TY  - JOUR
AU  - Mijatović, Nevenka
AU  - Terzić, Anja
AU  - Miličić, Ljiljana
AU  - Živojinović, Dragana
PY  - 2020
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4557
AB  - Natural zeolite and bentonite were utilized as mineral additives in the mix-design of environmentally safe cement-based building materials. The adsorptive abilities of these two clayey raw materials, i.e. their affinity to immobilize heavy metal ions Zn2+, Ni2+, Pb2+ and Cu2+ were investigated. Singleand multi-solutions of Zn2+, Ni2+, Pb2+ and Cu2+ were prepared for the experiment. The obtained results were submitted to analysis via pseudo-first and pseudo-second order kinetic models. Langmuir and Freundlich isotherms were analyzed. Bentonite exhibited better adsorption affinity than zeolite towards all four investigated cations. As a proof, a leaching test was conducted on seven different cement binders with different mineral additives (fly ash, zeolite, bentonite). The leachates obtained on the samples of cement with addition of fly ash and clay (either zeolite or bentonite) contained lower concentrations of Zn2+, Ni2+, Pb2+ and Cu2+ ions than leachates obtained on the samples of cement binder with fly ash solely as a result of adsorption and hydration mechanisms that immobilized heavy metals within cementitious composites.
AB  - Prirodni zeolit i bentonit korišćeni su kao mineralni dodaci u mešavinskom dizajnu ekološki sigurnih građevinskih materijala na bazi cementa. Ispitane su adsorptivne sposobnosti ove dve glinene sirovine, tj. njihov afinitet da imobiliziraju jone teških metala Zn2+, Ni2+, Pb2+ i Cu2+. Za eksperiment su pripremljeni pojedinačni i multi-rastvori Zn2+, Ni2+, Pb2+ i Cu2+ . Dobijeni rezultati su analizirani pomoću kinetičkih modela pseudo prvog i pseudo drugog reda. Analizirane su izoterme Langmuira i Freundlicha. Bentonit je pokazao bolji adsorpcioni afinitet od zeolita prema sva četiri ispitivana katjona. Kao dokaz, ispitano je ispitivanje ispiranja na sedam različitih veziva za cement sa različitim mineralnim dodacima (leteći pepeo, zeolit, bentonit). Eluati dobijeni na uzorcima cementa sa dodatkom letećeg pepela i gline (bilo zeolita ili bentonita) sadržavale su niže koncentracije jona Zn2+, Ni2+, Pb2+ i Cu2+ u odnosu na eluat dobijen na uzorcima cementnog veziva sa letećim pepelom. Razlog za dobijanje ovakvih rezultata su adsorpcioni i hidratacioni mehanizmi koji imobiliziraju teške metale u cementnim kompozitima.
PB  - Engineering Society for Corrosion, Belgrade, Serbia
T2  - Zaštita materijala
T1  - Immobilization of heavy metal ions Zn2+, Ni2+, Pb2+ and Cu2+ in the structure of cement-based materials
T1  - Imobilizacija teških metalnih jona Zn2+, Ni2+, Pb2+ i Cu2+ u strukturi materijala na bazi cementa
EP  - 127
IS  - 2
SP  - 116
VL  - 61
DO  - 10.5937/zasmat2002116M
ER  - 

