TY  - JOUR
AU  - Tadić, Tamara
AU  - Marković, Bojana
AU  - Radulović, Jelena
AU  - Lukić, Jelena
AU  - Suručić, Ljiljana
AU  - Nastasović, Aleksandra
AU  - Onjia, Antonije
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5200
AB  - A core-shell amino-functionalized glycidyl methacrylate magnetic molecularly imprinted polymer (MIP) was synthesized by the suspension polymerization/surface imprinting method and characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), mercury porosimetry, nitrogen gas adsorption–desorption, and elemental analysis. This MIP was used as the sorbent in dispersive solid-phase microextraction (DSPME) of aniline from textile wastewater prior to high-performance liquid chromatography-mass spectrometry (HPLC-MS) measurements. Since aniline is toxic and a probable human carcinogen, its determination in water is of great significance. This is a challenging task because aniline is usually present at trace levels. The effects of different DSPME variables on the preconcentration efficiency have been studied by using the Plackett–Burman screening design of experiments (DoE) followed by response surface methodology optimization using the Box-Behnken design. Thus, DoE enabled the investigation of several variables simultaneously. Under optimized conditions, aniline was effectively and selectively separated by a small amount of the DSPME sorbent and detected in real textile wastewater samples. The method detection limit of 1 ng mL−1 was attained, with good method linearity and acceptable recovery and precision. The results showed that the studied MIP could be a reliable DSPME sorbent for efficiently analyzing trace aniline in real wastewater samples.
PB  - MDPI
T2  - Sustainability (Switzerland)
T1  - A Core-Shell Amino-Functionalized Magnetic Molecularly Imprinted Polymer Based on Glycidyl Methacrylate for Dispersive Solid-Phase Microextraction of Aniline
IS  - 15
SP  - 9222
VL  - 14
DO  - 10.3390/su14159222
ER  - 

@article{
author = "Tadić, Tamara and Marković, Bojana and Radulović, Jelena and Lukić, Jelena and Suručić, Ljiljana and Nastasović, Aleksandra and Onjia, Antonije",
year = "2022",
abstract = "A core-shell amino-functionalized glycidyl methacrylate magnetic molecularly imprinted polymer (MIP) was synthesized by the suspension polymerization/surface imprinting method and characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), mercury porosimetry, nitrogen gas adsorption–desorption, and elemental analysis. This MIP was used as the sorbent in dispersive solid-phase microextraction (DSPME) of aniline from textile wastewater prior to high-performance liquid chromatography-mass spectrometry (HPLC-MS) measurements. Since aniline is toxic and a probable human carcinogen, its determination in water is of great significance. This is a challenging task because aniline is usually present at trace levels. The effects of different DSPME variables on the preconcentration efficiency have been studied by using the Plackett–Burman screening design of experiments (DoE) followed by response surface methodology optimization using the Box-Behnken design. Thus, DoE enabled the investigation of several variables simultaneously. Under optimized conditions, aniline was effectively and selectively separated by a small amount of the DSPME sorbent and detected in real textile wastewater samples. The method detection limit of 1 ng mL−1 was attained, with good method linearity and acceptable recovery and precision. The results showed that the studied MIP could be a reliable DSPME sorbent for efficiently analyzing trace aniline in real wastewater samples.",
publisher = "MDPI",
journal = "Sustainability (Switzerland)",
title = "A Core-Shell Amino-Functionalized Magnetic Molecularly Imprinted Polymer Based on Glycidyl Methacrylate for Dispersive Solid-Phase Microextraction of Aniline",
number = "15",
pages = "9222",
volume = "14",
doi = "10.3390/su14159222"
}

Tadić, T., Marković, B., Radulović, J., Lukić, J., Suručić, L., Nastasović, A.,& Onjia, A.. (2022). A Core-Shell Amino-Functionalized Magnetic Molecularly Imprinted Polymer Based on Glycidyl Methacrylate for Dispersive Solid-Phase Microextraction of Aniline. in Sustainability (Switzerland)
MDPI., 14(15), 9222.
https://doi.org/10.3390/su14159222

Tadić T, Marković B, Radulović J, Lukić J, Suručić L, Nastasović A, Onjia A. A Core-Shell Amino-Functionalized Magnetic Molecularly Imprinted Polymer Based on Glycidyl Methacrylate for Dispersive Solid-Phase Microextraction of Aniline. in Sustainability (Switzerland). 2022;14(15):9222.
doi:10.3390/su14159222 .

Tadić, Tamara, Marković, Bojana, Radulović, Jelena, Lukić, Jelena, Suručić, Ljiljana, Nastasović, Aleksandra, Onjia, Antonije, "A Core-Shell Amino-Functionalized Magnetic Molecularly Imprinted Polymer Based on Glycidyl Methacrylate for Dispersive Solid-Phase Microextraction of Aniline" in Sustainability (Switzerland), 14, no. 15 (2022):9222,
https://doi.org/10.3390/su14159222 . .

TY  - JOUR
AU  - Nastasović, Aleksandra
AU  - Marković, Bojana
AU  - Suručić, Ljiljana
AU  - Onjia, Antonije
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5129
AB  - The industrialization and urbanization expansion have increased the demand for precious and rare earth elements (REEs). In addition, environmental concerns regarding the toxic effects of heavy metals on living organisms imposed an urgent need for efficient methods for their removal from wastewaters and aqueous solutions. The most efficient technique for metal ions removal from wastewaters is adsorption due to its reversibility and high efficiency. Numerous adsorbents were mentioned as possible metal ions adsorbents in the literature. Chelating polymer ligands (CPLs) with adaptable surface chemistry, high affinity towards targeted metal ions, high capacity, fast kinetics, chemically stable, and reusable are especially attractive. This review is focused on methacrylatebased magnetic and non-magnetic porous sorbents. Special attention was devoted to amino-modified glycidyl methacrylate (GMA) copolymers. Main adsorption parameters, kinetic models, adsorption isotherms, thermodynamics of the adsorption process, as well as regeneration of the polymeric sorbents were discussed.
PB  - MDPI
T2  - Metals
T1  - Methacrylate-Based Polymeric Sorbents for Recovery of Metals from Aqueous Solutions
IS  - 5
SP  - 814
VL  - 12
DO  - 10.3390/met12050814
ER  - 

@article{
author = "Nastasović, Aleksandra and Marković, Bojana and Suručić, Ljiljana and Onjia, Antonije",
year = "2022",
abstract = "The industrialization and urbanization expansion have increased the demand for precious and rare earth elements (REEs). In addition, environmental concerns regarding the toxic effects of heavy metals on living organisms imposed an urgent need for efficient methods for their removal from wastewaters and aqueous solutions. The most efficient technique for metal ions removal from wastewaters is adsorption due to its reversibility and high efficiency. Numerous adsorbents were mentioned as possible metal ions adsorbents in the literature. Chelating polymer ligands (CPLs) with adaptable surface chemistry, high affinity towards targeted metal ions, high capacity, fast kinetics, chemically stable, and reusable are especially attractive. This review is focused on methacrylatebased magnetic and non-magnetic porous sorbents. Special attention was devoted to amino-modified glycidyl methacrylate (GMA) copolymers. Main adsorption parameters, kinetic models, adsorption isotherms, thermodynamics of the adsorption process, as well as regeneration of the polymeric sorbents were discussed.",
publisher = "MDPI",
journal = "Metals",
title = "Methacrylate-Based Polymeric Sorbents for Recovery of Metals from Aqueous Solutions",
number = "5",
pages = "814",
volume = "12",
doi = "10.3390/met12050814"
}

Nastasović, A., Marković, B., Suručić, L.,& Onjia, A.. (2022). Methacrylate-Based Polymeric Sorbents for Recovery of Metals from Aqueous Solutions. in Metals
MDPI., 12(5), 814.
https://doi.org/10.3390/met12050814

Nastasović A, Marković B, Suručić L, Onjia A. Methacrylate-Based Polymeric Sorbents for Recovery of Metals from Aqueous Solutions. in Metals. 2022;12(5):814.
doi:10.3390/met12050814 .

Nastasović, Aleksandra, Marković, Bojana, Suručić, Ljiljana, Onjia, Antonije, "Methacrylate-Based Polymeric Sorbents for Recovery of Metals from Aqueous Solutions" in Metals, 12, no. 5 (2022):814,
https://doi.org/10.3390/met12050814 . .

TY  - JOUR
AU  - Ekmeščić, Bojana
AU  - Maksin, Danijela
AU  - Marković, Jelena P.
AU  - Vuković, Zorica M.
AU  - Hercigonja, Radmila
AU  - Nastasović, Aleksandra
AU  - Onjia, Antonije
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4104
AB  - The presented study describes macroporous crosslinked poly(glycidyl methacrylateco-ethylene glycol dimethacrylate) [PGME] functionalized with diethylenetriamine [PGME-deta] as a potential recovery agent for Mo(VI) oxyanions from aqueous solutions. Sorption studies were carried out by varying experimental conditions (pH, time, concentration, temperature). Kinetics of Mo(VI) sorption was investigated in batch (static) experiments, in the temperature range 298-343 K. Sorption dynamics data were fitted to seven chemical-reaction and particle-diffusion models. The kinetics studies showed that Mo(VI) sorption adhered to the pseudo-second-order model under all investigated operating conditions. The sorption kinetics was determined to be governed by both the intraparticle diffusion and the external film diffusion to a lesser extent. The temperature rise promotes the molybdate species removal, with the maximum experimental uptake capacity of 4.02 mmol g(-1) at 298 K, at the selected pH which is consistent with the predominance range of hydrolized polynuclear Mo(VI) forms and optimum electrostatic attraction.
PB  - Elsevier, Amsterdam
T2  - Arabian Journal of Chemistry
T1  - Recovery of molybdenum oxyanions using macroporous copolymer grafted with diethylenetriamine
EP  - 3638
IS  - 8
SP  - 3628
VL  - 12
DO  - 10.1016/j.arabjc.2015.11.010
ER  - 

@article{
author = "Ekmeščić, Bojana and Maksin, Danijela and Marković, Jelena P. and Vuković, Zorica M. and Hercigonja, Radmila and Nastasović, Aleksandra and Onjia, Antonije",
year = "2019",
abstract = "The presented study describes macroporous crosslinked poly(glycidyl methacrylateco-ethylene glycol dimethacrylate) [PGME] functionalized with diethylenetriamine [PGME-deta] as a potential recovery agent for Mo(VI) oxyanions from aqueous solutions. Sorption studies were carried out by varying experimental conditions (pH, time, concentration, temperature). Kinetics of Mo(VI) sorption was investigated in batch (static) experiments, in the temperature range 298-343 K. Sorption dynamics data were fitted to seven chemical-reaction and particle-diffusion models. The kinetics studies showed that Mo(VI) sorption adhered to the pseudo-second-order model under all investigated operating conditions. The sorption kinetics was determined to be governed by both the intraparticle diffusion and the external film diffusion to a lesser extent. The temperature rise promotes the molybdate species removal, with the maximum experimental uptake capacity of 4.02 mmol g(-1) at 298 K, at the selected pH which is consistent with the predominance range of hydrolized polynuclear Mo(VI) forms and optimum electrostatic attraction.",
publisher = "Elsevier, Amsterdam",
journal = "Arabian Journal of Chemistry",
title = "Recovery of molybdenum oxyanions using macroporous copolymer grafted with diethylenetriamine",
pages = "3638-3628",
number = "8",
volume = "12",
doi = "10.1016/j.arabjc.2015.11.010"
}

Ekmeščić, B., Maksin, D., Marković, J. P., Vuković, Z. M., Hercigonja, R., Nastasović, A.,& Onjia, A.. (2019). Recovery of molybdenum oxyanions using macroporous copolymer grafted with diethylenetriamine. in Arabian Journal of Chemistry
Elsevier, Amsterdam., 12(8), 3628-3638.
https://doi.org/10.1016/j.arabjc.2015.11.010

Ekmeščić B, Maksin D, Marković JP, Vuković ZM, Hercigonja R, Nastasović A, Onjia A. Recovery of molybdenum oxyanions using macroporous copolymer grafted with diethylenetriamine. in Arabian Journal of Chemistry. 2019;12(8):3628-3638.
doi:10.1016/j.arabjc.2015.11.010 .

Ekmeščić, Bojana, Maksin, Danijela, Marković, Jelena P., Vuković, Zorica M., Hercigonja, Radmila, Nastasović, Aleksandra, Onjia, Antonije, "Recovery of molybdenum oxyanions using macroporous copolymer grafted with diethylenetriamine" in Arabian Journal of Chemistry, 12, no. 8 (2019):3628-3638,
https://doi.org/10.1016/j.arabjc.2015.11.010 . .

