AU  - Karanović, Ljiljana
AU  - Đorđević, Tamara
AU  - Dapčević, Aleksandra
PY  - 2007
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1201
AB  - Bi0.93H0.33K1.09O3.Pb-17(0.07), cubic, Im (3) over bar (no. 213), a = 10.013(l) angstrom, V = 1003.9 angstrom(3), Z = 12, R-gt(F) = 0.010, wR(ref)(F-2) = 0.023, T = 295 K.
PB  - Oldenbourg Verlag, Munich
T2  - Zeitschrift Fur Kristallographie-New Crystal Structures
T1  - Crystal structure of potassium lead bismuth oxide hydrate, K-1.09(Bi0.93Pb0.07)O-3 center dot 1/6H(2)O
EP  - 366
IS  - 4
SP  - 365
VL  - 222
DO  - 10.1524/ncrs.2007.0155
ER  - 
@article{
author = "Poleti, Dejan and Karanović, Ljiljana and Đorđević, Tamara and Dapčević, Aleksandra",
year = "2007",
abstract = "Bi0.93H0.33K1.09O3.Pb-17(0.07), cubic, Im (3) over bar (no. 213), a = 10.013(l) angstrom, V = 1003.9 angstrom(3), Z = 12, R-gt(F) = 0.010, wR(ref)(F-2) = 0.023, T = 295 K.",
publisher = "Oldenbourg Verlag, Munich",
journal = "Zeitschrift Fur Kristallographie-New Crystal Structures",
title = "Crystal structure of potassium lead bismuth oxide hydrate, K-1.09(Bi0.93Pb0.07)O-3 center dot 1/6H(2)O",
pages = "366-365",
number = "4",
volume = "222",
doi = "10.1524/ncrs.2007.0155"
}
Poleti, D., Karanović, L., Đorđević, T.,& Dapčević, A.. (2007). Crystal structure of potassium lead bismuth oxide hydrate, K-1.09(Bi0.93Pb0.07)O-3 center dot 1/6H(2)O. in Zeitschrift Fur Kristallographie-New Crystal Structures
Oldenbourg Verlag, Munich., 222(4), 365-366.
https://doi.org/10.1524/ncrs.2007.0155
Poleti D, Karanović L, Đorđević T, Dapčević A. Crystal structure of potassium lead bismuth oxide hydrate, K-1.09(Bi0.93Pb0.07)O-3 center dot 1/6H(2)O. in Zeitschrift Fur Kristallographie-New Crystal Structures. 2007;222(4):365-366.
doi:10.1524/ncrs.2007.0155 .
Poleti, Dejan, Karanović, Ljiljana, Đorđević, Tamara, Dapčević, Aleksandra, "Crystal structure of potassium lead bismuth oxide hydrate, K-1.09(Bi0.93Pb0.07)O-3 center dot 1/6H(2)O" in Zeitschrift Fur Kristallographie-New Crystal Structures, 222, no. 4 (2007):365-366,
https://doi.org/10.1524/ncrs.2007.0155 . .

Disorder of lattice solvent molecules in the structure of hexaaqua(μ2-1,2,4,5-benzenetetracarboxylato)-bis(2,2’-dipyridylamine)dinickel(II) hexahydrate DMSO solvate

Poleti, Dejan; Karanović, Ljiljana; Kremenović, Aleksandar; Rogan, Jelena

(Serbian Chemical Society, Belgrade, 2007)

