Živković, Predrag M.

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Authority KeyName Variants
orcid::0000-0002-9268-9495
  • Živković, Predrag M. (39)
  • Živković, Predrag (6)
  • Živković, P.M. (1)
Projects
Electrochemical synthesis and characterization of nanostructured functional materials for application in new technologies Modifikacija metalnih i nemetalnih materijala elektroprovodnim polimerima za primenu u novim tehnologijama
Synthesis, processing and applications of nanostructured multifunctional materials with defined properties Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM)
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200135 (University of Belgrade, Faculty of Technology and Metallurgy) Proučavanje sinteze, strukture i aktivnosti organskih jedinjenja prirodnog i sintetskog porekla
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča) Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200116 (University of Belgrade, Faculty of Agriculture)
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200162 (University of Belgrade, Faculty of Physics) Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200175 (Institute of Technical Sciences of SASA, Belgrade)
Deposition of ultrafinepowders of metals and alloys and nanostructured surfaces by electrochemical techniques AdCatFC - Advanced Catalysts for Low Temperature Fuel Cells: From Model System to Sustainable Catalysts
1420326 COST Action MP1407-STSM grant ECOST-STSM-MP1407-39458.
Reinforcing of Nanotechnology and Functional Materials Centre Ministry of Science and Environmental Protection of Serbia for financial support (Project 1694).
Ministry of Science and Environmental Protection of the Republic of Serbia under the research project “Electrochemical analysis and characterization of alloy composites and micro structured materials" (H1821). This work was supported by the Ministry of Science, Technology and Development of the Republic of Serbia under the research project "Electrochemical analysis and characterization of alloys composites and micro structured materials" (H1821).
US Department of Energy/National Nuclear Security Administration (Grant: NA0003979) US National Science Foundation (Grant: DMR EiR 2101041, NSF DMR PREM 2122044)

Author's Bibliography

Structural, Mechanical, and Barrier Properties of the Polyvinylidene Fluoride-Bacterial Nanocellulose-Based Hybrid Composite

Janićijević, Aleksandra; Filipović, Suzana; Sknepnek, Aleksandra; Salević-Jelić, Ana; Jančić-Heinemann, Radmila; Petrović, Miloš; Petronijević, Ivan; Stamenović, Marina; Živković, Predrag; Potkonjak, Nebojša; Pavlović, Vladimir B.

(MDPI, 2024)

TY  - JOUR
AU  - Janićijević, Aleksandra
AU  - Filipović, Suzana
AU  - Sknepnek, Aleksandra
AU  - Salević-Jelić, Ana
AU  - Jančić-Heinemann, Radmila
AU  - Petrović, Miloš
AU  - Petronijević, Ivan
AU  - Stamenović, Marina
AU  - Živković, Predrag
AU  - Potkonjak, Nebojša
AU  - Pavlović, Vladimir B.
PY  - 2024
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7454
AB  - This study presents an analysis of films which consist of two layers; one layer is PVDF as the matrix, along with fillers BaTiO3 (BT), and the second is one bacterial nanocellulose (BNC) filled with Fe3O4. The mass fraction of BT in PVDF was 5%, and the samples were differentiated based on the duration of the mechanical activation of BT. This innovative PVDF laminate polymer with environmentally friendly fillers aligns with the concept of circular usage, resulting in a reduction in plastic content and potential improvement of the piezoelectric properties of the entire composite. This work presents new, multifunctional “green” packaging materials that potentially could be a good alternative to specific popular materials used for this purpose. The synthesis of the films was carried out using the hot press method. Tensile tests, water vapor permeability examination, and structural analyses using SEM-EDS and FTIR have been conducted. The sample PVDF/BT20/BNC/Fe3O4 exhibited the best barrier properties (impermeability to water vapor), while the highest tensile strength and toughness were exhibited by the PVDF/BT5/BNC/Fe3O4 sample.
PB  - MDPI
T2  - Polymers
T1  - Structural, Mechanical, and Barrier Properties of the Polyvinylidene Fluoride-Bacterial Nanocellulose-Based Hybrid Composite
IS  - 8
SP  - 1033
VL  - 16
DO  - 10.3390/polym16081033
ER  - 
@article{
author = "Janićijević, Aleksandra and Filipović, Suzana and Sknepnek, Aleksandra and Salević-Jelić, Ana and Jančić-Heinemann, Radmila and Petrović, Miloš and Petronijević, Ivan and Stamenović, Marina and Živković, Predrag and Potkonjak, Nebojša and Pavlović, Vladimir B.",
year = "2024",
abstract = "This study presents an analysis of films which consist of two layers; one layer is PVDF as the matrix, along with fillers BaTiO3 (BT), and the second is one bacterial nanocellulose (BNC) filled with Fe3O4. The mass fraction of BT in PVDF was 5%, and the samples were differentiated based on the duration of the mechanical activation of BT. This innovative PVDF laminate polymer with environmentally friendly fillers aligns with the concept of circular usage, resulting in a reduction in plastic content and potential improvement of the piezoelectric properties of the entire composite. This work presents new, multifunctional “green” packaging materials that potentially could be a good alternative to specific popular materials used for this purpose. The synthesis of the films was carried out using the hot press method. Tensile tests, water vapor permeability examination, and structural analyses using SEM-EDS and FTIR have been conducted. The sample PVDF/BT20/BNC/Fe3O4 exhibited the best barrier properties (impermeability to water vapor), while the highest tensile strength and toughness were exhibited by the PVDF/BT5/BNC/Fe3O4 sample.",
publisher = "MDPI",
journal = "Polymers",
title = "Structural, Mechanical, and Barrier Properties of the Polyvinylidene Fluoride-Bacterial Nanocellulose-Based Hybrid Composite",
number = "8",
pages = "1033",
volume = "16",
doi = "10.3390/polym16081033"
}
Janićijević, A., Filipović, S., Sknepnek, A., Salević-Jelić, A., Jančić-Heinemann, R., Petrović, M., Petronijević, I., Stamenović, M., Živković, P., Potkonjak, N.,& Pavlović, V. B.. (2024). Structural, Mechanical, and Barrier Properties of the Polyvinylidene Fluoride-Bacterial Nanocellulose-Based Hybrid Composite. in Polymers
MDPI., 16(8), 1033.
https://doi.org/10.3390/polym16081033
Janićijević A, Filipović S, Sknepnek A, Salević-Jelić A, Jančić-Heinemann R, Petrović M, Petronijević I, Stamenović M, Živković P, Potkonjak N, Pavlović VB. Structural, Mechanical, and Barrier Properties of the Polyvinylidene Fluoride-Bacterial Nanocellulose-Based Hybrid Composite. in Polymers. 2024;16(8):1033.
doi:10.3390/polym16081033 .
Janićijević, Aleksandra, Filipović, Suzana, Sknepnek, Aleksandra, Salević-Jelić, Ana, Jančić-Heinemann, Radmila, Petrović, Miloš, Petronijević, Ivan, Stamenović, Marina, Živković, Predrag, Potkonjak, Nebojša, Pavlović, Vladimir B., "Structural, Mechanical, and Barrier Properties of the Polyvinylidene Fluoride-Bacterial Nanocellulose-Based Hybrid Composite" in Polymers, 16, no. 8 (2024):1033,
https://doi.org/10.3390/polym16081033 . .

Reduction of fines in recycled paper white water via cellulase enzymes

Jevtović, Đorđe; Živković, Predrag; Milivojević, Ana; Bezbradica, Dejan; Van Der Auwera, Luc

(North Carolina State University, 2024)

TY  - JOUR
AU  - Jevtović, Đorđe
AU  - Živković, Predrag
AU  - Milivojević, Ana
AU  - Bezbradica, Dejan
AU  - Van Der Auwera, Luc
PY  - 2024
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6987
AB  - Due to the high wastepaper recyclability and water-loop system closure, packaging paper mills struggle with increased fines, causing runnability issues. Cellulase enzymes are a preferred treatment choice for the improvement of the pulp refining in stock preparation area but are not widely used or easy to introduce in the production process. Different cellulase enzymes were tested, and those with the highest activity were introduced to the white-water (WW) samples with the aim to reduce fines content as potentially new enzyme applications on the paper machine. The first portion of the study involved the development of an experiment model to find and confirm the optimal enzyme process parameters (40 °C, pH 5.7, reaction time 3 h, and 0.18% v/v enzyme addition) for laboratory made white-water. The second portion of the study included turbidity, colloidal charge, flow cytometry (FCM), and chemical oxygen demand (COD) analysis on industrial and laboratory made white-water samples at optimized process parameters. Obtained results corresponded to reduced fines content in white-water samples, which justified commercial usage of cellulase enzymes on recycled paper machine short loop and potentially increased machine runnability without negative influence on wastewater treatment plant.
PB  - North Carolina State University
T2  - BioResources
T1  - Reduction of fines in recycled paper white water via cellulase enzymes
EP  - 655
IS  - 1
SP  - 635
VL  - 19
DO  - 10.15376/biores.19.1.635-655
ER  - 
@article{
author = "Jevtović, Đorđe and Živković, Predrag and Milivojević, Ana and Bezbradica, Dejan and Van Der Auwera, Luc",
year = "2024",
abstract = "Due to the high wastepaper recyclability and water-loop system closure, packaging paper mills struggle with increased fines, causing runnability issues. Cellulase enzymes are a preferred treatment choice for the improvement of the pulp refining in stock preparation area but are not widely used or easy to introduce in the production process. Different cellulase enzymes were tested, and those with the highest activity were introduced to the white-water (WW) samples with the aim to reduce fines content as potentially new enzyme applications on the paper machine. The first portion of the study involved the development of an experiment model to find and confirm the optimal enzyme process parameters (40 °C, pH 5.7, reaction time 3 h, and 0.18% v/v enzyme addition) for laboratory made white-water. The second portion of the study included turbidity, colloidal charge, flow cytometry (FCM), and chemical oxygen demand (COD) analysis on industrial and laboratory made white-water samples at optimized process parameters. Obtained results corresponded to reduced fines content in white-water samples, which justified commercial usage of cellulase enzymes on recycled paper machine short loop and potentially increased machine runnability without negative influence on wastewater treatment plant.",
publisher = "North Carolina State University",
journal = "BioResources",
title = "Reduction of fines in recycled paper white water via cellulase enzymes",
pages = "655-635",
number = "1",
volume = "19",
doi = "10.15376/biores.19.1.635-655"
}
Jevtović, Đ., Živković, P., Milivojević, A., Bezbradica, D.,& Van Der Auwera, L.. (2024). Reduction of fines in recycled paper white water via cellulase enzymes. in BioResources
North Carolina State University., 19(1), 635-655.
https://doi.org/10.15376/biores.19.1.635-655
Jevtović Đ, Živković P, Milivojević A, Bezbradica D, Van Der Auwera L. Reduction of fines in recycled paper white water via cellulase enzymes. in BioResources. 2024;19(1):635-655.
doi:10.15376/biores.19.1.635-655 .
Jevtović, Đorđe, Živković, Predrag, Milivojević, Ana, Bezbradica, Dejan, Van Der Auwera, Luc, "Reduction of fines in recycled paper white water via cellulase enzymes" in BioResources, 19, no. 1 (2024):635-655,
https://doi.org/10.15376/biores.19.1.635-655 . .

Dielectric and Structural Properties of the Hybrid Material Polyvinylidene Fluoride-Bacterial Nanocellulose-Based Composite

Janićijević, Aleksandra; Filipović, Suzana; Sknepnek, Aleksandra; Vlahović, Branislav; Đorđević, Nenad; Kovačević, Danijela; Mirković, Miljana; Petronijević, Ivan; Živković, Predrag; Rogan, Jelena; Pavlović, Vladimir B.

(MDPI, 2023)

TY  - JOUR
AU  - Janićijević, Aleksandra
AU  - Filipović, Suzana
AU  - Sknepnek, Aleksandra
AU  - Vlahović, Branislav
AU  - Đorđević, Nenad
AU  - Kovačević, Danijela
AU  - Mirković, Miljana
AU  - Petronijević, Ivan
AU  - Živković, Predrag
AU  - Rogan, Jelena
AU  - Pavlović, Vladimir B.
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6805
AB  - In the search for environmentally friendly materials with a wide range of properties, polymer composites have emerged as a promising alternative due to their multifunctional properties. This study focuses on the synthesis of composite materials consisting of four components: bacterial nanocellulose (BNC) modified with magnetic Fe3O4, and a mixture of BaTiO3 (BT) and polyvinylidene fluoride (PVDF). The BT powder was mechanically activated prior to mixing with PVDF. The influence of BT mechanical activation and BNC with magnetic particles on the PVDF matrix was investigated. The obtained composite films’ structural characteristics, morphology, and dielectric properties are presented. This research provides insights into the relationship between mechanical activation of the filler and structural and dielectric properties in the PVDF/BT/BNC/Fe3O4 system, creating the way for the development of materials with a wide range of diverse properties that support the concept of green technologies.
PB  - MDPI
T2  - Polymers
T1  - Dielectric and Structural Properties of the Hybrid Material Polyvinylidene Fluoride-Bacterial Nanocellulose-Based Composite
IS  - 20
SP  - 4080
VL  - 15
DO  - 10.3390/polym15204080
ER  - 
@article{
author = "Janićijević, Aleksandra and Filipović, Suzana and Sknepnek, Aleksandra and Vlahović, Branislav and Đorđević, Nenad and Kovačević, Danijela and Mirković, Miljana and Petronijević, Ivan and Živković, Predrag and Rogan, Jelena and Pavlović, Vladimir B.",
year = "2023",
abstract = "In the search for environmentally friendly materials with a wide range of properties, polymer composites have emerged as a promising alternative due to their multifunctional properties. This study focuses on the synthesis of composite materials consisting of four components: bacterial nanocellulose (BNC) modified with magnetic Fe3O4, and a mixture of BaTiO3 (BT) and polyvinylidene fluoride (PVDF). The BT powder was mechanically activated prior to mixing with PVDF. The influence of BT mechanical activation and BNC with magnetic particles on the PVDF matrix was investigated. The obtained composite films’ structural characteristics, morphology, and dielectric properties are presented. This research provides insights into the relationship between mechanical activation of the filler and structural and dielectric properties in the PVDF/BT/BNC/Fe3O4 system, creating the way for the development of materials with a wide range of diverse properties that support the concept of green technologies.",
publisher = "MDPI",
journal = "Polymers",
title = "Dielectric and Structural Properties of the Hybrid Material Polyvinylidene Fluoride-Bacterial Nanocellulose-Based Composite",
number = "20",
pages = "4080",
volume = "15",
doi = "10.3390/polym15204080"
}
Janićijević, A., Filipović, S., Sknepnek, A., Vlahović, B., Đorđević, N., Kovačević, D., Mirković, M., Petronijević, I., Živković, P., Rogan, J.,& Pavlović, V. B.. (2023). Dielectric and Structural Properties of the Hybrid Material Polyvinylidene Fluoride-Bacterial Nanocellulose-Based Composite. in Polymers
MDPI., 15(20), 4080.
https://doi.org/10.3390/polym15204080
Janićijević A, Filipović S, Sknepnek A, Vlahović B, Đorđević N, Kovačević D, Mirković M, Petronijević I, Živković P, Rogan J, Pavlović VB. Dielectric and Structural Properties of the Hybrid Material Polyvinylidene Fluoride-Bacterial Nanocellulose-Based Composite. in Polymers. 2023;15(20):4080.
doi:10.3390/polym15204080 .
Janićijević, Aleksandra, Filipović, Suzana, Sknepnek, Aleksandra, Vlahović, Branislav, Đorđević, Nenad, Kovačević, Danijela, Mirković, Miljana, Petronijević, Ivan, Živković, Predrag, Rogan, Jelena, Pavlović, Vladimir B., "Dielectric and Structural Properties of the Hybrid Material Polyvinylidene Fluoride-Bacterial Nanocellulose-Based Composite" in Polymers, 15, no. 20 (2023):4080,
https://doi.org/10.3390/polym15204080 . .
1