@article{
author = "Mijatović, Nevenka and Terzić, Anja and Miličić, Ljiljana and Živojinović, Dragana",
year = "2020",
abstract = "Natural zeolite and bentonite were utilized as mineral additives in the mix-design of environmentally safe cement-based building materials. The adsorptive abilities of these two clayey raw materials, i.e. their affinity to immobilize heavy metal ions Zn2+, Ni2+, Pb2+ and Cu2+ were investigated. Singleand multi-solutions of Zn2+, Ni2+, Pb2+ and Cu2+ were prepared for the experiment. The obtained results were submitted to analysis via pseudo-first and pseudo-second order kinetic models. Langmuir and Freundlich isotherms were analyzed. Bentonite exhibited better adsorption affinity than zeolite towards all four investigated cations. As a proof, a leaching test was conducted on seven different cement binders with different mineral additives (fly ash, zeolite, bentonite). The leachates obtained on the samples of cement with addition of fly ash and clay (either zeolite or bentonite) contained lower concentrations of Zn2+, Ni2+, Pb2+ and Cu2+ ions than leachates obtained on the samples of cement binder with fly ash solely as a result of adsorption and hydration mechanisms that immobilized heavy metals within cementitious composites., Prirodni zeolit i bentonit korišćeni su kao mineralni dodaci u mešavinskom dizajnu ekološki sigurnih građevinskih materijala na bazi cementa. Ispitane su adsorptivne sposobnosti ove dve glinene sirovine, tj. njihov afinitet da imobiliziraju jone teških metala Zn2+, Ni2+, Pb2+ i Cu2+. Za eksperiment su pripremljeni pojedinačni i multi-rastvori Zn2+, Ni2+, Pb2+ i Cu2+ . Dobijeni rezultati su analizirani pomoću kinetičkih modela pseudo prvog i pseudo drugog reda. Analizirane su izoterme Langmuira i Freundlicha. Bentonit je pokazao bolji adsorpcioni afinitet od zeolita prema sva četiri ispitivana katjona. Kao dokaz, ispitano je ispitivanje ispiranja na sedam različitih veziva za cement sa različitim mineralnim dodacima (leteći pepeo, zeolit, bentonit). Eluati dobijeni na uzorcima cementa sa dodatkom letećeg pepela i gline (bilo zeolita ili bentonita) sadržavale su niže koncentracije jona Zn2+, Ni2+, Pb2+ i Cu2+ u odnosu na eluat dobijen na uzorcima cementnog veziva sa letećim pepelom. Razlog za dobijanje ovakvih rezultata su adsorpcioni i hidratacioni mehanizmi koji imobiliziraju teške metale u cementnim kompozitima.",
publisher = "Engineering Society for Corrosion, Belgrade, Serbia",
journal = "Zaštita materijala",
title = "Immobilization of heavy metal ions Zn2+, Ni2+, Pb2+ and Cu2+ in the structure of cement-based materials, Imobilizacija teških metalnih jona Zn2+, Ni2+, Pb2+ i Cu2+ u strukturi materijala na bazi cementa",
pages = "127-116",
number = "2",
volume = "61",
doi = "10.5937/zasmat2002116M"
}

Mijatović, N., Terzić, A., Miličić, L.,& Živojinović, D.. (2020). Immobilization of heavy metal ions Zn2+, Ni2+, Pb2+ and Cu2+ in the structure of cement-based materials. in Zaštita materijala
Engineering Society for Corrosion, Belgrade, Serbia., 61(2), 116-127.
https://doi.org/10.5937/zasmat2002116M

Mijatović N, Terzić A, Miličić L, Živojinović D. Immobilization of heavy metal ions Zn2+, Ni2+, Pb2+ and Cu2+ in the structure of cement-based materials. in Zaštita materijala. 2020;61(2):116-127.
doi:10.5937/zasmat2002116M .

Mijatović, Nevenka, Terzić, Anja, Miličić, Ljiljana, Živojinović, Dragana, "Immobilization of heavy metal ions Zn2+, Ni2+, Pb2+ and Cu2+ in the structure of cement-based materials" in Zaštita materijala, 61, no. 2 (2020):116-127,
https://doi.org/10.5937/zasmat2002116M . .

TY  - CONF
AU  - Mijatović, Nevenka
AU  - Terzić, Anja
AU  - Miličić, Ljiljana
AU  - Živojinović, Dragana
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7313
AB  - The novel global trends for waste materials processing and recycling, as well as new
European standards for sampling and testing of these materials, require better performances of
analytical methods for the chemical analysis and improvements regarding their matrices. In this
study, a new method for optical emission spectrometry with inductively coupled plasma (ICP-OES)
has been developed and subsequently validated for determination of 35 elements comprised in
leachates of fly ash and composites based on fly ash, i.e. cement pastes and mortars. Validation
performances and the uncertainty measurement were determined and calculated via three different
routes: validation method, participation in proficiency testing schemes and standard method. It is
proved that this method is acceptable for the determination of all 35 elements in this matrix. The
obtained results highlight a new simple and effective analyzing route for quantity determination of
undesired trace elements in fluids upon conducted leaching test.
PB  - Bor : University of Belgrade, Technical Faculty
C3  - Proceedings / XIII International Mineral Processing and Recycling Conference, MPRC, Belgrade, Serbia, 8-10 May 2019
T1  - Validation of ICP–OES procedure for major and trace elements determination in the leachates of fly ash and fly ash based composites
EP  - 76
SP  - 70
UR  - https://hdl.handle.net/21.15107/rcub_technorep_7313
ER  - 