TY  - JOUR
AU  - Poleti, Dejan
AU  - Karanović, Ljiljana
AU  - Kremenović, Aleksandar
AU  - Rogan, Jelena
PY  - 2007
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1166
AB  - The crystal structure of the complex [Ni2(btc)(dipya)2(H2O)6]⋅6H2O·DMSO (btc = tetra-anion of 1,2,4,5-benzenetetracarboxylic acid, dipya = 2,2’-dipyridylamine) was refined in the triclinic system, space group P1, using low temperature (170 K) X-ray diffraction data. The compound consists of binuclear complex entities and lattice solvent molecules making pseudo-layers parallel to the 101 plane and channels parallel to the b-axis. The observed structural features were compared with the previously reported results and formula [Ni2(btc)(dipya)2(H2O)6]⋅4H2O based on room temperature X-ray diffraction data. A possible arrangement of the disordered lattice solvent molecules located in the structural channels is described and discussed. It is concluded that the layout of these molecules is non-centrosymmetric, although the remaining and main part of the structure is centrosymmetric. .
AB  - Kristalna struktura kompleksa [Ni2(btc)(dipya)2(H2O)6]⋅6H2O·DMSO (btc = tetraanjon 1,2,4,5-benzentetrakarboksilne kiseline, dipya = 2,2’-dipiridilamin) utačnjena je u trikliničnom sistemu, prostorna grupa P1, na osnovu podataka dobijenih rendgenskom difrakcijom na niskoj temperaturi (170K). Jedinjenje se sastoji od binuklearnih kompleksnih jedinki i nekoordiniranih molekula rastvarača, koji formiraju pseudo-slojeve paralelne ravni 101 i kanale paralelne b-osi. Strukturne karakteristike kompleksa upoređene su sa ranije objavljenim rezultatima i formulom [Ni2(btc)(dipya)2(H2O)6]⋅4H2O, koji su bili zasnovani na podacima prikupljenim na sobnoj temperaturi. U radu je opisan i diskutovan mogući raspored neuređenih molekula rastvarača koji se nalaze u ranije pomenutim kanalima. Zaključeno je da raspored tih molekula mora biti necentrosimetričan, iako je preostali i najveći deo strukture centrosimetričan. .
PB  - Serbian Chemical Society, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Disorder of lattice solvent molecules in the structure of hexaaqua(μ2-1,2,4,5-benzenetetracarboxylato)-bis(2,2’-dipyridylamine)dinickel(II) hexahydrate DMSO solvate
T1  - Neuređenost molekula rastvarača u strukturi heksaakva(μ2-1,2,4,5-benzentetrakarboksilato)-bis(2,2’-dipiridilamin)dinikal(II)-heksahidrata-DMSO solvata
EP  - 771
IS  - 8-9
SP  - 767
VL  - 72
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1166
ER  - 
@article{
author = "Poleti, Dejan and Karanović, Ljiljana and Kremenović, Aleksandar and Rogan, Jelena",
year = "2007",
abstract = "The crystal structure of the complex [Ni2(btc)(dipya)2(H2O)6]⋅6H2O·DMSO (btc = tetra-anion of 1,2,4,5-benzenetetracarboxylic acid, dipya = 2,2’-dipyridylamine) was refined in the triclinic system, space group P1, using low temperature (170 K) X-ray diffraction data. The compound consists of binuclear complex entities and lattice solvent molecules making pseudo-layers parallel to the 101 plane and channels parallel to the b-axis. The observed structural features were compared with the previously reported results and formula [Ni2(btc)(dipya)2(H2O)6]⋅4H2O based on room temperature X-ray diffraction data. A possible arrangement of the disordered lattice solvent molecules located in the structural channels is described and discussed. It is concluded that the layout of these molecules is non-centrosymmetric, although the remaining and main part of the structure is centrosymmetric. ., Kristalna struktura kompleksa [Ni2(btc)(dipya)2(H2O)6]⋅6H2O·DMSO (btc = tetraanjon 1,2,4,5-benzentetrakarboksilne kiseline, dipya = 2,2’-dipiridilamin) utačnjena je u trikliničnom sistemu, prostorna grupa P1, na osnovu podataka dobijenih rendgenskom difrakcijom na niskoj temperaturi (170K). Jedinjenje se sastoji od binuklearnih kompleksnih jedinki i nekoordiniranih molekula rastvarača, koji formiraju pseudo-slojeve paralelne ravni 101 i kanale paralelne b-osi. Strukturne karakteristike kompleksa upoređene su sa ranije objavljenim rezultatima i formulom [Ni2(btc)(dipya)2(H2O)6]⋅4H2O, koji su bili zasnovani na podacima prikupljenim na sobnoj temperaturi. U radu je opisan i diskutovan mogući raspored neuređenih molekula rastvarača koji se nalaze u ranije pomenutim kanalima. Zaključeno je da raspored tih molekula mora biti necentrosimetričan, iako je preostali i najveći deo strukture centrosimetričan. .",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Disorder of lattice solvent molecules in the structure of hexaaqua(μ2-1,2,4,5-benzenetetracarboxylato)-bis(2,2’-dipyridylamine)dinickel(II) hexahydrate DMSO solvate, Neuređenost molekula rastvarača u strukturi heksaakva(μ2-1,2,4,5-benzentetrakarboksilato)-bis(2,2’-dipiridilamin)dinikal(II)-heksahidrata-DMSO solvata",
pages = "771-767",
number = "8-9",
volume = "72",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1166"
}
Poleti, D., Karanović, L., Kremenović, A.,& Rogan, J.. (2007). Disorder of lattice solvent molecules in the structure of hexaaqua(μ2-1,2,4,5-benzenetetracarboxylato)-bis(2,2’-dipyridylamine)dinickel(II) hexahydrate DMSO solvate. in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 72(8-9), 767-771.
https://hdl.handle.net/21.15107/rcub_technorep_1166
Poleti D, Karanović L, Kremenović A, Rogan J. Disorder of lattice solvent molecules in the structure of hexaaqua(μ2-1,2,4,5-benzenetetracarboxylato)-bis(2,2’-dipyridylamine)dinickel(II) hexahydrate DMSO solvate. in Journal of the Serbian Chemical Society. 2007;72(8-9):767-771.
https://hdl.handle.net/21.15107/rcub_technorep_1166 .
Poleti, Dejan, Karanović, Ljiljana, Kremenović, Aleksandar, Rogan, Jelena, "Disorder of lattice solvent molecules in the structure of hexaaqua(μ2-1,2,4,5-benzenetetracarboxylato)-bis(2,2’-dipyridylamine)dinickel(II) hexahydrate DMSO solvate" in Journal of the Serbian Chemical Society, 72, no. 8-9 (2007):767-771,
https://hdl.handle.net/21.15107/rcub_technorep_1166 .
1
1

The evolution of structure induced by intensive milling in the system 2Bi 2 O 3 · 3TiO 2

Zdujić, Miodrag; Poleti, Dejan; Jovalekić, Čedomir; Karanović, Ljiljana

(Elsevier, 2006)