INFLUENCE OF ELECTRODEPOSITION REGIME AND Sn:Pd RATIOS IN Sn-Pd ELECTROCATALYSTS ON ETHANOL OXIDATION REACTION

Lović, Jelena D.; Nikolić, Nebojša D.; Živković, Predrag M.; Dimitrijević, Silvana B.; Stevanović, Maja

(Society of Chemists and Technologists of Macedonia, 2023)

TY  - JOUR
AU  - Lović, Jelena D.
AU  - Nikolić, Nebojša D.
AU  - Živković, Predrag M.
AU  - Dimitrijević, Silvana B.
AU  - Stevanović, Maja
PY  - 2023
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6608
AB  - A series of bimetallic Sn-Pd catalysts were prepared by a template-free two step electrodeposition method. According to this method, Sn was electrodeposited firstly in potentiostatic or galvanostatic regime on Cu electrodes in the form of dendrites, then Pd was galvanostatically electrodeposited in the second step on the electrode with the electrodeposited Sn dendrites. The produced Sn-Pd electrocatalysts were compared with an electrocatalyst obtained by Pd electrodeposition on a bare Cu electrode. The morphological and elemental analysis of Sn-Pd and Pd electrocatalysts was performed by means of scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS) techniques. The dendrites of various shapes and degree of branching were obtained by Sn deposition depending on electrodeposition regime, while Pd was electrodeposited in a form of compact Pd islands on both Sn dendrites and the Cu electrode. Cyclic voltammetry (CV) was applied for the electrochemical examination of Sn-Pd and Pd catalysts towards the ethanol oxidation reaction (EOR) in the alkaline solution. The electrocatalyst Sn0.6-Pd0.4 with an atomic ratio of 60 at.% Sn-40 at.% Pd showed higher oxidation efficiency and better tolerance towards intermediate species in EOR than the other examined electrocatalysts. It was shown that the lower fraction of Pd, relative to Sn, was crucial to achieving optimal synergy of Sn with Pd thus contributing to enhanced electrochemical behavior regarding EOR.
AB  - Серија на биметални катализатори со различни односи на Sn:Pd беа подготвени со методотна двостепена електродепозиција без користење шаблонски протокол. Според овој метод, прво Sn во форма на дендрити беше нанесен електрохемиски во потенциостатски или галваностатски режим врз површината на Cu-електроди. Потоа, во вториот чекор, Pd беше галваностатски нанесен на електродата врз нанесените дендрити од Sn. Вака добиените Sn:Pd-електрокатализатори беа споредени со електрокатализатори добиени со нанесување на Pd на чиста Cu електрода. Морфолошката и елементарната анализа на Sn:Pd и Pd-електрокатализаторите беше направена со помош на скенирачка електронска микроскопија (SEM) и со примена на рендгенска спектроскопија со енергетска дисперзија (EDS). Дендритите со различни форми и различен степен на разгранување беа добиени со нанесување Sn во зависност од режимот на електродепозиција, додека Pd беше нанесен во форма на компактни острови врз дендритите од Pd и Sn на површината на Cu-електродата. Цикличната волтаметрија (CV) беше применета за електрохемиското испитување на Sn:Pd и Pd-катализаторите во од аспект на оксидацијата на етанолот во алкална средина. Eлектрокатализаторот Sn0.6-Pd0,4 со атомски однос од 60 % Sn и 40 % Pd покажа поголема ефикасност на оксидација и поголема толеранција во однос на интермедијарните супстрати отколку другите испитани електрокатализатори. Се покажа дека помал удел на Pd во однос на Sn е еден од клучните фактори за обезбедување оптимална синергија на Sn со Pd, при што на овој начин беше забележана зголемена електрохемиска активност односно оксидацијата на етанолот.
PB  - Society of Chemists and Technologists of Macedonia
T2  - Macedonian Journal of Chemistry and Chemical Engineering
T1  - INFLUENCE OF ELECTRODEPOSITION REGIME AND Sn:Pd RATIOS IN Sn-Pd ELECTROCATALYSTS ON ETHANOL OXIDATION REACTION
T1  - ВЛИЈАНИЕ НА РЕЖИМОТ НА ЕЛЕКТРОДЕПОЗИЦИЈАТА И НА ОДНОСИТЕ НА Sn:Pd ВО Sn-Pd-ЕЛЕКТРОКАТАЛИЗАТОРИТЕ ВРЗ ОКСИДАЦИЈАТА НА ЕТАНОЛОТ
EP  - 102
IS  - 1
SP  - 93
VL  - 42
DO  - 10.20450/mjcce.2023.2702
ER  - 
@article{
author = "Lović, Jelena D. and Nikolić, Nebojša D. and Živković, Predrag M. and Dimitrijević, Silvana B. and Stevanović, Maja",
year = "2023",
abstract = "A series of bimetallic Sn-Pd catalysts were prepared by a template-free two step electrodeposition method. According to this method, Sn was electrodeposited firstly in potentiostatic or galvanostatic regime on Cu electrodes in the form of dendrites, then Pd was galvanostatically electrodeposited in the second step on the electrode with the electrodeposited Sn dendrites. The produced Sn-Pd electrocatalysts were compared with an electrocatalyst obtained by Pd electrodeposition on a bare Cu electrode. The morphological and elemental analysis of Sn-Pd and Pd electrocatalysts was performed by means of scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS) techniques. The dendrites of various shapes and degree of branching were obtained by Sn deposition depending on electrodeposition regime, while Pd was electrodeposited in a form of compact Pd islands on both Sn dendrites and the Cu electrode. Cyclic voltammetry (CV) was applied for the electrochemical examination of Sn-Pd and Pd catalysts towards the ethanol oxidation reaction (EOR) in the alkaline solution. The electrocatalyst Sn0.6-Pd0.4 with an atomic ratio of 60 at.% Sn-40 at.% Pd showed higher oxidation efficiency and better tolerance towards intermediate species in EOR than the other examined electrocatalysts. It was shown that the lower fraction of Pd, relative to Sn, was crucial to achieving optimal synergy of Sn with Pd thus contributing to enhanced electrochemical behavior regarding EOR., Серија на биметални катализатори со различни односи на Sn:Pd беа подготвени со методотна двостепена електродепозиција без користење шаблонски протокол. Според овој метод, прво Sn во форма на дендрити беше нанесен електрохемиски во потенциостатски или галваностатски режим врз површината на Cu-електроди. Потоа, во вториот чекор, Pd беше галваностатски нанесен на електродата врз нанесените дендрити од Sn. Вака добиените Sn:Pd-електрокатализатори беа споредени со електрокатализатори добиени со нанесување на Pd на чиста Cu електрода. Морфолошката и елементарната анализа на Sn:Pd и Pd-електрокатализаторите беше направена со помош на скенирачка електронска микроскопија (SEM) и со примена на рендгенска спектроскопија со енергетска дисперзија (EDS). Дендритите со различни форми и различен степен на разгранување беа добиени со нанесување Sn во зависност од режимот на електродепозиција, додека Pd беше нанесен во форма на компактни острови врз дендритите од Pd и Sn на површината на Cu-електродата. Цикличната волтаметрија (CV) беше применета за електрохемиското испитување на Sn:Pd и Pd-катализаторите во од аспект на оксидацијата на етанолот во алкална средина. Eлектрокатализаторот Sn0.6-Pd0,4 со атомски однос од 60 % Sn и 40 % Pd покажа поголема ефикасност на оксидација и поголема толеранција во однос на интермедијарните супстрати отколку другите испитани електрокатализатори. Се покажа дека помал удел на Pd во однос на Sn е еден од клучните фактори за обезбедување оптимална синергија на Sn со Pd, при што на овој начин беше забележана зголемена електрохемиска активност односно оксидацијата на етанолот.",
publisher = "Society of Chemists and Technologists of Macedonia",
journal = "Macedonian Journal of Chemistry and Chemical Engineering",
title = "INFLUENCE OF ELECTRODEPOSITION REGIME AND Sn:Pd RATIOS IN Sn-Pd ELECTROCATALYSTS ON ETHANOL OXIDATION REACTION, ВЛИЈАНИЕ НА РЕЖИМОТ НА ЕЛЕКТРОДЕПОЗИЦИЈАТА И НА ОДНОСИТЕ НА Sn:Pd ВО Sn-Pd-ЕЛЕКТРОКАТАЛИЗАТОРИТЕ ВРЗ ОКСИДАЦИЈАТА НА ЕТАНОЛОТ",
pages = "102-93",
number = "1",
volume = "42",
doi = "10.20450/mjcce.2023.2702"
}
Lović, J. D., Nikolić, N. D., Živković, P. M., Dimitrijević, S. B.,& Stevanović, M.. (2023). INFLUENCE OF ELECTRODEPOSITION REGIME AND Sn:Pd RATIOS IN Sn-Pd ELECTROCATALYSTS ON ETHANOL OXIDATION REACTION. in Macedonian Journal of Chemistry and Chemical Engineering
Society of Chemists and Technologists of Macedonia., 42(1), 93-102.
https://doi.org/10.20450/mjcce.2023.2702
Lović JD, Nikolić ND, Živković PM, Dimitrijević SB, Stevanović M. INFLUENCE OF ELECTRODEPOSITION REGIME AND Sn:Pd RATIOS IN Sn-Pd ELECTROCATALYSTS ON ETHANOL OXIDATION REACTION. in Macedonian Journal of Chemistry and Chemical Engineering. 2023;42(1):93-102.
doi:10.20450/mjcce.2023.2702 .
Lović, Jelena D., Nikolić, Nebojša D., Živković, Predrag M., Dimitrijević, Silvana B., Stevanović, Maja, "INFLUENCE OF ELECTRODEPOSITION REGIME AND Sn:Pd RATIOS IN Sn-Pd ELECTROCATALYSTS ON ETHANOL OXIDATION REACTION" in Macedonian Journal of Chemistry and Chemical Engineering, 42, no. 1 (2023):93-102,
https://doi.org/10.20450/mjcce.2023.2702 . .

Morphology and Structure of Electrolytically Synthesized Tin Dendritic Nanostructures

Nikolić, Nebojša D.; Lović, Jelena; Maksimović, Vesna; Živković, Predrag M.

(MDPI, 2022)

TY  - JOUR
AU  - Nikolić, Nebojša D.
AU  - Lović, Jelena
AU  - Maksimović, Vesna
AU  - Živković, Predrag M.
PY  - 2022
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5202
AB  - The formation of tin dendritic nanostructures by electrolysis from the alkaline electrolytehas been investigated. Morphology and structure of Sn dendrites produced applying both potentiostatic and galvanostatic regimes of the electrolysis are characterized by SEM and XRD, respectively. Depending on the applied cathodic potentials, three types of Sn dendrites were obtained: (a) needle like and spear-like, (b) fern-like, and (c) stem-like dendrites. The very branchy dendrites with branches of the prismatic shape obtained by the galvanostatic regime of electrolysis represented anovel type of Sn dendrites, not previously reported in the literature. To explain the formation ofvarious dendritic forms, correlation with the polarization characteristics for this electrodepositionsystem is considered. The needle-like and the spear-like dendrites represented monocrystals of(200),(400) preferred orientation, the fern-like dendrites exhibited the predominant (220),(440) preferredorientation, while in the stem-like particles Sn crystallites were oriented to a greater extent inthe (440) crystal plane than in other planes. The galvanostatically synthesized Sn particles possessed the strong (200),(400) preferred orientation. The strong influence of parameters and regimes ofelectrodeposition on structural characteristics of Sn dendrites is explained by the fundamental lawsof electrocrystallization taking into consideration the concept of slow-growing and fast-growingcrystal planes.
PB  - MDPI
T2  - Metals
T1  - Morphology and Structure of Electrolytically Synthesized Tin Dendritic Nanostructures
IS  - 7
SP  - 1201
VL  - 12
DO  - 10.3390/met12071201
ER  - 
@article{
author = "Nikolić, Nebojša D. and Lović, Jelena and Maksimović, Vesna and Živković, Predrag M.",
year = "2022",
abstract = "The formation of tin dendritic nanostructures by electrolysis from the alkaline electrolytehas been investigated. Morphology and structure of Sn dendrites produced applying both potentiostatic and galvanostatic regimes of the electrolysis are characterized by SEM and XRD, respectively. Depending on the applied cathodic potentials, three types of Sn dendrites were obtained: (a) needle like and spear-like, (b) fern-like, and (c) stem-like dendrites. The very branchy dendrites with branches of the prismatic shape obtained by the galvanostatic regime of electrolysis represented anovel type of Sn dendrites, not previously reported in the literature. To explain the formation ofvarious dendritic forms, correlation with the polarization characteristics for this electrodepositionsystem is considered. The needle-like and the spear-like dendrites represented monocrystals of(200),(400) preferred orientation, the fern-like dendrites exhibited the predominant (220),(440) preferredorientation, while in the stem-like particles Sn crystallites were oriented to a greater extent inthe (440) crystal plane than in other planes. The galvanostatically synthesized Sn particles possessed the strong (200),(400) preferred orientation. The strong influence of parameters and regimes ofelectrodeposition on structural characteristics of Sn dendrites is explained by the fundamental lawsof electrocrystallization taking into consideration the concept of slow-growing and fast-growingcrystal planes.",
publisher = "MDPI",
journal = "Metals",
title = "Morphology and Structure of Electrolytically Synthesized Tin Dendritic Nanostructures",
number = "7",
pages = "1201",
volume = "12",
doi = "10.3390/met12071201"
}
Nikolić, N. D., Lović, J., Maksimović, V.,& Živković, P. M.. (2022). Morphology and Structure of Electrolytically Synthesized Tin Dendritic Nanostructures. in Metals
MDPI., 12(7), 1201.
https://doi.org/10.3390/met12071201
Nikolić ND, Lović J, Maksimović V, Živković PM. Morphology and Structure of Electrolytically Synthesized Tin Dendritic Nanostructures. in Metals. 2022;12(7):1201.
doi:10.3390/met12071201 .
Nikolić, Nebojša D., Lović, Jelena, Maksimović, Vesna, Živković, Predrag M., "Morphology and Structure of Electrolytically Synthesized Tin Dendritic Nanostructures" in Metals, 12, no. 7 (2022):1201,
https://doi.org/10.3390/met12071201 . .
3
4