TY  - JOUR
AU  - Marković, Bojana M.
AU  - Spasojević, Vojislav
AU  - Dapčević, Aleksandra
AU  - Vuković, Zorica M.
AU  - Pavlović, Vladimir B.
AU  - Ranđelović, Danijela
AU  - Nastasović, Aleksandra
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4179
AB  - Magnetic and non-magnetic macroporous crosslinked copolymers of glycidyl methacrylate and trimethylolpropane trimethacrylate were prepared by suspension copolymerization and functionalized with diethylenetriamine. The samples were characterized by mercury porosimetry, scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), Fourier transform infrared spectroscopy analysis (FTIR-ATR), thermogravimetric analysis (TGA), X-ray diffractometry (XRD), atomic force microscopy (AFM), transmission electron microscopy (TEM) and SQUID magnetometry. The FTIR-ATR analysis of synthesized magnetic nanocomposites confirmed the presence of magnetite and successful aminofunctionalization. Non-functionalized and amino-functionalized nanocomposites exhibited superparamagnetic behavior at 300 K, with a saturation magnetization of 5.0 emu/g and 2.9 emu/g, respectively. TEM analysis of the magnetic nanocomposite has shown that magnetic nanoparticles were homogeneously dispersed in the polymer matrix. It was demonstrated that incorporation of magnetic nanoparticles enhanced the thermal stability of the magnetic nanocomposite in comparison to the initial non-magnetic macroporous copolymer.
PB  - Savez hemijskih inženjera, Beograd
T2  - Hemijska industrija
T1  - Characterization of glycidyl methacrylate based magnetic nanocomposites
EP  - 35
IS  - 1
SP  - 25
VL  - 73
DO  - 10.2298/HEMIND181113006M
ER  - 

@article{
author = "Marković, Bojana M. and Spasojević, Vojislav and Dapčević, Aleksandra and Vuković, Zorica M. and Pavlović, Vladimir B. and Ranđelović, Danijela and Nastasović, Aleksandra",
year = "2019",
abstract = "Magnetic and non-magnetic macroporous crosslinked copolymers of glycidyl methacrylate and trimethylolpropane trimethacrylate were prepared by suspension copolymerization and functionalized with diethylenetriamine. The samples were characterized by mercury porosimetry, scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), Fourier transform infrared spectroscopy analysis (FTIR-ATR), thermogravimetric analysis (TGA), X-ray diffractometry (XRD), atomic force microscopy (AFM), transmission electron microscopy (TEM) and SQUID magnetometry. The FTIR-ATR analysis of synthesized magnetic nanocomposites confirmed the presence of magnetite and successful aminofunctionalization. Non-functionalized and amino-functionalized nanocomposites exhibited superparamagnetic behavior at 300 K, with a saturation magnetization of 5.0 emu/g and 2.9 emu/g, respectively. TEM analysis of the magnetic nanocomposite has shown that magnetic nanoparticles were homogeneously dispersed in the polymer matrix. It was demonstrated that incorporation of magnetic nanoparticles enhanced the thermal stability of the magnetic nanocomposite in comparison to the initial non-magnetic macroporous copolymer.",
publisher = "Savez hemijskih inženjera, Beograd",
journal = "Hemijska industrija",
title = "Characterization of glycidyl methacrylate based magnetic nanocomposites",
pages = "35-25",
number = "1",
volume = "73",
doi = "10.2298/HEMIND181113006M"
}

Marković, B. M., Spasojević, V., Dapčević, A., Vuković, Z. M., Pavlović, V. B., Ranđelović, D.,& Nastasović, A.. (2019). Characterization of glycidyl methacrylate based magnetic nanocomposites. in Hemijska industrija
Savez hemijskih inženjera, Beograd., 73(1), 25-35.
https://doi.org/10.2298/HEMIND181113006M

Marković BM, Spasojević V, Dapčević A, Vuković ZM, Pavlović VB, Ranđelović D, Nastasović A. Characterization of glycidyl methacrylate based magnetic nanocomposites. in Hemijska industrija. 2019;73(1):25-35.
doi:10.2298/HEMIND181113006M .

Marković, Bojana M., Spasojević, Vojislav, Dapčević, Aleksandra, Vuković, Zorica M., Pavlović, Vladimir B., Ranđelović, Danijela, Nastasović, Aleksandra, "Characterization of glycidyl methacrylate based magnetic nanocomposites" in Hemijska industrija, 73, no. 1 (2019):25-35,
https://doi.org/10.2298/HEMIND181113006M . .

TY  - JOUR
AU  - Suručić, Ljiljana T.
AU  - Nastasović, Aleksandra
AU  - Rakić, Aleksandra
AU  - Onjia, Antonije
AU  - Popović, Aleksandar R.
AU  - Janjić, Goran
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4197
PB  - 5th World Congress on Mechanical, Chemical, and Material Engineering, MCM 2019
T2  - Proceedings of the World Congress on Mechanical, Chemical, and Material Engineering
T1  - Comparative study of W(VI) and Cr(VI) oxyanions binding ability with magnetic polymer nanocomposite
DO  - 10.11159/iccpe19.125
ER  - 

@article{
author = "Suručić, Ljiljana T. and Nastasović, Aleksandra and Rakić, Aleksandra and Onjia, Antonije and Popović, Aleksandar R. and Janjić, Goran",
year = "2019",
publisher = "5th World Congress on Mechanical, Chemical, and Material Engineering, MCM 2019",
journal = "Proceedings of the World Congress on Mechanical, Chemical, and Material Engineering",
title = "Comparative study of W(VI) and Cr(VI) oxyanions binding ability with magnetic polymer nanocomposite",
doi = "10.11159/iccpe19.125"
}

Suručić, L. T., Nastasović, A., Rakić, A., Onjia, A., Popović, A. R.,& Janjić, G.. (2019). Comparative study of W(VI) and Cr(VI) oxyanions binding ability with magnetic polymer nanocomposite. in Proceedings of the World Congress on Mechanical, Chemical, and Material Engineering
5th World Congress on Mechanical, Chemical, and Material Engineering, MCM 2019..
https://doi.org/10.11159/iccpe19.125

Suručić LT, Nastasović A, Rakić A, Onjia A, Popović AR, Janjić G. Comparative study of W(VI) and Cr(VI) oxyanions binding ability with magnetic polymer nanocomposite. in Proceedings of the World Congress on Mechanical, Chemical, and Material Engineering. 2019;.
doi:10.11159/iccpe19.125 .

Suručić, Ljiljana T., Nastasović, Aleksandra, Rakić, Aleksandra, Onjia, Antonije, Popović, Aleksandar R., Janjić, Goran, "Comparative study of W(VI) and Cr(VI) oxyanions binding ability with magnetic polymer nanocomposite" in Proceedings of the World Congress on Mechanical, Chemical, and Material Engineering (2019),
https://doi.org/10.11159/iccpe19.125 . .

TY  - JOUR
AU  - Suručić, Ljiljana T.
AU  - Janjić, Goran
AU  - Rakić, Aleksandra
AU  - Nastasović, Aleksandra
AU  - Popović, Aleksandar R.
AU  - Milčić, Miloš
AU  - Onjia, Antonije
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4217
AB  - With regard to the harmful effects of heavy metals on human health and the environment, the demand for synthesis and investigation of macromolecules with large capacity of harmful substances sorption is ever greater. Quantum-chemical methods may be applied in structural modeling, prediction, and characterization of such molecules and reactions. Sorption of metal ions (Cu2+, Cd2+, Co2+, and Ni2+) to triethylenetetramine-functionalized copolymer poly(GMA-co-EGDMA)-teta was successfully modeled by quantum chemical calculations, at the B3LYP//6-311++G**/lanl2dz level. Optimized structures of metal complexes were used for calculation of real binding energy of metal ion within the complex (Er). Solvent and hydrolyzation effects were essential for obtaining the objective values. Solvent effect was included in Er by using the total solvation energy for reaction of formation of tetaOH complex (Es1, the first approach) or by using dehydration energy of free metal ion (Es2, the second approach). Experimental results were confirmed in our theoretical analyses (using the second approach).
PB  - Springer, New York
T2  - Journal of Molecular Modeling
T1  - Theoretical modeling of sorption of metal ions on amino-functionalized macroporous copolymer in aqueous solution
IS  - 6
VL  - 25
DO  - 10.1007/s00894-019-4053-0
ER  - 

@article{
author = "Suručić, Ljiljana T. and Janjić, Goran and Rakić, Aleksandra and Nastasović, Aleksandra and Popović, Aleksandar R. and Milčić, Miloš and Onjia, Antonije",
year = "2019",
abstract = "With regard to the harmful effects of heavy metals on human health and the environment, the demand for synthesis and investigation of macromolecules with large capacity of harmful substances sorption is ever greater. Quantum-chemical methods may be applied in structural modeling, prediction, and characterization of such molecules and reactions. Sorption of metal ions (Cu2+, Cd2+, Co2+, and Ni2+) to triethylenetetramine-functionalized copolymer poly(GMA-co-EGDMA)-teta was successfully modeled by quantum chemical calculations, at the B3LYP//6-311++G**/lanl2dz level. Optimized structures of metal complexes were used for calculation of real binding energy of metal ion within the complex (Er). Solvent and hydrolyzation effects were essential for obtaining the objective values. Solvent effect was included in Er by using the total solvation energy for reaction of formation of tetaOH complex (Es1, the first approach) or by using dehydration energy of free metal ion (Es2, the second approach). Experimental results were confirmed in our theoretical analyses (using the second approach).",
publisher = "Springer, New York",
journal = "Journal of Molecular Modeling",
title = "Theoretical modeling of sorption of metal ions on amino-functionalized macroporous copolymer in aqueous solution",
number = "6",
volume = "25",
doi = "10.1007/s00894-019-4053-0"
}

Suručić, L. T., Janjić, G., Rakić, A., Nastasović, A., Popović, A. R., Milčić, M.,& Onjia, A.. (2019). Theoretical modeling of sorption of metal ions on amino-functionalized macroporous copolymer in aqueous solution. in Journal of Molecular Modeling
Springer, New York., 25(6).
https://doi.org/10.1007/s00894-019-4053-0

Suručić LT, Janjić G, Rakić A, Nastasović A, Popović AR, Milčić M, Onjia A. Theoretical modeling of sorption of metal ions on amino-functionalized macroporous copolymer in aqueous solution. in Journal of Molecular Modeling. 2019;25(6).
doi:10.1007/s00894-019-4053-0 .

Suručić, Ljiljana T., Janjić, Goran, Rakić, Aleksandra, Nastasović, Aleksandra, Popović, Aleksandar R., Milčić, Miloš, Onjia, Antonije, "Theoretical modeling of sorption of metal ions on amino-functionalized macroporous copolymer in aqueous solution" in Journal of Molecular Modeling, 25, no. 6 (2019),
https://doi.org/10.1007/s00894-019-4053-0 . .

TY  - JOUR
AU  - Suručić, Ljiljana T.
AU  - Nastasović, Aleksandra
AU  - Onjia, Antonije
AU  - Janjić, Goran
AU  - Rakić, Aleksandra
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4208
AB  - Polymer-based, highly porous nanocomposites with functionalized ligands attached to the core structure are extremely efficient in the detection, removal and recovery of metals through the process of sorption. Quantum-chemical models could be helpful for sorption process analyses. The sorption of Cu(II) ions by amino-functionalized chelating macroporous copolymers poly(GMA-co-EGDMA)-amine and sorption selectivity of the subject copolymers, ethylenediamine (en), diethylenetriamine (dien) and triethylenetetramine (trien), were successfully modelled by quantum chemical calculations. Considering the crystal structures from CSD and experimental conditions during the formation of metal complexes, the most frequent mononuclear complexes are those with the tetradentate teta ligand, while binuclear complexes are formed when the metal ion is in large excess. Although the en-copolymer was the most effective functionalized one, higher maximum sorption capacities (Q(max)) were observed for the dien- and trien-copolymers, due to their abilities to form binuclear complexes. The enthalpy term has the greatest contribution to the total Gibbs energy change of reaction for the formation of mononuclear Cu(II) complexes (Delta G(aq)), while the solvation energy of the reaction has the greatest contribution in the formation of binuclear complexes. The results of the study indicate that small amines with the ability to form binuclear complex are the best choice for functionalization of the considered copolymer.
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - Design of an amino-functionalized chelating macroporous copolymer poly(GMA-co-EGDMA) for the sorption of Cu(II) ions
EP  - 1404
IS  - 12
SP  - 1391
VL  - 84
DO  - 10.2298/JSC190125031S
ER  - 

@article{
author = "Suručić, Ljiljana T. and Nastasović, Aleksandra and Onjia, Antonije and Janjić, Goran and Rakić, Aleksandra",
year = "2019",
abstract = "Polymer-based, highly porous nanocomposites with functionalized ligands attached to the core structure are extremely efficient in the detection, removal and recovery of metals through the process of sorption. Quantum-chemical models could be helpful for sorption process analyses. The sorption of Cu(II) ions by amino-functionalized chelating macroporous copolymers poly(GMA-co-EGDMA)-amine and sorption selectivity of the subject copolymers, ethylenediamine (en), diethylenetriamine (dien) and triethylenetetramine (trien), were successfully modelled by quantum chemical calculations. Considering the crystal structures from CSD and experimental conditions during the formation of metal complexes, the most frequent mononuclear complexes are those with the tetradentate teta ligand, while binuclear complexes are formed when the metal ion is in large excess. Although the en-copolymer was the most effective functionalized one, higher maximum sorption capacities (Q(max)) were observed for the dien- and trien-copolymers, due to their abilities to form binuclear complexes. The enthalpy term has the greatest contribution to the total Gibbs energy change of reaction for the formation of mononuclear Cu(II) complexes (Delta G(aq)), while the solvation energy of the reaction has the greatest contribution in the formation of binuclear complexes. The results of the study indicate that small amines with the ability to form binuclear complex are the best choice for functionalization of the considered copolymer.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Design of an amino-functionalized chelating macroporous copolymer poly(GMA-co-EGDMA) for the sorption of Cu(II) ions",
pages = "1404-1391",
number = "12",
volume = "84",
doi = "10.2298/JSC190125031S"
}

Suručić, L. T., Nastasović, A., Onjia, A., Janjić, G.,& Rakić, A.. (2019). Design of an amino-functionalized chelating macroporous copolymer poly(GMA-co-EGDMA) for the sorption of Cu(II) ions. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 84(12), 1391-1404.
https://doi.org/10.2298/JSC190125031S

Suručić LT, Nastasović A, Onjia A, Janjić G, Rakić A. Design of an amino-functionalized chelating macroporous copolymer poly(GMA-co-EGDMA) for the sorption of Cu(II) ions. in Journal of the Serbian Chemical Society. 2019;84(12):1391-1404.
doi:10.2298/JSC190125031S .

