Rakočević, Zlatko Lj.

Link to this page

Authority KeyName Variants
orcid::0000-0003-4876-5195
  • Rakočević, Zlatko Lj. (23)
Projects
Functional, Functionalized and Advanced Nanomaterials Synthesis, processing and applications of nanostructured multifunctional materials with defined properties
Development and Application of Methods and Materials for Monitoring New Organic Contaminants, Toxic Compounds and Heavy Metals Directed synthesis, structure and properties of multifunctional materials
Synthesis and characterization of novel functional polymers and polymeric nanocomposites UEFISCDI [304/2011]
COST-European Cooperation in Science and TechnologyEuropean Cooperation in Science and Technology (COST) ERC advanced grant "PICOPROP" [670918]
ERC advanced grant “PICOPROP” (Grant No. 670918) German Serbian DAAD bilateral collaboration [451-03-01038/2015-09118/18]
Reinforcing of Nanotechnology and Functional Materials Centre Size-, shape- and structure- dependent properties of nanoparticles and nanocomposites
Advanced technologies for monitoring and environmental protection from chemical pollutants and radiation burden Physics and Chemistry with Ion Beams
Razvoj metoda za separaciju, predkoncentrisanje, određivanje i uklanjanje zagađivača okoline Sinteza i karakterizacija polimera i polimernih (nano)kompozita definisane molekulske i nadmolekulske strukture
Application of biotechnological methods for sustainable exploitation of by-products of agro-industry Project MESTD, br. 1806: Electrodeposition of metal powders at a constant and at a periodically changing rate
"Start up for science 2016" organized by the Centre for leadership development, Serbia Swiss National Science Foundation (No. 160169)
Swiss National Science FoundationSwiss National Science Foundation (SNSF) [160169] UEFISCDI under the contract ID 304/2011

Author's Bibliography

Doping of TiO2 nanotubes with nitrogen by annealing in ammonia for visible light activation: Influence of pre- and post-annealing in air

Bjelajac, Anđelika; Petrović, Rada; Popović, Maja; Rakočević, Zlatko Lj.; Socol, Gabriel; Mihailescu, Ion N.; Janaćković, Đorđe

(Elsevier Ltd, 2019)

TY  - JOUR
AU  - Bjelajac, Anđelika
AU  - Petrović, Rada
AU  - Popović, Maja
AU  - Rakočević, Zlatko Lj.
AU  - Socol, Gabriel
AU  - Mihailescu, Ion N.
AU  - Janaćković, Đorđe
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5027
AB  - The ∼60 nm wide and ∼2 μm long TiO2 nanotubes were obtained by anodization of Ti films sputtered on F-doped tin oxide glass. For N-doping the samples were annealed in ammonia atmosphere. The effect of pre- and post-annealing in air on the nature and amount of incorporated N was studied by X-ray photoelectron spectroscopy. By measuring the absorption spectra of the obtained samples and interpreting the corresponding Tauc plots it was shown that the sample annealed just in ammonia showed the highest visible light absorption even after sputtering cleaning and a decrease of N amount from 3.8% to 1%. Pre and/or post annealing in air led to smaller amount of incorporated N, that caused less pronounced absorption enhancement and smaller band gap narrowing compared to the sample annealed only in ammonia. By fitting of N 1 s line, the contribution that was assigned to substitutional N was detected only in the samples that did not sustained post-annealing. The study showed that post-annealing in air might lead to partial conversion of N atoms in TiO2 to oxidized nitrogen species that are easily removed with sputtering. It is also possible that substitutional nitrogen was suppressed by oxygen from air to move to interstitial site. Weakly bonded NOx surface species, which are cleaned away by sputtering, can be removed by post-annealing in air. Those surface species could act as sensitizers and when their amounts are reduced, the core absorption properties, as a result of interstitial incorporation of N in TiO2 structure, were revealed. Much lower visible light sensitization was achieved in the case of pre-annealed sample in comparison to sample without pre-annealing, regardless the same quantity and type of incorporated nitrogen.
PB  - Elsevier Ltd
T2  - Thin Solid Films
T1  - Doping of TiO2 nanotubes with nitrogen by annealing in ammonia for visible light activation: Influence of pre- and post-annealing in air
SP  - 137598
VL  - 692
DO  - 10.1016/j.tsf.2019.137598
ER  - 
@article{
author = "Bjelajac, Anđelika and Petrović, Rada and Popović, Maja and Rakočević, Zlatko Lj. and Socol, Gabriel and Mihailescu, Ion N. and Janaćković, Đorđe",
year = "2019",
abstract = "The ∼60 nm wide and ∼2 μm long TiO2 nanotubes were obtained by anodization of Ti films sputtered on F-doped tin oxide glass. For N-doping the samples were annealed in ammonia atmosphere. The effect of pre- and post-annealing in air on the nature and amount of incorporated N was studied by X-ray photoelectron spectroscopy. By measuring the absorption spectra of the obtained samples and interpreting the corresponding Tauc plots it was shown that the sample annealed just in ammonia showed the highest visible light absorption even after sputtering cleaning and a decrease of N amount from 3.8% to 1%. Pre and/or post annealing in air led to smaller amount of incorporated N, that caused less pronounced absorption enhancement and smaller band gap narrowing compared to the sample annealed only in ammonia. By fitting of N 1 s line, the contribution that was assigned to substitutional N was detected only in the samples that did not sustained post-annealing. The study showed that post-annealing in air might lead to partial conversion of N atoms in TiO2 to oxidized nitrogen species that are easily removed with sputtering. It is also possible that substitutional nitrogen was suppressed by oxygen from air to move to interstitial site. Weakly bonded NOx surface species, which are cleaned away by sputtering, can be removed by post-annealing in air. Those surface species could act as sensitizers and when their amounts are reduced, the core absorption properties, as a result of interstitial incorporation of N in TiO2 structure, were revealed. Much lower visible light sensitization was achieved in the case of pre-annealed sample in comparison to sample without pre-annealing, regardless the same quantity and type of incorporated nitrogen.",
publisher = "Elsevier Ltd",
journal = "Thin Solid Films",
title = "Doping of TiO2 nanotubes with nitrogen by annealing in ammonia for visible light activation: Influence of pre- and post-annealing in air",
pages = "137598",
volume = "692",
doi = "10.1016/j.tsf.2019.137598"
}
Bjelajac, A., Petrović, R., Popović, M., Rakočević, Z. Lj., Socol, G., Mihailescu, I. N.,& Janaćković, Đ.. (2019). Doping of TiO2 nanotubes with nitrogen by annealing in ammonia for visible light activation: Influence of pre- and post-annealing in air. in Thin Solid Films
Elsevier Ltd., 692, 137598.
https://doi.org/10.1016/j.tsf.2019.137598
Bjelajac A, Petrović R, Popović M, Rakočević ZL, Socol G, Mihailescu IN, Janaćković Đ. Doping of TiO2 nanotubes with nitrogen by annealing in ammonia for visible light activation: Influence of pre- and post-annealing in air. in Thin Solid Films. 2019;692:137598.
doi:10.1016/j.tsf.2019.137598 .
Bjelajac, Anđelika, Petrović, Rada, Popović, Maja, Rakočević, Zlatko Lj., Socol, Gabriel, Mihailescu, Ion N., Janaćković, Đorđe, "Doping of TiO2 nanotubes with nitrogen by annealing in ammonia for visible light activation: Influence of pre- and post-annealing in air" in Thin Solid Films, 692 (2019):137598,
https://doi.org/10.1016/j.tsf.2019.137598 . .
12
10
13

Doping of TiO2 nanotubes with nitrogen by annealing in ammonia for visible light activation: Influence of pre- and post-annealing in air

Bjelajac, Anđelika; Petrović, Rada; Popović, Maja; Rakočević, Zlatko Lj.; Socol, Gabriel; Mihailescu, Ion N.; Janaćković, Đorđe

(Elsevier Science Sa, Lausanne, 2019)

TY  - JOUR
AU  - Bjelajac, Anđelika
AU  - Petrović, Rada
AU  - Popović, Maja
AU  - Rakočević, Zlatko Lj.
AU  - Socol, Gabriel
AU  - Mihailescu, Ion N.
AU  - Janaćković, Đorđe
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4092
AB  - The similar to 60 nm wide and similar to 2 mu m long TiO2 nanotubes were obtained by anodization of Ti films sputtered on F-doped tin oxide glass. For N-doping the samples were annealed in ammonia atmosphere. The effect of pre- and post-annealing in air on the nature and amount of incorporated N was studied by X-ray photoelectron spectroscopy. By measuring the absorption spectra of the obtained samples and interpreting the corresponding Tauc plots it was shown that the sample annealed just in ammonia showed the highest visible light absorption even after sputtering cleaning and a decrease of N amount from 3.8% to 1%. Pre and/or post annealing in air led to smaller amount of incorporated N, that caused less pronounced absorption enhancement and smaller band gap narrowing compared to the sample annealed only in ammonia. By fitting of N 1 s line, the contribution that was assigned to substitutional N was detected only in the samples that did not sustained post-annealing. The study showed that post-annealing in air might lead to partial conversion of N atoms in TiO2 to oxidized nitrogen species that are easily removed with sputtering. It is also possible that substitutional nitrogen was suppressed by oxygen from air to move to interstitial site. Weakly bonded NOx surface species, which are cleaned away by sputtering, can be removed by post-annealing in air. Those surface species could act as sensitizers and when their amounts are reduced, the core absorption properties, as a result of interstitial incorporation of N in TiO2 structure, were revealed. Much lower visible light sensitization was achieved in the case of pre-annealed sample in comparison to sample without pre-annealing, regardless the same quantity and type of incorporated nitrogen.
PB  - Elsevier Science Sa, Lausanne
T2  - Thin Solid Films
T1  - Doping of TiO2 nanotubes with nitrogen by annealing in ammonia for visible light activation: Influence of pre- and post-annealing in air
SP  - 137598
VL  - 692
DO  - 10.1016/j.tsf.2019.137598
ER  - 
@article{
author = "Bjelajac, Anđelika and Petrović, Rada and Popović, Maja and Rakočević, Zlatko Lj. and Socol, Gabriel and Mihailescu, Ion N. and Janaćković, Đorđe",
year = "2019",
abstract = "The similar to 60 nm wide and similar to 2 mu m long TiO2 nanotubes were obtained by anodization of Ti films sputtered on F-doped tin oxide glass. For N-doping the samples were annealed in ammonia atmosphere. The effect of pre- and post-annealing in air on the nature and amount of incorporated N was studied by X-ray photoelectron spectroscopy. By measuring the absorption spectra of the obtained samples and interpreting the corresponding Tauc plots it was shown that the sample annealed just in ammonia showed the highest visible light absorption even after sputtering cleaning and a decrease of N amount from 3.8% to 1%. Pre and/or post annealing in air led to smaller amount of incorporated N, that caused less pronounced absorption enhancement and smaller band gap narrowing compared to the sample annealed only in ammonia. By fitting of N 1 s line, the contribution that was assigned to substitutional N was detected only in the samples that did not sustained post-annealing. The study showed that post-annealing in air might lead to partial conversion of N atoms in TiO2 to oxidized nitrogen species that are easily removed with sputtering. It is also possible that substitutional nitrogen was suppressed by oxygen from air to move to interstitial site. Weakly bonded NOx surface species, which are cleaned away by sputtering, can be removed by post-annealing in air. Those surface species could act as sensitizers and when their amounts are reduced, the core absorption properties, as a result of interstitial incorporation of N in TiO2 structure, were revealed. Much lower visible light sensitization was achieved in the case of pre-annealed sample in comparison to sample without pre-annealing, regardless the same quantity and type of incorporated nitrogen.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Thin Solid Films",
title = "Doping of TiO2 nanotubes with nitrogen by annealing in ammonia for visible light activation: Influence of pre- and post-annealing in air",
pages = "137598",
volume = "692",
doi = "10.1016/j.tsf.2019.137598"
}
Bjelajac, A., Petrović, R., Popović, M., Rakočević, Z. Lj., Socol, G., Mihailescu, I. N.,& Janaćković, Đ.. (2019). Doping of TiO2 nanotubes with nitrogen by annealing in ammonia for visible light activation: Influence of pre- and post-annealing in air. in Thin Solid Films
Elsevier Science Sa, Lausanne., 692, 137598.
https://doi.org/10.1016/j.tsf.2019.137598
Bjelajac A, Petrović R, Popović M, Rakočević ZL, Socol G, Mihailescu IN, Janaćković Đ. Doping of TiO2 nanotubes with nitrogen by annealing in ammonia for visible light activation: Influence of pre- and post-annealing in air. in Thin Solid Films. 2019;692:137598.
doi:10.1016/j.tsf.2019.137598 .
Bjelajac, Anđelika, Petrović, Rada, Popović, Maja, Rakočević, Zlatko Lj., Socol, Gabriel, Mihailescu, Ion N., Janaćković, Đorđe, "Doping of TiO2 nanotubes with nitrogen by annealing in ammonia for visible light activation: Influence of pre- and post-annealing in air" in Thin Solid Films, 692 (2019):137598,
https://doi.org/10.1016/j.tsf.2019.137598 . .
12
10

Dry-pressed anodized titania nanotube/CH3NH3PbI3 single crystal heterojunctions: The beneficial role of N doping

Vujančević, Jelena; Andričević, Pavao; Bjelajac, Anđelika; Đokić, Veljko; Popović, Maja; Rakočević, Zlatko Lj.; Horvath, Endre; Kollar, Marton; Nafradi, Balint; Schiller, Andreas; Domanski, Konrad; Forro, Laszlo; Pavlović, Vera P.; Janaćković, Đorđe

(Elsevier Sci Ltd, Oxford, 2019)