A Method for Evaluating Human Observer's Perception of Color Differences

Gazibaric, Zoran; Cviljusac, Vladimir; Živković, Predrag; Mrvac, Nikola

(2021)

TY  - JOUR
AU  - Gazibaric, Zoran
AU  - Cviljusac, Vladimir
AU  - Živković, Predrag
AU  - Mrvac, Nikola
PY  - 2021
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4840
AB  - The purpose of this paper is to propose a new method for evaluating a human observer's perception of color differences in digital environment. The method is based on recording the observer's reaction when watching the fields of different colors. The fields are shown on high-end expanded gamut calibration monitor driven by originally developed software for performing the test. The method is convenient for quantification of an individual observer's tolerance to color difference for one or more specific colors. It could help in situations when color is a critical parameter for product quality, to quantitatively determine color tolerance that would be acceptable for the final user or client.
T2  - Tehnicki Vjesnik-Technical Gazette
T1  - A Method for Evaluating Human Observer's Perception of Color Differences
EP  - 2101
IS  - 6
SP  - 2094
VL  - 28
DO  - 10.17559/TV-20201027193639
ER  - 
@article{
author = "Gazibaric, Zoran and Cviljusac, Vladimir and Živković, Predrag and Mrvac, Nikola",
year = "2021",
abstract = "The purpose of this paper is to propose a new method for evaluating a human observer's perception of color differences in digital environment. The method is based on recording the observer's reaction when watching the fields of different colors. The fields are shown on high-end expanded gamut calibration monitor driven by originally developed software for performing the test. The method is convenient for quantification of an individual observer's tolerance to color difference for one or more specific colors. It could help in situations when color is a critical parameter for product quality, to quantitatively determine color tolerance that would be acceptable for the final user or client.",
journal = "Tehnicki Vjesnik-Technical Gazette",
title = "A Method for Evaluating Human Observer's Perception of Color Differences",
pages = "2101-2094",
number = "6",
volume = "28",
doi = "10.17559/TV-20201027193639"
}
Gazibaric, Z., Cviljusac, V., Živković, P.,& Mrvac, N.. (2021). A Method for Evaluating Human Observer's Perception of Color Differences. in Tehnicki Vjesnik-Technical Gazette, 28(6), 2094-2101.
https://doi.org/10.17559/TV-20201027193639
Gazibaric Z, Cviljusac V, Živković P, Mrvac N. A Method for Evaluating Human Observer's Perception of Color Differences. in Tehnicki Vjesnik-Technical Gazette. 2021;28(6):2094-2101.
doi:10.17559/TV-20201027193639 .
Gazibaric, Zoran, Cviljusac, Vladimir, Živković, Predrag, Mrvac, Nikola, "A Method for Evaluating Human Observer's Perception of Color Differences" in Tehnicki Vjesnik-Technical Gazette, 28, no. 6 (2021):2094-2101,
https://doi.org/10.17559/TV-20201027193639 . .

Optimization of process of the honeycomb-like structure formation by the regime of reversing current (RC) in the second range

Nikolić, Nebojša D.; Živković, Predrag M.; Elezović, Nevenka; Lačnjevac, Uroš

(Springer-Verlag, 2020)

TY  - JOUR
AU  - Nikolić, Nebojša D.
AU  - Živković, Predrag M.
AU  - Elezović, Nevenka
AU  - Lačnjevac, Uroš
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5890
AB  - Formation of the honeycomb-like electrodes of copper by the regime of reversing current (RC) in the second range has beeninvestigated. Morphological and structural characteristics of this electrode type obtained by various parameters of RC regimeswere examined by the techniques of scanning electron and optical microscopies, while the amount of hydrogen produced duringelectrodeposition process was quantified by determination of the average current efficiency for hydrogen evolution reaction. Tooptimize the process of formation of the honeycomb-like electrodes, the following parameters of square wave RC regimes wereanalyzed: the cathodic current density, the same anodic to cathodic time ratios but various durations of the cathodic and theanodic pulses, and the various values of the anodic to cathodic time ratios. The minimal amount of hydrogen spent for formationof the honeycomb-like electrodes with maximal number of holes formed from detached hydrogen bubbles is obtained with theanodic to cathodic time ratio of 0.50 and duration of the cathodic and anodic pulses of 2 and 1 s, respectively. To explainformation of the honeycomb-like electrodes of optimal morphological and structural characteristics, the upgraded mathematicalmodel defining the RC regime in the second range was proposed and discussed.
PB  - Springer-Verlag
T2  - Journal of Solid State Electrochemistry
T1  - Optimization of process of the honeycomb-like structure formation by the regime of reversing current (RC) in the second range
EP  - 1624
IS  - 7
SP  - 1615
VL  - 24
DO  - 10.1007/s10008-020-04658-3
ER  - 
@article{
author = "Nikolić, Nebojša D. and Živković, Predrag M. and Elezović, Nevenka and Lačnjevac, Uroš",
year = "2020",
abstract = "Formation of the honeycomb-like electrodes of copper by the regime of reversing current (RC) in the second range has beeninvestigated. Morphological and structural characteristics of this electrode type obtained by various parameters of RC regimeswere examined by the techniques of scanning electron and optical microscopies, while the amount of hydrogen produced duringelectrodeposition process was quantified by determination of the average current efficiency for hydrogen evolution reaction. Tooptimize the process of formation of the honeycomb-like electrodes, the following parameters of square wave RC regimes wereanalyzed: the cathodic current density, the same anodic to cathodic time ratios but various durations of the cathodic and theanodic pulses, and the various values of the anodic to cathodic time ratios. The minimal amount of hydrogen spent for formationof the honeycomb-like electrodes with maximal number of holes formed from detached hydrogen bubbles is obtained with theanodic to cathodic time ratio of 0.50 and duration of the cathodic and anodic pulses of 2 and 1 s, respectively. To explainformation of the honeycomb-like electrodes of optimal morphological and structural characteristics, the upgraded mathematicalmodel defining the RC regime in the second range was proposed and discussed.",
publisher = "Springer-Verlag",
journal = "Journal of Solid State Electrochemistry",
title = "Optimization of process of the honeycomb-like structure formation by the regime of reversing current (RC) in the second range",
pages = "1624-1615",
number = "7",
volume = "24",
doi = "10.1007/s10008-020-04658-3"
}
Nikolić, N. D., Živković, P. M., Elezović, N.,& Lačnjevac, U.. (2020). Optimization of process of the honeycomb-like structure formation by the regime of reversing current (RC) in the second range. in Journal of Solid State Electrochemistry
Springer-Verlag., 24(7), 1615-1624.
https://doi.org/10.1007/s10008-020-04658-3
Nikolić ND, Živković PM, Elezović N, Lačnjevac U. Optimization of process of the honeycomb-like structure formation by the regime of reversing current (RC) in the second range. in Journal of Solid State Electrochemistry. 2020;24(7):1615-1624.
doi:10.1007/s10008-020-04658-3 .
Nikolić, Nebojša D., Živković, Predrag M., Elezović, Nevenka, Lačnjevac, Uroš, "Optimization of process of the honeycomb-like structure formation by the regime of reversing current (RC) in the second range" in Journal of Solid State Electrochemistry, 24, no. 7 (2020):1615-1624,
https://doi.org/10.1007/s10008-020-04658-3 . .
4
2
4

Mechanism of formation of the honeycomb-like structures by the regime of the reversing current (RC) in the second range

Berkesi, Kata; Živković, Predrag M.; Elezović, Nevenka; Lačnjevac, Uroš; Hristoforou, Evangelos; Nikolić, Nebojša D.

(Elsevier B.V., 2019)

TY  - JOUR
AU  - Berkesi, Kata
AU  - Živković, Predrag M.
AU  - Elezović, Nevenka
AU  - Lačnjevac, Uroš
AU  - Hristoforou, Evangelos
AU  - Nikolić, Nebojša D.
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5895
AB  - Electrodeposition of copper in the hydrogen co-deposition range by the regime of reversing current (RC) in the second range has been investigated by determination of the average current efficiency for hydrogen evolution reaction and by scanning electron (SEM) and optical (OM) microscopic analysis of the obtained deposits. Keeping the cathodic current density, the cathodic and the anodic pulses constant in all experiments, the anodic current density (ja) values were varied: 40, 80, 160, 240 and 320 mA cm−2. The Cu deposits produced by the RC regimes with different anodic current density values were compared with that obtained in a constant galvanostatic regime (DC) at the current density equal to the cathodic current density in the RC regimes. The honeycomb-like structures were formed in the DC regime and by the RC regimes with ja of 40 and 80 mA cm−2. The hole size in them was in the 60–70 μm range. Due to the decrease of quantity of evolved hydrogen with increasing anodic current density, the larger dish-like holes with dendrites at their bottom and shoulder were formed with ja values of 160, 240 and 320 mA cm−2. The maximum number of holes, and hence, the largest specific surface area of the honeycomb-like electrodes was obtained with ja = 80 mA cm−2, that can be ascribed to a suppression of coalescence of neighboring hydrogen bubbles. Application of the RC regime also led to the increase of uniformity of structures, what is concluded by cross section analysis of the formed honeycomb-like electrodes. For the first time, mechanism of Cu electrodeposition in the hydrogen co-deposition range by the RC regime in the second range was proposed and discussed.
PB  - Elsevier B.V.
T2  - Journal of Electroanalytical Chemistry
T1  - Mechanism of formation of the honeycomb-like structures by the regime of the reversing current (RC) in the second range
EP  - 410
SP  - 401
VL  - 833
DO  - 10.1016/j.jelechem.2018.12.021
ER  - 
@article{
author = "Berkesi, Kata and Živković, Predrag M. and Elezović, Nevenka and Lačnjevac, Uroš and Hristoforou, Evangelos and Nikolić, Nebojša D.",
year = "2019",
abstract = "Electrodeposition of copper in the hydrogen co-deposition range by the regime of reversing current (RC) in the second range has been investigated by determination of the average current efficiency for hydrogen evolution reaction and by scanning electron (SEM) and optical (OM) microscopic analysis of the obtained deposits. Keeping the cathodic current density, the cathodic and the anodic pulses constant in all experiments, the anodic current density (ja) values were varied: 40, 80, 160, 240 and 320 mA cm−2. The Cu deposits produced by the RC regimes with different anodic current density values were compared with that obtained in a constant galvanostatic regime (DC) at the current density equal to the cathodic current density in the RC regimes. The honeycomb-like structures were formed in the DC regime and by the RC regimes with ja of 40 and 80 mA cm−2. The hole size in them was in the 60–70 μm range. Due to the decrease of quantity of evolved hydrogen with increasing anodic current density, the larger dish-like holes with dendrites at their bottom and shoulder were formed with ja values of 160, 240 and 320 mA cm−2. The maximum number of holes, and hence, the largest specific surface area of the honeycomb-like electrodes was obtained with ja = 80 mA cm−2, that can be ascribed to a suppression of coalescence of neighboring hydrogen bubbles. Application of the RC regime also led to the increase of uniformity of structures, what is concluded by cross section analysis of the formed honeycomb-like electrodes. For the first time, mechanism of Cu electrodeposition in the hydrogen co-deposition range by the RC regime in the second range was proposed and discussed.",
publisher = "Elsevier B.V.",
journal = "Journal of Electroanalytical Chemistry",
title = "Mechanism of formation of the honeycomb-like structures by the regime of the reversing current (RC) in the second range",
pages = "410-401",
volume = "833",
doi = "10.1016/j.jelechem.2018.12.021"
}
Berkesi, K., Živković, P. M., Elezović, N., Lačnjevac, U., Hristoforou, E.,& Nikolić, N. D.. (2019). Mechanism of formation of the honeycomb-like structures by the regime of the reversing current (RC) in the second range. in Journal of Electroanalytical Chemistry
Elsevier B.V.., 833, 401-410.
https://doi.org/10.1016/j.jelechem.2018.12.021
Berkesi K, Živković PM, Elezović N, Lačnjevac U, Hristoforou E, Nikolić ND. Mechanism of formation of the honeycomb-like structures by the regime of the reversing current (RC) in the second range. in Journal of Electroanalytical Chemistry. 2019;833:401-410.
doi:10.1016/j.jelechem.2018.12.021 .
Berkesi, Kata, Živković, Predrag M., Elezović, Nevenka, Lačnjevac, Uroš, Hristoforou, Evangelos, Nikolić, Nebojša D., "Mechanism of formation of the honeycomb-like structures by the regime of the reversing current (RC) in the second range" in Journal of Electroanalytical Chemistry, 833 (2019):401-410,
https://doi.org/10.1016/j.jelechem.2018.12.021 . .
4
3
4