@conference{
author = "Mijatović, Nevenka and Terzić, Anja and Miličić, Ljiljana and Živojinović, Dragana",
year = "2019",
abstract = "The novel global trends for waste materials processing and recycling, as well as new
European standards for sampling and testing of these materials, require better performances of
analytical methods for the chemical analysis and improvements regarding their matrices. In this
study, a new method for optical emission spectrometry with inductively coupled plasma (ICP-OES)
has been developed and subsequently validated for determination of 35 elements comprised in
leachates of fly ash and composites based on fly ash, i.e. cement pastes and mortars. Validation
performances and the uncertainty measurement were determined and calculated via three different
routes: validation method, participation in proficiency testing schemes and standard method. It is
proved that this method is acceptable for the determination of all 35 elements in this matrix. The
obtained results highlight a new simple and effective analyzing route for quantity determination of
undesired trace elements in fluids upon conducted leaching test.",
publisher = "Bor : University of Belgrade, Technical Faculty",
journal = "Proceedings / XIII International Mineral Processing and Recycling Conference, MPRC, Belgrade, Serbia, 8-10 May 2019",
title = "Validation of ICP–OES procedure for major and trace elements determination in the leachates of fly ash and fly ash based composites",
pages = "76-70",
url = "https://hdl.handle.net/21.15107/rcub_technorep_7313"
}

Mijatović, N., Terzić, A., Miličić, L.,& Živojinović, D.. (2019). Validation of ICP–OES procedure for major and trace elements determination in the leachates of fly ash and fly ash based composites. in Proceedings / XIII International Mineral Processing and Recycling Conference, MPRC, Belgrade, Serbia, 8-10 May 2019
Bor : University of Belgrade, Technical Faculty., 70-76.
https://hdl.handle.net/21.15107/rcub_technorep_7313

Mijatović N, Terzić A, Miličić L, Živojinović D. Validation of ICP–OES procedure for major and trace elements determination in the leachates of fly ash and fly ash based composites. in Proceedings / XIII International Mineral Processing and Recycling Conference, MPRC, Belgrade, Serbia, 8-10 May 2019. 2019;:70-76.
https://hdl.handle.net/21.15107/rcub_technorep_7313 .

Mijatović, Nevenka, Terzić, Anja, Miličić, Ljiljana, Živojinović, Dragana, "Validation of ICP–OES procedure for major and trace elements determination in the leachates of fly ash and fly ash based composites" in Proceedings / XIII International Mineral Processing and Recycling Conference, MPRC, Belgrade, Serbia, 8-10 May 2019 (2019):70-76,
https://hdl.handle.net/21.15107/rcub_technorep_7313 .

TY  - JOUR
AU  - Mijatović, Nevenka
AU  - Terzić, Anja
AU  - Pezo, Lato
AU  - Milicić, Ljiljana
AU  - Živojinović, Dragana
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4097
AB  - Adjustment and subsequent validation of energy-dispersive X-ray fluorescence (ED-XRF) method for cement based binders with addition of mineral raw materials (fly ash, zeolite and bentonite) was conducted. Eighteen chemical elements present in the material composition were analyzed: ten major elements (Si, Al, Fe, Ca, Mg, S, Na, K, Ti, P) and eight trace elements (Cr, Zn, Cu, As, Ni, Pb, Sr, Mn). Thirty-five samples of either certified reference materials or reference materials of cement, fly ash and clay were utilized during adjustment and optimization of the investigated ED-XRF procedure. The method was consecutively validated in terms of selectivity, precision, working range, linearity, accuracy, robustness, limits of detection and quantification. Thirty-two samples in total, i.e. three certified reference materials and twenty-nine reference materials, were simultaneously analyzed by ED-XRF and inductively coupled plasma optical emission spectrometry (ICP-OES). Comparison of the outputs of monitored methods showed infinitesimally small differences, as correlation coefficients were extremely good (approximate to 1), which highlighted ED-XRF as highly satiable alternative for ICP-OES for the chemical analysis of cement binders.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Spectrochimica Acta Part B-Atomic Spectroscopy
T1  - Validation of energy-dispersive X-ray fluorescence procedure for determination of major and trace elements present in the cement based composites
SP  - 105729
VL  - 162
DO  - 10.1016/j.sab.2019.105729
ER  - 