TY  - JOUR
AU  - Vujančević, Jelena
AU  - Andričević, Pavao
AU  - Bjelajac, Anđelika
AU  - Đokić, Veljko
AU  - Popović, Maja
AU  - Rakočević, Zlatko Lj.
AU  - Horvath, Endre
AU  - Kollar, Marton
AU  - Nafradi, Balint
AU  - Schiller, Andreas
AU  - Domanski, Konrad
AU  - Forro, Laszlo
AU  - Pavlović, Vera P.
AU  - Janaćković, Đorđe
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4251
AB  - Highly ordered, anodically grown TiO2 nanotubes on titanium supports were annealed in ammonia atmosphere in order to incorporate nitrogen doping ( lt = 2 at.%) in the titanium oxide lattice. FESEM micrographs revealed nanotubes with an average outer diameter of 101.5 +/- 1.5 nm and an average wall thickness of about 13 nm. Anatase crystals were formed inside the tubes after annealing in ammonia atmosphere for 30 min. With further annealing, rutile peaks appeared due to the thermal oxidation of the foil and rise as the duration of heat treatment was increased. The concentration and chemical nature of nitrogen in the nanotube arrays can be correlated to the optical response of dry-pressed heterojunctions of doped TiO2/CH3NH3PbI3 single crystals. The N-TiO2/perovskite heterojunction with the highest amount of interstitial nitrogen exhibited an improved photocurrent, indicating the importance of the semiconductor doping-based heterojunction optimization strategies to deliver competitive levels of halide perovskite-based optoelectronic devices to be envisioned for urban infrastructures.
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Dry-pressed anodized titania nanotube/CH3NH3PbI3 single crystal heterojunctions: The beneficial role of N doping
EP  - 10020
IS  - 8
SP  - 10013
VL  - 45
DO  - 10.1016/j.ceramint.2019.02.045
ER  - 
@article{
author = "Vujančević, Jelena and Andričević, Pavao and Bjelajac, Anđelika and Đokić, Veljko and Popović, Maja and Rakočević, Zlatko Lj. and Horvath, Endre and Kollar, Marton and Nafradi, Balint and Schiller, Andreas and Domanski, Konrad and Forro, Laszlo and Pavlović, Vera P. and Janaćković, Đorđe",
year = "2019",
abstract = "Highly ordered, anodically grown TiO2 nanotubes on titanium supports were annealed in ammonia atmosphere in order to incorporate nitrogen doping ( lt = 2 at.%) in the titanium oxide lattice. FESEM micrographs revealed nanotubes with an average outer diameter of 101.5 +/- 1.5 nm and an average wall thickness of about 13 nm. Anatase crystals were formed inside the tubes after annealing in ammonia atmosphere for 30 min. With further annealing, rutile peaks appeared due to the thermal oxidation of the foil and rise as the duration of heat treatment was increased. The concentration and chemical nature of nitrogen in the nanotube arrays can be correlated to the optical response of dry-pressed heterojunctions of doped TiO2/CH3NH3PbI3 single crystals. The N-TiO2/perovskite heterojunction with the highest amount of interstitial nitrogen exhibited an improved photocurrent, indicating the importance of the semiconductor doping-based heterojunction optimization strategies to deliver competitive levels of halide perovskite-based optoelectronic devices to be envisioned for urban infrastructures.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Dry-pressed anodized titania nanotube/CH3NH3PbI3 single crystal heterojunctions: The beneficial role of N doping",
pages = "10020-10013",
number = "8",
volume = "45",
doi = "10.1016/j.ceramint.2019.02.045"
}
Vujančević, J., Andričević, P., Bjelajac, A., Đokić, V., Popović, M., Rakočević, Z. Lj., Horvath, E., Kollar, M., Nafradi, B., Schiller, A., Domanski, K., Forro, L., Pavlović, V. P.,& Janaćković, Đ.. (2019). Dry-pressed anodized titania nanotube/CH3NH3PbI3 single crystal heterojunctions: The beneficial role of N doping. in Ceramics International
Elsevier Sci Ltd, Oxford., 45(8), 10013-10020.
https://doi.org/10.1016/j.ceramint.2019.02.045
Vujančević J, Andričević P, Bjelajac A, Đokić V, Popović M, Rakočević ZL, Horvath E, Kollar M, Nafradi B, Schiller A, Domanski K, Forro L, Pavlović VP, Janaćković Đ. Dry-pressed anodized titania nanotube/CH3NH3PbI3 single crystal heterojunctions: The beneficial role of N doping. in Ceramics International. 2019;45(8):10013-10020.
doi:10.1016/j.ceramint.2019.02.045 .
Vujančević, Jelena, Andričević, Pavao, Bjelajac, Anđelika, Đokić, Veljko, Popović, Maja, Rakočević, Zlatko Lj., Horvath, Endre, Kollar, Marton, Nafradi, Balint, Schiller, Andreas, Domanski, Konrad, Forro, Laszlo, Pavlović, Vera P., Janaćković, Đorđe, "Dry-pressed anodized titania nanotube/CH3NH3PbI3 single crystal heterojunctions: The beneficial role of N doping" in Ceramics International, 45, no. 8 (2019):10013-10020,
https://doi.org/10.1016/j.ceramint.2019.02.045 . .
5
2
2

Supporting information for the article: Vujančević, J., Andričević, P., Bjelajac, A., Đokić, V., Popović, M., Rakočević, Z., Horváth, E., Kollár, M., Náfrádi, B., Schiller, A., Domanski, K., Forró, L., Pavlović, V., Janaćković, Đ., 2019. Dry-pressed anodized titania nanotube/CH3NH3PbI3 single crystal heterojunctions: The beneficial role of N doping. Ceramics International 45, 10013–10020. https://doi.org/10.1016/j.ceramint.2019.02.045

Vujančević, Jelena; Andričević, Pavao; Bjelajac, Anđelika; Đokić, Veljko; Popović, Maja; Rakočević, Zlatko Lj.; Horváth, Endre; Kollar, Marton; Náfrádi, Bálint; Schiller, Andreas; Domanski, Konrad; Forró, Laszlo; Pavlović, Vera P.; Janaćković, Đorđe

(2019)

TY  - DATA
AU  - Vujančević, Jelena
AU  - Andričević, Pavao
AU  - Bjelajac, Anđelika
AU  - Đokić, Veljko
AU  - Popović, Maja
AU  - Rakočević, Zlatko Lj.
AU  - Horváth, Endre
AU  - Kollar, Marton
AU  - Náfrádi, Bálint
AU  - Schiller, Andreas
AU  - Domanski, Konrad
AU  - Forró, Laszlo
AU  - Pavlović, Vera P.
AU  - Janaćković, Đorđe
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4163
AB  - Table S1. Reported methods for nitrogen doping of anodized TiO2 nanotube arrays; Figure S1. SEM images and statistical distributions of outer diameters obtained by analyzing SEM micrographs of 100 nanotubes; Table S2. Average morphology parameters for TiO2-undoped, TiO2-N30, TiO2-N60 and TiO2-N90 samples; Table S3. Average crystals size for TiO2-undoped, TiO2-N30, TiO2-N60 and TiO2-N90 samples; Figure S2. Deconvoluted XPS spectra of N 1s core level of Ti foil (black line-experimental, grey line-background, magenta line-envelope); Table S4. Peak positions and atomic percentages of N1s core levels for TiO2-undoped, TiO2-N30, TiO2-N60 and TiO2-N90 samples; Table S5. Positions and atomic percentages of Ti 2p3/2 and O1s core peaks for TiO2-undoped, TiO2-N30, TiO2-N60 and TiO2-N90 samples; Figure S3. The time evolution of the current during the preconditioning of the TiO2/perovskite sample at a bias voltage of 100 V for 75 sec. Dashed line is the logarithmic fit of the base line of the current time evolution; Figure S4. Ideality factor for TiO2-undoped, TiO2-N30, TiO2-N60 and TiO2-N90 samples
T2  - Ceramics International
T1  - Supporting information for the article: Vujančević, J., Andričević, P., Bjelajac, A., Đokić, V., Popović, M., Rakočević, Z., Horváth, E., Kollár, M., Náfrádi, B., Schiller, A., Domanski, K., Forró, L., Pavlović, V., Janaćković, Đ., 2019. Dry-pressed anodized titania nanotube/CH3NH3PbI3 single crystal heterojunctions: The beneficial role of N doping. Ceramics International 45, 10013–10020. https://doi.org/10.1016/j.ceramint.2019.02.045
UR  - https://hdl.handle.net/21.15107/rcub_dais_5969
ER  - 
@misc{
author = "Vujančević, Jelena and Andričević, Pavao and Bjelajac, Anđelika and Đokić, Veljko and Popović, Maja and Rakočević, Zlatko Lj. and Horváth, Endre and Kollar, Marton and Náfrádi, Bálint and Schiller, Andreas and Domanski, Konrad and Forró, Laszlo and Pavlović, Vera P. and Janaćković, Đorđe",
year = "2019",
abstract = "Table S1. Reported methods for nitrogen doping of anodized TiO2 nanotube arrays; Figure S1. SEM images and statistical distributions of outer diameters obtained by analyzing SEM micrographs of 100 nanotubes; Table S2. Average morphology parameters for TiO2-undoped, TiO2-N30, TiO2-N60 and TiO2-N90 samples; Table S3. Average crystals size for TiO2-undoped, TiO2-N30, TiO2-N60 and TiO2-N90 samples; Figure S2. Deconvoluted XPS spectra of N 1s core level of Ti foil (black line-experimental, grey line-background, magenta line-envelope); Table S4. Peak positions and atomic percentages of N1s core levels for TiO2-undoped, TiO2-N30, TiO2-N60 and TiO2-N90 samples; Table S5. Positions and atomic percentages of Ti 2p3/2 and O1s core peaks for TiO2-undoped, TiO2-N30, TiO2-N60 and TiO2-N90 samples; Figure S3. The time evolution of the current during the preconditioning of the TiO2/perovskite sample at a bias voltage of 100 V for 75 sec. Dashed line is the logarithmic fit of the base line of the current time evolution; Figure S4. Ideality factor for TiO2-undoped, TiO2-N30, TiO2-N60 and TiO2-N90 samples",
journal = "Ceramics International",
title = "Supporting information for the article: Vujančević, J., Andričević, P., Bjelajac, A., Đokić, V., Popović, M., Rakočević, Z., Horváth, E., Kollár, M., Náfrádi, B., Schiller, A., Domanski, K., Forró, L., Pavlović, V., Janaćković, Đ., 2019. Dry-pressed anodized titania nanotube/CH3NH3PbI3 single crystal heterojunctions: The beneficial role of N doping. Ceramics International 45, 10013–10020. https://doi.org/10.1016/j.ceramint.2019.02.045",
url = "https://hdl.handle.net/21.15107/rcub_dais_5969"
}
Vujančević, J., Andričević, P., Bjelajac, A., Đokić, V., Popović, M., Rakočević, Z. Lj., Horváth, E., Kollar, M., Náfrádi, B., Schiller, A., Domanski, K., Forró, L., Pavlović, V. P.,& Janaćković, Đ.. (2019). Supporting information for the article: Vujančević, J., Andričević, P., Bjelajac, A., Đokić, V., Popović, M., Rakočević, Z., Horváth, E., Kollár, M., Náfrádi, B., Schiller, A., Domanski, K., Forró, L., Pavlović, V., Janaćković, Đ., 2019. Dry-pressed anodized titania nanotube/CH3NH3PbI3 single crystal heterojunctions: The beneficial role of N doping. Ceramics International 45, 10013–10020. https://doi.org/10.1016/j.ceramint.2019.02.045. in Ceramics International.
https://hdl.handle.net/21.15107/rcub_dais_5969
Vujančević J, Andričević P, Bjelajac A, Đokić V, Popović M, Rakočević ZL, Horváth E, Kollar M, Náfrádi B, Schiller A, Domanski K, Forró L, Pavlović VP, Janaćković Đ. Supporting information for the article: Vujančević, J., Andričević, P., Bjelajac, A., Đokić, V., Popović, M., Rakočević, Z., Horváth, E., Kollár, M., Náfrádi, B., Schiller, A., Domanski, K., Forró, L., Pavlović, V., Janaćković, Đ., 2019. Dry-pressed anodized titania nanotube/CH3NH3PbI3 single crystal heterojunctions: The beneficial role of N doping. Ceramics International 45, 10013–10020. https://doi.org/10.1016/j.ceramint.2019.02.045. in Ceramics International. 2019;.
https://hdl.handle.net/21.15107/rcub_dais_5969 .
Vujančević, Jelena, Andričević, Pavao, Bjelajac, Anđelika, Đokić, Veljko, Popović, Maja, Rakočević, Zlatko Lj., Horváth, Endre, Kollar, Marton, Náfrádi, Bálint, Schiller, Andreas, Domanski, Konrad, Forró, Laszlo, Pavlović, Vera P., Janaćković, Đorđe, "Supporting information for the article: Vujančević, J., Andričević, P., Bjelajac, A., Đokić, V., Popović, M., Rakočević, Z., Horváth, E., Kollár, M., Náfrádi, B., Schiller, A., Domanski, K., Forró, L., Pavlović, V., Janaćković, Đ., 2019. Dry-pressed anodized titania nanotube/CH3NH3PbI3 single crystal heterojunctions: The beneficial role of N doping. Ceramics International 45, 10013–10020. https://doi.org/10.1016/j.ceramint.2019.02.045" in Ceramics International (2019),
https://hdl.handle.net/21.15107/rcub_dais_5969 .

Silicon nanostructuring by Ag ions implantation through nanosphere lithography mask

Modrić-Šahbazović, Almedina; Novaković, Mirjana M.; Schmidt, Emanuel O.; Gazdić, Izet; Đokić, Veljko; Peruško, Davor; Bibić, Nataša M.; Ronning, Carsten; Rakočević, Zlatko Lj.