TY  - JOUR
AU  - Zdujić, Miodrag
AU  - Poleti, Dejan
AU  - Jovalekić, Čedomir
AU  - Karanović, Ljiljana
PY  - 2006
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5466
AB  - Concurrent mechanochemical treatment of either a stoichiometric 2Bi 2 O 3 · 3TiO 2 powder mixture or (pulverized) Bi 4 Ti 3 O 12 compound was performed in a planetary ball mill. Relevant structural parameters: crystallite size, amount of amorphous phase and the transformed fraction (as a result of chemical reaction between Bi 2 O 3 and TiO 2 ) of the powders milled for various milling times and intensities were derived from X-ray powder diffraction data. The obtained structural parameters were used to follow the kinetics of the reduction of crystallite size, amorphous phase formation and chemical reaction. In the powder mixture, during the early stage of mechanochemical treatment the Bi 2 (CO 3 )O 2 phase was found as an intermediate product which transformed into the highly amorphized Bi 4 Ti 3 O 12 phase as the milling progressed. On the other hand, mechanochemical treatment of Bi 4 Ti 3 O 12 powder induced a gradual deformation of the crystal lattice and destruction of the perovskite-type structure. However, in both cases, after a certain milling time, a very disordered, amorphous/nanocrystalline structure was obtained. It was demonstrated that in the steady state, the amorphous/nanocrystalline phase ratio depends on the milling conditions. Higher milling intensities induce 'nanocrystallization' of the amorphous phase, i.e., precipitation of crystallites with an average size below 20 nm. A kinetic model involving a nanocrystalline ↔ amorphous reaction, in which the forward and reverse reaction were first-order was postulated and used to analyze the formation of an amorphous phase.
PB  - Elsevier
T2  - Journal of Non-Crystalline Solids
T1  - The evolution of structure induced by intensive milling in the system 2Bi 2 O 3 · 3TiO 2
EP  - 3068
IS  - 28-29
SP  - 3058
VL  - 352
DO  - 10.1016/j.jnoncrysol.2006.03.072
ER  - 
@article{
author = "Zdujić, Miodrag and Poleti, Dejan and Jovalekić, Čedomir and Karanović, Ljiljana",
year = "2006",
abstract = "Concurrent mechanochemical treatment of either a stoichiometric 2Bi 2 O 3 · 3TiO 2 powder mixture or (pulverized) Bi 4 Ti 3 O 12 compound was performed in a planetary ball mill. Relevant structural parameters: crystallite size, amount of amorphous phase and the transformed fraction (as a result of chemical reaction between Bi 2 O 3 and TiO 2 ) of the powders milled for various milling times and intensities were derived from X-ray powder diffraction data. The obtained structural parameters were used to follow the kinetics of the reduction of crystallite size, amorphous phase formation and chemical reaction. In the powder mixture, during the early stage of mechanochemical treatment the Bi 2 (CO 3 )O 2 phase was found as an intermediate product which transformed into the highly amorphized Bi 4 Ti 3 O 12 phase as the milling progressed. On the other hand, mechanochemical treatment of Bi 4 Ti 3 O 12 powder induced a gradual deformation of the crystal lattice and destruction of the perovskite-type structure. However, in both cases, after a certain milling time, a very disordered, amorphous/nanocrystalline structure was obtained. It was demonstrated that in the steady state, the amorphous/nanocrystalline phase ratio depends on the milling conditions. Higher milling intensities induce 'nanocrystallization' of the amorphous phase, i.e., precipitation of crystallites with an average size below 20 nm. A kinetic model involving a nanocrystalline ↔ amorphous reaction, in which the forward and reverse reaction were first-order was postulated and used to analyze the formation of an amorphous phase.",
publisher = "Elsevier",
journal = "Journal of Non-Crystalline Solids",
title = "The evolution of structure induced by intensive milling in the system 2Bi 2 O 3 · 3TiO 2",
pages = "3068-3058",
number = "28-29",
volume = "352",
doi = "10.1016/j.jnoncrysol.2006.03.072"
}
Zdujić, M., Poleti, D., Jovalekić, Č.,& Karanović, L.. (2006). The evolution of structure induced by intensive milling in the system 2Bi 2 O 3 · 3TiO 2. in Journal of Non-Crystalline Solids
Elsevier., 352(28-29), 3058-3068.
https://doi.org/10.1016/j.jnoncrysol.2006.03.072
Zdujić M, Poleti D, Jovalekić Č, Karanović L. The evolution of structure induced by intensive milling in the system 2Bi 2 O 3 · 3TiO 2. in Journal of Non-Crystalline Solids. 2006;352(28-29):3058-3068.
doi:10.1016/j.jnoncrysol.2006.03.072 .
Zdujić, Miodrag, Poleti, Dejan, Jovalekić, Čedomir, Karanović, Ljiljana, "The evolution of structure induced by intensive milling in the system 2Bi 2 O 3 · 3TiO 2" in Journal of Non-Crystalline Solids, 352, no. 28-29 (2006):3058-3068,
https://doi.org/10.1016/j.jnoncrysol.2006.03.072 . .
18
15
22

Synthesis, structure, and thermal properties of two new inorganic-organic framework compounds: Hexaaqua(mu(2)-1,2,4,5-benzenetetracarboxylato)-bis(N,N '-1,10-phenathroline)dicobalt(II) dihydrate and hexaaqua(mu(2)-1,2,4,5-benzenetetracarboxylato)-bis(N,N

Rogan, Jelena; Poleti, Dejan; Karanović, Ljiljana

(Wiley-VCH Verlag Gmbh, Weinheim, 2006)