Overpotential controls the morphology of electrolytically produced copper dendritic forms

Nikolić, Nebojša D.; Živković, Predrag M.; Pavlović, Miomir; Baščarević, Zvezdana

(Belgrade : Serbian Chemical Society, 2019)

TY  - JOUR
AU  - Nikolić, Nebojša D.
AU  - Živković, Predrag M.
AU  - Pavlović, Miomir
AU  - Baščarević, Zvezdana
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5905
AB  - The morphologies of copper dendritic forms obtained in both potentiostatic and galvanostatic regimes of electrolysis with various amounts of the electricity were analyzed by the scanning electron microscopy (SEM) technique. Irrespective of amount of passed electricity, 3D (three dimensional) pine-like dendrites with sharp tips were formed in the potentiostatic regime of electrolysis. On the other hand, the amount of passed electricity had a strong effect on the shape of the 3D pine-like dendrites formed in the galvanostatic regime of electrolysis. Dendrites with sharp tips were formed with smaller amount of passed electricity, while dendrites with globular tips were formed with larger amounts. The change in the shape of the galvanostatically synthesized 3D pine-like dendrites was explained by comparison with copper deposits obtained potentiostatically at overpotentials that corresponded to the final overpotentials during galvanostatic regime of electrolysis for the analyzed amounts of electricity. Based on the similarity of the obtained morphologies at the macro level, it was concluded that the overpotential plays a crucial role in the formation of the electrolytically synthesized dendrites and that the controlled conditions of electrolysis could represent a suitable way for a synthesis of spherical Cu particles by electrolysis.
AB  - Морфологије дендритичних форми бакра добијене потенциостатским и галваностатским режимима електролизе са различитим количинама наелектрисања су биле анализиране техником скенирајуће електронске микроскопије (СЕМ). Без обзира на количину пропуштеног наелектрисања, 3D (тродимензионални) дендрити налик стаблубора са оштрим врховима су били формирани потенциостатским режимом електролизе. На другој страни, количина пропуштеног наелектрисања је имала строг утицај на облик3D дендрита налик бору формираних галваностатским режимом електролизе. Дендритиса оштрим врховима су били формирани са мањом, док дендрити чији врхови су глобуле су били формирани са већом количином пропуштеног наелектрисања. Промена облика галваностатски синтетизованих 3D дендрита налик бору је била објашњена поређењем са потенциостатски добијеним талозима бакра на пренапетостима које су одговарале крајњим пренапетостима током галваностатског режима електролизе за анализиране количине наелектрисања. На основу сличности њихових морфологија на макро нивоу, закључено је да пренапетост игра пресудну улогу на облик електролитички синтетизованих дендрита, и да контролисани услови електролизе представљају погодан начин за синтезу сферичних честица бакра поступком електролизе-
PB  - Belgrade : Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Overpotential controls the morphology of electrolytically produced copper dendritic forms
T1  - Пренапетост контролише морфологију електролитички произведених дендритичних форми бакра
EP  - 1220
IS  - 11
SP  - 1209
VL  - 84
DO  - 10.2298/JSC190522066N
ER  - 
@article{
author = "Nikolić, Nebojša D. and Živković, Predrag M. and Pavlović, Miomir and Baščarević, Zvezdana",
year = "2019",
abstract = "The morphologies of copper dendritic forms obtained in both potentiostatic and galvanostatic regimes of electrolysis with various amounts of the electricity were analyzed by the scanning electron microscopy (SEM) technique. Irrespective of amount of passed electricity, 3D (three dimensional) pine-like dendrites with sharp tips were formed in the potentiostatic regime of electrolysis. On the other hand, the amount of passed electricity had a strong effect on the shape of the 3D pine-like dendrites formed in the galvanostatic regime of electrolysis. Dendrites with sharp tips were formed with smaller amount of passed electricity, while dendrites with globular tips were formed with larger amounts. The change in the shape of the galvanostatically synthesized 3D pine-like dendrites was explained by comparison with copper deposits obtained potentiostatically at overpotentials that corresponded to the final overpotentials during galvanostatic regime of electrolysis for the analyzed amounts of electricity. Based on the similarity of the obtained morphologies at the macro level, it was concluded that the overpotential plays a crucial role in the formation of the electrolytically synthesized dendrites and that the controlled conditions of electrolysis could represent a suitable way for a synthesis of spherical Cu particles by electrolysis., Морфологије дендритичних форми бакра добијене потенциостатским и галваностатским режимима електролизе са различитим количинама наелектрисања су биле анализиране техником скенирајуће електронске микроскопије (СЕМ). Без обзира на количину пропуштеног наелектрисања, 3D (тродимензионални) дендрити налик стаблубора са оштрим врховима су били формирани потенциостатским режимом електролизе. На другој страни, количина пропуштеног наелектрисања је имала строг утицај на облик3D дендрита налик бору формираних галваностатским режимом електролизе. Дендритиса оштрим врховима су били формирани са мањом, док дендрити чији врхови су глобуле су били формирани са већом количином пропуштеног наелектрисања. Промена облика галваностатски синтетизованих 3D дендрита налик бору је била објашњена поређењем са потенциостатски добијеним талозима бакра на пренапетостима које су одговарале крајњим пренапетостима током галваностатског режима електролизе за анализиране количине наелектрисања. На основу сличности њихових морфологија на макро нивоу, закључено је да пренапетост игра пресудну улогу на облик електролитички синтетизованих дендрита, и да контролисани услови електролизе представљају погодан начин за синтезу сферичних честица бакра поступком електролизе-",
publisher = "Belgrade : Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Overpotential controls the morphology of electrolytically produced copper dendritic forms, Пренапетост контролише морфологију електролитички произведених дендритичних форми бакра",
pages = "1220-1209",
number = "11",
volume = "84",
doi = "10.2298/JSC190522066N"
}
Nikolić, N. D., Živković, P. M., Pavlović, M.,& Baščarević, Z.. (2019). Overpotential controls the morphology of electrolytically produced copper dendritic forms. in Journal of the Serbian Chemical Society
Belgrade : Serbian Chemical Society., 84(11), 1209-1220.
https://doi.org/10.2298/JSC190522066N
Nikolić ND, Živković PM, Pavlović M, Baščarević Z. Overpotential controls the morphology of electrolytically produced copper dendritic forms. in Journal of the Serbian Chemical Society. 2019;84(11):1209-1220.
doi:10.2298/JSC190522066N .
Nikolić, Nebojša D., Živković, Predrag M., Pavlović, Miomir, Baščarević, Zvezdana, "Overpotential controls the morphology of electrolytically produced copper dendritic forms" in Journal of the Serbian Chemical Society, 84, no. 11 (2019):1209-1220,
https://doi.org/10.2298/JSC190522066N . .
10
9
13

Improving the Packaging Performance of Low-Density Polyethylene With PCL/Nanocellulose/Copper(II)Oxide Barrier Layer

Đorđević, Nenad; Marinković, Aleksandar; Živković, Predrag M.; Kovačević, Danijela; Dimitrijević, Suzana; Kokol, Vanja; Uskoković, Petar

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2018)

TY  - JOUR
AU  - Đorđević, Nenad
AU  - Marinković, Aleksandar
AU  - Živković, Predrag M.
AU  - Kovačević, Danijela
AU  - Dimitrijević, Suzana
AU  - Kokol, Vanja
AU  - Uskoković, Petar
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3894
AB  - A novel double layered hybrid materials, consisting of low density polyethylene (LDPE) base layer and polycaprolactone (PCL) top layer containing surface modified nanocellulose (NC) based nanocomposites in 0.5 and 2% loadings, were studied in order to design multipurpose packaging material. NC was covalently modified with maleic anhydride (MA) to obtain NCMA, and upon co-precipitation of copper (II) oxide (CuO) on NC and NCMA surface, NC-CuO and NCMA-CuO nanocomposite materials were produced. Two drying methods, conventional and lyophilization, were applied to investigate process influences on the properties of obtained hybrid material. Oxygen transmission rate and antimicrobial activity were determined for all produced hybrid materials. PE-PCL-NCMA-CuO-L2 exhibited the highest antifungal properties, indicating contribution of MA residual group and drying conditions (liophylisation) to achievement of 97% reduction in cell viability of C. albicans. The sample with 2% of NCMA-CuO, PE-PCL-NCMA-CuO2, demonstrated to be the most promising material regarding improvment in antibacterial and antifugal activity, as well as 16% lower value of the oxygen transmission rate in comparison to pure LDPE.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Improving the Packaging Performance of Low-Density Polyethylene With PCL/Nanocellulose/Copper(II)Oxide Barrier Layer
EP  - 161
IS  - 2
SP  - 149
VL  - 50
DO  - 10.2298/SOS1802149D
ER  - 
@article{
author = "Đorđević, Nenad and Marinković, Aleksandar and Živković, Predrag M. and Kovačević, Danijela and Dimitrijević, Suzana and Kokol, Vanja and Uskoković, Petar",
year = "2018",
abstract = "A novel double layered hybrid materials, consisting of low density polyethylene (LDPE) base layer and polycaprolactone (PCL) top layer containing surface modified nanocellulose (NC) based nanocomposites in 0.5 and 2% loadings, were studied in order to design multipurpose packaging material. NC was covalently modified with maleic anhydride (MA) to obtain NCMA, and upon co-precipitation of copper (II) oxide (CuO) on NC and NCMA surface, NC-CuO and NCMA-CuO nanocomposite materials were produced. Two drying methods, conventional and lyophilization, were applied to investigate process influences on the properties of obtained hybrid material. Oxygen transmission rate and antimicrobial activity were determined for all produced hybrid materials. PE-PCL-NCMA-CuO-L2 exhibited the highest antifungal properties, indicating contribution of MA residual group and drying conditions (liophylisation) to achievement of 97% reduction in cell viability of C. albicans. The sample with 2% of NCMA-CuO, PE-PCL-NCMA-CuO2, demonstrated to be the most promising material regarding improvment in antibacterial and antifugal activity, as well as 16% lower value of the oxygen transmission rate in comparison to pure LDPE.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Improving the Packaging Performance of Low-Density Polyethylene With PCL/Nanocellulose/Copper(II)Oxide Barrier Layer",
pages = "161-149",
number = "2",
volume = "50",
doi = "10.2298/SOS1802149D"
}
Đorđević, N., Marinković, A., Živković, P. M., Kovačević, D., Dimitrijević, S., Kokol, V.,& Uskoković, P.. (2018). Improving the Packaging Performance of Low-Density Polyethylene With PCL/Nanocellulose/Copper(II)Oxide Barrier Layer. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 50(2), 149-161.
https://doi.org/10.2298/SOS1802149D
Đorđević N, Marinković A, Živković PM, Kovačević D, Dimitrijević S, Kokol V, Uskoković P. Improving the Packaging Performance of Low-Density Polyethylene With PCL/Nanocellulose/Copper(II)Oxide Barrier Layer. in Science of Sintering. 2018;50(2):149-161.
doi:10.2298/SOS1802149D .
Đorđević, Nenad, Marinković, Aleksandar, Živković, Predrag M., Kovačević, Danijela, Dimitrijević, Suzana, Kokol, Vanja, Uskoković, Petar, "Improving the Packaging Performance of Low-Density Polyethylene With PCL/Nanocellulose/Copper(II)Oxide Barrier Layer" in Science of Sintering, 50, no. 2 (2018):149-161,
https://doi.org/10.2298/SOS1802149D . .
3
4
3
5

Surface Properties of HAP Particles obtained by Hydrothermal Decomposition of Urea and Calcium-EDTA Chelates

Janković-Častvan, Ivona; Lazarević, Slavica; Radovanović, Željko; Đokić, Veljko; Popovic, Daniela; Bjelajac, Anđelika; Živković, Predrag; Petrović, Rada; Janaćković, Đorđe

(2017)


                                            

                                            
Janković-Častvan, I., Lazarević, S., Radovanović, Ž., Đokić, V., Popovic, D., Bjelajac, A., Živković, P., Petrović, R.,& Janaćković, Đ.. (2017). Surface Properties of HAP Particles obtained by Hydrothermal Decomposition of Urea and Calcium-EDTA Chelates. in Matični naučni odbor za materijale i hemijske tehnologije.
https://hdl.handle.net/21.15107/rcub_technorep_6034
Janković-Častvan I, Lazarević S, Radovanović Ž, Đokić V, Popovic D, Bjelajac A, Živković P, Petrović R, Janaćković Đ. Surface Properties of HAP Particles obtained by Hydrothermal Decomposition of Urea and Calcium-EDTA Chelates. in Matični naučni odbor za materijale i hemijske tehnologije. 2017;.
https://hdl.handle.net/21.15107/rcub_technorep_6034 .
Janković-Častvan, Ivona, Lazarević, Slavica, Radovanović, Željko, Đokić, Veljko, Popovic, Daniela, Bjelajac, Anđelika, Živković, Predrag, Petrović, Rada, Janaćković, Đorđe, "Surface Properties of HAP Particles obtained by Hydrothermal Decomposition of Urea and Calcium-EDTA Chelates" in Matični naučni odbor za materijale i hemijske tehnologije (2017),
https://hdl.handle.net/21.15107/rcub_technorep_6034 .