@article{
author = "Mijatović, Nevenka and Terzić, Anja and Pezo, Lato and Milicić, Ljiljana and Živojinović, Dragana",
year = "2019",
abstract = "Adjustment and subsequent validation of energy-dispersive X-ray fluorescence (ED-XRF) method for cement based binders with addition of mineral raw materials (fly ash, zeolite and bentonite) was conducted. Eighteen chemical elements present in the material composition were analyzed: ten major elements (Si, Al, Fe, Ca, Mg, S, Na, K, Ti, P) and eight trace elements (Cr, Zn, Cu, As, Ni, Pb, Sr, Mn). Thirty-five samples of either certified reference materials or reference materials of cement, fly ash and clay were utilized during adjustment and optimization of the investigated ED-XRF procedure. The method was consecutively validated in terms of selectivity, precision, working range, linearity, accuracy, robustness, limits of detection and quantification. Thirty-two samples in total, i.e. three certified reference materials and twenty-nine reference materials, were simultaneously analyzed by ED-XRF and inductively coupled plasma optical emission spectrometry (ICP-OES). Comparison of the outputs of monitored methods showed infinitesimally small differences, as correlation coefficients were extremely good (approximate to 1), which highlighted ED-XRF as highly satiable alternative for ICP-OES for the chemical analysis of cement binders.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Spectrochimica Acta Part B-Atomic Spectroscopy",
title = "Validation of energy-dispersive X-ray fluorescence procedure for determination of major and trace elements present in the cement based composites",
pages = "105729",
volume = "162",
doi = "10.1016/j.sab.2019.105729"
}

Mijatović, N., Terzić, A., Pezo, L., Milicić, L.,& Živojinović, D.. (2019). Validation of energy-dispersive X-ray fluorescence procedure for determination of major and trace elements present in the cement based composites. in Spectrochimica Acta Part B-Atomic Spectroscopy
Pergamon-Elsevier Science Ltd, Oxford., 162, 105729.
https://doi.org/10.1016/j.sab.2019.105729

Mijatović N, Terzić A, Pezo L, Milicić L, Živojinović D. Validation of energy-dispersive X-ray fluorescence procedure for determination of major and trace elements present in the cement based composites. in Spectrochimica Acta Part B-Atomic Spectroscopy. 2019;162:105729.
doi:10.1016/j.sab.2019.105729 .

Mijatović, Nevenka, Terzić, Anja, Pezo, Lato, Milicić, Ljiljana, Živojinović, Dragana, "Validation of energy-dispersive X-ray fluorescence procedure for determination of major and trace elements present in the cement based composites" in Spectrochimica Acta Part B-Atomic Spectroscopy, 162 (2019):105729,
https://doi.org/10.1016/j.sab.2019.105729 . .

TY  - JOUR
AU  - Mijatović, Nevenka
AU  - Terzić, Anja
AU  - Pezo, Lato
AU  - Milicić, Ljiljana
AU  - Milosavljević, Aleksandra
AU  - Živojinović, Dragana
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4137
AB  - New global tendencies for waste materials reusing in building materials are imposing the request for improved performances of chemical analysis methods and the improvements of matrices used. A new method for optical emission spectrometry with inductively coupled plasma (ICP-OES) is developed and validated for the chemical analysis (35 elements: Al, Be, Cd, So, Cr, Cu, Fe, Mn, Mo, Ni, V, Mo, Zn, Pb , Bi, Si, Zr, W, As, Se, Sb, Sn, Ti, Ba, B, Ag, Mg, Ca, K, Na, S, P, Ga, In, Li) in leachate of fly ash. Validation performances and the uncertainty of measurement were resolved. Uncertainty of measurements were resolved by three routes: validation procedure, participation in proficiency testing (PT) schemes and standard method. The obtained method is a new simple and effective analyzing route for determination of undesired trace elements and their quantity comprised in leachates of fly ash, and leachates of building materials with addition of fly ash (cement binders and mortars). In order to prove its accuracy and precision, the developed method was employed on laboratory samples of cement binders and mortars. Results were compared with limit values provided in the standard. Multivariate analyses, i.e. cluster analysis and principal component analysis, were applied to establish interrelations between analyzed samples, and to certify the developed ICP-OES method.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Novel Approach for Determination of Potentially Toxic Elements via ICP-OES in Aqueous Solutions of Building Materials with Industrial Byproduct Addition
EP  - 444
IS  - 4
SP  - 429
VL  - 51
DO  - 10.2298/SOS1904429M
ER  - 