TY  - JOUR
AU  - Rogan, Jelena
AU  - Poleti, Dejan
AU  - Karanović, Ljiljana
PY  - 2006
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/894
AB  - Two binuclear complexes [Co-2(C10H2O8)(C12H8N2)(2) (H2O)(6)]center dot 2H(2)O (1) and [Ni-2(C10H2O8)(C10H9N3)(2)(H2O)(6)]center dot 4H(2)O (2) were synthesized and their structures were determined by X-ray structure analysis. In both structures metal centres are in deformed octahedral environments and they are linked by bis-monodentately coordinated 1,2,4,5-benzenetetracarboxylate ligands as bridging units. In the packing arrangements of both compounds, binuclear units are connected by hydrogen bonds forming 2D pseudo-layers, strengthened by face-to-face pi-pi stacking interactions. The pseudolayers further construct 3D in organic-organic frameworks via system of hydrogen bonds. The complexes were also characterized by IR spectroscopy, TG and DSC analysis. Dehydration processes and thermal stability of the complexes are discussed. The dehydration enthalpies are calculated and the possible decomposition mechanisms are assumed.
PB  - Wiley-VCH Verlag Gmbh, Weinheim
T2  - Zeitschrift Fur Anorganische Und Allgemeine Chemie
T1  - Synthesis, structure, and thermal properties of two new inorganic-organic framework compounds: Hexaaqua(mu(2)-1,2,4,5-benzenetetracarboxylato)-bis(N,N '-1,10-phenathroline)dicobalt(II) dihydrate and hexaaqua(mu(2)-1,2,4,5-benzenetetracarboxylato)-bis(N,N
EP  - 139
IS  - 1
SP  - 133
VL  - 632
DO  - 10.1002/zaac.200500292
ER  - 
@article{
author = "Rogan, Jelena and Poleti, Dejan and Karanović, Ljiljana",
year = "2006",
abstract = "Two binuclear complexes [Co-2(C10H2O8)(C12H8N2)(2) (H2O)(6)]center dot 2H(2)O (1) and [Ni-2(C10H2O8)(C10H9N3)(2)(H2O)(6)]center dot 4H(2)O (2) were synthesized and their structures were determined by X-ray structure analysis. In both structures metal centres are in deformed octahedral environments and they are linked by bis-monodentately coordinated 1,2,4,5-benzenetetracarboxylate ligands as bridging units. In the packing arrangements of both compounds, binuclear units are connected by hydrogen bonds forming 2D pseudo-layers, strengthened by face-to-face pi-pi stacking interactions. The pseudolayers further construct 3D in organic-organic frameworks via system of hydrogen bonds. The complexes were also characterized by IR spectroscopy, TG and DSC analysis. Dehydration processes and thermal stability of the complexes are discussed. The dehydration enthalpies are calculated and the possible decomposition mechanisms are assumed.",
publisher = "Wiley-VCH Verlag Gmbh, Weinheim",
journal = "Zeitschrift Fur Anorganische Und Allgemeine Chemie",
title = "Synthesis, structure, and thermal properties of two new inorganic-organic framework compounds: Hexaaqua(mu(2)-1,2,4,5-benzenetetracarboxylato)-bis(N,N '-1,10-phenathroline)dicobalt(II) dihydrate and hexaaqua(mu(2)-1,2,4,5-benzenetetracarboxylato)-bis(N,N",
pages = "139-133",
number = "1",
volume = "632",
doi = "10.1002/zaac.200500292"
}
Rogan, J., Poleti, D.,& Karanović, L.. (2006). Synthesis, structure, and thermal properties of two new inorganic-organic framework compounds: Hexaaqua(mu(2)-1,2,4,5-benzenetetracarboxylato)-bis(N,N '-1,10-phenathroline)dicobalt(II) dihydrate and hexaaqua(mu(2)-1,2,4,5-benzenetetracarboxylato)-bis(N,N. in Zeitschrift Fur Anorganische Und Allgemeine Chemie
Wiley-VCH Verlag Gmbh, Weinheim., 632(1), 133-139.
https://doi.org/10.1002/zaac.200500292
Rogan J, Poleti D, Karanović L. Synthesis, structure, and thermal properties of two new inorganic-organic framework compounds: Hexaaqua(mu(2)-1,2,4,5-benzenetetracarboxylato)-bis(N,N '-1,10-phenathroline)dicobalt(II) dihydrate and hexaaqua(mu(2)-1,2,4,5-benzenetetracarboxylato)-bis(N,N. in Zeitschrift Fur Anorganische Und Allgemeine Chemie. 2006;632(1):133-139.
doi:10.1002/zaac.200500292 .
Rogan, Jelena, Poleti, Dejan, Karanović, Ljiljana, "Synthesis, structure, and thermal properties of two new inorganic-organic framework compounds: Hexaaqua(mu(2)-1,2,4,5-benzenetetracarboxylato)-bis(N,N '-1,10-phenathroline)dicobalt(II) dihydrate and hexaaqua(mu(2)-1,2,4,5-benzenetetracarboxylato)-bis(N,N" in Zeitschrift Fur Anorganische Und Allgemeine Chemie, 632, no. 1 (2006):133-139,
https://doi.org/10.1002/zaac.200500292 . .
17
21
19

1,3-Propanediammonium [μ4-1,2,4,5-benzenetetracarboxylato(4-) ]copper(II) dihydrate with a microporous structure