Application of the general theory of disperse deposits formation in an investigation of mechanism of zinc electrodeposition from the alkaline electrolytes

Nikolić, Nebojša D.; Živković, Predrag M.; Lović, Jelena; Branković, Goran

(Elsevier, 2017)

TY  - JOUR
AU  - Nikolić, Nebojša D.
AU  - Živković, Predrag M.
AU  - Lović, Jelena
AU  - Branković, Goran
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5815
AB  - In this study, mechanism of electrodeposition of zinc from the alkaline electrolytes has been investigated using the general theory of disperse deposits formation. The exchange current densities in the range 18.4-88 mA cm(-2) were determined using new method based on comparison of experimental and simulated polarization curves, and the excellent agreement with the values found in the literature has been attained. Correlation between the polarization characteristics and morphologies of zinc deposits characterized by the scanning electron microscopic (SEM) technique was established. The spongy-like particles constructed from nanofilaments and the large grains or boulders were formed in the zone of the fast increase of the current density with the overpotential before the plateau of the limiting diffusion current density was reached. The shape of dendrites, formed inside the plateau of the limiting diffusion current density and at the higher ones, strongly depended on overpotential of the electrodeposition. Mechanism of formation of all obtained forms was discussed by the consideration of the different rates of growth of surface protrusions in a function of the overpotential of electrodeposition through the analysis of the change of the ratio between the height and the radius of the protrusions. In order to confirm of the proposed mechanism, comparison with polarization and morphological characteristics of the other metals characterized by the different exchange current density values was made and discussed. Although zinc is classified in the group of the normal metals characterized by the high values of the exchange current density, it was found that the polarization and morphological characteristics of zinc show certain and strong similarities with those of copper, classifying zinc just at boundary between the normal and intermediate metals, that is confirmed by the estimation of the exchange current density value for zinc.
PB  - Elsevier
T2  - Journal of Electroanalytical Chemistry
T1  - Application of the general theory of disperse deposits formation in an investigation of mechanism of zinc electrodeposition from the alkaline electrolytes
EP  - 74
SP  - 65
VL  - 785
DO  - 10.1016/j.jelechem.2016.12.024
ER  - 
@article{
author = "Nikolić, Nebojša D. and Živković, Predrag M. and Lović, Jelena and Branković, Goran",
year = "2017",
abstract = "In this study, mechanism of electrodeposition of zinc from the alkaline electrolytes has been investigated using the general theory of disperse deposits formation. The exchange current densities in the range 18.4-88 mA cm(-2) were determined using new method based on comparison of experimental and simulated polarization curves, and the excellent agreement with the values found in the literature has been attained. Correlation between the polarization characteristics and morphologies of zinc deposits characterized by the scanning electron microscopic (SEM) technique was established. The spongy-like particles constructed from nanofilaments and the large grains or boulders were formed in the zone of the fast increase of the current density with the overpotential before the plateau of the limiting diffusion current density was reached. The shape of dendrites, formed inside the plateau of the limiting diffusion current density and at the higher ones, strongly depended on overpotential of the electrodeposition. Mechanism of formation of all obtained forms was discussed by the consideration of the different rates of growth of surface protrusions in a function of the overpotential of electrodeposition through the analysis of the change of the ratio between the height and the radius of the protrusions. In order to confirm of the proposed mechanism, comparison with polarization and morphological characteristics of the other metals characterized by the different exchange current density values was made and discussed. Although zinc is classified in the group of the normal metals characterized by the high values of the exchange current density, it was found that the polarization and morphological characteristics of zinc show certain and strong similarities with those of copper, classifying zinc just at boundary between the normal and intermediate metals, that is confirmed by the estimation of the exchange current density value for zinc.",
publisher = "Elsevier",
journal = "Journal of Electroanalytical Chemistry",
title = "Application of the general theory of disperse deposits formation in an investigation of mechanism of zinc electrodeposition from the alkaline electrolytes",
pages = "74-65",
volume = "785",
doi = "10.1016/j.jelechem.2016.12.024"
}
Nikolić, N. D., Živković, P. M., Lović, J.,& Branković, G.. (2017). Application of the general theory of disperse deposits formation in an investigation of mechanism of zinc electrodeposition from the alkaline electrolytes. in Journal of Electroanalytical Chemistry
Elsevier., 785, 65-74.
https://doi.org/10.1016/j.jelechem.2016.12.024
Nikolić ND, Živković PM, Lović J, Branković G. Application of the general theory of disperse deposits formation in an investigation of mechanism of zinc electrodeposition from the alkaline electrolytes. in Journal of Electroanalytical Chemistry. 2017;785:65-74.
doi:10.1016/j.jelechem.2016.12.024 .
Nikolić, Nebojša D., Živković, Predrag M., Lović, Jelena, Branković, Goran, "Application of the general theory of disperse deposits formation in an investigation of mechanism of zinc electrodeposition from the alkaline electrolytes" in Journal of Electroanalytical Chemistry, 785 (2017):65-74,
https://doi.org/10.1016/j.jelechem.2016.12.024 . .
15
12
18

Estimation of the exchange current density and comparative analysis of morphology of electrochemically produced lead and zinc deposits

Nikolić, Nebojša D.; Živković, Predrag M.; Branković, Goran; Pavlović, Miomir

(Serbian Chemical Society, 2017)

TY  - JOUR
AU  - Nikolić, Nebojša D.
AU  - Živković, Predrag M.
AU  - Branković, Goran
AU  - Pavlović, Miomir
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5818
AB  - The processes of lead and zinc electrodeposition from the very dilute electrolytes were compared by the analysis of polarization characteristics and by the scanning electron microscopic (SEM) analysis of the morphology of the deposits obtained in the galvanostatic regime of electrolysis. The exchange current densities for lead and zinc were estimated by comparison of experimentally obtained polarization curves with the simulated ones obtained for the different the exchange current density to the limiting diffusion current density ratios. Using this way for the estimation of the exchange current density, it is shown that the exchange current density for Pb was more than 1300 times higher than the one for Zn. In this way, it is confirmed that the Pb electrodeposition processes are considerably faster than the Zn electrodeposition processes. The difference in the rate of electrochemical processes was confirmed by a comparison of morphologies of lead and zinc deposits obtained at current densities which corresponded to 0.25 and 0.50 values of the limiting diffusion current densities.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Estimation of the exchange current density and comparative analysis of morphology of electrochemically produced lead and zinc deposits
EP  - 550
IS  - 5
SP  - 539
VL  - 82
DO  - 10.2298/JSC161114029N
ER  - 
@article{
author = "Nikolić, Nebojša D. and Živković, Predrag M. and Branković, Goran and Pavlović, Miomir",
year = "2017",
abstract = "The processes of lead and zinc electrodeposition from the very dilute electrolytes were compared by the analysis of polarization characteristics and by the scanning electron microscopic (SEM) analysis of the morphology of the deposits obtained in the galvanostatic regime of electrolysis. The exchange current densities for lead and zinc were estimated by comparison of experimentally obtained polarization curves with the simulated ones obtained for the different the exchange current density to the limiting diffusion current density ratios. Using this way for the estimation of the exchange current density, it is shown that the exchange current density for Pb was more than 1300 times higher than the one for Zn. In this way, it is confirmed that the Pb electrodeposition processes are considerably faster than the Zn electrodeposition processes. The difference in the rate of electrochemical processes was confirmed by a comparison of morphologies of lead and zinc deposits obtained at current densities which corresponded to 0.25 and 0.50 values of the limiting diffusion current densities.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Estimation of the exchange current density and comparative analysis of morphology of electrochemically produced lead and zinc deposits",
pages = "550-539",
number = "5",
volume = "82",
doi = "10.2298/JSC161114029N"
}
Nikolić, N. D., Živković, P. M., Branković, G.,& Pavlović, M.. (2017). Estimation of the exchange current density and comparative analysis of morphology of electrochemically produced lead and zinc deposits. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 82(5), 539-550.
https://doi.org/10.2298/JSC161114029N
Nikolić ND, Živković PM, Branković G, Pavlović M. Estimation of the exchange current density and comparative analysis of morphology of electrochemically produced lead and zinc deposits. in Journal of the Serbian Chemical Society. 2017;82(5):539-550.
doi:10.2298/JSC161114029N .
Nikolić, Nebojša D., Živković, Predrag M., Branković, Goran, Pavlović, Miomir, "Estimation of the exchange current density and comparative analysis of morphology of electrochemically produced lead and zinc deposits" in Journal of the Serbian Chemical Society, 82, no. 5 (2017):539-550,
https://doi.org/10.2298/JSC161114029N . .
3
4
4

PVB/sepiolite nanocomposites as reinforcement agents for paper

Janković-Častvan, Ivona; Lazarević, Slavica; Stojanović, Dušica; Živković, Predrag M.; Petrović, Rada; Janaćković, Đorđe

(Srpsko hemijsko društvo, Beograd, 2016)

TY  - JOUR
AU  - Janković-Častvan, Ivona
AU  - Lazarević, Slavica
AU  - Stojanović, Dušica
AU  - Živković, Predrag M.
AU  - Petrović, Rada
AU  - Janaćković, Đorđe
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3320
AB  - In order to improve the mechanical properties of paper, 1, 3 and 5 wt. % of sepiolite were dispersed in a poly(vinyl butyral) (PVB) matrix and coated onto the surface of schrenz (110 g m(-2)). Deagglomerated sepiolite nanofibers in the PVB matrix on the paper surface were observed by scanning electron microscopy. The glass transition temperature of schrenz with PVB/sepiolite coatings was not changed with increasing content of sepiolite. Two different methods were used to evaluate the mechanical properties of the paper sample reinforced with PVB/sepiolite nanocomposites: tensile testing and nanoindentation. The values of breaking force and tensile energy absorption of the reinforced paper samples obtained by tensile testing were increased by up 10 %. The values of the reduced elastic modulus and hardness obtained by nanoindentation were increased by up to 78 %. The best improvement of the mechanical properties was shown by the paper sample coated with PVB/3 wt. % sepiolite nanocomposite.
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - PVB/sepiolite nanocomposites as reinforcement agents for paper
EP  - 1305
IS  - 11
SP  - 1295
VL  - 81
DO  - 10.2298/JSC160506067J
ER  - 
@article{
author = "Janković-Častvan, Ivona and Lazarević, Slavica and Stojanović, Dušica and Živković, Predrag M. and Petrović, Rada and Janaćković, Đorđe",
year = "2016",
abstract = "In order to improve the mechanical properties of paper, 1, 3 and 5 wt. % of sepiolite were dispersed in a poly(vinyl butyral) (PVB) matrix and coated onto the surface of schrenz (110 g m(-2)). Deagglomerated sepiolite nanofibers in the PVB matrix on the paper surface were observed by scanning electron microscopy. The glass transition temperature of schrenz with PVB/sepiolite coatings was not changed with increasing content of sepiolite. Two different methods were used to evaluate the mechanical properties of the paper sample reinforced with PVB/sepiolite nanocomposites: tensile testing and nanoindentation. The values of breaking force and tensile energy absorption of the reinforced paper samples obtained by tensile testing were increased by up 10 %. The values of the reduced elastic modulus and hardness obtained by nanoindentation were increased by up to 78 %. The best improvement of the mechanical properties was shown by the paper sample coated with PVB/3 wt. % sepiolite nanocomposite.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "PVB/sepiolite nanocomposites as reinforcement agents for paper",
pages = "1305-1295",
number = "11",
volume = "81",
doi = "10.2298/JSC160506067J"
}
Janković-Častvan, I., Lazarević, S., Stojanović, D., Živković, P. M., Petrović, R.,& Janaćković, Đ.. (2016). PVB/sepiolite nanocomposites as reinforcement agents for paper. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 81(11), 1295-1305.
https://doi.org/10.2298/JSC160506067J
Janković-Častvan I, Lazarević S, Stojanović D, Živković PM, Petrović R, Janaćković Đ. PVB/sepiolite nanocomposites as reinforcement agents for paper. in Journal of the Serbian Chemical Society. 2016;81(11):1295-1305.
doi:10.2298/JSC160506067J .
Janković-Častvan, Ivona, Lazarević, Slavica, Stojanović, Dušica, Živković, Predrag M., Petrović, Rada, Janaćković, Đorđe, "PVB/sepiolite nanocomposites as reinforcement agents for paper" in Journal of the Serbian Chemical Society, 81, no. 11 (2016):1295-1305,
https://doi.org/10.2298/JSC160506067J . .
5
4
5

Relationship between the kinetic parameters and morphology of electrochemically deposited lead

Nikolić, Nebojša D.; Živković, Predrag M.; Stevanović, Sanja; Branković, Goran

(Serbian Chemical Society, 2016)

TY  - JOUR
AU  - Nikolić, Nebojša D.
AU  - Živković, Predrag M.
AU  - Stevanović, Sanja
AU  - Branković, Goran
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5838
AB  - The processes of lead electrodeposition from electrolytes of various concentrations of sodium nitrate as the supporting electrolyte have been examined by chronoamperometry and by the scanning electron microscopic (SEM) analysis of deposits obtained in the potentiostatic regime of electrolysis. The good agreement between the diffusion coefficents determined by Cottrell equation and non-linear fitting method was observed. For the first time, the transition from the mixed ohmic-diffusion to the full diffusion control was defined from the analysis of Cottrell equation. The parameters, such as the number density of active sites and the nucleation rate constant, obtained by non-linear fitting method were discussed in accordance with the fact that lead belongs to the group of metals characterized by the high values of the exchange current density. The data obtained by the chronoamperometric analysis were succesfully correlated with morphologies of electrodeposited lead obtained in the different types of electrodeposition control.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Relationship between the kinetic parameters and morphology of electrochemically deposited lead
EP  - 566
IS  - 5
SP  - 553
VL  - 81
DO  - 10.2298/JSC151218028N
ER  - 
@article{
author = "Nikolić, Nebojša D. and Živković, Predrag M. and Stevanović, Sanja and Branković, Goran",
year = "2016",
abstract = "The processes of lead electrodeposition from electrolytes of various concentrations of sodium nitrate as the supporting electrolyte have been examined by chronoamperometry and by the scanning electron microscopic (SEM) analysis of deposits obtained in the potentiostatic regime of electrolysis. The good agreement between the diffusion coefficents determined by Cottrell equation and non-linear fitting method was observed. For the first time, the transition from the mixed ohmic-diffusion to the full diffusion control was defined from the analysis of Cottrell equation. The parameters, such as the number density of active sites and the nucleation rate constant, obtained by non-linear fitting method were discussed in accordance with the fact that lead belongs to the group of metals characterized by the high values of the exchange current density. The data obtained by the chronoamperometric analysis were succesfully correlated with morphologies of electrodeposited lead obtained in the different types of electrodeposition control.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Relationship between the kinetic parameters and morphology of electrochemically deposited lead",
pages = "566-553",
number = "5",
volume = "81",
doi = "10.2298/JSC151218028N"
}
Nikolić, N. D., Živković, P. M., Stevanović, S.,& Branković, G.. (2016). Relationship between the kinetic parameters and morphology of electrochemically deposited lead. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 81(5), 553-566.
https://doi.org/10.2298/JSC151218028N
Nikolić ND, Živković PM, Stevanović S, Branković G. Relationship between the kinetic parameters and morphology of electrochemically deposited lead. in Journal of the Serbian Chemical Society. 2016;81(5):553-566.
doi:10.2298/JSC151218028N .
Nikolić, Nebojša D., Živković, Predrag M., Stevanović, Sanja, Branković, Goran, "Relationship between the kinetic parameters and morphology of electrochemically deposited lead" in Journal of the Serbian Chemical Society, 81, no. 5 (2016):553-566,
https://doi.org/10.2298/JSC151218028N . .
2
4
5

The shape of the polarization curve and diagnostic criteria for control of the metal electrodeposition process

Popov, Konstantin I.; Živković, Predrag M.; Jokić, Bojan; Nikolić, Nebojša D.