@article{
author = "Mijatović, Nevenka and Terzić, Anja and Pezo, Lato and Milicić, Ljiljana and Milosavljević, Aleksandra and Živojinović, Dragana",
year = "2019",
abstract = "New global tendencies for waste materials reusing in building materials are imposing the request for improved performances of chemical analysis methods and the improvements of matrices used. A new method for optical emission spectrometry with inductively coupled plasma (ICP-OES) is developed and validated for the chemical analysis (35 elements: Al, Be, Cd, So, Cr, Cu, Fe, Mn, Mo, Ni, V, Mo, Zn, Pb , Bi, Si, Zr, W, As, Se, Sb, Sn, Ti, Ba, B, Ag, Mg, Ca, K, Na, S, P, Ga, In, Li) in leachate of fly ash. Validation performances and the uncertainty of measurement were resolved. Uncertainty of measurements were resolved by three routes: validation procedure, participation in proficiency testing (PT) schemes and standard method. The obtained method is a new simple and effective analyzing route for determination of undesired trace elements and their quantity comprised in leachates of fly ash, and leachates of building materials with addition of fly ash (cement binders and mortars). In order to prove its accuracy and precision, the developed method was employed on laboratory samples of cement binders and mortars. Results were compared with limit values provided in the standard. Multivariate analyses, i.e. cluster analysis and principal component analysis, were applied to establish interrelations between analyzed samples, and to certify the developed ICP-OES method.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Novel Approach for Determination of Potentially Toxic Elements via ICP-OES in Aqueous Solutions of Building Materials with Industrial Byproduct Addition",
pages = "444-429",
number = "4",
volume = "51",
doi = "10.2298/SOS1904429M"
}

Mijatović, N., Terzić, A., Pezo, L., Milicić, L., Milosavljević, A.,& Živojinović, D.. (2019). Novel Approach for Determination of Potentially Toxic Elements via ICP-OES in Aqueous Solutions of Building Materials with Industrial Byproduct Addition. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 51(4), 429-444.
https://doi.org/10.2298/SOS1904429M

Mijatović N, Terzić A, Pezo L, Milicić L, Milosavljević A, Živojinović D. Novel Approach for Determination of Potentially Toxic Elements via ICP-OES in Aqueous Solutions of Building Materials with Industrial Byproduct Addition. in Science of Sintering. 2019;51(4):429-444.
doi:10.2298/SOS1904429M .

Mijatović, Nevenka, Terzić, Anja, Pezo, Lato, Milicić, Ljiljana, Milosavljević, Aleksandra, Živojinović, Dragana, "Novel Approach for Determination of Potentially Toxic Elements via ICP-OES in Aqueous Solutions of Building Materials with Industrial Byproduct Addition" in Science of Sintering, 51, no. 4 (2019):429-444,
https://doi.org/10.2298/SOS1904429M . .

TY  - JOUR
AU  - Mijatović, Nevenka
AU  - Terzić, Anja
AU  - Pezo, Lato
AU  - Milicić, Ljiljana
AU  - Živojinović, Dragana
PY  - 2019
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5039
AB  - Adjustment and subsequent validation of energy-dispersive X-ray fluorescence (ED-XRF) method for cement based binders with addition of mineral raw materials (fly ash, zeolite and bentonite) was conducted. Eighteen chemical elements present in the material composition were analyzed: ten major elements (Si, Al, Fe, Ca, Mg, S, Na, K, Ti, P) and eight trace elements (Cr, Zn, Cu, As, Ni, Pb, Sr, Mn). Thirty-five samples of either certified reference materials or reference materials of cement, fly ash and clay were utilized during adjustment and optimization of the investigated ED-XRF procedure. The method was consecutively validated in terms of selectivity, precision, working range, linearity, accuracy, robustness, limits of detection and quantification. Thirty-two samples in total, i.e. three certified reference materials and twenty-nine reference materials, were simultaneously analyzed by ED-XRF and inductively coupled plasma optical emission spectrometry (ICP-OES). Comparison of the outputs of monitored methods showed infinitesimally small differences, as correlation coefficients were extremely good (≈1), which highlighted ED-XRF as highly satiable alternative for ICP-OES for the chemical analysis of cement binders.
PB  - Elsevier B.V.
T2  - Spectrochimica Acta - Part B Atomic Spectroscopy
T1  - Validation of energy-dispersive X-ray fluorescence procedure for determination of major and trace elements present in the cement based composites
SP  - 105729
VL  - 162
DO  - 10.1016/j.sab.2019.105729
ER  - 