Poleti, Dejan; Karanović, Ljiljana

(Serbian Chemical Society, 2005)

TY  - JOUR
AU  - Poleti, Dejan
AU  - Karanović, Ljiljana
PY  - 2005
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5445
AB  - Crystal structure analysis of the title complex, (H3NC 3H6NH3)[Cu{C6H2(COO) 4}] ·2H2O, showed that the structure is built up from Cu(II) and tetradentate 1,2,4,5-benzenetetracarboxylate(4-) (btc) ions forming a 3D open-framework with two different channels extending parallel to the [110]/[1,-1,0] and [001] directions. The first, wider channels accommodate 1,3-propanediammonium cations, whereas the second ones are filled with H 2O molecules. The Cu(II) ions are in a tetrahedrally distorted square-planar environment consisting of four carboxylate O atoms from four different btc ligands. The four uncoordinated O atoms from the same carboxylate groups are placed around Cu(II) at longer distances (≈ 2.8 A), forming a distorted sphenoid. The complex crystallizes in the orthorhombic space group Cc2m with a = 8.887(1), b = 11.493(2), c = 16.457(3) Å, K= 1680.9(5) Å3 and Z=4. Final agreement indices are: R, = 0.0303 for 1012 reflections with 1 > 2σ(I), wR2 = 0.0493 for 1317 independent reflections and 123 refined parameters. The compound was also characterized by IR spectroscopy and TG/DSC analysis.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - 1,3-Propanediammonium [μ4-1,2,4,5-benzenetetracarboxylato(4-) ]copper(II) dihydrate with a microporous structure
EP  - 1450
IS  - 12
SP  - 1441
VL  - 70
DO  - 10.2298/JSC0512441P
ER  - 
@article{
author = "Poleti, Dejan and Karanović, Ljiljana",
year = "2005",
abstract = "Crystal structure analysis of the title complex, (H3NC 3H6NH3)[Cu{C6H2(COO) 4}] ·2H2O, showed that the structure is built up from Cu(II) and tetradentate 1,2,4,5-benzenetetracarboxylate(4-) (btc) ions forming a 3D open-framework with two different channels extending parallel to the [110]/[1,-1,0] and [001] directions. The first, wider channels accommodate 1,3-propanediammonium cations, whereas the second ones are filled with H 2O molecules. The Cu(II) ions are in a tetrahedrally distorted square-planar environment consisting of four carboxylate O atoms from four different btc ligands. The four uncoordinated O atoms from the same carboxylate groups are placed around Cu(II) at longer distances (≈ 2.8 A), forming a distorted sphenoid. The complex crystallizes in the orthorhombic space group Cc2m with a = 8.887(1), b = 11.493(2), c = 16.457(3) Å, K= 1680.9(5) Å3 and Z=4. Final agreement indices are: R, = 0.0303 for 1012 reflections with 1 > 2σ(I), wR2 = 0.0493 for 1317 independent reflections and 123 refined parameters. The compound was also characterized by IR spectroscopy and TG/DSC analysis.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "1,3-Propanediammonium [μ4-1,2,4,5-benzenetetracarboxylato(4-) ]copper(II) dihydrate with a microporous structure",
pages = "1450-1441",
number = "12",
volume = "70",
doi = "10.2298/JSC0512441P"
}
Poleti, D.,& Karanović, L.. (2005). 1,3-Propanediammonium [μ4-1,2,4,5-benzenetetracarboxylato(4-) ]copper(II) dihydrate with a microporous structure. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 70(12), 1441-1450.
https://doi.org/10.2298/JSC0512441P
Poleti D, Karanović L. 1,3-Propanediammonium [μ4-1,2,4,5-benzenetetracarboxylato(4-) ]copper(II) dihydrate with a microporous structure. in Journal of the Serbian Chemical Society. 2005;70(12):1441-1450.
doi:10.2298/JSC0512441P .
Poleti, Dejan, Karanović, Ljiljana, "1,3-Propanediammonium [μ4-1,2,4,5-benzenetetracarboxylato(4-) ]copper(II) dihydrate with a microporous structure" in Journal of the Serbian Chemical Society, 70, no. 12 (2005):1441-1450,
https://doi.org/10.2298/JSC0512441P . .
7
6
5

Mechanochemical synthesis of gamma-Bi2O3

Poleti, Dejan; Karanović, Ljiljana; Zdujić, Miodrag; Jovalekić, Čedomir; Branković, Zorica

(Amsterdam : Elsevier, 2004)