Suručić, Ljiljana T., Nastasović, Aleksandra, Onjia, Antonije, Janjić, Goran, Rakić, Aleksandra, "Design of an amino-functionalized chelating macroporous copolymer poly(GMA-co-EGDMA) for the sorption of Cu(II) ions" in Journal of the Serbian Chemical Society, 84, no. 12 (2019):1391-1404,
https://doi.org/10.2298/JSC190125031S . .

TY  - JOUR
AU  - Marković, Bojana M.
AU  - Stefanović, Ivan
AU  - Hercigonja, Radmila
AU  - Pergal, Marija
AU  - Marković, Jelena P.
AU  - Onjia, Antonije
AU  - Nastasović, Aleksandra
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3753
AB  - Macroporous copolymers of poly[(glycidyl methacrylate)-co-(ethylene glycol dimethacrylate)] (PGME) with various crosslinker (ethylene glycol dimethacrylate) concentrations and porosity parameters and additionally functionalized with hexamethylene diamine (PGME-HD) were tested as potential Cr(VI) oxyanion sorbents from aqueous solutions. Kinetics of Cr(VI) sorption was investigated in the temperature range 298-343 K and the results were fitted to chemical reaction and particle diffusion models. The Cr(VI) sorption obeys the pseudo-second-order model with definite influence of pore diffusion. A temperature rise promotes chromium removal, with a maximum experimental uptake capacity of 4.21 mmol g(-1) at 343 K for the sample with the highest amino group concentration. Equilibrium data were analysed with Langmuir, Freundlich and Temkin adsorption isotherm models. Thermodynamic parameters, i.e. Gibbs free energy (G(0)), enthalpy (H-0) and entropy change (S-0) and activation energy of sorption (E-a), were calculated. The Cr(VI) adsorption onto PGME-HD was found to be spontaneous and endothermic, with increased randomness in the system. Desorption experiments show that chromium anion sorption was reversible and the PGME-HD sample GMA 60 HD was easily regenerated with 0.1 mol L-1 NaOH up to 90% recovery in the fourth sorption/desorption cycle. In the fifth cycle, a substantial sorption loss of 37% was observed.
PB  - Wiley, Hoboken
T2  - Polymer International
T1  - Novel hexamethylene diamine-functionalized macroporous copolymer for chromium removal from aqueous solutions
EP  - 689
IS  - 5
SP  - 679
VL  - 66
DO  - 10.1002/pi.5306
ER  - 

@article{
author = "Marković, Bojana M. and Stefanović, Ivan and Hercigonja, Radmila and Pergal, Marija and Marković, Jelena P. and Onjia, Antonije and Nastasović, Aleksandra",
year = "2017",
abstract = "Macroporous copolymers of poly[(glycidyl methacrylate)-co-(ethylene glycol dimethacrylate)] (PGME) with various crosslinker (ethylene glycol dimethacrylate) concentrations and porosity parameters and additionally functionalized with hexamethylene diamine (PGME-HD) were tested as potential Cr(VI) oxyanion sorbents from aqueous solutions. Kinetics of Cr(VI) sorption was investigated in the temperature range 298-343 K and the results were fitted to chemical reaction and particle diffusion models. The Cr(VI) sorption obeys the pseudo-second-order model with definite influence of pore diffusion. A temperature rise promotes chromium removal, with a maximum experimental uptake capacity of 4.21 mmol g(-1) at 343 K for the sample with the highest amino group concentration. Equilibrium data were analysed with Langmuir, Freundlich and Temkin adsorption isotherm models. Thermodynamic parameters, i.e. Gibbs free energy (G(0)), enthalpy (H-0) and entropy change (S-0) and activation energy of sorption (E-a), were calculated. The Cr(VI) adsorption onto PGME-HD was found to be spontaneous and endothermic, with increased randomness in the system. Desorption experiments show that chromium anion sorption was reversible and the PGME-HD sample GMA 60 HD was easily regenerated with 0.1 mol L-1 NaOH up to 90% recovery in the fourth sorption/desorption cycle. In the fifth cycle, a substantial sorption loss of 37% was observed.",
publisher = "Wiley, Hoboken",
journal = "Polymer International",
title = "Novel hexamethylene diamine-functionalized macroporous copolymer for chromium removal from aqueous solutions",
pages = "689-679",
number = "5",
volume = "66",
doi = "10.1002/pi.5306"
}

Marković, B. M., Stefanović, I., Hercigonja, R., Pergal, M., Marković, J. P., Onjia, A.,& Nastasović, A.. (2017). Novel hexamethylene diamine-functionalized macroporous copolymer for chromium removal from aqueous solutions. in Polymer International
Wiley, Hoboken., 66(5), 679-689.
https://doi.org/10.1002/pi.5306

Marković BM, Stefanović I, Hercigonja R, Pergal M, Marković JP, Onjia A, Nastasović A. Novel hexamethylene diamine-functionalized macroporous copolymer for chromium removal from aqueous solutions. in Polymer International. 2017;66(5):679-689.
doi:10.1002/pi.5306 .

Marković, Bojana M., Stefanović, Ivan, Hercigonja, Radmila, Pergal, Marija, Marković, Jelena P., Onjia, Antonije, Nastasović, Aleksandra, "Novel hexamethylene diamine-functionalized macroporous copolymer for chromium removal from aqueous solutions" in Polymer International, 66, no. 5 (2017):679-689,
https://doi.org/10.1002/pi.5306 . .

TY  - JOUR
AU  - Marković, Bojana M.
AU  - Vuković, Zorica M.
AU  - Spasojević, Vojislav
AU  - Kusigerski, Vladan
AU  - Pavlović, Vladimir B.
AU  - Onjia, Antonije
AU  - Nastasović, Aleksandra
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3752
AB  - Magnetic macroporous crosslinked copolymer glycidyl methacrylate (GMA) and ethylene glycol dimethacrylate (EGDMA) samples with different magnetite content were prepared by suspension copolymerization and functionalized with diethylene triamine. Samples were characterized by elemental analysis, mercury porosimetry, Fourier transform infrared spectroscopy (FTIR) analysis, scanning electron microscopy with energy-dispersive X-ray spectroscopy, transmission electron microscopy, SQUID magnetometry and X-ray photoelectron spectroscopy (XPS). The selected amino-functionalized sample was tested as a potential sorbent for the Mo(VI) and Re(VII) oxyanions from aqueous solutions. The influence of pH, ionic strength and possible interfering of cations and anions was investigated. Equilibrium data were analyzed with Langmuir, Freundlich and Tempkin adsorption isotherm models. Sorption studies were carried out in a batch competitive experiments, in the pH range 1-8, at 298 K. Obtained results indicate that 92% of Re(VII) and 98% of Mo(VI) were sorbed at pH 2.
PB  - Elsevier Science Sa, Lausanne
T2  - Journal of Alloys and Compounds
T1  - Selective magnetic GMA based potential sorbents for molybdenum and rhenium sorption
EP  - 50
SP  - 38
VL  - 705
DO  - 10.1016/j.jallcom.2017.02.108
ER  - 

@article{
author = "Marković, Bojana M. and Vuković, Zorica M. and Spasojević, Vojislav and Kusigerski, Vladan and Pavlović, Vladimir B. and Onjia, Antonije and Nastasović, Aleksandra",
year = "2017",
abstract = "Magnetic macroporous crosslinked copolymer glycidyl methacrylate (GMA) and ethylene glycol dimethacrylate (EGDMA) samples with different magnetite content were prepared by suspension copolymerization and functionalized with diethylene triamine. Samples were characterized by elemental analysis, mercury porosimetry, Fourier transform infrared spectroscopy (FTIR) analysis, scanning electron microscopy with energy-dispersive X-ray spectroscopy, transmission electron microscopy, SQUID magnetometry and X-ray photoelectron spectroscopy (XPS). The selected amino-functionalized sample was tested as a potential sorbent for the Mo(VI) and Re(VII) oxyanions from aqueous solutions. The influence of pH, ionic strength and possible interfering of cations and anions was investigated. Equilibrium data were analyzed with Langmuir, Freundlich and Tempkin adsorption isotherm models. Sorption studies were carried out in a batch competitive experiments, in the pH range 1-8, at 298 K. Obtained results indicate that 92% of Re(VII) and 98% of Mo(VI) were sorbed at pH 2.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Journal of Alloys and Compounds",
title = "Selective magnetic GMA based potential sorbents for molybdenum and rhenium sorption",
pages = "50-38",
volume = "705",
doi = "10.1016/j.jallcom.2017.02.108"
}

Marković, B. M., Vuković, Z. M., Spasojević, V., Kusigerski, V., Pavlović, V. B., Onjia, A.,& Nastasović, A.. (2017). Selective magnetic GMA based potential sorbents for molybdenum and rhenium sorption. in Journal of Alloys and Compounds
Elsevier Science Sa, Lausanne., 705, 38-50.
https://doi.org/10.1016/j.jallcom.2017.02.108

Marković BM, Vuković ZM, Spasojević V, Kusigerski V, Pavlović VB, Onjia A, Nastasović A. Selective magnetic GMA based potential sorbents for molybdenum and rhenium sorption. in Journal of Alloys and Compounds. 2017;705:38-50.
doi:10.1016/j.jallcom.2017.02.108 .

Marković, Bojana M., Vuković, Zorica M., Spasojević, Vojislav, Kusigerski, Vladan, Pavlović, Vladimir B., Onjia, Antonije, Nastasović, Aleksandra, "Selective magnetic GMA based potential sorbents for molybdenum and rhenium sorption" in Journal of Alloys and Compounds, 705 (2017):38-50,
https://doi.org/10.1016/j.jallcom.2017.02.108 . .