(Elsevier Science Bv, Amsterdam, 2019)

TY  - JOUR
AU  - Modrić-Šahbazović, Almedina
AU  - Novaković, Mirjana M.
AU  - Schmidt, Emanuel O.
AU  - Gazdić, Izet
AU  - Đokić, Veljko
AU  - Peruško, Davor
AU  - Bibić, Nataša M.
AU  - Ronning, Carsten
AU  - Rakočević, Zlatko Lj.
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4160
AB  - Nanosphere lithography is an effective technique for high throughput fabrication of well-ordered patterns on large areas. This study reports on nanostructuring of silicon samples by means of Ag ions implantation through self-organized polystyrene (PS) masks. The PS nanospheres with a diameter of similar to 150 nm were self-assembled in a hexagonal array on top of Si(100) wafers, and then used as a mask for subsequent 60 keV silver ion implantation. Different fluences were applied up to 2 x 10(16) ions/cm(2) in order to create a distribution of different sizes and densities of buried metal nanoparticles. The surface morphology and the subsurface structures were studied by scanning electron microscopy and cross-sectional transmission electron microscopy, as a function of the mask deformation upon irradiation and the implantation parameters itself. We demonstrate that Ag is implanted into Si only through the mask openings, thus forming a regular array of amorphized regions over the wide area of silicon substrate. These fragments are of similar dimensions of the spheres with widths of about 190 nm and distributed over 60 nm in depth due to the given ion range. At the subsurface region of the implanted fragments, the synthesis of small sized and optically active Ag nanoparticles is clearly observed. The samples show a strong absorption peak in the long-wavelength region from 689 to 745 nm characteristic for surface plasmon resonance excitations, which could be fitted well using the Maxwell-Garnett's theory.
PB  - Elsevier Science Bv, Amsterdam
T2  - Optical Materials
T1  - Silicon nanostructuring by Ag ions implantation through nanosphere lithography mask
EP  - 515
SP  - 508
VL  - 88
DO  - 10.1016/j.optmat.2018.12.022
ER  - 
@article{
author = "Modrić-Šahbazović, Almedina and Novaković, Mirjana M. and Schmidt, Emanuel O. and Gazdić, Izet and Đokić, Veljko and Peruško, Davor and Bibić, Nataša M. and Ronning, Carsten and Rakočević, Zlatko Lj.",
year = "2019",
abstract = "Nanosphere lithography is an effective technique for high throughput fabrication of well-ordered patterns on large areas. This study reports on nanostructuring of silicon samples by means of Ag ions implantation through self-organized polystyrene (PS) masks. The PS nanospheres with a diameter of similar to 150 nm were self-assembled in a hexagonal array on top of Si(100) wafers, and then used as a mask for subsequent 60 keV silver ion implantation. Different fluences were applied up to 2 x 10(16) ions/cm(2) in order to create a distribution of different sizes and densities of buried metal nanoparticles. The surface morphology and the subsurface structures were studied by scanning electron microscopy and cross-sectional transmission electron microscopy, as a function of the mask deformation upon irradiation and the implantation parameters itself. We demonstrate that Ag is implanted into Si only through the mask openings, thus forming a regular array of amorphized regions over the wide area of silicon substrate. These fragments are of similar dimensions of the spheres with widths of about 190 nm and distributed over 60 nm in depth due to the given ion range. At the subsurface region of the implanted fragments, the synthesis of small sized and optically active Ag nanoparticles is clearly observed. The samples show a strong absorption peak in the long-wavelength region from 689 to 745 nm characteristic for surface plasmon resonance excitations, which could be fitted well using the Maxwell-Garnett's theory.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Optical Materials",
title = "Silicon nanostructuring by Ag ions implantation through nanosphere lithography mask",
pages = "515-508",
volume = "88",
doi = "10.1016/j.optmat.2018.12.022"
}
Modrić-Šahbazović, A., Novaković, M. M., Schmidt, E. O., Gazdić, I., Đokić, V., Peruško, D., Bibić, N. M., Ronning, C.,& Rakočević, Z. Lj.. (2019). Silicon nanostructuring by Ag ions implantation through nanosphere lithography mask. in Optical Materials
Elsevier Science Bv, Amsterdam., 88, 508-515.
https://doi.org/10.1016/j.optmat.2018.12.022
Modrić-Šahbazović A, Novaković MM, Schmidt EO, Gazdić I, Đokić V, Peruško D, Bibić NM, Ronning C, Rakočević ZL. Silicon nanostructuring by Ag ions implantation through nanosphere lithography mask. in Optical Materials. 2019;88:508-515.
doi:10.1016/j.optmat.2018.12.022 .
Modrić-Šahbazović, Almedina, Novaković, Mirjana M., Schmidt, Emanuel O., Gazdić, Izet, Đokić, Veljko, Peruško, Davor, Bibić, Nataša M., Ronning, Carsten, Rakočević, Zlatko Lj., "Silicon nanostructuring by Ag ions implantation through nanosphere lithography mask" in Optical Materials, 88 (2019):508-515,
https://doi.org/10.1016/j.optmat.2018.12.022 . .
7
7
8

Formation of a large-area monolayer of polystyrene film via the spin-coating method

Modrić-Šahbazović, Almedina; Novaković, Mirjana M.; Đokić, Veljko; Gazdić, Izet; Bibić, Nataša M.; Rakočević, Zlatko Lj.

(Univerzitet u Beogradu - Institut za nuklearne nauke Vinča, Beograd, 2018)

TY  - JOUR
AU  - Modrić-Šahbazović, Almedina
AU  - Novaković, Mirjana M.
AU  - Đokić, Veljko
AU  - Gazdić, Izet
AU  - Bibić, Nataša M.
AU  - Rakočević, Zlatko Lj.
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3920
AB  - The self-assembly methods, an inexpensive and high throughput technique capable of producing nanostructure arrays, relies on the formation on a monolayer of self-assembled nanospheres. This paper reports on the formation of large-areas monolayer polystyrene particles similar to 150 nm in diameter onto monocrystalline Si (100) substrates by using the spin-coating method. In this method, the quality of the deposited monolayer is determined by the balance between spinning and solvent evaporation, accounted by two different forces, the centrifugal force and viscous shearing force, and their interplay. The key process parameters which influence the deposition process and determine the properties of polystyrene monolayers such as the spinning rate, time and concentration of PS particles in the solution were studied. By varying the experimental conditions in different steps the films quality can be easily improved and the optimized experimental parameters were achieved. A homogenous and well-ordered PS monolayer with a high surface coverage of similar to 94 % was formed on a large-area substrate of 1 cm x1 cm at specific conditions of a 2000 rpm spinning rate, 2 wt. % polystyrene solution concentration and 210 s duration of the spinning process. We conclude that this method can be useful in a variety of applications since it offers a stable and controllable approach to the fabrication of monolayer polystyrene films on a large-scale.
PB  - Univerzitet u Beogradu - Institut za nuklearne nauke Vinča, Beograd
T2  - Nuclear Technology & Radiation Protection
T1  - Formation of a large-area monolayer of polystyrene film via the spin-coating method
EP  - 251
IS  - 3
SP  - 246
VL  - 33
DO  - 10.2298/NTRP1803246M
ER  - 
@article{
author = "Modrić-Šahbazović, Almedina and Novaković, Mirjana M. and Đokić, Veljko and Gazdić, Izet and Bibić, Nataša M. and Rakočević, Zlatko Lj.",
year = "2018",
abstract = "The self-assembly methods, an inexpensive and high throughput technique capable of producing nanostructure arrays, relies on the formation on a monolayer of self-assembled nanospheres. This paper reports on the formation of large-areas monolayer polystyrene particles similar to 150 nm in diameter onto monocrystalline Si (100) substrates by using the spin-coating method. In this method, the quality of the deposited monolayer is determined by the balance between spinning and solvent evaporation, accounted by two different forces, the centrifugal force and viscous shearing force, and their interplay. The key process parameters which influence the deposition process and determine the properties of polystyrene monolayers such as the spinning rate, time and concentration of PS particles in the solution were studied. By varying the experimental conditions in different steps the films quality can be easily improved and the optimized experimental parameters were achieved. A homogenous and well-ordered PS monolayer with a high surface coverage of similar to 94 % was formed on a large-area substrate of 1 cm x1 cm at specific conditions of a 2000 rpm spinning rate, 2 wt. % polystyrene solution concentration and 210 s duration of the spinning process. We conclude that this method can be useful in a variety of applications since it offers a stable and controllable approach to the fabrication of monolayer polystyrene films on a large-scale.",
publisher = "Univerzitet u Beogradu - Institut za nuklearne nauke Vinča, Beograd",
journal = "Nuclear Technology & Radiation Protection",
title = "Formation of a large-area monolayer of polystyrene film via the spin-coating method",
pages = "251-246",
number = "3",
volume = "33",
doi = "10.2298/NTRP1803246M"
}
Modrić-Šahbazović, A., Novaković, M. M., Đokić, V., Gazdić, I., Bibić, N. M.,& Rakočević, Z. Lj.. (2018). Formation of a large-area monolayer of polystyrene film via the spin-coating method. in Nuclear Technology & Radiation Protection
Univerzitet u Beogradu - Institut za nuklearne nauke Vinča, Beograd., 33(3), 246-251.
https://doi.org/10.2298/NTRP1803246M
Modrić-Šahbazović A, Novaković MM, Đokić V, Gazdić I, Bibić NM, Rakočević ZL. Formation of a large-area monolayer of polystyrene film via the spin-coating method. in Nuclear Technology & Radiation Protection. 2018;33(3):246-251.
doi:10.2298/NTRP1803246M .
Modrić-Šahbazović, Almedina, Novaković, Mirjana M., Đokić, Veljko, Gazdić, Izet, Bibić, Nataša M., Rakočević, Zlatko Lj., "Formation of a large-area monolayer of polystyrene film via the spin-coating method" in Nuclear Technology & Radiation Protection, 33, no. 3 (2018):246-251,
https://doi.org/10.2298/NTRP1803246M . .
1

Copper-polyaniline nanocomposite: Role of physicochemical properties on the antimicrobial activity and genotoxicity evaluation

Bogdanović, Una; Dimitrijević, Suzana; Škapin, Srečo Davor; Popović, Maja; Rakočević, Zlatko Lj.; Leskovac, Andreja; Petrović, Sandra; Stoiljković, Milovan; Vodnik, Vesna

(Elsevier, Amsterdam, 2018)

TY  - JOUR
AU  - Bogdanović, Una
AU  - Dimitrijević, Suzana
AU  - Škapin, Srečo Davor
AU  - Popović, Maja
AU  - Rakočević, Zlatko Lj.
AU  - Leskovac, Andreja
AU  - Petrović, Sandra
AU  - Stoiljković, Milovan
AU  - Vodnik, Vesna
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3928
AB  - Copper nanoparticles (Cu NPs) have proven to own excellent antimicrobial efficacy, but the problems of easy oxidation and aggregation limit their practical application. Here, nanocomposite based on polyaniline (PANI) and Cu NPs solved this problem and brought additional physicochemical properties that are markedly advantageous for antimicrobial applications. Current work exploits this potential, to examine its time- and concentration-dependent antimicrobial activity, employing E. coli, S. aureus, and C. albicans as a model microbial species. Regarding the presence of polaronic charge carriers in the fibrous polyaniline network, effects of Cu NPs size and their partially oxidized surfaces (the data were confirmed by HRTEM, FESEM, XRD, Raman and XPS analysis), as well as rapid copper ions release, Cu-PANI nanocomposite showed efficient bactericidal and fungicidal activities at the concentrations  lt = 1 ppm, within the incubation time of 2 h. Beside the quantitative analysis, the high levels of cellular disruption for all tested microbes were evidenced by atomic force microscopy. Moreover, the minimum inhibitory and bactericidal concentrations of the Cu-PANI nanocomposite were lower than those reported for other nanocomposites. Using such low concentrations is recognized as a good way to avoid its toxicity toward the environment. For this purpose, Cu-PANI nanocomposite is tested for its genotoxicity and influence on the oxidative status of the human cells in vitro.
PB  - Elsevier, Amsterdam
T2  - Materials Science & Engineering C-Materials for Biological Applications
T1  - Copper-polyaniline nanocomposite: Role of physicochemical properties on the antimicrobial activity and genotoxicity evaluation
EP  - 60
SP  - 49
VL  - 93
DO  - 10.1016/j.msec.2018.07.067
ER  - 
@article{
author = "Bogdanović, Una and Dimitrijević, Suzana and Škapin, Srečo Davor and Popović, Maja and Rakočević, Zlatko Lj. and Leskovac, Andreja and Petrović, Sandra and Stoiljković, Milovan and Vodnik, Vesna",
year = "2018",
abstract = "Copper nanoparticles (Cu NPs) have proven to own excellent antimicrobial efficacy, but the problems of easy oxidation and aggregation limit their practical application. Here, nanocomposite based on polyaniline (PANI) and Cu NPs solved this problem and brought additional physicochemical properties that are markedly advantageous for antimicrobial applications. Current work exploits this potential, to examine its time- and concentration-dependent antimicrobial activity, employing E. coli, S. aureus, and C. albicans as a model microbial species. Regarding the presence of polaronic charge carriers in the fibrous polyaniline network, effects of Cu NPs size and their partially oxidized surfaces (the data were confirmed by HRTEM, FESEM, XRD, Raman and XPS analysis), as well as rapid copper ions release, Cu-PANI nanocomposite showed efficient bactericidal and fungicidal activities at the concentrations  lt = 1 ppm, within the incubation time of 2 h. Beside the quantitative analysis, the high levels of cellular disruption for all tested microbes were evidenced by atomic force microscopy. Moreover, the minimum inhibitory and bactericidal concentrations of the Cu-PANI nanocomposite were lower than those reported for other nanocomposites. Using such low concentrations is recognized as a good way to avoid its toxicity toward the environment. For this purpose, Cu-PANI nanocomposite is tested for its genotoxicity and influence on the oxidative status of the human cells in vitro.",
publisher = "Elsevier, Amsterdam",
journal = "Materials Science & Engineering C-Materials for Biological Applications",
title = "Copper-polyaniline nanocomposite: Role of physicochemical properties on the antimicrobial activity and genotoxicity evaluation",
pages = "60-49",
volume = "93",
doi = "10.1016/j.msec.2018.07.067"
}
Bogdanović, U., Dimitrijević, S., Škapin, S. D., Popović, M., Rakočević, Z. Lj., Leskovac, A., Petrović, S., Stoiljković, M.,& Vodnik, V.. (2018). Copper-polyaniline nanocomposite: Role of physicochemical properties on the antimicrobial activity and genotoxicity evaluation. in Materials Science & Engineering C-Materials for Biological Applications
Elsevier, Amsterdam., 93, 49-60.
https://doi.org/10.1016/j.msec.2018.07.067
Bogdanović U, Dimitrijević S, Škapin SD, Popović M, Rakočević ZL, Leskovac A, Petrović S, Stoiljković M, Vodnik V. Copper-polyaniline nanocomposite: Role of physicochemical properties on the antimicrobial activity and genotoxicity evaluation. in Materials Science & Engineering C-Materials for Biological Applications. 2018;93:49-60.
doi:10.1016/j.msec.2018.07.067 .
Bogdanović, Una, Dimitrijević, Suzana, Škapin, Srečo Davor, Popović, Maja, Rakočević, Zlatko Lj., Leskovac, Andreja, Petrović, Sandra, Stoiljković, Milovan, Vodnik, Vesna, "Copper-polyaniline nanocomposite: Role of physicochemical properties on the antimicrobial activity and genotoxicity evaluation" in Materials Science & Engineering C-Materials for Biological Applications, 93 (2018):49-60,
https://doi.org/10.1016/j.msec.2018.07.067 . .
25
14
24

Structural Characteristics and Bonding Environment of Ag Nanoparticles Synthesized by Gamma Irradiation Within Thermo-Responsive Poly(N-isopropylacrylamide) Hydrogel

Spasojević, Jelena P.; Radosavljević, Aleksandra; Krstić, Jelena I.; Mitrić, Miodrag; Popović, Maja; Rakočević, Zlatko Lj.; Kalagasidis Krušić, Melina; Kačarević-Popović, Zorica M.