(Serbian Chemical Society, 2016)

TY  - JOUR
AU  - Popov, Konstantin I.
AU  - Živković, Predrag M.
AU  - Jokić, Bojan
AU  - Nikolić, Nebojša D.
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5846
AB  - The simulated shapes of the polarization curves were correlated with the type of metal electrodeposition process control as a function of the ratio of the exchange current density to the limiting diffusion current density (j(0)/j(L)). Diagnostic criteria based on the j(0)/j(L) ratios were established. For j(0)/j(L) > 100, the system is under the ohmic control. In the range 1  LT  j(0)/j(L)  LT = 100, there is mixed ohmic-diffusion control. Pure diffusion control appears in the range 0.1  LT  j(0)/j(L)  LT = 1. For j(0)/j(L)  LT = 0.1, the system is activation controlled at low overpotentials. The proposed diagnostic criteria were verified by comparison of the simulated curves with experimentally recorded ones and by morphological analysis of deposits obtained under the different types of control of the metal electrodeposition process.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - The shape of the polarization curve and diagnostic criteria for control of the metal electrodeposition process
EP  - 306
IS  - 3
SP  - 291
VL  - 81
DO  - 10.2298/JSC150717076P
ER  - 
@article{
author = "Popov, Konstantin I. and Živković, Predrag M. and Jokić, Bojan and Nikolić, Nebojša D.",
year = "2016",
abstract = "The simulated shapes of the polarization curves were correlated with the type of metal electrodeposition process control as a function of the ratio of the exchange current density to the limiting diffusion current density (j(0)/j(L)). Diagnostic criteria based on the j(0)/j(L) ratios were established. For j(0)/j(L) > 100, the system is under the ohmic control. In the range 1  LT  j(0)/j(L)  LT = 100, there is mixed ohmic-diffusion control. Pure diffusion control appears in the range 0.1  LT  j(0)/j(L)  LT = 1. For j(0)/j(L)  LT = 0.1, the system is activation controlled at low overpotentials. The proposed diagnostic criteria were verified by comparison of the simulated curves with experimentally recorded ones and by morphological analysis of deposits obtained under the different types of control of the metal electrodeposition process.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "The shape of the polarization curve and diagnostic criteria for control of the metal electrodeposition process",
pages = "306-291",
number = "3",
volume = "81",
doi = "10.2298/JSC150717076P"
}
Popov, K. I., Živković, P. M., Jokić, B.,& Nikolić, N. D.. (2016). The shape of the polarization curve and diagnostic criteria for control of the metal electrodeposition process. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 81(3), 291-306.
https://doi.org/10.2298/JSC150717076P
Popov KI, Živković PM, Jokić B, Nikolić ND. The shape of the polarization curve and diagnostic criteria for control of the metal electrodeposition process. in Journal of the Serbian Chemical Society. 2016;81(3):291-306.
doi:10.2298/JSC150717076P .
Popov, Konstantin I., Živković, Predrag M., Jokić, Bojan, Nikolić, Nebojša D., "The shape of the polarization curve and diagnostic criteria for control of the metal electrodeposition process" in Journal of the Serbian Chemical Society, 81, no. 3 (2016):291-306,
https://doi.org/10.2298/JSC150717076P . .
8
10
11

Improvement of the mechanical properties of paper by starch coatings modified with sepiolite nanoparticles

Janković-Častvan, Ivona; Lazarević, Slavica; Stojanović, Dušica; Živković, Predrag M.; Petrović, Rada; Janaćković, Đorđe

(Wiley-VCH Verlag Gmbh, Weinheim, 2015)

TY  - JOUR
AU  - Janković-Častvan, Ivona
AU  - Lazarević, Slavica
AU  - Stojanović, Dušica
AU  - Živković, Predrag M.
AU  - Petrović, Rada
AU  - Janaćković, Đorđe
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3049
AB  - The modern and rapidly developing paper and board industry requires more efficient agents for the surface of paper in order to improve the mechanical properties. The starch coating used for the reinforcement of schrenz (110g/m(2)) contained ultrasonicated nanoparticles of the mineral sepiolite. The viscosity of starch dispersions modified with different concentration of sepiolite was followed at the temperature of the coating on schrenz. The values of the breaking length, bursting strength and CMT-strength of the paper reinforced with modified starch were increased by up to 20%. The viscoelastic properties as storage modulus were increased, too. Scanning electron microscopy of the samples showed deagglomeration and homogeneity of the sepiolite nanoparticles.
PB  - Wiley-VCH Verlag Gmbh, Weinheim
T2  - Starch-Starke
T1  - Improvement of the mechanical properties of paper by starch coatings modified with sepiolite nanoparticles
EP  - 380
IS  - 3-4
SP  - 373
VL  - 67
DO  - 10.1002/star.201400171
ER  - 
@article{
author = "Janković-Častvan, Ivona and Lazarević, Slavica and Stojanović, Dušica and Živković, Predrag M. and Petrović, Rada and Janaćković, Đorđe",
year = "2015",
abstract = "The modern and rapidly developing paper and board industry requires more efficient agents for the surface of paper in order to improve the mechanical properties. The starch coating used for the reinforcement of schrenz (110g/m(2)) contained ultrasonicated nanoparticles of the mineral sepiolite. The viscosity of starch dispersions modified with different concentration of sepiolite was followed at the temperature of the coating on schrenz. The values of the breaking length, bursting strength and CMT-strength of the paper reinforced with modified starch were increased by up to 20%. The viscoelastic properties as storage modulus were increased, too. Scanning electron microscopy of the samples showed deagglomeration and homogeneity of the sepiolite nanoparticles.",
publisher = "Wiley-VCH Verlag Gmbh, Weinheim",
journal = "Starch-Starke",
title = "Improvement of the mechanical properties of paper by starch coatings modified with sepiolite nanoparticles",
pages = "380-373",
number = "3-4",
volume = "67",
doi = "10.1002/star.201400171"
}
Janković-Častvan, I., Lazarević, S., Stojanović, D., Živković, P. M., Petrović, R.,& Janaćković, Đ.. (2015). Improvement of the mechanical properties of paper by starch coatings modified with sepiolite nanoparticles. in Starch-Starke
Wiley-VCH Verlag Gmbh, Weinheim., 67(3-4), 373-380.
https://doi.org/10.1002/star.201400171
Janković-Častvan I, Lazarević S, Stojanović D, Živković PM, Petrović R, Janaćković Đ. Improvement of the mechanical properties of paper by starch coatings modified with sepiolite nanoparticles. in Starch-Starke. 2015;67(3-4):373-380.
doi:10.1002/star.201400171 .
Janković-Častvan, Ivona, Lazarević, Slavica, Stojanović, Dušica, Živković, Predrag M., Petrović, Rada, Janaćković, Đorđe, "Improvement of the mechanical properties of paper by starch coatings modified with sepiolite nanoparticles" in Starch-Starke, 67, no. 3-4 (2015):373-380,
https://doi.org/10.1002/star.201400171 . .
14
14
16

The potentiostatic current transients and the role of local diffusion fields in formation of the 2D lead dendrites from the concentrated electrolyte

Nikolić, Nebojša D.; Popov, Konstantin I.; Ivanović, Evica; Branković, Goran; Stevanović, Sanja; Živković, Predrag M.

(Elsevier, 2015)

TY  - JOUR
AU  - Nikolić, Nebojša D.
AU  - Popov, Konstantin I.
AU  - Ivanović, Evica
AU  - Branković, Goran
AU  - Stevanović, Sanja
AU  - Živković, Predrag M.
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5806
AB  - Electrodeposition of lead from the concentrated nitrate electrolyte in the potentiostatic regime of electrolysis has been investigated by the analysis of the potentiostatic current transients and scanning electron microscope (SEM). It was found that the process of Pb nucleation from the concentrated electrolyte follows Scharifker model based on the 3D (three-dimensional) instantaneous nucleation with diffusion-controlled growth. The deviations of the obtained dependencies from the theoretical prediction for this model have been also discussed. Needle-like and fern-like dendrites, as well as crystals of irregular shape (precursors of dendrites) were formed in the diffusion controlled electrodeposition. The SEM analysis of these dendritic forms revealed their 2D (two-dimensional) growth. The size of needle-like dendrites was considerably larger than the size of both the fern-like dendrites and the irregular crystals. Although the electrodeposition process occurred inside the linear diffusion layer of the macroelectrode, the shape and size of dendrites were determined by the effect of local diffusion fields formed around tips (spherical diffusion) and top edges (cylindrical diffusion) of protrusions formed in the initial stage of the electrodeposition. The growth rates under the conditions of spherical and cylindrical diffusion control were mutually compared and a faster growth under the conditions of the spherical, in relation to the cylindrical diffusion, was proved. The effect of the current density distribution on formation of the final forms of Pb dendrites was also discussed.
PB  - Elsevier
T2  - Journal of Electroanalytical Chemistry
T1  - The potentiostatic current transients and the role of local diffusion fields in formation of the 2D lead dendrites from the concentrated electrolyte
EP  - 148
SP  - 137
VL  - 739
DO  - 10.1016/j.jelechem.2014.12.020
ER  - 
@article{
author = "Nikolić, Nebojša D. and Popov, Konstantin I. and Ivanović, Evica and Branković, Goran and Stevanović, Sanja and Živković, Predrag M.",
year = "2015",
abstract = "Electrodeposition of lead from the concentrated nitrate electrolyte in the potentiostatic regime of electrolysis has been investigated by the analysis of the potentiostatic current transients and scanning electron microscope (SEM). It was found that the process of Pb nucleation from the concentrated electrolyte follows Scharifker model based on the 3D (three-dimensional) instantaneous nucleation with diffusion-controlled growth. The deviations of the obtained dependencies from the theoretical prediction for this model have been also discussed. Needle-like and fern-like dendrites, as well as crystals of irregular shape (precursors of dendrites) were formed in the diffusion controlled electrodeposition. The SEM analysis of these dendritic forms revealed their 2D (two-dimensional) growth. The size of needle-like dendrites was considerably larger than the size of both the fern-like dendrites and the irregular crystals. Although the electrodeposition process occurred inside the linear diffusion layer of the macroelectrode, the shape and size of dendrites were determined by the effect of local diffusion fields formed around tips (spherical diffusion) and top edges (cylindrical diffusion) of protrusions formed in the initial stage of the electrodeposition. The growth rates under the conditions of spherical and cylindrical diffusion control were mutually compared and a faster growth under the conditions of the spherical, in relation to the cylindrical diffusion, was proved. The effect of the current density distribution on formation of the final forms of Pb dendrites was also discussed.",
publisher = "Elsevier",
journal = "Journal of Electroanalytical Chemistry",
title = "The potentiostatic current transients and the role of local diffusion fields in formation of the 2D lead dendrites from the concentrated electrolyte",
pages = "148-137",
volume = "739",
doi = "10.1016/j.jelechem.2014.12.020"
}
Nikolić, N. D., Popov, K. I., Ivanović, E., Branković, G., Stevanović, S.,& Živković, P. M.. (2015). The potentiostatic current transients and the role of local diffusion fields in formation of the 2D lead dendrites from the concentrated electrolyte. in Journal of Electroanalytical Chemistry
Elsevier., 739, 137-148.
https://doi.org/10.1016/j.jelechem.2014.12.020
Nikolić ND, Popov KI, Ivanović E, Branković G, Stevanović S, Živković PM. The potentiostatic current transients and the role of local diffusion fields in formation of the 2D lead dendrites from the concentrated electrolyte. in Journal of Electroanalytical Chemistry. 2015;739:137-148.
doi:10.1016/j.jelechem.2014.12.020 .
Nikolić, Nebojša D., Popov, Konstantin I., Ivanović, Evica, Branković, Goran, Stevanović, Sanja, Živković, Predrag M., "The potentiostatic current transients and the role of local diffusion fields in formation of the 2D lead dendrites from the concentrated electrolyte" in Journal of Electroanalytical Chemistry, 739 (2015):137-148,
https://doi.org/10.1016/j.jelechem.2014.12.020 . .
20
18
23

Comparative analysis of the polarization and morphological characteristics of electrochemically produced powder forms of the intermediate metals

Nikolić, Nebojša D.; Živković, Predrag M.; Jokić, Bojan; Pavlović, Miomir; Stevanović, Jasmina

(Macedonian Journal of Chemistry and Chemical Engineering, 2014)