TY  - JOUR
AU  - Poleti, Dejan
AU  - Karanović, Ljiljana
AU  - Zdujić, Miodrag
AU  - Jovalekić, Čedomir
AU  - Branković, Zorica
PY  - 2004
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5416
AB  - A series of gamma-Bi2O3 phases doped with Zn, Si, Pb and Fe was prepared by mechanochemical treatment of corresponding oxide mixtures with a nominal composition 6Bi(2)O(3) (.) MOx (MOx = ZnO, SiO2, PbO) and 12Bi(2)O(3) (.) Fe2O3 using high-energy ball mill. The products are characterized by X-ray powder diffraction technique. Influence of milling conditions: milling time from 5 min to 10 h, milling medium (steel or ZrO2) and injected mechanical power on unit-cell parameters and crystallinity of products, as well as on reaction kinetics are investigated and discussed.
PB  - Amsterdam : Elsevier
T2  - Solid State Sciences
T1  - Mechanochemical synthesis of gamma-Bi2O3
EP  - 245
IS  - 3
SP  - 239
VL  - 6
DO  - 10.1016/j.solidstatesciences.2003.12.003
UR  - https://hdl.handle.net/21.15107/rcub_dais_12880
ER  - 
@article{
author = "Poleti, Dejan and Karanović, Ljiljana and Zdujić, Miodrag and Jovalekić, Čedomir and Branković, Zorica",
year = "2004",
abstract = "A series of gamma-Bi2O3 phases doped with Zn, Si, Pb and Fe was prepared by mechanochemical treatment of corresponding oxide mixtures with a nominal composition 6Bi(2)O(3) (.) MOx (MOx = ZnO, SiO2, PbO) and 12Bi(2)O(3) (.) Fe2O3 using high-energy ball mill. The products are characterized by X-ray powder diffraction technique. Influence of milling conditions: milling time from 5 min to 10 h, milling medium (steel or ZrO2) and injected mechanical power on unit-cell parameters and crystallinity of products, as well as on reaction kinetics are investigated and discussed.",
publisher = "Amsterdam : Elsevier",
journal = "Solid State Sciences",
title = "Mechanochemical synthesis of gamma-Bi2O3",
pages = "245-239",
number = "3",
volume = "6",
doi = "10.1016/j.solidstatesciences.2003.12.003",
url = "https://hdl.handle.net/21.15107/rcub_dais_12880"
}
Poleti, D., Karanović, L., Zdujić, M., Jovalekić, Č.,& Branković, Z.. (2004). Mechanochemical synthesis of gamma-Bi2O3. in Solid State Sciences
Amsterdam : Elsevier., 6(3), 239-245.
https://doi.org/10.1016/j.solidstatesciences.2003.12.003
https://hdl.handle.net/21.15107/rcub_dais_12880
Poleti D, Karanović L, Zdujić M, Jovalekić Č, Branković Z. Mechanochemical synthesis of gamma-Bi2O3. in Solid State Sciences. 2004;6(3):239-245.
doi:10.1016/j.solidstatesciences.2003.12.003
https://hdl.handle.net/21.15107/rcub_dais_12880 .
Poleti, Dejan, Karanović, Ljiljana, Zdujić, Miodrag, Jovalekić, Čedomir, Branković, Zorica, "Mechanochemical synthesis of gamma-Bi2O3" in Solid State Sciences, 6, no. 3 (2004):239-245,
https://doi.org/10.1016/j.solidstatesciences.2003.12.003 .,
https://hdl.handle.net/21.15107/rcub_dais_12880 .
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Crystal structure of a new zigzag chain Cu(II) complex with terephthalato and 1,10-phenonthroline ligands, [Cu(C8H4O4)(C12H8N2)(H2O)]n

Rogan, Jelena; Poleti, Dejan; Karanović, Ljiljana

(Serbian Chemical Society, 2004)