TY  - JOUR
AU  - Tomković, Tanja
AU  - Radovanović, Filip
AU  - Grgur, Branimir
AU  - Nastasović, Aleksandra
AU  - Vasiljević-Radović, Dana
AU  - Onjia, Antonije
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3255
AB  - A novel method combining a traditional immersion precipitation process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution was used to prepare asymmetric polyethersulfone membranes with submicron particles incorporating glycidyl methacrylate copolymer. In order to introduce sulfonic groups, the epoxide rings of glycidyl methacrylate were opened using two methods. The first method was functionalization with sodium sulfite, and the second was functionalization with sulfuric acid and then grafting with 2-acrylamido-2-methylpropanesulfonic acid. The obtained membranes were characterized using infrared spectroscopy, conductometric titration and water permeability measurements. Scanning electron microscopy and atomic force microscopy were used to investigate the surface morphology and topology of the membranes. Dynamic adsorption of rhodamine B as a model dye was used to demonstrate the suitability of these novel membranes for membrane adsorption since the adsorption capacity for dye cations was much better for the membranes functionalized with sodium sulfite and the membranes grafted with 2-acrylamido-2-methylpropanesulfonic acid compared to the non-functionalized membranes.
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - Novel negatively charged membrane adsorbers made using a combination of photopolymerization and immersion precipitation
EP  - 431
IS  - 4
SP  - 419
VL  - 81
DO  - 10.2298/JSC150805083T
ER  - 

@article{
author = "Tomković, Tanja and Radovanović, Filip and Grgur, Branimir and Nastasović, Aleksandra and Vasiljević-Radović, Dana and Onjia, Antonije",
year = "2016",
abstract = "A novel method combining a traditional immersion precipitation process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution was used to prepare asymmetric polyethersulfone membranes with submicron particles incorporating glycidyl methacrylate copolymer. In order to introduce sulfonic groups, the epoxide rings of glycidyl methacrylate were opened using two methods. The first method was functionalization with sodium sulfite, and the second was functionalization with sulfuric acid and then grafting with 2-acrylamido-2-methylpropanesulfonic acid. The obtained membranes were characterized using infrared spectroscopy, conductometric titration and water permeability measurements. Scanning electron microscopy and atomic force microscopy were used to investigate the surface morphology and topology of the membranes. Dynamic adsorption of rhodamine B as a model dye was used to demonstrate the suitability of these novel membranes for membrane adsorption since the adsorption capacity for dye cations was much better for the membranes functionalized with sodium sulfite and the membranes grafted with 2-acrylamido-2-methylpropanesulfonic acid compared to the non-functionalized membranes.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Novel negatively charged membrane adsorbers made using a combination of photopolymerization and immersion precipitation",
pages = "431-419",
number = "4",
volume = "81",
doi = "10.2298/JSC150805083T"
}

Tomković, T., Radovanović, F., Grgur, B., Nastasović, A., Vasiljević-Radović, D.,& Onjia, A.. (2016). Novel negatively charged membrane adsorbers made using a combination of photopolymerization and immersion precipitation. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 81(4), 419-431.
https://doi.org/10.2298/JSC150805083T

Tomković T, Radovanović F, Grgur B, Nastasović A, Vasiljević-Radović D, Onjia A. Novel negatively charged membrane adsorbers made using a combination of photopolymerization and immersion precipitation. in Journal of the Serbian Chemical Society. 2016;81(4):419-431.
doi:10.2298/JSC150805083T .

Tomković, Tanja, Radovanović, Filip, Grgur, Branimir, Nastasović, Aleksandra, Vasiljević-Radović, Dana, Onjia, Antonije, "Novel negatively charged membrane adsorbers made using a combination of photopolymerization and immersion precipitation" in Journal of the Serbian Chemical Society, 81, no. 4 (2016):419-431,
https://doi.org/10.2298/JSC150805083T . .

TY  - JOUR
AU  - Nastasović, Aleksandra
AU  - Ekmeščić, Bojana
AU  - Sandić, Zvjezdana P.
AU  - Ranđelović, Danijela
AU  - Mozetić, Miran
AU  - Vesel, Alenka
AU  - Onjia, Antonije
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3230
AB  - The mechanism of Cu(II), Cd(II) and Pb(II) ions sorption from aqueous solutions by macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) (PGME) functionalized by reaction of the pendant epoxy groups with diethylene triamine (PGME-deta) was studied using X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) analysis. Atomic force microscopy (AFM) and scanning energy-dispersive X-ray spectroscopy (SEM-EDX) were used for the determination of surface morphology of the copolymer particles. The sorption behavior of heavy metals Cu(II), Cd(II) and Pb(II) ions sorption was investigated in batch static experiments under non-competitive conditions at room temperature (298 K). The obtained results were fitted to pseudo-first order, pseudo-second order and intraparticle diffusion kinetic model. The kinetics studies showed that Cu(II), Cd(II) and Pb(II) sorption obeys the pseudo-second-order model under all investigated operating conditions with evident influence of pore diffusion.
PB  - Elsevier Science Bv, Amsterdam
T2  - Applied Surface Science
T1  - Mechanism of Cu(II), Cd(II) and Pb(II) ions sorption from aqueous solutions by macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate)
EP  - 615
SP  - 605
VL  - 385
DO  - 10.1016/j.apsusc.2016.05.165
ER  - 

@article{
author = "Nastasović, Aleksandra and Ekmeščić, Bojana and Sandić, Zvjezdana P. and Ranđelović, Danijela and Mozetić, Miran and Vesel, Alenka and Onjia, Antonije",
year = "2016",
abstract = "The mechanism of Cu(II), Cd(II) and Pb(II) ions sorption from aqueous solutions by macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) (PGME) functionalized by reaction of the pendant epoxy groups with diethylene triamine (PGME-deta) was studied using X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) analysis. Atomic force microscopy (AFM) and scanning energy-dispersive X-ray spectroscopy (SEM-EDX) were used for the determination of surface morphology of the copolymer particles. The sorption behavior of heavy metals Cu(II), Cd(II) and Pb(II) ions sorption was investigated in batch static experiments under non-competitive conditions at room temperature (298 K). The obtained results were fitted to pseudo-first order, pseudo-second order and intraparticle diffusion kinetic model. The kinetics studies showed that Cu(II), Cd(II) and Pb(II) sorption obeys the pseudo-second-order model under all investigated operating conditions with evident influence of pore diffusion.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Applied Surface Science",
title = "Mechanism of Cu(II), Cd(II) and Pb(II) ions sorption from aqueous solutions by macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate)",
pages = "615-605",
volume = "385",
doi = "10.1016/j.apsusc.2016.05.165"
}

Nastasović, A., Ekmeščić, B., Sandić, Z. P., Ranđelović, D., Mozetić, M., Vesel, A.,& Onjia, A.. (2016). Mechanism of Cu(II), Cd(II) and Pb(II) ions sorption from aqueous solutions by macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate). in Applied Surface Science
Elsevier Science Bv, Amsterdam., 385, 605-615.
https://doi.org/10.1016/j.apsusc.2016.05.165

Nastasović A, Ekmeščić B, Sandić ZP, Ranđelović D, Mozetić M, Vesel A, Onjia A. Mechanism of Cu(II), Cd(II) and Pb(II) ions sorption from aqueous solutions by macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate). in Applied Surface Science. 2016;385:605-615.
doi:10.1016/j.apsusc.2016.05.165 .

Nastasović, Aleksandra, Ekmeščić, Bojana, Sandić, Zvjezdana P., Ranđelović, Danijela, Mozetić, Miran, Vesel, Alenka, Onjia, Antonije, "Mechanism of Cu(II), Cd(II) and Pb(II) ions sorption from aqueous solutions by macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate)" in Applied Surface Science, 385 (2016):605-615,
https://doi.org/10.1016/j.apsusc.2016.05.165 . .

TY  - JOUR
AU  - Maksin, Danijela
AU  - Nastasović, Aleksandra
AU  - Maksin, Tatjana N.
AU  - Sandić, Zvjezdana P.
AU  - Loos, Katja
AU  - Ekmeščić, Bojana
AU  - Onjia, Antonije
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3470
AB  - Synthesis of an unconventional resin based on 4-vinylpyridine (4-VP) and its Cu(II) sorption behavior were studied. Three samples of macroporous crosslinked poly(4-vinylpyridine-co-ethylene glycol dimethacrylate) (P4VPE) with different porosity parameters were prepared by suspension copolymerization by varying the n-heptane amount in the inert component. The samples were characterized by mercury porosimetry, elemental analysis and X-ray photoelectron spectroscopy (XPS). The sorption of P4VPE for Cu(II) ions, determined under non-competitive conditions, was relatively rapid, i.e., the maximum capacity was reached within 30 min. The maximum experimental sorption capacity for the sample with the highest values of pore diameter and specific pore volume (sample 3, Q(eq) = 89 mg g(-1)) was 17.5 times higher than for the sample with the lowest values of pore diameter and specific pore volume (sample 1, Q(eq) = 5.1 mg g(-1)). Since the values for pyridine content in all P4VPE samples were almost the same, it was concluded that the porosity parameters have predominant influence on Cu(II) sorption rates on P4VPE. The sorption behavior and the rate-controlling mechanisms were analyzed using six kinetic models (pseudo-first order, pseudo-second order, Elovich, intraparticle diffusion, Bangham and Boyd models). XPS study clarified the nature of the formed P4VPE-Cu(II) species.
PB  - Savez hemijskih inženjera, Beograd
T2  - Hemijska industrija
T1  - Cu(II) immobilization onto a one-step synthesized poly(4-vinylpyridine-co-ethylene glycol dimethacrylate) resin: Kinetics and XPS analysis
EP  - 19
IS  - 1
SP  - 9
VL  - 70
DO  - 10.2298/HEMIND141203007M
ER  - 

@article{
author = "Maksin, Danijela and Nastasović, Aleksandra and Maksin, Tatjana N. and Sandić, Zvjezdana P. and Loos, Katja and Ekmeščić, Bojana and Onjia, Antonije",
year = "2016",
abstract = "Synthesis of an unconventional resin based on 4-vinylpyridine (4-VP) and its Cu(II) sorption behavior were studied. Three samples of macroporous crosslinked poly(4-vinylpyridine-co-ethylene glycol dimethacrylate) (P4VPE) with different porosity parameters were prepared by suspension copolymerization by varying the n-heptane amount in the inert component. The samples were characterized by mercury porosimetry, elemental analysis and X-ray photoelectron spectroscopy (XPS). The sorption of P4VPE for Cu(II) ions, determined under non-competitive conditions, was relatively rapid, i.e., the maximum capacity was reached within 30 min. The maximum experimental sorption capacity for the sample with the highest values of pore diameter and specific pore volume (sample 3, Q(eq) = 89 mg g(-1)) was 17.5 times higher than for the sample with the lowest values of pore diameter and specific pore volume (sample 1, Q(eq) = 5.1 mg g(-1)). Since the values for pyridine content in all P4VPE samples were almost the same, it was concluded that the porosity parameters have predominant influence on Cu(II) sorption rates on P4VPE. The sorption behavior and the rate-controlling mechanisms were analyzed using six kinetic models (pseudo-first order, pseudo-second order, Elovich, intraparticle diffusion, Bangham and Boyd models). XPS study clarified the nature of the formed P4VPE-Cu(II) species.",
publisher = "Savez hemijskih inženjera, Beograd",
journal = "Hemijska industrija",
title = "Cu(II) immobilization onto a one-step synthesized poly(4-vinylpyridine-co-ethylene glycol dimethacrylate) resin: Kinetics and XPS analysis",
pages = "19-9",
number = "1",
volume = "70",
doi = "10.2298/HEMIND141203007M"
}

Maksin, D., Nastasović, A., Maksin, T. N., Sandić, Z. P., Loos, K., Ekmeščić, B.,& Onjia, A.. (2016). Cu(II) immobilization onto a one-step synthesized poly(4-vinylpyridine-co-ethylene glycol dimethacrylate) resin: Kinetics and XPS analysis. in Hemijska industrija
Savez hemijskih inženjera, Beograd., 70(1), 9-19.
https://doi.org/10.2298/HEMIND141203007M

Maksin D, Nastasović A, Maksin TN, Sandić ZP, Loos K, Ekmeščić B, Onjia A. Cu(II) immobilization onto a one-step synthesized poly(4-vinylpyridine-co-ethylene glycol dimethacrylate) resin: Kinetics and XPS analysis. in Hemijska industrija. 2016;70(1):9-19.
doi:10.2298/HEMIND141203007M .

Maksin, Danijela, Nastasović, Aleksandra, Maksin, Tatjana N., Sandić, Zvjezdana P., Loos, Katja, Ekmeščić, Bojana, Onjia, Antonije, "Cu(II) immobilization onto a one-step synthesized poly(4-vinylpyridine-co-ethylene glycol dimethacrylate) resin: Kinetics and XPS analysis" in Hemijska industrija, 70, no. 1 (2016):9-19,
https://doi.org/10.2298/HEMIND141203007M . .