(Wiley, Hoboken, 2017)

TY  - JOUR
AU  - Spasojević, Jelena P.
AU  - Radosavljević, Aleksandra
AU  - Krstić, Jelena I.
AU  - Mitrić, Miodrag
AU  - Popović, Maja
AU  - Rakočević, Zlatko Lj.
AU  - Kalagasidis Krušić, Melina
AU  - Kačarević-Popović, Zorica M.
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3718
AB  - To produce well-defined metal clusters stabilized in protective matrix, poly(N-isopropylacrylamide) (PNi-PAAm) hydrogel with different initial concentration of polymer was used as nanoreactor. The in situ synthesis of well dispersed silver nanoparticles (AgNPs) was performed by gamma irradiation. The obtained AgNPs are spherical in shape with the diameter less than 20 nm. Crystalline properties of nanoparticles such as size, texture coefficient, strain, stress, lattice parameter, d-spacing, and dislocation density have been calculated using XRD data. Results confirm that the changes of lattice parameter of crystalline AgNPs sensitively reflect their state of strain and stress depending on the formation conditions (i.e., on the concentration of PNiPAAm) and on the diameter of AgNPs. The negative lattice strain and compression stress were observed for the smaller AgNPs (lattice contraction), while for the larger AgNPs are positively strained and under tensile stress (lattice expansion). XPS spectra revealed the donor-acceptor type of interaction between carbonyl oxygen from PNiPAAm and AgNPs (positive shift of high BE component of O 1s and negative shift of Ag 3d BE). The greater dislocation density of smaller AgNPs incorporated in more concentrated PNiPAAm, resulted in more binding sites and stronger interaction with polymer.
PB  - Wiley, Hoboken
T2  - Polymer Composites
T1  - Structural Characteristics and Bonding Environment of Ag Nanoparticles Synthesized by Gamma Irradiation Within Thermo-Responsive Poly(N-isopropylacrylamide) Hydrogel
EP  - 1026
IS  - 5
SP  - 1014
VL  - 38
DO  - 10.1002/pc.23665
ER  - 
@article{
author = "Spasojević, Jelena P. and Radosavljević, Aleksandra and Krstić, Jelena I. and Mitrić, Miodrag and Popović, Maja and Rakočević, Zlatko Lj. and Kalagasidis Krušić, Melina and Kačarević-Popović, Zorica M.",
year = "2017",
abstract = "To produce well-defined metal clusters stabilized in protective matrix, poly(N-isopropylacrylamide) (PNi-PAAm) hydrogel with different initial concentration of polymer was used as nanoreactor. The in situ synthesis of well dispersed silver nanoparticles (AgNPs) was performed by gamma irradiation. The obtained AgNPs are spherical in shape with the diameter less than 20 nm. Crystalline properties of nanoparticles such as size, texture coefficient, strain, stress, lattice parameter, d-spacing, and dislocation density have been calculated using XRD data. Results confirm that the changes of lattice parameter of crystalline AgNPs sensitively reflect their state of strain and stress depending on the formation conditions (i.e., on the concentration of PNiPAAm) and on the diameter of AgNPs. The negative lattice strain and compression stress were observed for the smaller AgNPs (lattice contraction), while for the larger AgNPs are positively strained and under tensile stress (lattice expansion). XPS spectra revealed the donor-acceptor type of interaction between carbonyl oxygen from PNiPAAm and AgNPs (positive shift of high BE component of O 1s and negative shift of Ag 3d BE). The greater dislocation density of smaller AgNPs incorporated in more concentrated PNiPAAm, resulted in more binding sites and stronger interaction with polymer.",
publisher = "Wiley, Hoboken",
journal = "Polymer Composites",
title = "Structural Characteristics and Bonding Environment of Ag Nanoparticles Synthesized by Gamma Irradiation Within Thermo-Responsive Poly(N-isopropylacrylamide) Hydrogel",
pages = "1026-1014",
number = "5",
volume = "38",
doi = "10.1002/pc.23665"
}
Spasojević, J. P., Radosavljević, A., Krstić, J. I., Mitrić, M., Popović, M., Rakočević, Z. Lj., Kalagasidis Krušić, M.,& Kačarević-Popović, Z. M.. (2017). Structural Characteristics and Bonding Environment of Ag Nanoparticles Synthesized by Gamma Irradiation Within Thermo-Responsive Poly(N-isopropylacrylamide) Hydrogel. in Polymer Composites
Wiley, Hoboken., 38(5), 1014-1026.
https://doi.org/10.1002/pc.23665
Spasojević JP, Radosavljević A, Krstić JI, Mitrić M, Popović M, Rakočević ZL, Kalagasidis Krušić M, Kačarević-Popović ZM. Structural Characteristics and Bonding Environment of Ag Nanoparticles Synthesized by Gamma Irradiation Within Thermo-Responsive Poly(N-isopropylacrylamide) Hydrogel. in Polymer Composites. 2017;38(5):1014-1026.
doi:10.1002/pc.23665 .
Spasojević, Jelena P., Radosavljević, Aleksandra, Krstić, Jelena I., Mitrić, Miodrag, Popović, Maja, Rakočević, Zlatko Lj., Kalagasidis Krušić, Melina, Kačarević-Popović, Zorica M., "Structural Characteristics and Bonding Environment of Ag Nanoparticles Synthesized by Gamma Irradiation Within Thermo-Responsive Poly(N-isopropylacrylamide) Hydrogel" in Polymer Composites, 38, no. 5 (2017):1014-1026,
https://doi.org/10.1002/pc.23665 . .
13
6
14

Structural, Chemical and Magnetic Properties of Nickel Vertical Posts Obtained by Glancing Angle Deposition Technique

Potočnik, Jelena; Nenadović, Miloš; Jokić, Bojan M.; Popović, Maja; Rakočević, Zlatko Lj.

(2017)

TY  - JOUR
AU  - Potočnik, Jelena
AU  - Nenadović, Miloš
AU  - Jokić, Bojan M.
AU  - Popović, Maja
AU  - Rakočević, Zlatko Lj.
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5853
AB  - In this work, Glancing Angle Deposition technique was used for obtaining nanostructured nickel thin film with vertical posts on glass substrate which was positioned 75 degrees with respect to the substrate normal and rotated with a suitable constant speed. The obtained nickel thin film was characterized by Scanning Electron Microscopy, Atomic Force Microscopy and X-ray Photoelectron Spectroscopy. It was found that the deposited thin film consists of 94.0 at.% of nickel. Magnetic properties of the deposited thin film were determined by Magneto-Optical Kerr Effect Microscopy. According to the obtained coercivity values, it can be concluded that the nickel thin film shows uniaxial magnetic anisotropy.
T2  - Science of Sintering
T1  - Structural, Chemical and Magnetic Properties of Nickel Vertical Posts Obtained by Glancing Angle Deposition Technique
EP  - 79
IS  - 1
SP  - 73
VL  - 49
DO  - 10.2298/SOS1701073P
ER  - 
@article{
author = "Potočnik, Jelena and Nenadović, Miloš and Jokić, Bojan M. and Popović, Maja and Rakočević, Zlatko Lj.",
year = "2017",
abstract = "In this work, Glancing Angle Deposition technique was used for obtaining nanostructured nickel thin film with vertical posts on glass substrate which was positioned 75 degrees with respect to the substrate normal and rotated with a suitable constant speed. The obtained nickel thin film was characterized by Scanning Electron Microscopy, Atomic Force Microscopy and X-ray Photoelectron Spectroscopy. It was found that the deposited thin film consists of 94.0 at.% of nickel. Magnetic properties of the deposited thin film were determined by Magneto-Optical Kerr Effect Microscopy. According to the obtained coercivity values, it can be concluded that the nickel thin film shows uniaxial magnetic anisotropy.",
journal = "Science of Sintering",
title = "Structural, Chemical and Magnetic Properties of Nickel Vertical Posts Obtained by Glancing Angle Deposition Technique",
pages = "79-73",
number = "1",
volume = "49",
doi = "10.2298/SOS1701073P"
}
Potočnik, J., Nenadović, M., Jokić, B. M., Popović, M.,& Rakočević, Z. Lj.. (2017). Structural, Chemical and Magnetic Properties of Nickel Vertical Posts Obtained by Glancing Angle Deposition Technique. in Science of Sintering, 49(1), 73-79.
https://doi.org/10.2298/SOS1701073P
Potočnik J, Nenadović M, Jokić BM, Popović M, Rakočević ZL. Structural, Chemical and Magnetic Properties of Nickel Vertical Posts Obtained by Glancing Angle Deposition Technique. in Science of Sintering. 2017;49(1):73-79.
doi:10.2298/SOS1701073P .
Potočnik, Jelena, Nenadović, Miloš, Jokić, Bojan M., Popović, Maja, Rakočević, Zlatko Lj., "Structural, Chemical and Magnetic Properties of Nickel Vertical Posts Obtained by Glancing Angle Deposition Technique" in Science of Sintering, 49, no. 1 (2017):73-79,
https://doi.org/10.2298/SOS1701073P . .
1
1
2

Absorption boost of TiO2 nanotubes by doping with N and sensitization with CdS quantum dots

Bjelajac, Anđelika; Đokić, Veljko; Petrović, Rada; Bundaleski, Nenad; Socol, Gabriel; Mihailescu, Ion N.; Rakočević, Zlatko Lj.; Janaćković, Đorđe

(Elsevier Sci Ltd, Oxford, 2017)

TY  - JOUR
AU  - Bjelajac, Anđelika
AU  - Đokić, Veljko
AU  - Petrović, Rada
AU  - Bundaleski, Nenad
AU  - Socol, Gabriel
AU  - Mihailescu, Ion N.
AU  - Rakočević, Zlatko Lj.
AU  - Janaćković, Đorđe
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3631
AB  - A process of obtaining N-doped TiO2 nanotubes sensitized by CdS nanoparticles is presented, including detailed characterizations performed along the synthesis. Transparent TiO2 films consisting of nanotubes, 2.5 mu m long and of similar to 60 nm inner diameter, were obtained after anodization of a titanium film deposited onto FTO glass substrate. N-doping was achieved by annealing of TiO2 film in ammonia. X-ray Photoelectron Spectroscopy measurements showed that nitrogen was substitutionally incorporated in the TiO2 matrix, with the N:Ti concentration ratio of 1:100. The doping changed the optical properties of the material in such a way that the absorption edge was shifted from 380 nm to 507 nm, as observed from diffuse reflectance spectra. The influence of the microwave (MW) irradiation on the synthesized CdS quantum dots and their optical properties was investigated. It was shown that the diameter of CdS nanoparticles was increased due to releasing of S-2-ions from dimethyl sulfoxide (DMSO) as a consequence of the MW treatment. The (N)TiO2 films were then used as substrates for matrix assisted pulsed laser deposition of the CdS quantum dots with DMSO as a matrix. The laser parameters for the deposition were optimized in order to preserve the nanotubular structure open, the latter being an important feature of this type of photoanode. The structure obtained under optimized conditions has an additional absorption edge shift, reaching 603 nm.
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Absorption boost of TiO2 nanotubes by doping with N and sensitization with CdS quantum dots
EP  - 15046
IS  - 17
SP  - 15040
VL  - 43
DO  - 10.1016/j.ceramint.2017.08.029
ER  - 
@article{
author = "Bjelajac, Anđelika and Đokić, Veljko and Petrović, Rada and Bundaleski, Nenad and Socol, Gabriel and Mihailescu, Ion N. and Rakočević, Zlatko Lj. and Janaćković, Đorđe",
year = "2017",
abstract = "A process of obtaining N-doped TiO2 nanotubes sensitized by CdS nanoparticles is presented, including detailed characterizations performed along the synthesis. Transparent TiO2 films consisting of nanotubes, 2.5 mu m long and of similar to 60 nm inner diameter, were obtained after anodization of a titanium film deposited onto FTO glass substrate. N-doping was achieved by annealing of TiO2 film in ammonia. X-ray Photoelectron Spectroscopy measurements showed that nitrogen was substitutionally incorporated in the TiO2 matrix, with the N:Ti concentration ratio of 1:100. The doping changed the optical properties of the material in such a way that the absorption edge was shifted from 380 nm to 507 nm, as observed from diffuse reflectance spectra. The influence of the microwave (MW) irradiation on the synthesized CdS quantum dots and their optical properties was investigated. It was shown that the diameter of CdS nanoparticles was increased due to releasing of S-2-ions from dimethyl sulfoxide (DMSO) as a consequence of the MW treatment. The (N)TiO2 films were then used as substrates for matrix assisted pulsed laser deposition of the CdS quantum dots with DMSO as a matrix. The laser parameters for the deposition were optimized in order to preserve the nanotubular structure open, the latter being an important feature of this type of photoanode. The structure obtained under optimized conditions has an additional absorption edge shift, reaching 603 nm.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Absorption boost of TiO2 nanotubes by doping with N and sensitization with CdS quantum dots",
pages = "15046-15040",
number = "17",
volume = "43",
doi = "10.1016/j.ceramint.2017.08.029"
}
Bjelajac, A., Đokić, V., Petrović, R., Bundaleski, N., Socol, G., Mihailescu, I. N., Rakočević, Z. Lj.,& Janaćković, Đ.. (2017). Absorption boost of TiO2 nanotubes by doping with N and sensitization with CdS quantum dots. in Ceramics International
Elsevier Sci Ltd, Oxford., 43(17), 15040-15046.
https://doi.org/10.1016/j.ceramint.2017.08.029
Bjelajac A, Đokić V, Petrović R, Bundaleski N, Socol G, Mihailescu IN, Rakočević ZL, Janaćković Đ. Absorption boost of TiO2 nanotubes by doping with N and sensitization with CdS quantum dots. in Ceramics International. 2017;43(17):15040-15046.
doi:10.1016/j.ceramint.2017.08.029 .
Bjelajac, Anđelika, Đokić, Veljko, Petrović, Rada, Bundaleski, Nenad, Socol, Gabriel, Mihailescu, Ion N., Rakočević, Zlatko Lj., Janaćković, Đorđe, "Absorption boost of TiO2 nanotubes by doping with N and sensitization with CdS quantum dots" in Ceramics International, 43, no. 17 (2017):15040-15046,
https://doi.org/10.1016/j.ceramint.2017.08.029 . .
12
10
12