TY  - JOUR
AU  - Nikolić, Nebojša D.
AU  - Živković, Predrag M.
AU  - Jokić, Bojan
AU  - Pavlović, Miomir
AU  - Stevanović, Jasmina
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5766
AB  - The polarization and morphological characteristics of powder forms of the group of the intermediate metals were examined by the analysis of silver and copper electrodeposition processes at high overpotentials. The pine-like dendrites constructed from the corncob-like forms, which are very similar to each other, were obtained by electrodeposition of these metals at the overpotential belonging to the plateaus of the limiting diffusion current density. A completely different situation was observed by the electrodeposition of silver and copper at the overpotential outside the plateaus of the limiting diffusion current density in the zone with the fast increase in current density with the overpotential. Silver dendrites, which were very similar to silver and copper dendrites obtained inside the plateaus of the limiting diffusion current density, were obtained at the overpotential outside the plateau. Due to the lower overpotential for hydrogen evolution for copper, hydrogen produced during the copper electrodeposition process strongly affected the surface morphology of copper. The same shape polarization curves with completely different surface morphologies of Cu and Ag electrodeposited at overpotentials after the inflection point clearly indicate the importance of morphological analysis in the investigation of polarization characteristics of the electrodeposition systems. The role of hydrogen as a crucial parameter in the continuous change of copper surface morphology from dendrites to honeycomb-like structures was investigated in detail. On the basis of this analysis, the transitional character of the intermediate metals between the normal and inert metals was considered. The typical powder forms characterising electrodeposition of the intermediate metals were also defined and systematized.
PB  - Macedonian Journal of Chemistry and Chemical Engineering
T2  - Macedonian Journal of Chemistry and Chemical Engineering
T1  - Comparative analysis of the polarization and morphological characteristics of electrochemically produced powder forms of the intermediate metals
EP  - 180
IS  - 2
SP  - 169
VL  - 33
UR  - https://hdl.handle.net/21.15107/rcub_cer_1482
ER  - 
@article{
author = "Nikolić, Nebojša D. and Živković, Predrag M. and Jokić, Bojan and Pavlović, Miomir and Stevanović, Jasmina",
year = "2014",
abstract = "The polarization and morphological characteristics of powder forms of the group of the intermediate metals were examined by the analysis of silver and copper electrodeposition processes at high overpotentials. The pine-like dendrites constructed from the corncob-like forms, which are very similar to each other, were obtained by electrodeposition of these metals at the overpotential belonging to the plateaus of the limiting diffusion current density. A completely different situation was observed by the electrodeposition of silver and copper at the overpotential outside the plateaus of the limiting diffusion current density in the zone with the fast increase in current density with the overpotential. Silver dendrites, which were very similar to silver and copper dendrites obtained inside the plateaus of the limiting diffusion current density, were obtained at the overpotential outside the plateau. Due to the lower overpotential for hydrogen evolution for copper, hydrogen produced during the copper electrodeposition process strongly affected the surface morphology of copper. The same shape polarization curves with completely different surface morphologies of Cu and Ag electrodeposited at overpotentials after the inflection point clearly indicate the importance of morphological analysis in the investigation of polarization characteristics of the electrodeposition systems. The role of hydrogen as a crucial parameter in the continuous change of copper surface morphology from dendrites to honeycomb-like structures was investigated in detail. On the basis of this analysis, the transitional character of the intermediate metals between the normal and inert metals was considered. The typical powder forms characterising electrodeposition of the intermediate metals were also defined and systematized.",
publisher = "Macedonian Journal of Chemistry and Chemical Engineering",
journal = "Macedonian Journal of Chemistry and Chemical Engineering",
title = "Comparative analysis of the polarization and morphological characteristics of electrochemically produced powder forms of the intermediate metals",
pages = "180-169",
number = "2",
volume = "33",
url = "https://hdl.handle.net/21.15107/rcub_cer_1482"
}
Nikolić, N. D., Živković, P. M., Jokić, B., Pavlović, M.,& Stevanović, J.. (2014). Comparative analysis of the polarization and morphological characteristics of electrochemically produced powder forms of the intermediate metals. in Macedonian Journal of Chemistry and Chemical Engineering
Macedonian Journal of Chemistry and Chemical Engineering., 33(2), 169-180.
https://hdl.handle.net/21.15107/rcub_cer_1482
Nikolić ND, Živković PM, Jokić B, Pavlović M, Stevanović J. Comparative analysis of the polarization and morphological characteristics of electrochemically produced powder forms of the intermediate metals. in Macedonian Journal of Chemistry and Chemical Engineering. 2014;33(2):169-180.
https://hdl.handle.net/21.15107/rcub_cer_1482 .
Nikolić, Nebojša D., Živković, Predrag M., Jokić, Bojan, Pavlović, Miomir, Stevanović, Jasmina, "Comparative analysis of the polarization and morphological characteristics of electrochemically produced powder forms of the intermediate metals" in Macedonian Journal of Chemistry and Chemical Engineering, 33, no. 2 (2014):169-180,
https://hdl.handle.net/21.15107/rcub_cer_1482 .
2
9

A new insight into the mechanism of lead electrodeposition: Ohmic-diffusion control of the electrodeposition process

Nikolić, Nebojša D.; Popov, Konstantin I.; Živković, Predrag M.; Branković, Goran

(Elsevier, 2013)

TY  - JOUR
AU  - Nikolić, Nebojša D.
AU  - Popov, Konstantin I.
AU  - Živković, Predrag M.
AU  - Branković, Goran
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5673
AB  - A new insight into the mechanism of lead electrodeposition from nitrate solutions is presented by analysis of the polarization characteristics and by scanning electron microscopic (SEM) analysis of the surface morphology of the lead deposits obtained in the potentiostatic regime of electrolysis. In dependence on the concentration of Pb(II) ions, the electrodeposition process is either mixed ohmic-diffusion or completely ohmic controlled. The ratio of the ohmic control to the total control of the electrodeposition process increased with increasing concentration of Pb(II) ions and at the higher concentrations of Pb(II) ions, the electrodeposition process became completely ohmic controlled. The polarization characteristics were well correlated with the morphologies of the obtained lead deposits. The formation of regular crystals was a characteristic of ohmic control of the electrodeposition process, while needle-like and fern-like dendrites were the predominant morphological forms obtained under diffusion control. The critical overpotentials for both dendritic growth initiation and instantaneous dendritic growth were analyzed and a mechanism of lead electrodeposition based on this analysis is presented. It was shown that the values of these critical overpotentials decreased and approached one another with increasing concentration of Pb(II) ions and finally became the same when full ohmic control was attained. The presented results were in good agreement with the predications of the general theory for the formation of disperse metal electrodeposits.
PB  - Elsevier
T2  - Journal of Electroanalytical Chemistry
T1  - A new insight into the mechanism of lead electrodeposition: Ohmic-diffusion control of the electrodeposition process
EP  - 76
SP  - 66
VL  - 691
DO  - 10.1016/j.jelechem.2012.12.011
ER  - 
@article{
author = "Nikolić, Nebojša D. and Popov, Konstantin I. and Živković, Predrag M. and Branković, Goran",
year = "2013",
abstract = "A new insight into the mechanism of lead electrodeposition from nitrate solutions is presented by analysis of the polarization characteristics and by scanning electron microscopic (SEM) analysis of the surface morphology of the lead deposits obtained in the potentiostatic regime of electrolysis. In dependence on the concentration of Pb(II) ions, the electrodeposition process is either mixed ohmic-diffusion or completely ohmic controlled. The ratio of the ohmic control to the total control of the electrodeposition process increased with increasing concentration of Pb(II) ions and at the higher concentrations of Pb(II) ions, the electrodeposition process became completely ohmic controlled. The polarization characteristics were well correlated with the morphologies of the obtained lead deposits. The formation of regular crystals was a characteristic of ohmic control of the electrodeposition process, while needle-like and fern-like dendrites were the predominant morphological forms obtained under diffusion control. The critical overpotentials for both dendritic growth initiation and instantaneous dendritic growth were analyzed and a mechanism of lead electrodeposition based on this analysis is presented. It was shown that the values of these critical overpotentials decreased and approached one another with increasing concentration of Pb(II) ions and finally became the same when full ohmic control was attained. The presented results were in good agreement with the predications of the general theory for the formation of disperse metal electrodeposits.",
publisher = "Elsevier",
journal = "Journal of Electroanalytical Chemistry",
title = "A new insight into the mechanism of lead electrodeposition: Ohmic-diffusion control of the electrodeposition process",
pages = "76-66",
volume = "691",
doi = "10.1016/j.jelechem.2012.12.011"
}
Nikolić, N. D., Popov, K. I., Živković, P. M.,& Branković, G.. (2013). A new insight into the mechanism of lead electrodeposition: Ohmic-diffusion control of the electrodeposition process. in Journal of Electroanalytical Chemistry
Elsevier., 691, 66-76.
https://doi.org/10.1016/j.jelechem.2012.12.011
Nikolić ND, Popov KI, Živković PM, Branković G. A new insight into the mechanism of lead electrodeposition: Ohmic-diffusion control of the electrodeposition process. in Journal of Electroanalytical Chemistry. 2013;691:66-76.
doi:10.1016/j.jelechem.2012.12.011 .
Nikolić, Nebojša D., Popov, Konstantin I., Živković, Predrag M., Branković, Goran, "A new insight into the mechanism of lead electrodeposition: Ohmic-diffusion control of the electrodeposition process" in Journal of Electroanalytical Chemistry, 691 (2013):66-76,
https://doi.org/10.1016/j.jelechem.2012.12.011 . .
41
37
48

Influence of the complex formation on the morphology of lead powder particles produced by the electrodeposition processes

Nikolić, Nebojša D.; Vastag, Gyöngyi Gy.; Živković, Predrag M.; Jokić, Bojan; Branković, Goran

(Elsevier, 2013)

TY  - JOUR
AU  - Nikolić, Nebojša D.
AU  - Vastag, Gyöngyi Gy.
AU  - Živković, Predrag M.
AU  - Jokić, Bojan
AU  - Branković, Goran
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5701
AB  - The processes of lead electrodeposition from the basic (nitrate) and complex (acetate) electrolytes were mutually compared by the analysis of their polarization characteristics and by the scanning electron microscopic (SEM) analysis of the morphology of formed deposits. Although the polarization characteristics of lead recorded from these two electrolytes were relatively similar to each other, the shape of formed dendrites strongly depended on the type of electrolyte. The dendrites composed of stalk and weak developed primary branches (the primary (P) type) were predominantly formed from the basic electrolyte. On the other hand, the very branchy dendrites composed of stalk and of both primary and secondary branches (the secondary (S) type) were mainly electrodeposited from the complex electrolyte. Considering the fact that the application of lead powder in many technologies is closely related with its surface morphology, the special attention was given to the analysis of the type of electrolytes on formation of the different dendritic forms. It was shown that formation of more branchy dendrites from the acetate electrolyte can be ascribed to the lower exchange current density (or to the lower rate of electrochemical process) for this electrolyte than for the nitrate one due to the process of complex formation.
PB  - Elsevier
T2  - Advanced Powder Technology
T1  - Influence of the complex formation on the morphology of lead powder particles produced by the electrodeposition processes
EP  - 682
IS  - 3
SP  - 674
VL  - 24
DO  - 10.1016/j.apt.2012.12.008
ER  - 
@article{
author = "Nikolić, Nebojša D. and Vastag, Gyöngyi Gy. and Živković, Predrag M. and Jokić, Bojan and Branković, Goran",
year = "2013",
abstract = "The processes of lead electrodeposition from the basic (nitrate) and complex (acetate) electrolytes were mutually compared by the analysis of their polarization characteristics and by the scanning electron microscopic (SEM) analysis of the morphology of formed deposits. Although the polarization characteristics of lead recorded from these two electrolytes were relatively similar to each other, the shape of formed dendrites strongly depended on the type of electrolyte. The dendrites composed of stalk and weak developed primary branches (the primary (P) type) were predominantly formed from the basic electrolyte. On the other hand, the very branchy dendrites composed of stalk and of both primary and secondary branches (the secondary (S) type) were mainly electrodeposited from the complex electrolyte. Considering the fact that the application of lead powder in many technologies is closely related with its surface morphology, the special attention was given to the analysis of the type of electrolytes on formation of the different dendritic forms. It was shown that formation of more branchy dendrites from the acetate electrolyte can be ascribed to the lower exchange current density (or to the lower rate of electrochemical process) for this electrolyte than for the nitrate one due to the process of complex formation.",
publisher = "Elsevier",
journal = "Advanced Powder Technology",
title = "Influence of the complex formation on the morphology of lead powder particles produced by the electrodeposition processes",
pages = "682-674",
number = "3",
volume = "24",
doi = "10.1016/j.apt.2012.12.008"
}
Nikolić, N. D., Vastag, G. Gy., Živković, P. M., Jokić, B.,& Branković, G.. (2013). Influence of the complex formation on the morphology of lead powder particles produced by the electrodeposition processes. in Advanced Powder Technology
Elsevier., 24(3), 674-682.
https://doi.org/10.1016/j.apt.2012.12.008
Nikolić ND, Vastag GG, Živković PM, Jokić B, Branković G. Influence of the complex formation on the morphology of lead powder particles produced by the electrodeposition processes. in Advanced Powder Technology. 2013;24(3):674-682.
doi:10.1016/j.apt.2012.12.008 .
Nikolić, Nebojša D., Vastag, Gyöngyi Gy., Živković, Predrag M., Jokić, Bojan, Branković, Goran, "Influence of the complex formation on the morphology of lead powder particles produced by the electrodeposition processes" in Advanced Powder Technology, 24, no. 3 (2013):674-682,
https://doi.org/10.1016/j.apt.2012.12.008 . .
23
22
26

Influence of the type of electrolyte on the morphological and crystallographic characteristics of lead powder particles

Nikolić, Nebojša D.; Maksimović, Vesna M.; Branković, Goran; Živković, Predrag M.; Pavlović, Miomir

(Serbian Chemical Society, 2013)