TY  - JOUR
AU  - Tomković, Tanja
AU  - Radovanović, Filip
AU  - Nastasović, Aleksandra
AU  - Vasiljević-Radović, Dana
AU  - Marković, Jelena P.
AU  - Grgur, Branimir
AU  - Onjia, Antonije
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3048
AB  - Asymmetric polyethersulfone membranes with submicron particles comprising crosslinked poly(glycidyl methacrylate-co-2-acrylamido-2-methylpropane sulfonic acid) were prepared by a combination of a traditional liquid phase inversion process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution. Scanning electron microscope images of the membrane cross-section revealed a hybrid structure with an interconnected network of submicron particles embedded within the porous polyethersulfone support. Permeation of toluidine blue solutions through non-functionalized membranes showed a dramatic effect of 2-acrylamido-2-methylpropane sulfonic acid concentration in the casting solution on the dynamic adsorption performance. The epoxide groups present in glycidyl methacrylate copolymer were transformed into amine functionalities by ring opening under alkaline conditions. Permeation of dilute Cu2+ solutions through functionalized membranes demonstrated that the plate height for some of these membranes was an order of magnitude smaller than for commercial particle-filled membranes used in solid phase extraction.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - European Polymer Journal
T1  - Solid phase extraction membranes with submicron multifunctional adsorbent particles
EP  - 100
SP  - 90
VL  - 63
DO  - 10.1016/j.eurpolymj.2014.12.015
ER  - 

@article{
author = "Tomković, Tanja and Radovanović, Filip and Nastasović, Aleksandra and Vasiljević-Radović, Dana and Marković, Jelena P. and Grgur, Branimir and Onjia, Antonije",
year = "2015",
abstract = "Asymmetric polyethersulfone membranes with submicron particles comprising crosslinked poly(glycidyl methacrylate-co-2-acrylamido-2-methylpropane sulfonic acid) were prepared by a combination of a traditional liquid phase inversion process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution. Scanning electron microscope images of the membrane cross-section revealed a hybrid structure with an interconnected network of submicron particles embedded within the porous polyethersulfone support. Permeation of toluidine blue solutions through non-functionalized membranes showed a dramatic effect of 2-acrylamido-2-methylpropane sulfonic acid concentration in the casting solution on the dynamic adsorption performance. The epoxide groups present in glycidyl methacrylate copolymer were transformed into amine functionalities by ring opening under alkaline conditions. Permeation of dilute Cu2+ solutions through functionalized membranes demonstrated that the plate height for some of these membranes was an order of magnitude smaller than for commercial particle-filled membranes used in solid phase extraction.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "European Polymer Journal",
title = "Solid phase extraction membranes with submicron multifunctional adsorbent particles",
pages = "100-90",
volume = "63",
doi = "10.1016/j.eurpolymj.2014.12.015"
}

Tomković, T., Radovanović, F., Nastasović, A., Vasiljević-Radović, D., Marković, J. P., Grgur, B.,& Onjia, A.. (2015). Solid phase extraction membranes with submicron multifunctional adsorbent particles. in European Polymer Journal
Pergamon-Elsevier Science Ltd, Oxford., 63, 90-100.
https://doi.org/10.1016/j.eurpolymj.2014.12.015

Tomković T, Radovanović F, Nastasović A, Vasiljević-Radović D, Marković JP, Grgur B, Onjia A. Solid phase extraction membranes with submicron multifunctional adsorbent particles. in European Polymer Journal. 2015;63:90-100.
doi:10.1016/j.eurpolymj.2014.12.015 .

Tomković, Tanja, Radovanović, Filip, Nastasović, Aleksandra, Vasiljević-Radović, Dana, Marković, Jelena P., Grgur, Branimir, Onjia, Antonije, "Solid phase extraction membranes with submicron multifunctional adsorbent particles" in European Polymer Journal, 63 (2015):90-100,
https://doi.org/10.1016/j.eurpolymj.2014.12.015 . .

TY  - JOUR
AU  - Stajčić, Aleksandar
AU  - Nastasović, Aleksandra
AU  - Stajić-Trošić, Jasna
AU  - Marković, Jelena P.
AU  - Onjia, Antonije
AU  - Radovanović, Filip
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2917
AB  - Polyethersulfone membranes with integrated negatively-charged hydrogel of crosslinked poly (acrylamido-2-methylpropane sulfonic acid) were prepared by a combination of a liquid phase inversion process with photopolymerization and crosslinking of functional monomers included in the casting solution. A designed experiment was conducted to select the optimal composition for preparing membranes with a sufficient degree of swelling and ion exchange capacity. Scanning electron microscopy images revealed an ultrafine hybrid structure with an interconnected network of submicron particles embedded within the microporous polyethersulfone support. An intramembrane diffusion model was used to describe kinetics of heavy metal sorption by these hydrogels and the calculated apparent diffusion coefficients were 2-3 times larger than in commercial ion-exchange resins. Equilibrium sorption of heavy metals was described using a semi-empirical Langmuir model.
PB  - Elsevier Sci Ltd, Oxford
T2  - Journal of Environmental Chemical Engineering
T1  - Novel membrane-supported hydrogel for removal of heavy metals
EP  - 461
IS  - 1
SP  - 453
VL  - 3
DO  - 10.1016/j.jece.2015.01.005
ER  - 

@article{
author = "Stajčić, Aleksandar and Nastasović, Aleksandra and Stajić-Trošić, Jasna and Marković, Jelena P. and Onjia, Antonije and Radovanović, Filip",
year = "2015",
abstract = "Polyethersulfone membranes with integrated negatively-charged hydrogel of crosslinked poly (acrylamido-2-methylpropane sulfonic acid) were prepared by a combination of a liquid phase inversion process with photopolymerization and crosslinking of functional monomers included in the casting solution. A designed experiment was conducted to select the optimal composition for preparing membranes with a sufficient degree of swelling and ion exchange capacity. Scanning electron microscopy images revealed an ultrafine hybrid structure with an interconnected network of submicron particles embedded within the microporous polyethersulfone support. An intramembrane diffusion model was used to describe kinetics of heavy metal sorption by these hydrogels and the calculated apparent diffusion coefficients were 2-3 times larger than in commercial ion-exchange resins. Equilibrium sorption of heavy metals was described using a semi-empirical Langmuir model.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Journal of Environmental Chemical Engineering",
title = "Novel membrane-supported hydrogel for removal of heavy metals",
pages = "461-453",
number = "1",
volume = "3",
doi = "10.1016/j.jece.2015.01.005"
}

Stajčić, A., Nastasović, A., Stajić-Trošić, J., Marković, J. P., Onjia, A.,& Radovanović, F.. (2015). Novel membrane-supported hydrogel for removal of heavy metals. in Journal of Environmental Chemical Engineering
Elsevier Sci Ltd, Oxford., 3(1), 453-461.
https://doi.org/10.1016/j.jece.2015.01.005

Stajčić A, Nastasović A, Stajić-Trošić J, Marković JP, Onjia A, Radovanović F. Novel membrane-supported hydrogel for removal of heavy metals. in Journal of Environmental Chemical Engineering. 2015;3(1):453-461.
doi:10.1016/j.jece.2015.01.005 .

Stajčić, Aleksandar, Nastasović, Aleksandra, Stajić-Trošić, Jasna, Marković, Jelena P., Onjia, Antonije, Radovanović, Filip, "Novel membrane-supported hydrogel for removal of heavy metals" in Journal of Environmental Chemical Engineering, 3, no. 1 (2015):453-461,
https://doi.org/10.1016/j.jece.2015.01.005 . .

TY  - JOUR
AU  - Radovanović, Filip
AU  - Nastasović, Aleksandra
AU  - Tomković, Tanja
AU  - Vasiljević-Radović, Dana
AU  - Nešić, Aleksandra
AU  - Veličković, Sava
AU  - Onjia, Antonije
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2836
AB  - Asymmetric polyethersulfone membranes with submicron particles comprising crosslinked glycidyl methacrylate copolymer were prepared by a combination of a traditional immersion precipitation process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution. As the concentration of polymerizable monomers increased the original macrovoid structure was replaced by a hybrid morphology with microglobules typical of macroporous methacrylate adsorbers embedded within microporous structure with no significant effects on water permeability. The epoxide groups present in glycidyl methacrylate copolymer were transformed into amine functionalities by ring opening under alkaline conditions. Permeation of Orange G solution at low transmembrane pressures was used to demonstrate suitability of these novel membranes for membrane adsorption.
PB  - Elsevier Science Bv, Amsterdam
T2  - Reactive & Functional Polymers
T1  - Novel membrane adsorbers incorporating functionalized polyglycidyl methacrylate
EP  - 10
SP  - 1
VL  - 77
DO  - 10.1016/j.reactfunctpolym.2014.01.007
ER  - 

@article{
author = "Radovanović, Filip and Nastasović, Aleksandra and Tomković, Tanja and Vasiljević-Radović, Dana and Nešić, Aleksandra and Veličković, Sava and Onjia, Antonije",
year = "2014",
abstract = "Asymmetric polyethersulfone membranes with submicron particles comprising crosslinked glycidyl methacrylate copolymer were prepared by a combination of a traditional immersion precipitation process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution. As the concentration of polymerizable monomers increased the original macrovoid structure was replaced by a hybrid morphology with microglobules typical of macroporous methacrylate adsorbers embedded within microporous structure with no significant effects on water permeability. The epoxide groups present in glycidyl methacrylate copolymer were transformed into amine functionalities by ring opening under alkaline conditions. Permeation of Orange G solution at low transmembrane pressures was used to demonstrate suitability of these novel membranes for membrane adsorption.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Reactive & Functional Polymers",
title = "Novel membrane adsorbers incorporating functionalized polyglycidyl methacrylate",
pages = "10-1",
volume = "77",
doi = "10.1016/j.reactfunctpolym.2014.01.007"
}

Radovanović, F., Nastasović, A., Tomković, T., Vasiljević-Radović, D., Nešić, A., Veličković, S.,& Onjia, A.. (2014). Novel membrane adsorbers incorporating functionalized polyglycidyl methacrylate. in Reactive & Functional Polymers
Elsevier Science Bv, Amsterdam., 77, 1-10.
https://doi.org/10.1016/j.reactfunctpolym.2014.01.007

Radovanović F, Nastasović A, Tomković T, Vasiljević-Radović D, Nešić A, Veličković S, Onjia A. Novel membrane adsorbers incorporating functionalized polyglycidyl methacrylate. in Reactive & Functional Polymers. 2014;77:1-10.
doi:10.1016/j.reactfunctpolym.2014.01.007 .

Radovanović, Filip, Nastasović, Aleksandra, Tomković, Tanja, Vasiljević-Radović, Dana, Nešić, Aleksandra, Veličković, Sava, Onjia, Antonije, "Novel membrane adsorbers incorporating functionalized polyglycidyl methacrylate" in Reactive & Functional Polymers, 77 (2014):1-10,
https://doi.org/10.1016/j.reactfunctpolym.2014.01.007 . .

TY  - DATA
AU  - Radovanović, Filip
AU  - Nastasović, Aleksandra
AU  - Tomković, Tanja
AU  - Vasiljević-Radović, Dana
AU  - Nešić, Aleksandra
AU  - Veličković, Sava
AU  - Onjia, Antonije
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2577
AB  - Asymmetric polyethersulfone membranes with submicron particles comprising crosslinked glycidyl methacrylate copolymer were prepared by a combination of a traditional immersion precipitation process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution. As the concentration of polymerizable monomers increased the original macrovoid structure was replaced by a hybrid morphology with microglobules typical of macroporous methacrylate adsorbers embedded within microporous structure with no significant effects on water permeability. The epoxide groups present in glycidyl methacrylate copolymer were transformed into amine functionalities by ring opening under alkaline conditions. Permeation of Orange G solution at low transmembrane pressures was used to demonstrate suitability of these novel membranes for membrane adsorption.
PB  - Elsevier, Amsterdam
T2  - Reactive & Functional Polymers
T1  - Supplementary materials for the article: Radovanović, F., Nastasović, A., Tomković, T., Vasiljević-Radović, D., Nešić, A., Veličković, S., Onjia, A., 2014. Novel membrane adsorbers incorporating functionalized polyglycidyl methacrylate. Reactive and Functional Polymers 77, 1–10. https://doi.org/10.1016/j.reactfunctpolym.2014.01.007
UR  - https://hdl.handle.net/21.15107/rcub_dais_4728
ER  - 

@misc{
author = "Radovanović, Filip and Nastasović, Aleksandra and Tomković, Tanja and Vasiljević-Radović, Dana and Nešić, Aleksandra and Veličković, Sava and Onjia, Antonije",
year = "2014",
abstract = "Asymmetric polyethersulfone membranes with submicron particles comprising crosslinked glycidyl methacrylate copolymer were prepared by a combination of a traditional immersion precipitation process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution. As the concentration of polymerizable monomers increased the original macrovoid structure was replaced by a hybrid morphology with microglobules typical of macroporous methacrylate adsorbers embedded within microporous structure with no significant effects on water permeability. The epoxide groups present in glycidyl methacrylate copolymer were transformed into amine functionalities by ring opening under alkaline conditions. Permeation of Orange G solution at low transmembrane pressures was used to demonstrate suitability of these novel membranes for membrane adsorption.",
publisher = "Elsevier, Amsterdam",
journal = "Reactive & Functional Polymers",
title = "Supplementary materials for the article: Radovanović, F., Nastasović, A., Tomković, T., Vasiljević-Radović, D., Nešić, A., Veličković, S., Onjia, A., 2014. Novel membrane adsorbers incorporating functionalized polyglycidyl methacrylate. Reactive and Functional Polymers 77, 1–10. https://doi.org/10.1016/j.reactfunctpolym.2014.01.007",
url = "https://hdl.handle.net/21.15107/rcub_dais_4728"
}

Radovanović, F., Nastasović, A., Tomković, T., Vasiljević-Radović, D., Nešić, A., Veličković, S.,& Onjia, A.. (2014). Supplementary materials for the article: Radovanović, F., Nastasović, A., Tomković, T., Vasiljević-Radović, D., Nešić, A., Veličković, S., Onjia, A., 2014. Novel membrane adsorbers incorporating functionalized polyglycidyl methacrylate. Reactive and Functional Polymers 77, 1–10. https://doi.org/10.1016/j.reactfunctpolym.2014.01.007. in Reactive & Functional Polymers
Elsevier, Amsterdam..
https://hdl.handle.net/21.15107/rcub_dais_4728

Radovanović F, Nastasović A, Tomković T, Vasiljević-Radović D, Nešić A, Veličković S, Onjia A. Supplementary materials for the article: Radovanović, F., Nastasović, A., Tomković, T., Vasiljević-Radović, D., Nešić, A., Veličković, S., Onjia, A., 2014. Novel membrane adsorbers incorporating functionalized polyglycidyl methacrylate. Reactive and Functional Polymers 77, 1–10. https://doi.org/10.1016/j.reactfunctpolym.2014.01.007. in Reactive & Functional Polymers. 2014;.
https://hdl.handle.net/21.15107/rcub_dais_4728 .