Preparation of boron-doped hydrothermal carbon from glucose for carbon paste electrode

Kalijadis, Ana; Đorđević, Jelena S.; Trtić-Petrović, Tatjana M.; Vukčević, Marija; Popović, Maja; Maksimović, Vesna; Rakočević, Zlatko Lj.; Laušević, Zoran

(Pergamon-Elsevier Science Ltd, Oxford, 2015)

TY  - JOUR
AU  - Kalijadis, Ana
AU  - Đorđević, Jelena S.
AU  - Trtić-Petrović, Tatjana M.
AU  - Vukčević, Marija
AU  - Popović, Maja
AU  - Maksimović, Vesna
AU  - Rakočević, Zlatko Lj.
AU  - Laušević, Zoran
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3074
AB  - Boron doped hydrothermal carbon microspheres were synthesized by introducing boric acid into glucose precursor solution to obtain boron concentration from 0.1 to 1 wt. %. Following hydrothermal treatment, samples were thermally treated to 1000 degrees C. For obtained samples structural and surface characterization were performed. Characterization of obtained samples as material for carbon paste electrode was achieved by measurement of the Fe (CN)(6)(3-/4-) redox couple and linuron determination. Catalytic effect of boric acid on hydrothermal reaction induced enlargement of particle size for boron doped samples. Significant reduction of specific surface area for samples with highest boron concentration was observed. Boron was substitutionally incorporated in the structure of doped samples and incorporation up to 0.6 wt. % in precursor solution generates structure ordering, which induces a reduction of surface active sites for oxygen adsorption in a greater extent. It was found that modified structural and surface characteristics are responsible for good electron transfer property of carbon paste electrode based on doped samples with nominal boron concentration range from 0.2 to 0.6 wt. %. However, it has been shown that sample with nominal boron concentration of 0.2 wt. % proved to be most promising candidate as a material for carbon paste electrode.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Carbon
T1  - Preparation of boron-doped hydrothermal carbon from glucose for carbon paste electrode
EP  - 50
SP  - 42
VL  - 95
DO  - 10.1016/j.carbon.2015.08.016
ER  - 
@article{
author = "Kalijadis, Ana and Đorđević, Jelena S. and Trtić-Petrović, Tatjana M. and Vukčević, Marija and Popović, Maja and Maksimović, Vesna and Rakočević, Zlatko Lj. and Laušević, Zoran",
year = "2015",
abstract = "Boron doped hydrothermal carbon microspheres were synthesized by introducing boric acid into glucose precursor solution to obtain boron concentration from 0.1 to 1 wt. %. Following hydrothermal treatment, samples were thermally treated to 1000 degrees C. For obtained samples structural and surface characterization were performed. Characterization of obtained samples as material for carbon paste electrode was achieved by measurement of the Fe (CN)(6)(3-/4-) redox couple and linuron determination. Catalytic effect of boric acid on hydrothermal reaction induced enlargement of particle size for boron doped samples. Significant reduction of specific surface area for samples with highest boron concentration was observed. Boron was substitutionally incorporated in the structure of doped samples and incorporation up to 0.6 wt. % in precursor solution generates structure ordering, which induces a reduction of surface active sites for oxygen adsorption in a greater extent. It was found that modified structural and surface characteristics are responsible for good electron transfer property of carbon paste electrode based on doped samples with nominal boron concentration range from 0.2 to 0.6 wt. %. However, it has been shown that sample with nominal boron concentration of 0.2 wt. % proved to be most promising candidate as a material for carbon paste electrode.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Carbon",
title = "Preparation of boron-doped hydrothermal carbon from glucose for carbon paste electrode",
pages = "50-42",
volume = "95",
doi = "10.1016/j.carbon.2015.08.016"
}
Kalijadis, A., Đorđević, J. S., Trtić-Petrović, T. M., Vukčević, M., Popović, M., Maksimović, V., Rakočević, Z. Lj.,& Laušević, Z.. (2015). Preparation of boron-doped hydrothermal carbon from glucose for carbon paste electrode. in Carbon
Pergamon-Elsevier Science Ltd, Oxford., 95, 42-50.
https://doi.org/10.1016/j.carbon.2015.08.016
Kalijadis A, Đorđević JS, Trtić-Petrović TM, Vukčević M, Popović M, Maksimović V, Rakočević ZL, Laušević Z. Preparation of boron-doped hydrothermal carbon from glucose for carbon paste electrode. in Carbon. 2015;95:42-50.
doi:10.1016/j.carbon.2015.08.016 .
Kalijadis, Ana, Đorđević, Jelena S., Trtić-Petrović, Tatjana M., Vukčević, Marija, Popović, Maja, Maksimović, Vesna, Rakočević, Zlatko Lj., Laušević, Zoran, "Preparation of boron-doped hydrothermal carbon from glucose for carbon paste electrode" in Carbon, 95 (2015):42-50,
https://doi.org/10.1016/j.carbon.2015.08.016 . .
39
27
36

The antimicrobial efficiency of silver activated sorbents

Đolić, Maja; Rajaković-Ognjanović, Vladana; Štrbac, Svetlana; Rakočević, Zlatko Lj.; Veljović, Đorđe; Dimitrijević, Suzana; Rajaković, Ljubinka V.

(Elsevier Science Bv, Amsterdam, 2015)

TY  - JOUR
AU  - Đolić, Maja
AU  - Rajaković-Ognjanović, Vladana
AU  - Štrbac, Svetlana
AU  - Rakočević, Zlatko Lj.
AU  - Veljović, Đorđe
AU  - Dimitrijević, Suzana
AU  - Rajaković, Ljubinka V.
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3093
AB  - This study is focused on the surface modifications of the materials that are used for antimicrobial water treatment. Sorbents of different origin were activated by Ag+-ions. The selection of the most appropriate materials and the most effective activation agents was done according to the results of the sorption and desorption kinetic studies. Sorption capacities of selected sorbents: granulated activated carbon (GAC), zeolite (Z), and titanium dioxide (T), activated by Ag+-ions were following: 42.06, 13.51 and 17.53 mg/g, respectively. The antimicrobial activity of Ag/Z, Ag/GAC and Ag/T sorbents were tested against Gram-negative bacteria E. coli, Gram-positive bacteria S. aureus and yeast C. albicans. After 15 min of exposure period, the highest cell removal was obtained using Ag/Z against S. aureus and E. coli, 98.8 and 93.5%, respectively. Yeast cell inactivation was unsatisfactory for all three activated sorbents. The antimicrobial pathway of the activated sorbents has been examined by two separate tests - Ag+-ions desorbed from the activated surface to the aqueous phase and microbial cell removal caused by the Ag+-ions from the solid phase (activated surface sites). The results indicated that disinfection process significantly depended on the microbial-activated sites interactions on the modified surface. The chemical state of the activating agent had crucial impact to the inhibition rate. The characterization of the native and modified sorbents was performed by X-ray diffraction technique, X-ray photoelectron spectroscopy and scanning electron microscope. The concentration of adsorbed and released ions was determined by inductively coupled plasma optical emission spectroscopy and mass spectrometry. The antimicrobial efficiency of activated sorbents was related not only to the concentration of the activating agent, but moreover on the surface characteristics of the material, which affects the distribution and the accessibility of the activating agent.
PB  - Elsevier Science Bv, Amsterdam
T2  - Applied Surface Science
T1  - The antimicrobial efficiency of silver activated sorbents
EP  - 831
SP  - 819
VL  - 357
DO  - 10.1016/j.apsusc.2015.09.032
ER  - 
@article{
author = "Đolić, Maja and Rajaković-Ognjanović, Vladana and Štrbac, Svetlana and Rakočević, Zlatko Lj. and Veljović, Đorđe and Dimitrijević, Suzana and Rajaković, Ljubinka V.",
year = "2015",
abstract = "This study is focused on the surface modifications of the materials that are used for antimicrobial water treatment. Sorbents of different origin were activated by Ag+-ions. The selection of the most appropriate materials and the most effective activation agents was done according to the results of the sorption and desorption kinetic studies. Sorption capacities of selected sorbents: granulated activated carbon (GAC), zeolite (Z), and titanium dioxide (T), activated by Ag+-ions were following: 42.06, 13.51 and 17.53 mg/g, respectively. The antimicrobial activity of Ag/Z, Ag/GAC and Ag/T sorbents were tested against Gram-negative bacteria E. coli, Gram-positive bacteria S. aureus and yeast C. albicans. After 15 min of exposure period, the highest cell removal was obtained using Ag/Z against S. aureus and E. coli, 98.8 and 93.5%, respectively. Yeast cell inactivation was unsatisfactory for all three activated sorbents. The antimicrobial pathway of the activated sorbents has been examined by two separate tests - Ag+-ions desorbed from the activated surface to the aqueous phase and microbial cell removal caused by the Ag+-ions from the solid phase (activated surface sites). The results indicated that disinfection process significantly depended on the microbial-activated sites interactions on the modified surface. The chemical state of the activating agent had crucial impact to the inhibition rate. The characterization of the native and modified sorbents was performed by X-ray diffraction technique, X-ray photoelectron spectroscopy and scanning electron microscope. The concentration of adsorbed and released ions was determined by inductively coupled plasma optical emission spectroscopy and mass spectrometry. The antimicrobial efficiency of activated sorbents was related not only to the concentration of the activating agent, but moreover on the surface characteristics of the material, which affects the distribution and the accessibility of the activating agent.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Applied Surface Science",
title = "The antimicrobial efficiency of silver activated sorbents",
pages = "831-819",
volume = "357",
doi = "10.1016/j.apsusc.2015.09.032"
}
Đolić, M., Rajaković-Ognjanović, V., Štrbac, S., Rakočević, Z. Lj., Veljović, Đ., Dimitrijević, S.,& Rajaković, L. V.. (2015). The antimicrobial efficiency of silver activated sorbents. in Applied Surface Science
Elsevier Science Bv, Amsterdam., 357, 819-831.
https://doi.org/10.1016/j.apsusc.2015.09.032
Đolić M, Rajaković-Ognjanović V, Štrbac S, Rakočević ZL, Veljović Đ, Dimitrijević S, Rajaković LV. The antimicrobial efficiency of silver activated sorbents. in Applied Surface Science. 2015;357:819-831.
doi:10.1016/j.apsusc.2015.09.032 .
Đolić, Maja, Rajaković-Ognjanović, Vladana, Štrbac, Svetlana, Rakočević, Zlatko Lj., Veljović, Đorđe, Dimitrijević, Suzana, Rajaković, Ljubinka V., "The antimicrobial efficiency of silver activated sorbents" in Applied Surface Science, 357 (2015):819-831,
https://doi.org/10.1016/j.apsusc.2015.09.032 . .
16
14
17

Catalysis of hydrogen evolution on different Pd/Au(111) nanostructures in alkaline solution

Smiljanić, Milutin Lj.; Srejić, Irina; Grgur, Branimir; Rakočević, Zlatko Lj.; Štrbac, Svetlana

(Pergamon-Elsevier Science Ltd, Oxford, 2013)

TY  - JOUR
AU  - Smiljanić, Milutin Lj.
AU  - Srejić, Irina
AU  - Grgur, Branimir
AU  - Rakočević, Zlatko Lj.
AU  - Štrbac, Svetlana
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2511
AB  - Hydrogen evolution reaction (HER) was studied on Pd/Au(1 1 1) bimetallic surfaces in alkaline solution. Au(1 1 1) was modified by palladium nanoislands spontaneously deposited using PdSO4 center dot 2H(2)O and PdCl2 salts. As revealed from both surface topography Atomic Force Microscopy (AFM) and phase AFM images, for the same deposition conditions, the obtained Pd/Au(1 1 1) nanostructures differ depending on the counter anion in the depositing palladium salt. These differences are reflected on their catalytic activity toward HER, which occurs between the potentials for pure consisting metals. HER proceeded with the same mechanism, but it is shifted to more positive potentials for Pd/Au(1 1 1) nanostructures obtained using PdCl2 salt with respect to ones obtained using PdSO4 salt. Better catalytic activity of Pd/Au(1 1 1) nanostructures obtained using PdCl2 salt can be explained by their surface structure consisting of smaller and thinner Pd nanoislands, preferentially deposited at steps, which provides more Pd and Pd/Au sites suitable for hydrogen evolution reaction.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Electrochimica Acta
T1  - Catalysis of hydrogen evolution on different Pd/Au(111) nanostructures in alkaline solution
EP  - 596
SP  - 589
VL  - 88
DO  - 10.1016/j.electacta.2012.10.128
ER  - 
@article{
author = "Smiljanić, Milutin Lj. and Srejić, Irina and Grgur, Branimir and Rakočević, Zlatko Lj. and Štrbac, Svetlana",
year = "2013",
abstract = "Hydrogen evolution reaction (HER) was studied on Pd/Au(1 1 1) bimetallic surfaces in alkaline solution. Au(1 1 1) was modified by palladium nanoislands spontaneously deposited using PdSO4 center dot 2H(2)O and PdCl2 salts. As revealed from both surface topography Atomic Force Microscopy (AFM) and phase AFM images, for the same deposition conditions, the obtained Pd/Au(1 1 1) nanostructures differ depending on the counter anion in the depositing palladium salt. These differences are reflected on their catalytic activity toward HER, which occurs between the potentials for pure consisting metals. HER proceeded with the same mechanism, but it is shifted to more positive potentials for Pd/Au(1 1 1) nanostructures obtained using PdCl2 salt with respect to ones obtained using PdSO4 salt. Better catalytic activity of Pd/Au(1 1 1) nanostructures obtained using PdCl2 salt can be explained by their surface structure consisting of smaller and thinner Pd nanoislands, preferentially deposited at steps, which provides more Pd and Pd/Au sites suitable for hydrogen evolution reaction.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Electrochimica Acta",
title = "Catalysis of hydrogen evolution on different Pd/Au(111) nanostructures in alkaline solution",
pages = "596-589",
volume = "88",
doi = "10.1016/j.electacta.2012.10.128"
}
Smiljanić, M. Lj., Srejić, I., Grgur, B., Rakočević, Z. Lj.,& Štrbac, S.. (2013). Catalysis of hydrogen evolution on different Pd/Au(111) nanostructures in alkaline solution. in Electrochimica Acta
Pergamon-Elsevier Science Ltd, Oxford., 88, 589-596.
https://doi.org/10.1016/j.electacta.2012.10.128
Smiljanić ML, Srejić I, Grgur B, Rakočević ZL, Štrbac S. Catalysis of hydrogen evolution on different Pd/Au(111) nanostructures in alkaline solution. in Electrochimica Acta. 2013;88:589-596.
doi:10.1016/j.electacta.2012.10.128 .
Smiljanić, Milutin Lj., Srejić, Irina, Grgur, Branimir, Rakočević, Zlatko Lj., Štrbac, Svetlana, "Catalysis of hydrogen evolution on different Pd/Au(111) nanostructures in alkaline solution" in Electrochimica Acta, 88 (2013):589-596,
https://doi.org/10.1016/j.electacta.2012.10.128 . .
36
33
37