@article{
author = "Mijatović, Nevenka and Terzić, Anja and Pezo, Lato and Milicić, Ljiljana and Živojinović, Dragana",
year = "2019",
abstract = "Adjustment and subsequent validation of energy-dispersive X-ray fluorescence (ED-XRF) method for cement based binders with addition of mineral raw materials (fly ash, zeolite and bentonite) was conducted. Eighteen chemical elements present in the material composition were analyzed: ten major elements (Si, Al, Fe, Ca, Mg, S, Na, K, Ti, P) and eight trace elements (Cr, Zn, Cu, As, Ni, Pb, Sr, Mn). Thirty-five samples of either certified reference materials or reference materials of cement, fly ash and clay were utilized during adjustment and optimization of the investigated ED-XRF procedure. The method was consecutively validated in terms of selectivity, precision, working range, linearity, accuracy, robustness, limits of detection and quantification. Thirty-two samples in total, i.e. three certified reference materials and twenty-nine reference materials, were simultaneously analyzed by ED-XRF and inductively coupled plasma optical emission spectrometry (ICP-OES). Comparison of the outputs of monitored methods showed infinitesimally small differences, as correlation coefficients were extremely good (≈1), which highlighted ED-XRF as highly satiable alternative for ICP-OES for the chemical analysis of cement binders.",
publisher = "Elsevier B.V.",
journal = "Spectrochimica Acta - Part B Atomic Spectroscopy",
title = "Validation of energy-dispersive X-ray fluorescence procedure for determination of major and trace elements present in the cement based composites",
pages = "105729",
volume = "162",
doi = "10.1016/j.sab.2019.105729"
}

Mijatović, N., Terzić, A., Pezo, L., Milicić, L.,& Živojinović, D.. (2019). Validation of energy-dispersive X-ray fluorescence procedure for determination of major and trace elements present in the cement based composites. in Spectrochimica Acta - Part B Atomic Spectroscopy
Elsevier B.V.., 162, 105729.
https://doi.org/10.1016/j.sab.2019.105729

Mijatović N, Terzić A, Pezo L, Milicić L, Živojinović D. Validation of energy-dispersive X-ray fluorescence procedure for determination of major and trace elements present in the cement based composites. in Spectrochimica Acta - Part B Atomic Spectroscopy. 2019;162:105729.
doi:10.1016/j.sab.2019.105729 .

Mijatović, Nevenka, Terzić, Anja, Pezo, Lato, Milicić, Ljiljana, Živojinović, Dragana, "Validation of energy-dispersive X-ray fluorescence procedure for determination of major and trace elements present in the cement based composites" in Spectrochimica Acta - Part B Atomic Spectroscopy, 162 (2019):105729,
https://doi.org/10.1016/j.sab.2019.105729 . .

TY  - JOUR
AU  - Vasić, Milica V.
AU  - Pezo, Lato L.
AU  - Zdravković, Jelena D.
AU  - Vrebalov, Marija
AU  - Radojević, Zagorka
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5091
AB  - This research describes a study of 11 selected samples of brick clays applied in roofing tile production, by using simultaneous thermal analysis. Additionally, the laboratory-sized samples were prepared and fired (850-950 °C) and technological properties were determined. Mathematical analysis was applied to sum all the experimental results and help discriminate the samples by their behavior during firing. The samples, very similar according to mineralogical and chemical content, as well as granulometry tests, were successfully grouped using principal component analysis (PCA). The PCA was used to explore and easily visualize the differences between samples. The PCA performed for differential thermal analysis (DTA), differential scanning calorimetry (DSC) and differential thermogravimetry (DTG) curves clearly showed that the heat flow was mainly influenced by carbonate content and its grain size, while DTG discriminated samples according to the contents of clay minerals and carbonates. In addition, dilatometry analysis revealed which samples underwent the highest densification during the firing process. The PCA analysis of fired products properties showed that the highest correlations were between water absorption with firing shrinkage and compressive strength.
PB  - International Institute for the Science of Sintering
T2  - Science of Sintering
T1  - Thermal, Ceramic and Technological Properties of Clays used in Production of Roofing Tiles – Principal Component Analysis
EP  - 500
IS  - 4
SP  - 487
VL  - 50
DO  - 10.2298/SOS1804487V
ER  - 