Radovanović, Filip, Nastasović, Aleksandra, Tomković, Tanja, Vasiljević-Radović, Dana, Nešić, Aleksandra, Veličković, Sava, Onjia, Antonije, "Supplementary materials for the article: Radovanović, F., Nastasović, A., Tomković, T., Vasiljević-Radović, D., Nešić, A., Veličković, S., Onjia, A., 2014. Novel membrane adsorbers incorporating functionalized polyglycidyl methacrylate. Reactive and Functional Polymers 77, 1–10. https://doi.org/10.1016/j.reactfunctpolym.2014.01.007" in Reactive & Functional Polymers (2014),
https://hdl.handle.net/21.15107/rcub_dais_4728 .

TY  - JOUR
AU  - Nastasović, Aleksandra
AU  - Ignjatović, Nenad
AU  - Uskoković, Dragan
AU  - Marković, Dana D.
AU  - Ekmeščić, Bojana
AU  - Maksin, Danijela
AU  - Onjia, Antonije
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2822
AB  - Inverse gas chromatography at infinite dilution was applied to determine the thermodynamic interactions of poly(l-lactide) (PLLA) and the composite of biphasic calcium phosphate and PLLA (BCP/PLLA). The specific retention volumes, , of 11 organic compounds of different chemical nature and polarity (non-polar, donor or acceptor) were determined in the temperature range of 308-378 K for PLLA and 308-398 K for BCP/PLLA. The weight fraction activity coefficients of test sorbates, , and the Flory-Huggins interaction parameters, , were estimated and discussed in terms of interactions of the sorbates with PLLA and BCP/PLLA. Also, the partial molar free energy, , the partial molar heat of mixing, , the sorption molar free energy, , the sorption enthalpy, , and the sorption entropy, , were analyzed. A different chromatographic behavior of the two investigated samples, PLLA and BCP/PLLA, was observed. The values of indicated n-alkanes, diethyl ether, tetrahydrofurane (THF), cyclohexane, benzene, dioxane (except for 338 K), and ethyl acetate (EtAc) (except for 338 K) as non-solvents, and chloroform (CHCl3) as good solvent (except for 378 K) for PLLA. For BCP/PLLA, CHCl3, EtAc (for 378 K), dioxane (except for 378 K), and THF were indicated as good solvents.
PB  - Springer, New York
T2  - Journal of Materials Science
T1  - Determination of thermodynamic interactions of polylactide and biphasic calcium phosphate/polylactidecomposite by inverse gas chromatography at infinite dilution
EP  - 5086
IS  - 14
SP  - 5076
VL  - 49
DO  - 10.1007/s10853-014-8214-3
ER  - 

@article{
author = "Nastasović, Aleksandra and Ignjatović, Nenad and Uskoković, Dragan and Marković, Dana D. and Ekmeščić, Bojana and Maksin, Danijela and Onjia, Antonije",
year = "2014",
abstract = "Inverse gas chromatography at infinite dilution was applied to determine the thermodynamic interactions of poly(l-lactide) (PLLA) and the composite of biphasic calcium phosphate and PLLA (BCP/PLLA). The specific retention volumes, , of 11 organic compounds of different chemical nature and polarity (non-polar, donor or acceptor) were determined in the temperature range of 308-378 K for PLLA and 308-398 K for BCP/PLLA. The weight fraction activity coefficients of test sorbates, , and the Flory-Huggins interaction parameters, , were estimated and discussed in terms of interactions of the sorbates with PLLA and BCP/PLLA. Also, the partial molar free energy, , the partial molar heat of mixing, , the sorption molar free energy, , the sorption enthalpy, , and the sorption entropy, , were analyzed. A different chromatographic behavior of the two investigated samples, PLLA and BCP/PLLA, was observed. The values of indicated n-alkanes, diethyl ether, tetrahydrofurane (THF), cyclohexane, benzene, dioxane (except for 338 K), and ethyl acetate (EtAc) (except for 338 K) as non-solvents, and chloroform (CHCl3) as good solvent (except for 378 K) for PLLA. For BCP/PLLA, CHCl3, EtAc (for 378 K), dioxane (except for 378 K), and THF were indicated as good solvents.",
publisher = "Springer, New York",
journal = "Journal of Materials Science",
title = "Determination of thermodynamic interactions of polylactide and biphasic calcium phosphate/polylactidecomposite by inverse gas chromatography at infinite dilution",
pages = "5086-5076",
number = "14",
volume = "49",
doi = "10.1007/s10853-014-8214-3"
}

Nastasović, A., Ignjatović, N., Uskoković, D., Marković, D. D., Ekmeščić, B., Maksin, D.,& Onjia, A.. (2014). Determination of thermodynamic interactions of polylactide and biphasic calcium phosphate/polylactidecomposite by inverse gas chromatography at infinite dilution. in Journal of Materials Science
Springer, New York., 49(14), 5076-5086.
https://doi.org/10.1007/s10853-014-8214-3

Nastasović A, Ignjatović N, Uskoković D, Marković DD, Ekmeščić B, Maksin D, Onjia A. Determination of thermodynamic interactions of polylactide and biphasic calcium phosphate/polylactidecomposite by inverse gas chromatography at infinite dilution. in Journal of Materials Science. 2014;49(14):5076-5086.
doi:10.1007/s10853-014-8214-3 .

Nastasović, Aleksandra, Ignjatović, Nenad, Uskoković, Dragan, Marković, Dana D., Ekmeščić, Bojana, Maksin, Danijela, Onjia, Antonije, "Determination of thermodynamic interactions of polylactide and biphasic calcium phosphate/polylactidecomposite by inverse gas chromatography at infinite dilution" in Journal of Materials Science, 49, no. 14 (2014):5076-5086,
https://doi.org/10.1007/s10853-014-8214-3 . .

TY  - JOUR
AU  - Vidojković, Sonja
AU  - Onjia, Antonije
AU  - Devečerski, Aleksandar
AU  - Grahovac, Nebojša N.
AU  - Nastasović, Aleksandra
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2720
AB  - The main causes of efficiency loss in thermal power plants are boiler tube failures that diminish unit reliability and availability, and raise the cost of the electric energy. For that reason, the regular examination of boiler tubes is indispensable measure for prevention of future malfunctions of power units. The microscopic examination of economizer's inner wall microstructure, the analysis of chemical composition of deposit using X-ray diffraction (XRD) and scanning electron microscopy/energy dispersive spectroscopy (SEM/EDS) have been performed in a subcritical power plant. Stress corrosion cracking, pitting corrosion, destroyed protective magnetite layer, presence of magnetite and hematite in deposit and corrosive impurities within the cracks have indicated the effect of inadequate quality of feedwater that cannot entirely ensure reliable operation of the boiler. It may be stated that maintenance of present boiler does not provide its reliable operation. The extensive chemical control of water/steam cycle was recommended.
PB  - Savez hemijskih inženjera, Beograd
T2  - Hemijska industrija
T1  - Economizer water-wall damages initiated by feedwater impurities
EP  - 563
IS  - 5
SP  - 559
VL  - 68
DO  - 10.2298/HEMIND130715082V
ER  - 

@article{
author = "Vidojković, Sonja and Onjia, Antonije and Devečerski, Aleksandar and Grahovac, Nebojša N. and Nastasović, Aleksandra",
year = "2014",
abstract = "The main causes of efficiency loss in thermal power plants are boiler tube failures that diminish unit reliability and availability, and raise the cost of the electric energy. For that reason, the regular examination of boiler tubes is indispensable measure for prevention of future malfunctions of power units. The microscopic examination of economizer's inner wall microstructure, the analysis of chemical composition of deposit using X-ray diffraction (XRD) and scanning electron microscopy/energy dispersive spectroscopy (SEM/EDS) have been performed in a subcritical power plant. Stress corrosion cracking, pitting corrosion, destroyed protective magnetite layer, presence of magnetite and hematite in deposit and corrosive impurities within the cracks have indicated the effect of inadequate quality of feedwater that cannot entirely ensure reliable operation of the boiler. It may be stated that maintenance of present boiler does not provide its reliable operation. The extensive chemical control of water/steam cycle was recommended.",
publisher = "Savez hemijskih inženjera, Beograd",
journal = "Hemijska industrija",
title = "Economizer water-wall damages initiated by feedwater impurities",
pages = "563-559",
number = "5",
volume = "68",
doi = "10.2298/HEMIND130715082V"
}

Vidojković, S., Onjia, A., Devečerski, A., Grahovac, N. N.,& Nastasović, A.. (2014). Economizer water-wall damages initiated by feedwater impurities. in Hemijska industrija
Savez hemijskih inženjera, Beograd., 68(5), 559-563.
https://doi.org/10.2298/HEMIND130715082V

Vidojković S, Onjia A, Devečerski A, Grahovac NN, Nastasović A. Economizer water-wall damages initiated by feedwater impurities. in Hemijska industrija. 2014;68(5):559-563.
doi:10.2298/HEMIND130715082V .

Vidojković, Sonja, Onjia, Antonije, Devečerski, Aleksandar, Grahovac, Nebojša N., Nastasović, Aleksandra, "Economizer water-wall damages initiated by feedwater impurities" in Hemijska industrija, 68, no. 5 (2014):559-563,
https://doi.org/10.2298/HEMIND130715082V . .

TY  - CONF
AU  - Tomković, Tanja
AU  - Radovanović, Filip
AU  - Nastasović, Aleksandra
AU  - Marković, Jelena
AU  - Ekmeščić, Bojana
AU  - Vidojković, Sonja
AU  - Onjia, Antonije
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2582
AB  - Novel polyethersulfone membranes with integrated submicron adsorbent particles were prepared by combining photoirradiation with liquid phase inversion. These particles consist of cross-linked poly(glycidyl methacrylate-co-acrylamido-2-methylpropane sulfonic acid), pGMA-AMPS. After membrane preparation, the epoxide groups were reacted with diethylene triamine to incorporate amine functionalities. Membranes were characterized using FTIR-ATR, SEM and dynamic adsorption of copper from a dilute solution. Effects of monomer concentrations on the properties and separation performance of membrane adsorbers are presented.
PB  - Belgrade, Serbia : Society of Physical Chemists of Serbia
C3  - Proceedings of the 12th International Conference on Fundamental and Applied Aspects of Physical Chem
T1  - Polyethersulfone membranes with integrated adsorbent particles for heavy metals capture
EP  - 790
SP  - 787
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7531
ER  - 

@conference{
author = "Tomković, Tanja and Radovanović, Filip and Nastasović, Aleksandra and Marković, Jelena and Ekmeščić, Bojana and Vidojković, Sonja and Onjia, Antonije",
year = "2014",
abstract = "Novel polyethersulfone membranes with integrated submicron adsorbent particles were prepared by combining photoirradiation with liquid phase inversion. These particles consist of cross-linked poly(glycidyl methacrylate-co-acrylamido-2-methylpropane sulfonic acid), pGMA-AMPS. After membrane preparation, the epoxide groups were reacted with diethylene triamine to incorporate amine functionalities. Membranes were characterized using FTIR-ATR, SEM and dynamic adsorption of copper from a dilute solution. Effects of monomer concentrations on the properties and separation performance of membrane adsorbers are presented.",
publisher = "Belgrade, Serbia : Society of Physical Chemists of Serbia",
journal = "Proceedings of the 12th International Conference on Fundamental and Applied Aspects of Physical Chem",
title = "Polyethersulfone membranes with integrated adsorbent particles for heavy metals capture",
pages = "790-787",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7531"
}

Tomković, T., Radovanović, F., Nastasović, A., Marković, J., Ekmeščić, B., Vidojković, S.,& Onjia, A.. (2014). Polyethersulfone membranes with integrated adsorbent particles for heavy metals capture. in Proceedings of the 12th International Conference on Fundamental and Applied Aspects of Physical Chem
Belgrade, Serbia : Society of Physical Chemists of Serbia., 787-790.
https://hdl.handle.net/21.15107/rcub_vinar_7531

Tomković T, Radovanović F, Nastasović A, Marković J, Ekmeščić B, Vidojković S, Onjia A. Polyethersulfone membranes with integrated adsorbent particles for heavy metals capture. in Proceedings of the 12th International Conference on Fundamental and Applied Aspects of Physical Chem. 2014;:787-790.
https://hdl.handle.net/21.15107/rcub_vinar_7531 .