Hydrogen evolution on Au(111) catalyzed by rhodium nanoislands

Smiljanić, Milutin Lj.; Srejić, Irina; Grgur, Branimir; Rakočević, Zlatko Lj.; Štrbac, Svetlana

(Elsevier Science Inc, New York, 2013)

TY  - JOUR
AU  - Smiljanić, Milutin Lj.
AU  - Srejić, Irina
AU  - Grgur, Branimir
AU  - Rakočević, Zlatko Lj.
AU  - Štrbac, Svetlana
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2535
AB  - Pronounced catalysis of hydrogen evolution reaction (HER) by rhodium nanoislands spontaneously deposited on Au(111) has been observed. Different Rh/Au(111) nanostructures were characterized ex situ by both height and phase imaging AFM. The most pronounced catalytic activity for HER in 0.5 M H2SO4 was obtained for 50% Rh coverage. This is ascribed to the suitable size of Rh nanoislands and to the electronic modification of Rh deposit by Au(111) substrate.
PB  - Elsevier Science Inc, New York
T2  - Electrochemistry Communications
T1  - Hydrogen evolution on Au(111) catalyzed by rhodium nanoislands
EP  - 39
SP  - 37
VL  - 28
DO  - 10.1016/j.elecom.2012.12.009
ER  - 
@article{
author = "Smiljanić, Milutin Lj. and Srejić, Irina and Grgur, Branimir and Rakočević, Zlatko Lj. and Štrbac, Svetlana",
year = "2013",
abstract = "Pronounced catalysis of hydrogen evolution reaction (HER) by rhodium nanoislands spontaneously deposited on Au(111) has been observed. Different Rh/Au(111) nanostructures were characterized ex situ by both height and phase imaging AFM. The most pronounced catalytic activity for HER in 0.5 M H2SO4 was obtained for 50% Rh coverage. This is ascribed to the suitable size of Rh nanoislands and to the electronic modification of Rh deposit by Au(111) substrate.",
publisher = "Elsevier Science Inc, New York",
journal = "Electrochemistry Communications",
title = "Hydrogen evolution on Au(111) catalyzed by rhodium nanoislands",
pages = "39-37",
volume = "28",
doi = "10.1016/j.elecom.2012.12.009"
}
Smiljanić, M. Lj., Srejić, I., Grgur, B., Rakočević, Z. Lj.,& Štrbac, S.. (2013). Hydrogen evolution on Au(111) catalyzed by rhodium nanoislands. in Electrochemistry Communications
Elsevier Science Inc, New York., 28, 37-39.
https://doi.org/10.1016/j.elecom.2012.12.009
Smiljanić ML, Srejić I, Grgur B, Rakočević ZL, Štrbac S. Hydrogen evolution on Au(111) catalyzed by rhodium nanoislands. in Electrochemistry Communications. 2013;28:37-39.
doi:10.1016/j.elecom.2012.12.009 .
Smiljanić, Milutin Lj., Srejić, Irina, Grgur, Branimir, Rakočević, Zlatko Lj., Štrbac, Svetlana, "Hydrogen evolution on Au(111) catalyzed by rhodium nanoislands" in Electrochemistry Communications, 28 (2013):37-39,
https://doi.org/10.1016/j.elecom.2012.12.009 . .
19
16
21

Catalysis of oxygen reduction on Au modified by Pd nanoislands in perchloric acid solution

Srejić, Irina; Smiljanić, Milutin Lj.; Grgur, Branimir; Rakočević, Zlatko Lj.; Štrbac, Svetlana

(Pergamon-Elsevier Science Ltd, Oxford, 2012)

TY  - JOUR
AU  - Srejić, Irina
AU  - Smiljanić, Milutin Lj.
AU  - Grgur, Branimir
AU  - Rakočević, Zlatko Lj.
AU  - Štrbac, Svetlana
PY  - 2012
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2212
AB  - Oxygen reduction reaction (ORR) was studied on polycrystalline gold, Au(poly), modified by nanosized palladium islands in 0.1 M HClO4 solution using rotating disc electrode technique. Paladium was spontaneously deposited from 1 mM PdSO4 center dot 2H(2)O + 0.5 M H2SO4 solution for various deposition times at a submonolayer coverage. Topography of obtained Pd/Au(poly) surfaces was observed by tapping mode atomic force microscopy (AFM), while chemical surface composition changes were detected by simultaneously performed phase AFM. Deposited Pd islands were nonuniform in size and randomly distributed over the gold substrate. Size and number of Pd islands increase with the increase of the deposition time, and consequently surface coverage increases too. Deposited Pd was also identified by the changes in cyclic voltammetry (CV) profiles from which an active surface area was estimated. Obtained Pd/Au(poly) surfaces have shown a significant catalytic activity towards oxygen reduction reaction which increases with the increase of Pd islands coverage. The initial potential of ORR was shifted positively, while reaction pathway changes from 2e-reduction on pure gold to 4e-reduction on Pd modified gold. Additionally, obtained Pd/Au(poly) surfaces have shown a significant activity towards hydrogen peroxide reduction (HPRR), which appear as an intermediate during ORR. This supports the assumption that ORR on Pd/Au(poly) occurs partly through 4e-series reduction pathway, the fraction of which increases with the increase of Pd coverage.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Electrochimica Acta
T1  - Catalysis of oxygen reduction on Au modified by Pd nanoislands in perchloric acid solution
EP  - 146
SP  - 140
VL  - 64
DO  - 10.1016/j.electacta.2011.12.130
ER  - 
@article{
author = "Srejić, Irina and Smiljanić, Milutin Lj. and Grgur, Branimir and Rakočević, Zlatko Lj. and Štrbac, Svetlana",
year = "2012",
abstract = "Oxygen reduction reaction (ORR) was studied on polycrystalline gold, Au(poly), modified by nanosized palladium islands in 0.1 M HClO4 solution using rotating disc electrode technique. Paladium was spontaneously deposited from 1 mM PdSO4 center dot 2H(2)O + 0.5 M H2SO4 solution for various deposition times at a submonolayer coverage. Topography of obtained Pd/Au(poly) surfaces was observed by tapping mode atomic force microscopy (AFM), while chemical surface composition changes were detected by simultaneously performed phase AFM. Deposited Pd islands were nonuniform in size and randomly distributed over the gold substrate. Size and number of Pd islands increase with the increase of the deposition time, and consequently surface coverage increases too. Deposited Pd was also identified by the changes in cyclic voltammetry (CV) profiles from which an active surface area was estimated. Obtained Pd/Au(poly) surfaces have shown a significant catalytic activity towards oxygen reduction reaction which increases with the increase of Pd islands coverage. The initial potential of ORR was shifted positively, while reaction pathway changes from 2e-reduction on pure gold to 4e-reduction on Pd modified gold. Additionally, obtained Pd/Au(poly) surfaces have shown a significant activity towards hydrogen peroxide reduction (HPRR), which appear as an intermediate during ORR. This supports the assumption that ORR on Pd/Au(poly) occurs partly through 4e-series reduction pathway, the fraction of which increases with the increase of Pd coverage.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Electrochimica Acta",
title = "Catalysis of oxygen reduction on Au modified by Pd nanoislands in perchloric acid solution",
pages = "146-140",
volume = "64",
doi = "10.1016/j.electacta.2011.12.130"
}
Srejić, I., Smiljanić, M. Lj., Grgur, B., Rakočević, Z. Lj.,& Štrbac, S.. (2012). Catalysis of oxygen reduction on Au modified by Pd nanoislands in perchloric acid solution. in Electrochimica Acta
Pergamon-Elsevier Science Ltd, Oxford., 64, 140-146.
https://doi.org/10.1016/j.electacta.2011.12.130
Srejić I, Smiljanić ML, Grgur B, Rakočević ZL, Štrbac S. Catalysis of oxygen reduction on Au modified by Pd nanoislands in perchloric acid solution. in Electrochimica Acta. 2012;64:140-146.
doi:10.1016/j.electacta.2011.12.130 .
Srejić, Irina, Smiljanić, Milutin Lj., Grgur, Branimir, Rakočević, Zlatko Lj., Štrbac, Svetlana, "Catalysis of oxygen reduction on Au modified by Pd nanoislands in perchloric acid solution" in Electrochimica Acta, 64 (2012):140-146,
https://doi.org/10.1016/j.electacta.2011.12.130 . .
19
19
19

Catalysis of Hydrogen Evolution on Au(111) Modified by Spontaneously Deposited Pd Nanoislands

Smiljanić, Milutin Lj.; Srejić, Irina; Grgur, Branimir; Rakočević, Zlatko Lj.; Štrbac, Svetlana

(Springer, New York, 2012)

TY  - JOUR
AU  - Smiljanić, Milutin Lj.
AU  - Srejić, Irina
AU  - Grgur, Branimir
AU  - Rakočević, Zlatko Lj.
AU  - Štrbac, Svetlana
PY  - 2012
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2149
AB  - Hydrogen evolution reaction was studied on Au(111) modified by palladium spontaneously deposited on the Au(111) surface from (1 mM PdSO4 center dot 2 H2O + 0.5 M H2SO4) solution at a submonolayer coverage. Number and size of Pd islands increased with the increase of the deposition time as observed by ex situ surface topography atomic force microscopy (AFM). The overall coverage of the underlying Au(111) surface by the deposited Pd islands was estimated from simultaneously acquired phase AFM images, which provided a clear contrast between different materials. The obtained Pd/Au(111) surfaces have shown a significant catalytic activity toward hydrogen evolution reaction in 0.5 M H2SO4 solution. This is discussed with respect to Pd islands size and coverage and to the influence of an electronic effect induced in Pd islands by the underlying Au(111) substrate.
PB  - Springer, New York
T2  - Electrocatalysis
T1  - Catalysis of Hydrogen Evolution on Au(111) Modified by Spontaneously Deposited Pd Nanoislands
EP  - 375
IS  - 3-4
SP  - 369
VL  - 3
DO  - 10.1007/s12678-012-0093-2
ER  - 
@article{
author = "Smiljanić, Milutin Lj. and Srejić, Irina and Grgur, Branimir and Rakočević, Zlatko Lj. and Štrbac, Svetlana",
year = "2012",
abstract = "Hydrogen evolution reaction was studied on Au(111) modified by palladium spontaneously deposited on the Au(111) surface from (1 mM PdSO4 center dot 2 H2O + 0.5 M H2SO4) solution at a submonolayer coverage. Number and size of Pd islands increased with the increase of the deposition time as observed by ex situ surface topography atomic force microscopy (AFM). The overall coverage of the underlying Au(111) surface by the deposited Pd islands was estimated from simultaneously acquired phase AFM images, which provided a clear contrast between different materials. The obtained Pd/Au(111) surfaces have shown a significant catalytic activity toward hydrogen evolution reaction in 0.5 M H2SO4 solution. This is discussed with respect to Pd islands size and coverage and to the influence of an electronic effect induced in Pd islands by the underlying Au(111) substrate.",
publisher = "Springer, New York",
journal = "Electrocatalysis",
title = "Catalysis of Hydrogen Evolution on Au(111) Modified by Spontaneously Deposited Pd Nanoislands",
pages = "375-369",
number = "3-4",
volume = "3",
doi = "10.1007/s12678-012-0093-2"
}
Smiljanić, M. Lj., Srejić, I., Grgur, B., Rakočević, Z. Lj.,& Štrbac, S.. (2012). Catalysis of Hydrogen Evolution on Au(111) Modified by Spontaneously Deposited Pd Nanoislands. in Electrocatalysis
Springer, New York., 3(3-4), 369-375.
https://doi.org/10.1007/s12678-012-0093-2
Smiljanić ML, Srejić I, Grgur B, Rakočević ZL, Štrbac S. Catalysis of Hydrogen Evolution on Au(111) Modified by Spontaneously Deposited Pd Nanoislands. in Electrocatalysis. 2012;3(3-4):369-375.
doi:10.1007/s12678-012-0093-2 .
Smiljanić, Milutin Lj., Srejić, Irina, Grgur, Branimir, Rakočević, Zlatko Lj., Štrbac, Svetlana, "Catalysis of Hydrogen Evolution on Au(111) Modified by Spontaneously Deposited Pd Nanoislands" in Electrocatalysis, 3, no. 3-4 (2012):369-375,
https://doi.org/10.1007/s12678-012-0093-2 . .
26
18
26

Sorption of zinc by novel pH-sensitive hydrogels based on chitosan, itaconic acid and methacrylic acid

Milosavljević, Nedeljko; Ristić, Mirjana; Perić-Grujić, Aleksandra; Filipović, Jovanka M.; Štrbac, Svetlana; Rakočević, Zlatko Lj.; Kalagasidis Krušić, Melina

(Elsevier, Amsterdam, 2011)