TY  - JOUR
AU  - Rogan, Jelena
AU  - Poleti, Dejan
AU  - Karanović, Ljiljana
PY  - 2004
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/611
AB  - X-Ray crystal structure analysis of the complex [Cu(tpth)(phen)(H2O)]n, where tpht is the dianion of terephthalic acid and phen is 1,10-phenanthroline showed that two crystallographically different, but chemically identical tpht ions with monodentately coordinated COO groups exist; both tpht ions act as bridging ligands forming zigzag chains. The Cu(II) ions are in a deformed trigonal bipyramidal environment consisting of two N atoms from phen, two O atoms from different tpht ligands and one O atom from coordinated H2O molecule. The crystal data are as follows: C20H14CuN2O5, Mr = 425.87 triclinic system, space group P 1, a = 9.007(5), b = 10.557(5), c = 11.554(5) Å, α= 114.343(5), β = 92.942(5), γ = 114.516(5) º, V = 877.3(7) Å3, Z = 2 F(000) = 434, ρx = 1.612 g cm-3, μ = 1.281 mm-1, R1 = 0.0280 for 4363 reflections with I  gt  2σ(I), wR2 = 0.0785 for 5104 independent reflections and 254 refined parameters. Some of data were compared with isostructural Co(II) and Zn(II) complexes having the same ligands.
AB  - Rendgenska strukturna analiza kompleksa [Cu(tpht)(phen)(H2O)]n, gde je tpht anjon tereftalne kiseline i phen je 1,10-fenantrolin, pokazala je da postoje dva kristalografski nezavisna, a hemijski identična tpht-jona, sa monodentatno koordiniranim COO-grupama; oba tpht-jona ponašaju se kao mostovni ligandi formirajući cik-cak lance. Cu(II)-joni su u deformisanom trigonalno-bipiramidalnom okruženju koje čine dva atoma N iz phen, dva atoma O iz različitih tpht-liganada i jedan atom O iz koordiniranog molekula H2O. Kristalografski podaci su sledeći: C20H14CuN2O5, Mr = 425,87, triklinični sistem, prostorna grupa P 1, a = 9,007(5), b = 10,557(5), c = 11,554(5) Å, α = 114,343(5), β = 92,942(5), γ = 114,516(5) º, V = 877,3(7) Å3, Z = 2, F(000) = 434, ρx = 1,612 g cm-3, μ = 1,281 mm-1, R1 = 0,0280 za 4363 refleksija sa I  gt  2 σ(I), wR2 = 0,0785 za 5104 nezavisnih refleksija i 254 utačnjavana parametra. Neki podaci su upoređeni sa izostrukturnim Co(II) i Zn(II) kompleksima sa istim ligandima.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Crystal structure of a new zigzag chain Cu(II) complex with terephthalato and 1,10-phenonthroline ligands, [Cu(C8H4O4)(C12H8N2)(H2O)]n
T1  - Kristalna struktura novog Lančastog cik-cak Cu(II) kompleksa sa tereftalato i 1,10-fenantrolin ligandima, [Cu(C8H4O4)(C12H8N2)(H2O)]n
EP  - 362
IS  - 5
SP  - 353
VL  - 69
DO  - 10.2298/JSC0405353R
UR  - https://hdl.handle.net/21.15107/rcub_technorep_611
ER  - 
@article{
author = "Rogan, Jelena and Poleti, Dejan and Karanović, Ljiljana",
year = "2004",
abstract = "X-Ray crystal structure analysis of the complex [Cu(tpth)(phen)(H2O)]n, where tpht is the dianion of terephthalic acid and phen is 1,10-phenanthroline showed that two crystallographically different, but chemically identical tpht ions with monodentately coordinated COO groups exist; both tpht ions act as bridging ligands forming zigzag chains. The Cu(II) ions are in a deformed trigonal bipyramidal environment consisting of two N atoms from phen, two O atoms from different tpht ligands and one O atom from coordinated H2O molecule. The crystal data are as follows: C20H14CuN2O5, Mr = 425.87 triclinic system, space group P 1, a = 9.007(5), b = 10.557(5), c = 11.554(5) Å, α= 114.343(5), β = 92.942(5), γ = 114.516(5) º, V = 877.3(7) Å3, Z = 2 F(000) = 434, ρx = 1.612 g cm-3, μ = 1.281 mm-1, R1 = 0.0280 for 4363 reflections with I  gt  2σ(I), wR2 = 0.0785 for 5104 independent reflections and 254 refined parameters. Some of data were compared with isostructural Co(II) and Zn(II) complexes having the same ligands., Rendgenska strukturna analiza kompleksa [Cu(tpht)(phen)(H2O)]n, gde je tpht anjon tereftalne kiseline i phen je 1,10-fenantrolin, pokazala je da postoje dva kristalografski nezavisna, a hemijski identična tpht-jona, sa monodentatno koordiniranim COO-grupama; oba tpht-jona ponašaju se kao mostovni ligandi formirajući cik-cak lance. Cu(II)-joni su u deformisanom trigonalno-bipiramidalnom okruženju koje čine dva atoma N iz phen, dva atoma O iz različitih tpht-liganada i jedan atom O iz koordiniranog molekula H2O. Kristalografski podaci su sledeći: C20H14CuN2O5, Mr = 425,87, triklinični sistem, prostorna grupa P 1, a = 9,007(5), b = 10,557(5), c = 11,554(5) Å, α = 114,343(5), β = 92,942(5), γ = 114,516(5) º, V = 877,3(7) Å3, Z = 2, F(000) = 434, ρx = 1,612 g cm-3, μ = 1,281 mm-1, R1 = 0,0280 za 4363 refleksija sa I  gt  2 σ(I), wR2 = 0,0785 za 5104 nezavisnih refleksija i 254 utačnjavana parametra. Neki podaci su upoređeni sa izostrukturnim Co(II) i Zn(II) kompleksima sa istim ligandima.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Crystal structure of a new zigzag chain Cu(II) complex with terephthalato and 1,10-phenonthroline ligands, [Cu(C8H4O4)(C12H8N2)(H2O)]n, Kristalna struktura novog Lančastog cik-cak Cu(II) kompleksa sa tereftalato i 1,10-fenantrolin ligandima, [Cu(C8H4O4)(C12H8N2)(H2O)]n",
pages = "362-353",
number = "5",
volume = "69",
doi = "10.2298/JSC0405353R",
url = "https://hdl.handle.net/21.15107/rcub_technorep_611"
}
Rogan, J., Poleti, D.,& Karanović, L.. (2004). Crystal structure of a new zigzag chain Cu(II) complex with terephthalato and 1,10-phenonthroline ligands, [Cu(C8H4O4)(C12H8N2)(H2O)]n. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 69(5), 353-362.
https://doi.org/10.2298/JSC0405353R
https://hdl.handle.net/21.15107/rcub_technorep_611
Rogan J, Poleti D, Karanović L. Crystal structure of a new zigzag chain Cu(II) complex with terephthalato and 1,10-phenonthroline ligands, [Cu(C8H4O4)(C12H8N2)(H2O)]n. in Journal of the Serbian Chemical Society. 2004;69(5):353-362.
doi:10.2298/JSC0405353R
https://hdl.handle.net/21.15107/rcub_technorep_611 .
Rogan, Jelena, Poleti, Dejan, Karanović, Ljiljana, "Crystal structure of a new zigzag chain Cu(II) complex with terephthalato and 1,10-phenonthroline ligands, [Cu(C8H4O4)(C12H8N2)(H2O)]n" in Journal of the Serbian Chemical Society, 69, no. 5 (2004):353-362,
https://doi.org/10.2298/JSC0405353R .,
https://hdl.handle.net/21.15107/rcub_technorep_611 .
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9
9