TY  - JOUR
AU  - Nikolić, Nebojša D.
AU  - Maksimović, Vesna M.
AU  - Branković, Goran
AU  - Živković, Predrag M.
AU  - Pavlović, Miomir
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5702
AB  - Lead electrodeposition processes from basic (nitrate) and complex (acetate) electrolytes were mutually compared by scanning electron microscopy and X-ray diffraction investigation of the produced powder particles. The shape of dendritic particles strongly depended on the type of electrolyte. Dendrites composed of a stalk and weakly developed primary branches (the primary type) were predominantly formed from the basic electrolyte. Ramified dendrites composed of a stalk and of both primary and secondary branches (the secondary type) were mainly formed from the complex electrolyte. In both types of powder particles, Pb crystallites were predominantly oriented in the (111) plane. The formation of powder particles of different shapes with strong (111) preferred orientation is discussed and explained by consideration of the general characteristics of the growth of crystals in electrocrystallization processes.
AB  - Procesi elektrohemijskog taloženja olova iz osnovnog (nitratnog) i kompleksnog (acetatnog) elektrolita su bili međusobno upoređeni tehnikom skenirajuće elektronske mikroskopije i rendgensko-difrakcionom analizom proizvedenih čestica praha. Oblik dendritičnih čestica je snažno zavisio od tipa elektrolita. Dendriti sastavljeni od stabla i slabo razvijenih grana (primarni tip) su bili predominantno formirani iz osnovnog elektrolita. Razgranati dendriti sastavljeni od stabla i od primarnih i sekundarnih grana (sekundarni tip) su bili uglavnom formirani iz kompleksnog elektrolita. U oba tipa praškastih čestica kristaliti olova su bili dominantno orijentisani u (111) ravni. Formiranje praškastih čestica sa strogom (111) orijentacijom je bilo diskutovano i objašnjeno razmatranjem opštih karakteristika rasta kristala u procesima elektrokristalizacije.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Influence of the type of electrolyte on the morphological and crystallographic characteristics of lead powder particles
T1  - Uticaj tipa elektrolita na morfološke i kristalografske karakteristike praškastih čestica olova
EP  - 1395
IS  - 9
SP  - 1387
VL  - 78
DO  - 10.2298/JSC130211034N
ER  - 
@article{
author = "Nikolić, Nebojša D. and Maksimović, Vesna M. and Branković, Goran and Živković, Predrag M. and Pavlović, Miomir",
year = "2013",
abstract = "Lead electrodeposition processes from basic (nitrate) and complex (acetate) electrolytes were mutually compared by scanning electron microscopy and X-ray diffraction investigation of the produced powder particles. The shape of dendritic particles strongly depended on the type of electrolyte. Dendrites composed of a stalk and weakly developed primary branches (the primary type) were predominantly formed from the basic electrolyte. Ramified dendrites composed of a stalk and of both primary and secondary branches (the secondary type) were mainly formed from the complex electrolyte. In both types of powder particles, Pb crystallites were predominantly oriented in the (111) plane. The formation of powder particles of different shapes with strong (111) preferred orientation is discussed and explained by consideration of the general characteristics of the growth of crystals in electrocrystallization processes., Procesi elektrohemijskog taloženja olova iz osnovnog (nitratnog) i kompleksnog (acetatnog) elektrolita su bili međusobno upoređeni tehnikom skenirajuće elektronske mikroskopije i rendgensko-difrakcionom analizom proizvedenih čestica praha. Oblik dendritičnih čestica je snažno zavisio od tipa elektrolita. Dendriti sastavljeni od stabla i slabo razvijenih grana (primarni tip) su bili predominantno formirani iz osnovnog elektrolita. Razgranati dendriti sastavljeni od stabla i od primarnih i sekundarnih grana (sekundarni tip) su bili uglavnom formirani iz kompleksnog elektrolita. U oba tipa praškastih čestica kristaliti olova su bili dominantno orijentisani u (111) ravni. Formiranje praškastih čestica sa strogom (111) orijentacijom je bilo diskutovano i objašnjeno razmatranjem opštih karakteristika rasta kristala u procesima elektrokristalizacije.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Influence of the type of electrolyte on the morphological and crystallographic characteristics of lead powder particles, Uticaj tipa elektrolita na morfološke i kristalografske karakteristike praškastih čestica olova",
pages = "1395-1387",
number = "9",
volume = "78",
doi = "10.2298/JSC130211034N"
}
Nikolić, N. D., Maksimović, V. M., Branković, G., Živković, P. M.,& Pavlović, M.. (2013). Influence of the type of electrolyte on the morphological and crystallographic characteristics of lead powder particles. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 78(9), 1387-1395.
https://doi.org/10.2298/JSC130211034N
Nikolić ND, Maksimović VM, Branković G, Živković PM, Pavlović M. Influence of the type of electrolyte on the morphological and crystallographic characteristics of lead powder particles. in Journal of the Serbian Chemical Society. 2013;78(9):1387-1395.
doi:10.2298/JSC130211034N .
Nikolić, Nebojša D., Maksimović, Vesna M., Branković, Goran, Živković, Predrag M., Pavlović, Miomir, "Influence of the type of electrolyte on the morphological and crystallographic characteristics of lead powder particles" in Journal of the Serbian Chemical Society, 78, no. 9 (2013):1387-1395,
https://doi.org/10.2298/JSC130211034N . .
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Formation of Disperse Silver Deposits by the Electrodeposition Processes at High Overpotentials

Popov, Konstantin I.; Živković, Predrag M.; Nikolić, Nebojša D.

(Esg, Belgrade, 2012)

TY  - JOUR
AU  - Popov, Konstantin I.
AU  - Živković, Predrag M.
AU  - Nikolić, Nebojša D.
PY  - 2012
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5687
AB  - In this study, electrodeposition of silver from nitrate solution at the high overpotentials was analyzed. Morphologies of silver deposits obtained at the different overpotentials and with the different electrodeposition times were examined using the technique of scanning electron microscopy (SEM). The different disperse morphological forms, such as granules, needle-like and spongy-dendritic ones were formed during silver electrodeposition from this solution. The size of granules decreased and their number increased with the increase of overpotential of electrodeposition. With the increasing overpotential, the induction time for the appearance of spongy-dendritic forms decreased with a tendency to increase their ramification. Mathematic model describing the mechanism of metal electrodeposition at the high overpotentials is proposed and discussed on the basis of the obtained silver surface morphology.
PB  - Esg, Belgrade
T2  - International Journal of Electrochemical Science
T1  - Formation of Disperse Silver Deposits by the Electrodeposition Processes at High Overpotentials
EP  - 696
IS  - 1
SP  - 686
VL  - 7
UR  - https://hdl.handle.net/21.15107/rcub_cer_1020
ER  - 
@article{
author = "Popov, Konstantin I. and Živković, Predrag M. and Nikolić, Nebojša D.",
year = "2012",
abstract = "In this study, electrodeposition of silver from nitrate solution at the high overpotentials was analyzed. Morphologies of silver deposits obtained at the different overpotentials and with the different electrodeposition times were examined using the technique of scanning electron microscopy (SEM). The different disperse morphological forms, such as granules, needle-like and spongy-dendritic ones were formed during silver electrodeposition from this solution. The size of granules decreased and their number increased with the increase of overpotential of electrodeposition. With the increasing overpotential, the induction time for the appearance of spongy-dendritic forms decreased with a tendency to increase their ramification. Mathematic model describing the mechanism of metal electrodeposition at the high overpotentials is proposed and discussed on the basis of the obtained silver surface morphology.",
publisher = "Esg, Belgrade",
journal = "International Journal of Electrochemical Science",
title = "Formation of Disperse Silver Deposits by the Electrodeposition Processes at High Overpotentials",
pages = "696-686",
number = "1",
volume = "7",
url = "https://hdl.handle.net/21.15107/rcub_cer_1020"
}
Popov, K. I., Živković, P. M.,& Nikolić, N. D.. (2012). Formation of Disperse Silver Deposits by the Electrodeposition Processes at High Overpotentials. in International Journal of Electrochemical Science
Esg, Belgrade., 7(1), 686-696.
https://hdl.handle.net/21.15107/rcub_cer_1020
Popov KI, Živković PM, Nikolić ND. Formation of Disperse Silver Deposits by the Electrodeposition Processes at High Overpotentials. in International Journal of Electrochemical Science. 2012;7(1):686-696.
https://hdl.handle.net/21.15107/rcub_cer_1020 .
Popov, Konstantin I., Živković, Predrag M., Nikolić, Nebojša D., "Formation of Disperse Silver Deposits by the Electrodeposition Processes at High Overpotentials" in International Journal of Electrochemical Science, 7, no. 1 (2012):686-696,
https://hdl.handle.net/21.15107/rcub_cer_1020 .
8
8

Electrodeposition and electroless deposition of metallic powders: A comparison

Djokić, S.S.; Nikolić, Nebojša D.; Živković, Predrag M.; Popov, Konstantin I.; Djokić, N.S.

(2011)

TY  - CONF
AU  - Djokić, S.S.
AU  - Nikolić, Nebojša D.
AU  - Živković, Predrag M.
AU  - Popov, Konstantin I.
AU  - Djokić, N.S.
PY  - 2011
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5592
AB  - Electrodeposition and electroless deposition of metallic powders were comparatively investigated. Electrodeposition of copper is accompanied with the simultaneous hydrogen evolution, which significantly influences the morphology of Cu powder. At lower overpotentials, branched dendrites were produced. At higher overpotentials honeycomb-like deposits of copper were obtained. Formation of silver powders was characterized by the comparison of the exchange and limiting current densities. Instantaneous growth of dendrites starts at low overpotential due to large exchange current density in silver nitrate solution. Formation of powders such as Ni, Co, Ag, Pd and Au from homogenous solutions using an appropriate reducing agent or via galvanic displacement reaction was demonstrated. The hydrolysis of metallic ions is crucial in the deposition metallic powders via electroless deposition from homogenous solutions. Oxides, such as Ag 2O, Cu 2O and CuO, suspended in water can successfully be reduced with an appropriate reducing agent, leading to the precipitation of metallic powders.
C3  - ECS Transactions
T1  - Electrodeposition and electroless deposition of metallic powders: A comparison
EP  - 31
IS  - 18
SP  - 7
VL  - 33
DO  - 10.1149/1.3551487
ER  - 
@conference{
author = "Djokić, S.S. and Nikolić, Nebojša D. and Živković, Predrag M. and Popov, Konstantin I. and Djokić, N.S.",
year = "2011",
abstract = "Electrodeposition and electroless deposition of metallic powders were comparatively investigated. Electrodeposition of copper is accompanied with the simultaneous hydrogen evolution, which significantly influences the morphology of Cu powder. At lower overpotentials, branched dendrites were produced. At higher overpotentials honeycomb-like deposits of copper were obtained. Formation of silver powders was characterized by the comparison of the exchange and limiting current densities. Instantaneous growth of dendrites starts at low overpotential due to large exchange current density in silver nitrate solution. Formation of powders such as Ni, Co, Ag, Pd and Au from homogenous solutions using an appropriate reducing agent or via galvanic displacement reaction was demonstrated. The hydrolysis of metallic ions is crucial in the deposition metallic powders via electroless deposition from homogenous solutions. Oxides, such as Ag 2O, Cu 2O and CuO, suspended in water can successfully be reduced with an appropriate reducing agent, leading to the precipitation of metallic powders.",
journal = "ECS Transactions",
title = "Electrodeposition and electroless deposition of metallic powders: A comparison",
pages = "31-7",
number = "18",
volume = "33",
doi = "10.1149/1.3551487"
}
Djokić, S.S., Nikolić, N. D., Živković, P. M., Popov, K. I.,& Djokić, N.S.. (2011). Electrodeposition and electroless deposition of metallic powders: A comparison. in ECS Transactions, 33(18), 7-31.
https://doi.org/10.1149/1.3551487
Djokić S, Nikolić ND, Živković PM, Popov KI, Djokić N. Electrodeposition and electroless deposition of metallic powders: A comparison. in ECS Transactions. 2011;33(18):7-31.
doi:10.1149/1.3551487 .
Djokić, S.S., Nikolić, Nebojša D., Živković, Predrag M., Popov, Konstantin I., Djokić, N.S., "Electrodeposition and electroless deposition of metallic powders: A comparison" in ECS Transactions, 33, no. 18 (2011):7-31,
https://doi.org/10.1149/1.3551487 . .
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30

A mathematical model of the current density distribution in electrochemical cells

Popov, Konstantin I.; Živković, Predrag M.; Nikolić, Nebojša D.

(Serbian Chemical Society, 2011)

TY  - JOUR
AU  - Popov, Konstantin I.
AU  - Živković, Predrag M.
AU  - Nikolić, Nebojša D.
PY  - 2011
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5626
AB  - An approach based on the equations of electrochemical kinetics for the estimation of the current density distribution in electrochemical cells is presented. This approach was employed for a theoretical explanation of the phenomena of the edge and corner effects. The effects of the geometry of the system, the kinetic parameters of the cathode reactions and the resistivity of the solution are also discussed. A procedure for a complete analysis of the current distribution in electrochemical cells is presented.
AB  - Prikazan je sažeti pregled ranijih rezultata i predstavljen je poboljšan pristup proceni raspodele struje u elektrohemijskim ćelijama. Ovaj pristup, zasnovan na jednačinama elektrohemijske kinetike, upotrebljen je za teorijsko objašnjenje ivičnih i ugaonih efekata. Takođe su diskutovani uticaji geometrije sistema, kinetičkih parametara katodnih reakcija i otpornosti rastvora. Predstavljena je procedura za kompletnu analizu raspodele struje u elektrohemijskim ćelijama.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - A mathematical model of the current density distribution in electrochemical cells
T1  - Matematički model raspodele gustine struje u elektrohemijskim ćelijama
EP  - 822
IS  - 6
SP  - 805
VL  - 76
DO  - 10.2298/JSC100312079P
ER  - 
@article{
author = "Popov, Konstantin I. and Živković, Predrag M. and Nikolić, Nebojša D.",
year = "2011",
abstract = "An approach based on the equations of electrochemical kinetics for the estimation of the current density distribution in electrochemical cells is presented. This approach was employed for a theoretical explanation of the phenomena of the edge and corner effects. The effects of the geometry of the system, the kinetic parameters of the cathode reactions and the resistivity of the solution are also discussed. A procedure for a complete analysis of the current distribution in electrochemical cells is presented., Prikazan je sažeti pregled ranijih rezultata i predstavljen je poboljšan pristup proceni raspodele struje u elektrohemijskim ćelijama. Ovaj pristup, zasnovan na jednačinama elektrohemijske kinetike, upotrebljen je za teorijsko objašnjenje ivičnih i ugaonih efekata. Takođe su diskutovani uticaji geometrije sistema, kinetičkih parametara katodnih reakcija i otpornosti rastvora. Predstavljena je procedura za kompletnu analizu raspodele struje u elektrohemijskim ćelijama.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "A mathematical model of the current density distribution in electrochemical cells, Matematički model raspodele gustine struje u elektrohemijskim ćelijama",
pages = "822-805",
number = "6",
volume = "76",
doi = "10.2298/JSC100312079P"
}
Popov, K. I., Živković, P. M.,& Nikolić, N. D.. (2011). A mathematical model of the current density distribution in electrochemical cells. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 76(6), 805-822.
https://doi.org/10.2298/JSC100312079P
Popov KI, Živković PM, Nikolić ND. A mathematical model of the current density distribution in electrochemical cells. in Journal of the Serbian Chemical Society. 2011;76(6):805-822.
doi:10.2298/JSC100312079P .
Popov, Konstantin I., Živković, Predrag M., Nikolić, Nebojša D., "A mathematical model of the current density distribution in electrochemical cells" in Journal of the Serbian Chemical Society, 76, no. 6 (2011):805-822,
https://doi.org/10.2298/JSC100312079P . .
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