TY  - JOUR
AU  - Milosavljević, Nedeljko
AU  - Ristić, Mirjana
AU  - Perić-Grujić, Aleksandra
AU  - Filipović, Jovanka M.
AU  - Štrbac, Svetlana
AU  - Rakočević, Zlatko Lj.
AU  - Kalagasidis Krušić, Melina
PY  - 2011
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1888
AB  - Novel pH-sensitive hydrogels based on chitosan, itaconic acid and methacrylic acid were applied as adsorbents for the removal of Zn2+ ions from aqueous solution. In batch tests, the influence of solution pH, contact time, initial metal ion concentration and temperature was examined. The sorption was found pH dependent, pH 5.5 being the optimum value. The adsorption process was well described by the pseudosecond order kinetic. The hydrogels were characterized by spectral (Fourier transform infrared-FTIR) and structural (SEM/EDX and atomic force microscopy-AFM) analyses. The surface topography changes were observed by atomic force microscopy, while the changes in surface composition were detected using phase imaging AFM. The negative values of free energy and enthalpy indicated that the adsorption is spontaneous and exothermic one. The best fitting isotherms were Langmuir and Redlich-Peterson and it was found that both linear and nonlinear methods were appropriate for obtaining the isotherm parameters. However, the increase of temperature leads to higher adsorption capacity, since swelling degree increased with temperature.
PB  - Elsevier, Amsterdam
T2  - Journal of Hazardous Materials
T1  - Sorption of zinc by novel pH-sensitive hydrogels based on chitosan, itaconic acid and methacrylic acid
EP  - 854
IS  - 2
SP  - 846
VL  - 192
DO  - 10.1016/j.jhazmat.2011.05.093
ER  - 
@article{
author = "Milosavljević, Nedeljko and Ristić, Mirjana and Perić-Grujić, Aleksandra and Filipović, Jovanka M. and Štrbac, Svetlana and Rakočević, Zlatko Lj. and Kalagasidis Krušić, Melina",
year = "2011",
abstract = "Novel pH-sensitive hydrogels based on chitosan, itaconic acid and methacrylic acid were applied as adsorbents for the removal of Zn2+ ions from aqueous solution. In batch tests, the influence of solution pH, contact time, initial metal ion concentration and temperature was examined. The sorption was found pH dependent, pH 5.5 being the optimum value. The adsorption process was well described by the pseudosecond order kinetic. The hydrogels were characterized by spectral (Fourier transform infrared-FTIR) and structural (SEM/EDX and atomic force microscopy-AFM) analyses. The surface topography changes were observed by atomic force microscopy, while the changes in surface composition were detected using phase imaging AFM. The negative values of free energy and enthalpy indicated that the adsorption is spontaneous and exothermic one. The best fitting isotherms were Langmuir and Redlich-Peterson and it was found that both linear and nonlinear methods were appropriate for obtaining the isotherm parameters. However, the increase of temperature leads to higher adsorption capacity, since swelling degree increased with temperature.",
publisher = "Elsevier, Amsterdam",
journal = "Journal of Hazardous Materials",
title = "Sorption of zinc by novel pH-sensitive hydrogels based on chitosan, itaconic acid and methacrylic acid",
pages = "854-846",
number = "2",
volume = "192",
doi = "10.1016/j.jhazmat.2011.05.093"
}
Milosavljević, N., Ristić, M., Perić-Grujić, A., Filipović, J. M., Štrbac, S., Rakočević, Z. Lj.,& Kalagasidis Krušić, M.. (2011). Sorption of zinc by novel pH-sensitive hydrogels based on chitosan, itaconic acid and methacrylic acid. in Journal of Hazardous Materials
Elsevier, Amsterdam., 192(2), 846-854.
https://doi.org/10.1016/j.jhazmat.2011.05.093
Milosavljević N, Ristić M, Perić-Grujić A, Filipović JM, Štrbac S, Rakočević ZL, Kalagasidis Krušić M. Sorption of zinc by novel pH-sensitive hydrogels based on chitosan, itaconic acid and methacrylic acid. in Journal of Hazardous Materials. 2011;192(2):846-854.
doi:10.1016/j.jhazmat.2011.05.093 .
Milosavljević, Nedeljko, Ristić, Mirjana, Perić-Grujić, Aleksandra, Filipović, Jovanka M., Štrbac, Svetlana, Rakočević, Zlatko Lj., Kalagasidis Krušić, Melina, "Sorption of zinc by novel pH-sensitive hydrogels based on chitosan, itaconic acid and methacrylic acid" in Journal of Hazardous Materials, 192, no. 2 (2011):846-854,
https://doi.org/10.1016/j.jhazmat.2011.05.093 . .
58
43
56

Removal of Cu2+ ions using hydrogels of chitosan, itaconic and methacrylic acid: FTIR, SEM/EDX, AFM, kinetic and equilibrium study

Milosavljević, Nedeljko; Ristić, Mirjana; Perić-Grujić, Aleksandra; Filipović, Jovanka M.; Štrbac, Svetlana; Rakočević, Zlatko Lj.; Kalagasidis Krušić, Melina

(Elsevier Science Bv, Amsterdam, 2011)

TY  - JOUR
AU  - Milosavljević, Nedeljko
AU  - Ristić, Mirjana
AU  - Perić-Grujić, Aleksandra
AU  - Filipović, Jovanka M.
AU  - Štrbac, Svetlana
AU  - Rakočević, Zlatko Lj.
AU  - Kalagasidis Krušić, Melina
PY  - 2011
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1860
AB  - A removal of Cu2+ ions from aqueous solutions onto hydrogels of chitosan. itaconic and methacrylic acid has been investigated using batch adsorption technique. The extent of adsorption was investigated as a function of pH, adsorbent dose, initial metal ion concentration, contact time and temperature. The FIR spectra showed that -NH2, -OH and -COOH groups are involved in the Cu2+ ions adsorption. The surface topography changes were observed by AFM, where the phase images indicated that sorption takes place on the surface of the hydrogel and in the bulk. Pseudo-first order, pseudo-second order and intraparticle diffusion models were analyzed and showed that the Cu2+ ions adsorption followed pseudo-second order kinetics. The equilibrium data were analyzed using Langmuir, Freundlich and Redlich-Peterson isotherms and the best interpretation was given by Redlich-Peterson. The adsorption capacity was found to be 122.59 mg/g, based on the non-linear Langmuir isotherm. Based on the separation factor. R-L, the Cu2+ ion adsorption is favorable, while the low activation energies indicate physisorption. Desorption experiments, done with a nitric acid, showed that the investigated hydrogels could be reused without significant losses of the initial properties even after three adsorption-sorption cycles.
PB  - Elsevier Science Bv, Amsterdam
T2  - Colloids and Surfaces A-Physicochemical and Engineering Aspects
T1  - Removal of Cu2+ ions using hydrogels of chitosan, itaconic and methacrylic acid: FTIR, SEM/EDX, AFM, kinetic and equilibrium study
EP  - 69
IS  - 1-3
SP  - 59
VL  - 388
DO  - 10.1016/j.colsurfa.2011.08.011
ER  - 
@article{
author = "Milosavljević, Nedeljko and Ristić, Mirjana and Perić-Grujić, Aleksandra and Filipović, Jovanka M. and Štrbac, Svetlana and Rakočević, Zlatko Lj. and Kalagasidis Krušić, Melina",
year = "2011",
abstract = "A removal of Cu2+ ions from aqueous solutions onto hydrogels of chitosan. itaconic and methacrylic acid has been investigated using batch adsorption technique. The extent of adsorption was investigated as a function of pH, adsorbent dose, initial metal ion concentration, contact time and temperature. The FIR spectra showed that -NH2, -OH and -COOH groups are involved in the Cu2+ ions adsorption. The surface topography changes were observed by AFM, where the phase images indicated that sorption takes place on the surface of the hydrogel and in the bulk. Pseudo-first order, pseudo-second order and intraparticle diffusion models were analyzed and showed that the Cu2+ ions adsorption followed pseudo-second order kinetics. The equilibrium data were analyzed using Langmuir, Freundlich and Redlich-Peterson isotherms and the best interpretation was given by Redlich-Peterson. The adsorption capacity was found to be 122.59 mg/g, based on the non-linear Langmuir isotherm. Based on the separation factor. R-L, the Cu2+ ion adsorption is favorable, while the low activation energies indicate physisorption. Desorption experiments, done with a nitric acid, showed that the investigated hydrogels could be reused without significant losses of the initial properties even after three adsorption-sorption cycles.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Colloids and Surfaces A-Physicochemical and Engineering Aspects",
title = "Removal of Cu2+ ions using hydrogels of chitosan, itaconic and methacrylic acid: FTIR, SEM/EDX, AFM, kinetic and equilibrium study",
pages = "69-59",
number = "1-3",
volume = "388",
doi = "10.1016/j.colsurfa.2011.08.011"
}
Milosavljević, N., Ristić, M., Perić-Grujić, A., Filipović, J. M., Štrbac, S., Rakočević, Z. Lj.,& Kalagasidis Krušić, M.. (2011). Removal of Cu2+ ions using hydrogels of chitosan, itaconic and methacrylic acid: FTIR, SEM/EDX, AFM, kinetic and equilibrium study. in Colloids and Surfaces A-Physicochemical and Engineering Aspects
Elsevier Science Bv, Amsterdam., 388(1-3), 59-69.
https://doi.org/10.1016/j.colsurfa.2011.08.011
Milosavljević N, Ristić M, Perić-Grujić A, Filipović JM, Štrbac S, Rakočević ZL, Kalagasidis Krušić M. Removal of Cu2+ ions using hydrogels of chitosan, itaconic and methacrylic acid: FTIR, SEM/EDX, AFM, kinetic and equilibrium study. in Colloids and Surfaces A-Physicochemical and Engineering Aspects. 2011;388(1-3):59-69.
doi:10.1016/j.colsurfa.2011.08.011 .
Milosavljević, Nedeljko, Ristić, Mirjana, Perić-Grujić, Aleksandra, Filipović, Jovanka M., Štrbac, Svetlana, Rakočević, Zlatko Lj., Kalagasidis Krušić, Melina, "Removal of Cu2+ ions using hydrogels of chitosan, itaconic and methacrylic acid: FTIR, SEM/EDX, AFM, kinetic and equilibrium study" in Colloids and Surfaces A-Physicochemical and Engineering Aspects, 388, no. 1-3 (2011):59-69,
https://doi.org/10.1016/j.colsurfa.2011.08.011 . .
85
68
92

Hydrogel based on chitosan, itaconic acid and methacrylic acid as adsorbent of Cd2+ ions from aqueous solution

Milosavljević, Nedeljko; Ristić, Mirjana; Perić-Grujić, Aleksandra; Filipović, Jovanka M.; Štrbac, Svetlana; Rakočević, Zlatko Lj.; Kalagasidis Krušić, Melina

(Elsevier Science Sa, Lausanne, 2010)

TY  - JOUR
AU  - Milosavljević, Nedeljko
AU  - Ristić, Mirjana
AU  - Perić-Grujić, Aleksandra
AU  - Filipović, Jovanka M.
AU  - Štrbac, Svetlana
AU  - Rakočević, Zlatko Lj.
AU  - Kalagasidis Krušić, Melina
PY  - 2010
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1716
AB  - A hydrogel has been synthesized by ionic crosslinking of chitosan (Ch) with itaconic acid (IA), followed by a free radical polymerization and crosslinking of Ch/IA network by adding methacrylic acid and the crosslinker. The resulting material (Ch/IA/MAA hydrogel) was characterized by spectral (Fourier transform infrared (FTIR)), thermal (thermogravimetric analysis (TGA)) and structural (SEM/EDX and atomic force microscopy (AFM)) analyses. The prepared hydrogel was investigated as potential adsorbent for removal of Cd2+ ions from aqueous solution. The effect of various physico-chemical parameters such as pH, adsorbent dosage, adsorbate concentration and contact time was studied in batch experiments. The results of spectral analyses of Cd-loaded hydrogel have shown that active functional groups are -NH2, -OH and -COOH. SEM/EDX analysis and AFM surface topography and phase images indicated that apart from the adsorption on the surface of the hydrogel, sorption takes place in the bulk, as well. The experimental kinetic and equilibrium data were better fitted by pseudo-second order kinetic model and Langmuir adsorption isotherm. The parameters obtained in thermodynamic studies showed that the adsorption of Cd2+ on Ch/IA/MAA hydrogel was spontaneous and exothermic in nature. Desorption studies were carried out using acid leaching (HNO3) and it has been shown that the regenerated hydrogel can be reused three times without any loss of adsorption capacity. The maximum adsorption of 285.7 mg/g has been obtained at pH 5.5 and the results of adsorption/desorption experiments implies that the Ch/IA/MAA hydrogel may be used as efficient sorbent for removal of Cd2+ ions from aqueous solution.
PB  - Elsevier Science Sa, Lausanne
T2  - Chemical Engineering Journal
T1  - Hydrogel based on chitosan, itaconic acid and methacrylic acid as adsorbent of Cd2+ ions from aqueous solution
EP  - 562
IS  - 2
SP  - 554
VL  - 165
DO  - 10.1016/j.cej.2010.09.072
ER  - 
@article{
author = "Milosavljević, Nedeljko and Ristić, Mirjana and Perić-Grujić, Aleksandra and Filipović, Jovanka M. and Štrbac, Svetlana and Rakočević, Zlatko Lj. and Kalagasidis Krušić, Melina",
year = "2010",
abstract = "A hydrogel has been synthesized by ionic crosslinking of chitosan (Ch) with itaconic acid (IA), followed by a free radical polymerization and crosslinking of Ch/IA network by adding methacrylic acid and the crosslinker. The resulting material (Ch/IA/MAA hydrogel) was characterized by spectral (Fourier transform infrared (FTIR)), thermal (thermogravimetric analysis (TGA)) and structural (SEM/EDX and atomic force microscopy (AFM)) analyses. The prepared hydrogel was investigated as potential adsorbent for removal of Cd2+ ions from aqueous solution. The effect of various physico-chemical parameters such as pH, adsorbent dosage, adsorbate concentration and contact time was studied in batch experiments. The results of spectral analyses of Cd-loaded hydrogel have shown that active functional groups are -NH2, -OH and -COOH. SEM/EDX analysis and AFM surface topography and phase images indicated that apart from the adsorption on the surface of the hydrogel, sorption takes place in the bulk, as well. The experimental kinetic and equilibrium data were better fitted by pseudo-second order kinetic model and Langmuir adsorption isotherm. The parameters obtained in thermodynamic studies showed that the adsorption of Cd2+ on Ch/IA/MAA hydrogel was spontaneous and exothermic in nature. Desorption studies were carried out using acid leaching (HNO3) and it has been shown that the regenerated hydrogel can be reused three times without any loss of adsorption capacity. The maximum adsorption of 285.7 mg/g has been obtained at pH 5.5 and the results of adsorption/desorption experiments implies that the Ch/IA/MAA hydrogel may be used as efficient sorbent for removal of Cd2+ ions from aqueous solution.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Chemical Engineering Journal",
title = "Hydrogel based on chitosan, itaconic acid and methacrylic acid as adsorbent of Cd2+ ions from aqueous solution",
pages = "562-554",
number = "2",
volume = "165",
doi = "10.1016/j.cej.2010.09.072"
}
Milosavljević, N., Ristić, M., Perić-Grujić, A., Filipović, J. M., Štrbac, S., Rakočević, Z. Lj.,& Kalagasidis Krušić, M.. (2010). Hydrogel based on chitosan, itaconic acid and methacrylic acid as adsorbent of Cd2+ ions from aqueous solution. in Chemical Engineering Journal
Elsevier Science Sa, Lausanne., 165(2), 554-562.
https://doi.org/10.1016/j.cej.2010.09.072
Milosavljević N, Ristić M, Perić-Grujić A, Filipović JM, Štrbac S, Rakočević ZL, Kalagasidis Krušić M. Hydrogel based on chitosan, itaconic acid and methacrylic acid as adsorbent of Cd2+ ions from aqueous solution. in Chemical Engineering Journal. 2010;165(2):554-562.
doi:10.1016/j.cej.2010.09.072 .
Milosavljević, Nedeljko, Ristić, Mirjana, Perić-Grujić, Aleksandra, Filipović, Jovanka M., Štrbac, Svetlana, Rakočević, Zlatko Lj., Kalagasidis Krušić, Melina, "Hydrogel based on chitosan, itaconic acid and methacrylic acid as adsorbent of Cd2+ ions from aqueous solution" in Chemical Engineering Journal, 165, no. 2 (2010):554-562,
https://doi.org/10.1016/j.cej.2010.09.072 . .
46
44
46

The estimation of solid copper surface tension in copper sulfate solutions

Popov, K.I.; Nikolic, N.D.; Rakočević, Zlatko Lj.