Tomković, Tanja, Radovanović, Filip, Nastasović, Aleksandra, Marković, Jelena, Ekmeščić, Bojana, Vidojković, Sonja, Onjia, Antonije, "Polyethersulfone membranes with integrated adsorbent particles for heavy metals capture" in Proceedings of the 12th International Conference on Fundamental and Applied Aspects of Physical Chem (2014):787-790,
https://hdl.handle.net/21.15107/rcub_vinar_7531 .

TY  - CONF
AU  - Tomković, Tanja
AU  - Radovanović, Filip
AU  - Nastasović, Aleksandra
AU  - Vasiljević-Radović, Dana
AU  - Onjia, Antonije
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2284
AB  - Membrane adsorption has started to replace fixed bed chromatography for separation and purification of small quantities of valuable species in biotechnology and related areas. Membrane functionalization is usually required to introduce affinity groups for these applications. In this work novel membranes adsorbers were prepared by combining liquid phase inversion with photopolymerization of the solution comprising polyethersulfone, glycidyl methacrylate, sodium salt of 2-acrylamido-2-methylpropane sulfonic acid and a cross-linker. Membranes were characterized using SEM, AFM, FTIR, titration and water permeability measurements. Dynamic adsorption of Toluidine blue as a model dye was used to demonstrate suitability of these novel membranes for membrane adsorption.
PB  - Belgrade: Institute of Technical Sciences of SASA
C3  - Program and the Book of Abstracts / Twelfth Young Researchers' Conference Materials Sciences and Eng
T1  - Novel membrane adsorbers incorporating cross-linked poly(glycidyl methacrylate-co-2-acrylamido-2-methylpropane sulfonic acid)
SP  - 38
UR  - https://hdl.handle.net/21.15107/rcub_technorep_2284
ER  - 

@conference{
author = "Tomković, Tanja and Radovanović, Filip and Nastasović, Aleksandra and Vasiljević-Radović, Dana and Onjia, Antonije",
year = "2013",
abstract = "Membrane adsorption has started to replace fixed bed chromatography for separation and purification of small quantities of valuable species in biotechnology and related areas. Membrane functionalization is usually required to introduce affinity groups for these applications. In this work novel membranes adsorbers were prepared by combining liquid phase inversion with photopolymerization of the solution comprising polyethersulfone, glycidyl methacrylate, sodium salt of 2-acrylamido-2-methylpropane sulfonic acid and a cross-linker. Membranes were characterized using SEM, AFM, FTIR, titration and water permeability measurements. Dynamic adsorption of Toluidine blue as a model dye was used to demonstrate suitability of these novel membranes for membrane adsorption.",
publisher = "Belgrade: Institute of Technical Sciences of SASA",
journal = "Program and the Book of Abstracts / Twelfth Young Researchers' Conference Materials Sciences and Eng",
title = "Novel membrane adsorbers incorporating cross-linked poly(glycidyl methacrylate-co-2-acrylamido-2-methylpropane sulfonic acid)",
pages = "38",
url = "https://hdl.handle.net/21.15107/rcub_technorep_2284"
}

Tomković, T., Radovanović, F., Nastasović, A., Vasiljević-Radović, D.,& Onjia, A.. (2013). Novel membrane adsorbers incorporating cross-linked poly(glycidyl methacrylate-co-2-acrylamido-2-methylpropane sulfonic acid). in Program and the Book of Abstracts / Twelfth Young Researchers' Conference Materials Sciences and Eng
Belgrade: Institute of Technical Sciences of SASA., 38.
https://hdl.handle.net/21.15107/rcub_technorep_2284

Tomković T, Radovanović F, Nastasović A, Vasiljević-Radović D, Onjia A. Novel membrane adsorbers incorporating cross-linked poly(glycidyl methacrylate-co-2-acrylamido-2-methylpropane sulfonic acid). in Program and the Book of Abstracts / Twelfth Young Researchers' Conference Materials Sciences and Eng. 2013;:38.
https://hdl.handle.net/21.15107/rcub_technorep_2284 .

Tomković, Tanja, Radovanović, Filip, Nastasović, Aleksandra, Vasiljević-Radović, Dana, Onjia, Antonije, "Novel membrane adsorbers incorporating cross-linked poly(glycidyl methacrylate-co-2-acrylamido-2-methylpropane sulfonic acid)" in Program and the Book of Abstracts / Twelfth Young Researchers' Conference Materials Sciences and Eng (2013):38,
https://hdl.handle.net/21.15107/rcub_technorep_2284 .

TY  - CONF
AU  - Stajčić, Aleksandar
AU  - Radovanović, Filip
AU  - Nastasović, Aleksandra
AU  - Stajić-Trošić, Jasna
AU  - Marković, Jelena
AU  - Onjia, Antonije
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2274
AB  - Hydrogels containing strong acid groups have been used in the past for the removal of heavy metals. Unfortunately such hydrogels exhibit poor mechanical properties and are generally difficult to handle. In this work we prepared asymmetric membranes incorporatingcross-linked 2-acrylamido-2-methyl-1-propane sulfonic acid (AMPS) hydrogel by combining photopolymerization and liquid phase inversion. An experimental design measuring water content and ion-exchange capacity of these membranes was used to select the optimal membrane composition for the removal of Pb2+, Ni2+, and Cd2+ ions from aqueous solutions. The results demonstrated fast sorption kinetics and high capacity for the investigated metals.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - Program and the Book of Abstracts / Twelfth Young Researchers' Conference Materials Sciences and Eng
T1  - Asymmetric hydrogel membranes for heavy metal adsorption
EP  - 40
SP  - 40
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7536
ER  - 

@conference{
author = "Stajčić, Aleksandar and Radovanović, Filip and Nastasović, Aleksandra and Stajić-Trošić, Jasna and Marković, Jelena and Onjia, Antonije",
year = "2013",
abstract = "Hydrogels containing strong acid groups have been used in the past for the removal of heavy metals. Unfortunately such hydrogels exhibit poor mechanical properties and are generally difficult to handle. In this work we prepared asymmetric membranes incorporatingcross-linked 2-acrylamido-2-methyl-1-propane sulfonic acid (AMPS) hydrogel by combining photopolymerization and liquid phase inversion. An experimental design measuring water content and ion-exchange capacity of these membranes was used to select the optimal membrane composition for the removal of Pb2+, Ni2+, and Cd2+ ions from aqueous solutions. The results demonstrated fast sorption kinetics and high capacity for the investigated metals.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "Program and the Book of Abstracts / Twelfth Young Researchers' Conference Materials Sciences and Eng",
title = "Asymmetric hydrogel membranes for heavy metal adsorption",
pages = "40-40",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7536"
}

Stajčić, A., Radovanović, F., Nastasović, A., Stajić-Trošić, J., Marković, J.,& Onjia, A.. (2013). Asymmetric hydrogel membranes for heavy metal adsorption. in Program and the Book of Abstracts / Twelfth Young Researchers' Conference Materials Sciences and Eng
Belgrade : Institute of Technical Sciences of SASA., 40-40.
https://hdl.handle.net/21.15107/rcub_vinar_7536

Stajčić A, Radovanović F, Nastasović A, Stajić-Trošić J, Marković J, Onjia A. Asymmetric hydrogel membranes for heavy metal adsorption. in Program and the Book of Abstracts / Twelfth Young Researchers' Conference Materials Sciences and Eng. 2013;:40-40.
https://hdl.handle.net/21.15107/rcub_vinar_7536 .

Stajčić, Aleksandar, Radovanović, Filip, Nastasović, Aleksandra, Stajić-Trošić, Jasna, Marković, Jelena, Onjia, Antonije, "Asymmetric hydrogel membranes for heavy metal adsorption" in Program and the Book of Abstracts / Twelfth Young Researchers' Conference Materials Sciences and Eng (2013):40-40,
https://hdl.handle.net/21.15107/rcub_vinar_7536 .

TY  - CONF
AU  - Radovanović, Filip
AU  - Tomković, Tanja
AU  - Nastasović, Aleksandra
AU  - Veličković, Sava
AU  - Nešić, Aleksandra
AU  - Onjia, Antonije
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2286
AB  - Polyethersulfone (PES) is frequently used for high-performance ultrafiltration membranes. Functionalization of PES membranes is required to introduce new groups for specific applications, such as affinity membranes for bioseparations [1]. Functionalization methods include bulk modification of PES material, blending of PES with another material, or surface modification of PES membranes [2]. In this work a novel method for introducing functional groups in asymmetric PES membranes is presented [3]. A cast film comprising PES, glycidyl methacrylate (GMA) and a common solvent was exposed to UV irradiation to form a gel of crosslinked polyGMA. The gel was then immersed in a water bath to create an asymmetric membrane with crosslinked polyGMA particles, as shown in Fig. 1. A simple treatment of these membranes with diethylene triamine was used to open the epoxide rings in polyGMA particles and introduce amine functional groups. The effects of monomer concentrations on the properties and separation performance of these novel membrane adsorbers will be presented.
PB  - Belgrade : Serbian Chemical Society
C3  - 8th International Conference of the Chemical Societies of the South-East European Countries - ICOSEC
T1  - Asymmetric polyethersulfone membranes with crosslinked poly(glycidyl methacrylate) particles
EP  - 128
SP  - 128
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7534
ER  - 

@conference{
author = "Radovanović, Filip and Tomković, Tanja and Nastasović, Aleksandra and Veličković, Sava and Nešić, Aleksandra and Onjia, Antonije",
year = "2013",
abstract = "Polyethersulfone (PES) is frequently used for high-performance ultrafiltration membranes. Functionalization of PES membranes is required to introduce new groups for specific applications, such as affinity membranes for bioseparations [1]. Functionalization methods include bulk modification of PES material, blending of PES with another material, or surface modification of PES membranes [2]. In this work a novel method for introducing functional groups in asymmetric PES membranes is presented [3]. A cast film comprising PES, glycidyl methacrylate (GMA) and a common solvent was exposed to UV irradiation to form a gel of crosslinked polyGMA. The gel was then immersed in a water bath to create an asymmetric membrane with crosslinked polyGMA particles, as shown in Fig. 1. A simple treatment of these membranes with diethylene triamine was used to open the epoxide rings in polyGMA particles and introduce amine functional groups. The effects of monomer concentrations on the properties and separation performance of these novel membrane adsorbers will be presented.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "8th International Conference of the Chemical Societies of the South-East European Countries - ICOSEC",
title = "Asymmetric polyethersulfone membranes with crosslinked poly(glycidyl methacrylate) particles",
pages = "128-128",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7534"
}

Radovanović, F., Tomković, T., Nastasović, A., Veličković, S., Nešić, A.,& Onjia, A.. (2013). Asymmetric polyethersulfone membranes with crosslinked poly(glycidyl methacrylate) particles. in 8th International Conference of the Chemical Societies of the South-East European Countries - ICOSEC
Belgrade : Serbian Chemical Society., 128-128.
https://hdl.handle.net/21.15107/rcub_vinar_7534

Radovanović F, Tomković T, Nastasović A, Veličković S, Nešić A, Onjia A. Asymmetric polyethersulfone membranes with crosslinked poly(glycidyl methacrylate) particles. in 8th International Conference of the Chemical Societies of the South-East European Countries - ICOSEC. 2013;:128-128.
https://hdl.handle.net/21.15107/rcub_vinar_7534 .

Radovanović, Filip, Tomković, Tanja, Nastasović, Aleksandra, Veličković, Sava, Nešić, Aleksandra, Onjia, Antonije, "Asymmetric polyethersulfone membranes with crosslinked poly(glycidyl methacrylate) particles" in 8th International Conference of the Chemical Societies of the South-East European Countries - ICOSEC (2013):128-128,
https://hdl.handle.net/21.15107/rcub_vinar_7534 .