Comparison of two polymeric transition metal complexes with 1,4-benzenedicarboxylate ions as bridging ligands, [Co(C8H4O4)(C12H8N2)(H2O)] and [Cu(C8H4O4)(C10H9N3)] center dot H2O

Karanović, Ljiljana; Poleti, Dejan; Rogan, Jelena; Bogdanović, Goran A.; Spasojević-de Bire, Anne

(Int Union Crystallography, Chester, 2002)

TY  - JOUR
AU  - Karanović, Ljiljana
AU  - Poleti, Dejan
AU  - Rogan, Jelena
AU  - Bogdanović, Goran A.
AU  - Spasojević-de Bire, Anne
PY  - 2002
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/437
AB  - The title complexes, catena-poly[[aqua(1,10-phenanthroline- kappa(2)N,N')cobalt(II)]-mu-benzene-1,4-dicarboxylato-kappa(2)O(1):O-4], [Co(C8H4O4)(C12H8N2)(H2O)], (I), and catena-poly[[[(di-2-pyridyl-kappaN-amine)copper(II)]-mu-benzene-1,4-dicarboxylato- kappa(4)O(1), O-1' :O-4,O-4'] hydrate], [Cu(C8H4O4)(C10H9N3)].H2O, (II), take the form of zigzag chains, with the 1,4-benzenedicarboxylate ion acting as an amphimonodentate ligand in (I) and a bis-bidentate ligand in (II). The Co-II ion in (I) is five-coordinate and has a distorted trigonal-bipyramidal geometry. The Cu-II ion in (II) is in a very distorted octahedral 4+2 environment, with the octahedron elongated along the trans O-Cu-O bonds and with a trans O-Cu-O angle of only 137.22 (8)degrees.
PB  - Int Union Crystallography, Chester
T2  - Acta Crystallographica Section C-Structural Chemistry
T1  - Comparison of two polymeric transition metal complexes with 1,4-benzenedicarboxylate ions as bridging ligands, [Co(C8H4O4)(C12H8N2)(H2O)] and [Cu(C8H4O4)(C10H9N3)] center dot H2O
EP  - m279
SP  - m275
VL  - 58
DO  - 10.1107/S0108270102004341
ER  - 
@article{
author = "Karanović, Ljiljana and Poleti, Dejan and Rogan, Jelena and Bogdanović, Goran A. and Spasojević-de Bire, Anne",
year = "2002",
abstract = "The title complexes, catena-poly[[aqua(1,10-phenanthroline- kappa(2)N,N')cobalt(II)]-mu-benzene-1,4-dicarboxylato-kappa(2)O(1):O-4], [Co(C8H4O4)(C12H8N2)(H2O)], (I), and catena-poly[[[(di-2-pyridyl-kappaN-amine)copper(II)]-mu-benzene-1,4-dicarboxylato- kappa(4)O(1), O-1' :O-4,O-4'] hydrate], [Cu(C8H4O4)(C10H9N3)].H2O, (II), take the form of zigzag chains, with the 1,4-benzenedicarboxylate ion acting as an amphimonodentate ligand in (I) and a bis-bidentate ligand in (II). The Co-II ion in (I) is five-coordinate and has a distorted trigonal-bipyramidal geometry. The Cu-II ion in (II) is in a very distorted octahedral 4+2 environment, with the octahedron elongated along the trans O-Cu-O bonds and with a trans O-Cu-O angle of only 137.22 (8)degrees.",
publisher = "Int Union Crystallography, Chester",
journal = "Acta Crystallographica Section C-Structural Chemistry",
title = "Comparison of two polymeric transition metal complexes with 1,4-benzenedicarboxylate ions as bridging ligands, [Co(C8H4O4)(C12H8N2)(H2O)] and [Cu(C8H4O4)(C10H9N3)] center dot H2O",
pages = "m279-m275",
volume = "58",
doi = "10.1107/S0108270102004341"
}
Karanović, L., Poleti, D., Rogan, J., Bogdanović, G. A.,& Spasojević-de Bire, A.. (2002). Comparison of two polymeric transition metal complexes with 1,4-benzenedicarboxylate ions as bridging ligands, [Co(C8H4O4)(C12H8N2)(H2O)] and [Cu(C8H4O4)(C10H9N3)] center dot H2O. in Acta Crystallographica Section C-Structural Chemistry
Int Union Crystallography, Chester., 58, m275-m279.
https://doi.org/10.1107/S0108270102004341
Karanović L, Poleti D, Rogan J, Bogdanović GA, Spasojević-de Bire A. Comparison of two polymeric transition metal complexes with 1,4-benzenedicarboxylate ions as bridging ligands, [Co(C8H4O4)(C12H8N2)(H2O)] and [Cu(C8H4O4)(C10H9N3)] center dot H2O. in Acta Crystallographica Section C-Structural Chemistry. 2002;58:m275-m279.
doi:10.1107/S0108270102004341 .
Karanović, Ljiljana, Poleti, Dejan, Rogan, Jelena, Bogdanović, Goran A., Spasojević-de Bire, Anne, "Comparison of two polymeric transition metal complexes with 1,4-benzenedicarboxylate ions as bridging ligands, [Co(C8H4O4)(C12H8N2)(H2O)] and [Cu(C8H4O4)(C10H9N3)] center dot H2O" in Acta Crystallographica Section C-Structural Chemistry, 58 (2002):m275-m279,
https://doi.org/10.1107/S0108270102004341 . .
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