(2002)

TY  - JOUR
AU  - Popov, K.I.
AU  - Nikolic, N.D.
AU  - Rakočević, Zlatko Lj.
PY  - 2002
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5373
AB  - In metal electrodeposition in the limiting diffusion current density range, the deposition current density remains constant regardless of the deposition overpotential used, At the same time, die larger the deposition overpotential is the more disperse is the formed deposit, which is characterised by an increase specific surface. The difference in die specific surface of disperse deposits obtained at two different overpotentials; in the limiting diffusion current density range is correlated with the difference between the deposition overpotentials. A method for the estimation of the surface tension of solid copper in copper sulfate solutions is also proposed.
T2  - Journal of the Serbian Chemical Society
T1  - The estimation of solid copper surface tension in copper sulfate solutions
EP  - 775
IS  - 11
SP  - 769
VL  - 67
DO  - 10.2298/JSC0211769P
ER  - 
@article{
author = "Popov, K.I. and Nikolic, N.D. and Rakočević, Zlatko Lj.",
year = "2002",
abstract = "In metal electrodeposition in the limiting diffusion current density range, the deposition current density remains constant regardless of the deposition overpotential used, At the same time, die larger the deposition overpotential is the more disperse is the formed deposit, which is characterised by an increase specific surface. The difference in die specific surface of disperse deposits obtained at two different overpotentials; in the limiting diffusion current density range is correlated with the difference between the deposition overpotentials. A method for the estimation of the surface tension of solid copper in copper sulfate solutions is also proposed.",
journal = "Journal of the Serbian Chemical Society",
title = "The estimation of solid copper surface tension in copper sulfate solutions",
pages = "775-769",
number = "11",
volume = "67",
doi = "10.2298/JSC0211769P"
}
Popov, K.I., Nikolic, N.D.,& Rakočević, Z. Lj.. (2002). The estimation of solid copper surface tension in copper sulfate solutions. in Journal of the Serbian Chemical Society, 67(11), 769-775.
https://doi.org/10.2298/JSC0211769P
Popov K, Nikolic N, Rakočević ZL. The estimation of solid copper surface tension in copper sulfate solutions. in Journal of the Serbian Chemical Society. 2002;67(11):769-775.
doi:10.2298/JSC0211769P .
Popov, K.I., Nikolic, N.D., Rakočević, Zlatko Lj., "The estimation of solid copper surface tension in copper sulfate solutions" in Journal of the Serbian Chemical Society, 67, no. 11 (2002):769-775,
https://doi.org/10.2298/JSC0211769P . .
12
11
12

The representative particle of copper powder and branch of copper dendrites

Popov, Konstantin I.; Nikolić, Nebojša D.; Rakočević, Zlatko Lj.

(Serbian Chemical Society, 2002)

TY  - JOUR
AU  - Popov, Konstantin I.
AU  - Nikolić, Nebojša D.
AU  - Rakočević, Zlatko Lj.
PY  - 2002
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5372
AB  - Electrochemically deposited copper powders, which are formed of particles of different size and morphology, are characterized by some properties like specific surface and apparent density. Aprocedure of the determination of a representative powder particle, exhibiting the same values of specific surface and apparent density as the powder is proposed. The proposed procedure also permints an explanation of the branching of copper dendrites.
AB  - Elektrohemijski istaloženi prahovi bakra se formiraju od čestica različitih dimenzija i morfologije su okarakterisani nekim osobinama kao što su specifična površina i prividna gustina (nasipna masa). Predložen je postupak određivanja reprezentativne čestice praha, koja ima iste vrednosti specifične površine i prividne gustine kao prah. Predložen postupak takođe omogućuje objašnjenje grananja dendrita bakra.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - The representative particle of copper powder and branch of copper dendrites
T1  - Reprezentativna čestica bakarnog praha i grananje dendrita bakra
EP  - 866
IS  - 12
SP  - 861
VL  - 67
DO  - 10.2298/JSC0212861P
ER  - 
@article{
author = "Popov, Konstantin I. and Nikolić, Nebojša D. and Rakočević, Zlatko Lj.",
year = "2002",
abstract = "Electrochemically deposited copper powders, which are formed of particles of different size and morphology, are characterized by some properties like specific surface and apparent density. Aprocedure of the determination of a representative powder particle, exhibiting the same values of specific surface and apparent density as the powder is proposed. The proposed procedure also permints an explanation of the branching of copper dendrites., Elektrohemijski istaloženi prahovi bakra se formiraju od čestica različitih dimenzija i morfologije su okarakterisani nekim osobinama kao što su specifična površina i prividna gustina (nasipna masa). Predložen je postupak određivanja reprezentativne čestice praha, koja ima iste vrednosti specifične površine i prividne gustine kao prah. Predložen postupak takođe omogućuje objašnjenje grananja dendrita bakra.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "The representative particle of copper powder and branch of copper dendrites, Reprezentativna čestica bakarnog praha i grananje dendrita bakra",
pages = "866-861",
number = "12",
volume = "67",
doi = "10.2298/JSC0212861P"
}
Popov, K. I., Nikolić, N. D.,& Rakočević, Z. Lj.. (2002). The representative particle of copper powder and branch of copper dendrites. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 67(12), 861-866.
https://doi.org/10.2298/JSC0212861P
Popov KI, Nikolić ND, Rakočević ZL. The representative particle of copper powder and branch of copper dendrites. in Journal of the Serbian Chemical Society. 2002;67(12):861-866.
doi:10.2298/JSC0212861P .
Popov, Konstantin I., Nikolić, Nebojša D., Rakočević, Zlatko Lj., "The representative particle of copper powder and branch of copper dendrites" in Journal of the Serbian Chemical Society, 67, no. 12 (2002):861-866,
https://doi.org/10.2298/JSC0212861P . .
9
8
9

Structural characteristics of bright copper surfaces

Nikolić, Nebojša D.; Rakočević, Zlatko Lj.; Popov, Konstantin I.

(2001)

TY  - JOUR
AU  - Nikolić, Nebojša D.
AU  - Rakočević, Zlatko Lj.
AU  - Popov, Konstantin I.
PY  - 2001
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5341
AB  - In this work, the structures of copper surfaces polished mechanically and polished both mechanically and electrochemically, as well as copper coatings obtained in the presence of basic and top brightening addition agents were examined and compared with the structure of a silver mirror. It was shown by the STM technique that the structural characteristics important for the mirror brightness of the copper surface polished both mechanically and electrochemically and the copper coating are: (1) flat and mutually parallel parts of the surface which are smooth on the atomic level and (2) distances between adjacent flat parts are comparative with the distances between the adjacent flat parts of a silver mirror. Also, on the basis of the STM analysis, a mathematical model treating brightness from the point of view of geometrical optics was developed. X-ray diffraction analysis of the copper surfaces showed that mirror brightness is not associated directly with the degree of preferred orientation.
T2  - Journal of Electroanalytical Chemistry
T1  - Structural characteristics of bright copper surfaces
EP  - 66
IS  - 1-2
SP  - 56
VL  - 514
DO  - 10.1016/S0022-0728(01)00626-X
ER  - 
@article{
author = "Nikolić, Nebojša D. and Rakočević, Zlatko Lj. and Popov, Konstantin I.",
year = "2001",
abstract = "In this work, the structures of copper surfaces polished mechanically and polished both mechanically and electrochemically, as well as copper coatings obtained in the presence of basic and top brightening addition agents were examined and compared with the structure of a silver mirror. It was shown by the STM technique that the structural characteristics important for the mirror brightness of the copper surface polished both mechanically and electrochemically and the copper coating are: (1) flat and mutually parallel parts of the surface which are smooth on the atomic level and (2) distances between adjacent flat parts are comparative with the distances between the adjacent flat parts of a silver mirror. Also, on the basis of the STM analysis, a mathematical model treating brightness from the point of view of geometrical optics was developed. X-ray diffraction analysis of the copper surfaces showed that mirror brightness is not associated directly with the degree of preferred orientation.",
journal = "Journal of Electroanalytical Chemistry",
title = "Structural characteristics of bright copper surfaces",
pages = "66-56",
number = "1-2",
volume = "514",
doi = "10.1016/S0022-0728(01)00626-X"
}
Nikolić, N. D., Rakočević, Z. Lj.,& Popov, K. I.. (2001). Structural characteristics of bright copper surfaces. in Journal of Electroanalytical Chemistry, 514(1-2), 56-66.
https://doi.org/10.1016/S0022-0728(01)00626-X
Nikolić ND, Rakočević ZL, Popov KI. Structural characteristics of bright copper surfaces. in Journal of Electroanalytical Chemistry. 2001;514(1-2):56-66.
doi:10.1016/S0022-0728(01)00626-X .
Nikolić, Nebojša D., Rakočević, Zlatko Lj., Popov, Konstantin I., "Structural characteristics of bright copper surfaces" in Journal of Electroanalytical Chemistry, 514, no. 1-2 (2001):56-66,
https://doi.org/10.1016/S0022-0728(01)00626-X . .
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The structure of bright zinc coatings

Nikolić, Nebojša D.; Popov, Konstantin I.; Rakočević, Zlatko Lj.; Đurović, Dejan; Pavlović, Miomir; Stojanović, Miodrag

(Serbian Chemical Society, 2000)

TY  - JOUR
AU  - Nikolić, Nebojša D.
AU  - Popov, Konstantin I.
AU  - Rakočević, Zlatko Lj.
AU  - Đurović, Dejan
AU  - Pavlović, Miomir
AU  - Stojanović, Miodrag
PY  - 2000
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5324
AB  - The structures of bright zinc coatings obtained from acid sulfate solutions in the presenceof dextrin/salicylaldehyde mixture were examined. It was shown by the STM technique that the surfaces of bright zinc coatings are covered by hexagonal zinc crys­tals, the tops of planes of which are flat and mutually parallel and which exhibit smooth­ness on the atomic level. X-Ray diffraction (XRD) analysis of the bright zinc coatings showed that the zinc crystallites are oriented in the (110) plane only.
AB  - Ispitana je struktura sjajnih prevlaka cinka istaloženih iz kiselog sulfatnog elektrolita sa dodatkom dekstrina i salicil aldehida. Pokazano je da je površina sjajnih prevlaka pokrivena heksagonalnim kristalima cinka, čiji vrhovi su ravni i međusobno paralelni, i koji su glatki na atomskom nivou. Rendgensko-difrakciona analiza sjajnih prevlaka cinka je pokazala da su kristaliti cinka orijentisani samo u (110) ravni.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - The structure of bright zinc coatings
T1  - Struktura sjajnih prevlaka cinka
EP  - 827
IS  - 11
SP  - 819
VL  - 65
DO  - 10.2298/jsc0011819n
ER  - 
@article{
author = "Nikolić, Nebojša D. and Popov, Konstantin I. and Rakočević, Zlatko Lj. and Đurović, Dejan and Pavlović, Miomir and Stojanović, Miodrag",
year = "2000",
abstract = "The structures of bright zinc coatings obtained from acid sulfate solutions in the presenceof dextrin/salicylaldehyde mixture were examined. It was shown by the STM technique that the surfaces of bright zinc coatings are covered by hexagonal zinc crys­tals, the tops of planes of which are flat and mutually parallel and which exhibit smooth­ness on the atomic level. X-Ray diffraction (XRD) analysis of the bright zinc coatings showed that the zinc crystallites are oriented in the (110) plane only., Ispitana je struktura sjajnih prevlaka cinka istaloženih iz kiselog sulfatnog elektrolita sa dodatkom dekstrina i salicil aldehida. Pokazano je da je površina sjajnih prevlaka pokrivena heksagonalnim kristalima cinka, čiji vrhovi su ravni i međusobno paralelni, i koji su glatki na atomskom nivou. Rendgensko-difrakciona analiza sjajnih prevlaka cinka je pokazala da su kristaliti cinka orijentisani samo u (110) ravni.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "The structure of bright zinc coatings, Struktura sjajnih prevlaka cinka",
pages = "827-819",
number = "11",
volume = "65",
doi = "10.2298/jsc0011819n"
}
Nikolić, N. D., Popov, K. I., Rakočević, Z. Lj., Đurović, D., Pavlović, M.,& Stojanović, M.. (2000). The structure of bright zinc coatings. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 65(11), 819-827.
https://doi.org/10.2298/jsc0011819n
Nikolić ND, Popov KI, Rakočević ZL, Đurović D, Pavlović M, Stojanović M. The structure of bright zinc coatings. in Journal of the Serbian Chemical Society. 2000;65(11):819-827.
doi:10.2298/jsc0011819n .
Nikolić, Nebojša D., Popov, Konstantin I., Rakočević, Zlatko Lj., Đurović, Dejan, Pavlović, Miomir, Stojanović, Miodrag, "The structure of bright zinc coatings" in Journal of the Serbian Chemical Society, 65, no. 11 (2000):819-827,
https://doi.org/10.2298/jsc0011819n . .
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