TY  - CONF
AU  - Radovanović, Filip
AU  - Tomković, Tanja
AU  - Nastasović, Aleksandra
AU  - Veličković, Sava
AU  - Nešić, Aleksandra
AU  - Onjia, Antonije
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2285
AB  - Ultrafiltration (UF) membranes are currently used in industry for the concentration of proteins and other macromolecules. Performance of UF membranes is generally limited by a trade-off between permeability and selectivity [1]. However, electrically-charged ultrafiltration membranes can provide a dramatic improvement in ultrafiltration performance [2]. Novel UF membranes were made by combining traditional immersion precipitation process for making membranes with photopolymerization of the casting solution comprising polyethersulfone, glycidyl methacrylate and other reactive monomers. Negative charges were introduced either by initially using 2-acrylamido-2-methylpropane sulfonic acid as a reactive monomer, or were later created by epoxide ring opening of crosslinked glycidyl methacrylate. As shown in Fig. 1, selectivity of these membranes significantly improved as the concentration of negatively-charged groups in the membrane increased. The effects of membrane composition on the properties and separation performance of these novel UF membranes will be presented.
PB  - Belgrade : Serbian Chemical Society
C3  - 8th International Conference of the Chemical Societies of the South-East European Countries - ICOSEC
T1  - Novel negatively-charged ultrafiltration membranes made by a combination of immersion precipitation and photopolymerization
EP  - 131
SP  - 131
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7535
ER  - 

@conference{
author = "Radovanović, Filip and Tomković, Tanja and Nastasović, Aleksandra and Veličković, Sava and Nešić, Aleksandra and Onjia, Antonije",
year = "2013",
abstract = "Ultrafiltration (UF) membranes are currently used in industry for the concentration of proteins and other macromolecules. Performance of UF membranes is generally limited by a trade-off between permeability and selectivity [1]. However, electrically-charged ultrafiltration membranes can provide a dramatic improvement in ultrafiltration performance [2]. Novel UF membranes were made by combining traditional immersion precipitation process for making membranes with photopolymerization of the casting solution comprising polyethersulfone, glycidyl methacrylate and other reactive monomers. Negative charges were introduced either by initially using 2-acrylamido-2-methylpropane sulfonic acid as a reactive monomer, or were later created by epoxide ring opening of crosslinked glycidyl methacrylate. As shown in Fig. 1, selectivity of these membranes significantly improved as the concentration of negatively-charged groups in the membrane increased. The effects of membrane composition on the properties and separation performance of these novel UF membranes will be presented.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "8th International Conference of the Chemical Societies of the South-East European Countries - ICOSEC",
title = "Novel negatively-charged ultrafiltration membranes made by a combination of immersion precipitation and photopolymerization",
pages = "131-131",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7535"
}

Radovanović, F., Tomković, T., Nastasović, A., Veličković, S., Nešić, A.,& Onjia, A.. (2013). Novel negatively-charged ultrafiltration membranes made by a combination of immersion precipitation and photopolymerization. in 8th International Conference of the Chemical Societies of the South-East European Countries - ICOSEC
Belgrade : Serbian Chemical Society., 131-131.
https://hdl.handle.net/21.15107/rcub_vinar_7535

Radovanović F, Tomković T, Nastasović A, Veličković S, Nešić A, Onjia A. Novel negatively-charged ultrafiltration membranes made by a combination of immersion precipitation and photopolymerization. in 8th International Conference of the Chemical Societies of the South-East European Countries - ICOSEC. 2013;:131-131.
https://hdl.handle.net/21.15107/rcub_vinar_7535 .

Radovanović, Filip, Tomković, Tanja, Nastasović, Aleksandra, Veličković, Sava, Nešić, Aleksandra, Onjia, Antonije, "Novel negatively-charged ultrafiltration membranes made by a combination of immersion precipitation and photopolymerization" in 8th International Conference of the Chemical Societies of the South-East European Countries - ICOSEC (2013):131-131,
https://hdl.handle.net/21.15107/rcub_vinar_7535 .

TY  - JOUR
AU  - Vidojković, Sonja
AU  - Onjia, Antonije
AU  - Matović, Branko
AU  - Grahovac, Nebojša N.
AU  - Maksimović, Vesna
AU  - Nastasović, Aleksandra
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2451
AB  - Prevention and minimizing corrosion processes on steam generating equipment is highly important in the thermal power industry. The maintenance of feedwater quality at a level corresponding to the standards of technological designing, followed by timely respond to the fluctuation of measured parameters, has a decisive role in corrosion prevention. In this study, the comprehensive chemical control of feedwater quality in 210 MW Thermal Power Plant (TPP) was carried out in order to evaluate its potentiality to assure reliable function of the boiler and discover possible irregularity that might be responsible for frequent boiler tube failures. Sensitive on-line and off-line analytical instruments were used for measuring key and diagnostic parameters considered to be crucial for boiler safety and performances. Obtained results provided evidences for exceeded levels of oxygen, silica, sodium, chloride, sulfate, copper, and conductivity what distinctly demonstrated necessity of feedwater control improvement. Consequently, more effective feedwater quality monitoring concept was recommended. In this paper, the explanation of presumable root causes of corrosive contaminants was given including basic directions for their maintenance in proscribed limits.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Applied Thermal Engineering
T1  - Extensive feedwater quality control and monitoring concept for preventing chemistry-related failures of boiler tubes in a subcritical thermal power plant
EP  - 694
IS  - 1-2
SP  - 683
VL  - 59
DO  - 10.1016/j.applthermaleng.2013.06.028
ER  - 

@article{
author = "Vidojković, Sonja and Onjia, Antonije and Matović, Branko and Grahovac, Nebojša N. and Maksimović, Vesna and Nastasović, Aleksandra",
year = "2013",
abstract = "Prevention and minimizing corrosion processes on steam generating equipment is highly important in the thermal power industry. The maintenance of feedwater quality at a level corresponding to the standards of technological designing, followed by timely respond to the fluctuation of measured parameters, has a decisive role in corrosion prevention. In this study, the comprehensive chemical control of feedwater quality in 210 MW Thermal Power Plant (TPP) was carried out in order to evaluate its potentiality to assure reliable function of the boiler and discover possible irregularity that might be responsible for frequent boiler tube failures. Sensitive on-line and off-line analytical instruments were used for measuring key and diagnostic parameters considered to be crucial for boiler safety and performances. Obtained results provided evidences for exceeded levels of oxygen, silica, sodium, chloride, sulfate, copper, and conductivity what distinctly demonstrated necessity of feedwater control improvement. Consequently, more effective feedwater quality monitoring concept was recommended. In this paper, the explanation of presumable root causes of corrosive contaminants was given including basic directions for their maintenance in proscribed limits.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Applied Thermal Engineering",
title = "Extensive feedwater quality control and monitoring concept for preventing chemistry-related failures of boiler tubes in a subcritical thermal power plant",
pages = "694-683",
number = "1-2",
volume = "59",
doi = "10.1016/j.applthermaleng.2013.06.028"
}

Vidojković, S., Onjia, A., Matović, B., Grahovac, N. N., Maksimović, V.,& Nastasović, A.. (2013). Extensive feedwater quality control and monitoring concept for preventing chemistry-related failures of boiler tubes in a subcritical thermal power plant. in Applied Thermal Engineering
Pergamon-Elsevier Science Ltd, Oxford., 59(1-2), 683-694.
https://doi.org/10.1016/j.applthermaleng.2013.06.028

Vidojković S, Onjia A, Matović B, Grahovac NN, Maksimović V, Nastasović A. Extensive feedwater quality control and monitoring concept for preventing chemistry-related failures of boiler tubes in a subcritical thermal power plant. in Applied Thermal Engineering. 2013;59(1-2):683-694.
doi:10.1016/j.applthermaleng.2013.06.028 .

Vidojković, Sonja, Onjia, Antonije, Matović, Branko, Grahovac, Nebojša N., Maksimović, Vesna, Nastasović, Aleksandra, "Extensive feedwater quality control and monitoring concept for preventing chemistry-related failures of boiler tubes in a subcritical thermal power plant" in Applied Thermal Engineering, 59, no. 1-2 (2013):683-694,
https://doi.org/10.1016/j.applthermaleng.2013.06.028 . .

TY  - JOUR
AU  - Momčilović, Milan Z.
AU  - Maksin, Danijela
AU  - Nastasović, Aleksandra
AU  - Onjia, Antonije
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2287
AB  - Pine cones of European Black pine are utilized as a precursor for obtaining powdered activated carbon. The concentrated phosphoric acid was used as an activating agent. A detailed study of the imidacloprid adsorption onto the obtained material was conducted. In this paper, the adsorption kinetics, the conditions of establishing equilibrium, the impact of the adsorbent mass, and pH of solutions was analyzed. It was concluded that in a short period 90 % of pesticide is removed from model solutions under the applied conditions, while the removal degree is even higher for lower initial concentrations and higher adsorbent masses. It was also elucidated that this pesticide is equally well adsorbed in both acid and basic solutions.
AB  - Šišarka crnog evropskog bora je korišćena kao prekursor za dobijanje praškastog aktivnog uglja. Kao aktivirajuće sredstvo u pripremi je upotrebljena koncentrovana fosforna kiselina. Izvršena je detaljna studija adsorpcije pesticida imidakloprida na sintetizovanom materijalu. U radu je izvršeno ispitivanje kinetike adsorpcije, uslova uspostavljanja ravnoteže procesa, uticaja mase adsorbensa, kao i pH rastvora. Utvrđeno je da se za relativno kratko vreme vrši uklanjanje oko 90 % pesticida iz modalnog rastvora pri ispitivanim uslovima, dok je stepen uklanjanja još veći za niže polazne koncentracije i više mase adsorbensa. Ispitivanjem uticaja pH rastvora utvrđeno je da se pesticid podjednako dobro adsorbuje u kiseloj i u baznoj sredini.
PB  - Univerzitet u Nišu - Tehnološki fakultet, Leskovac
T2  - Savremene tehnologije
T1  - The adsorption of imidacloprid onto activated carbon obtained by carbonization of pine cones
T1  - Adsorpcija imidakloprida na aktivnom uglju dobijenom karbonizacijom borove šišarke
EP  - 49
IS  - 2
SP  - 45
VL  - 2
UR  - https://hdl.handle.net/21.15107/rcub_technorep_2287
ER  - 

@article{
author = "Momčilović, Milan Z. and Maksin, Danijela and Nastasović, Aleksandra and Onjia, Antonije",
year = "2013",
abstract = "Pine cones of European Black pine are utilized as a precursor for obtaining powdered activated carbon. The concentrated phosphoric acid was used as an activating agent. A detailed study of the imidacloprid adsorption onto the obtained material was conducted. In this paper, the adsorption kinetics, the conditions of establishing equilibrium, the impact of the adsorbent mass, and pH of solutions was analyzed. It was concluded that in a short period 90 % of pesticide is removed from model solutions under the applied conditions, while the removal degree is even higher for lower initial concentrations and higher adsorbent masses. It was also elucidated that this pesticide is equally well adsorbed in both acid and basic solutions., Šišarka crnog evropskog bora je korišćena kao prekursor za dobijanje praškastog aktivnog uglja. Kao aktivirajuće sredstvo u pripremi je upotrebljena koncentrovana fosforna kiselina. Izvršena je detaljna studija adsorpcije pesticida imidakloprida na sintetizovanom materijalu. U radu je izvršeno ispitivanje kinetike adsorpcije, uslova uspostavljanja ravnoteže procesa, uticaja mase adsorbensa, kao i pH rastvora. Utvrđeno je da se za relativno kratko vreme vrši uklanjanje oko 90 % pesticida iz modalnog rastvora pri ispitivanim uslovima, dok je stepen uklanjanja još veći za niže polazne koncentracije i više mase adsorbensa. Ispitivanjem uticaja pH rastvora utvrđeno je da se pesticid podjednako dobro adsorbuje u kiseloj i u baznoj sredini.",
publisher = "Univerzitet u Nišu - Tehnološki fakultet, Leskovac",
journal = "Savremene tehnologije",
title = "The adsorption of imidacloprid onto activated carbon obtained by carbonization of pine cones, Adsorpcija imidakloprida na aktivnom uglju dobijenom karbonizacijom borove šišarke",
pages = "49-45",
number = "2",
volume = "2",
url = "https://hdl.handle.net/21.15107/rcub_technorep_2287"
}

Momčilović, M. Z., Maksin, D., Nastasović, A.,& Onjia, A.. (2013). The adsorption of imidacloprid onto activated carbon obtained by carbonization of pine cones. in Savremene tehnologije
Univerzitet u Nišu - Tehnološki fakultet, Leskovac., 2(2), 45-49.
https://hdl.handle.net/21.15107/rcub_technorep_2287

Momčilović MZ, Maksin D, Nastasović A, Onjia A. The adsorption of imidacloprid onto activated carbon obtained by carbonization of pine cones. in Savremene tehnologije. 2013;2(2):45-49.
https://hdl.handle.net/21.15107/rcub_technorep_2287 .

Momčilović, Milan Z., Maksin, Danijela, Nastasović, Aleksandra, Onjia, Antonije, "The adsorption of imidacloprid onto activated carbon obtained by carbonization of pine cones" in Savremene tehnologije, 2, no. 2 (2013):45-49,
https://hdl.handle.net/21.15107/rcub_technorep_2287 .