@article{
author = "Vasić, Milica V. and Pezo, Lato L. and Zdravković, Jelena D. and Vrebalov, Marija and Radojević, Zagorka",
year = "2018",
abstract = "This research describes a study of 11 selected samples of brick clays applied in roofing tile production, by using simultaneous thermal analysis. Additionally, the laboratory-sized samples were prepared and fired (850-950 °C) and technological properties were determined. Mathematical analysis was applied to sum all the experimental results and help discriminate the samples by their behavior during firing. The samples, very similar according to mineralogical and chemical content, as well as granulometry tests, were successfully grouped using principal component analysis (PCA). The PCA was used to explore and easily visualize the differences between samples. The PCA performed for differential thermal analysis (DTA), differential scanning calorimetry (DSC) and differential thermogravimetry (DTG) curves clearly showed that the heat flow was mainly influenced by carbonate content and its grain size, while DTG discriminated samples according to the contents of clay minerals and carbonates. In addition, dilatometry analysis revealed which samples underwent the highest densification during the firing process. The PCA analysis of fired products properties showed that the highest correlations were between water absorption with firing shrinkage and compressive strength.",
publisher = "International Institute for the Science of Sintering",
journal = "Science of Sintering",
title = "Thermal, Ceramic and Technological Properties of Clays used in Production of Roofing Tiles – Principal Component Analysis",
pages = "500-487",
number = "4",
volume = "50",
doi = "10.2298/SOS1804487V"
}

Vasić, M. V., Pezo, L. L., Zdravković, J. D., Vrebalov, M.,& Radojević, Z.. (2018). Thermal, Ceramic and Technological Properties of Clays used in Production of Roofing Tiles – Principal Component Analysis. in Science of Sintering
International Institute for the Science of Sintering., 50(4), 487-500.
https://doi.org/10.2298/SOS1804487V

Vasić MV, Pezo LL, Zdravković JD, Vrebalov M, Radojević Z. Thermal, Ceramic and Technological Properties of Clays used in Production of Roofing Tiles – Principal Component Analysis. in Science of Sintering. 2018;50(4):487-500.
doi:10.2298/SOS1804487V .

Vasić, Milica V., Pezo, Lato L., Zdravković, Jelena D., Vrebalov, Marija, Radojević, Zagorka, "Thermal, Ceramic and Technological Properties of Clays used in Production of Roofing Tiles – Principal Component Analysis" in Science of Sintering, 50, no. 4 (2018):487-500,
https://doi.org/10.2298/SOS1804487V . .

TY  - JOUR
AU  - Vasić, Milica
AU  - Pezo, Lato
AU  - Zdravković, Jelena
AU  - Backalić, Z.
AU  - Radojević, Zagorka
PY  - 2017
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5857
AB  - The aim of this study was to test montmorillonite and hydromica type of brick clays by using simultaneous thermal analysis and dilatometry in an assessment of the suitability of brick clays to produce building elements. The plasticity coefficient and drying susceptibility were determined to discover the behavior of brick clays. Fired products' characteristics were studied by performing water absorption and compressive strength tests. All the methods were employed in the construction of the firing curves in a tunnel kiln. The results could increase the degree of certainty to lead the production process towards obtaining the desired features of brick elements.
PB  - Elsevier Sci Ltd, Oxford
T2  - Construction and Building Materials
T1  - The study of thermal behavior of montmorillonite and hydromica brick clays in predicting tunnel kiln firing curve
EP  - 879
SP  - 872
VL  - 150
DO  - 10.1016/j.conbuildmat.2017.06.068
ER  - 

@article{
author = "Vasić, Milica and Pezo, Lato and Zdravković, Jelena and Backalić, Z. and Radojević, Zagorka",
year = "2017",
abstract = "The aim of this study was to test montmorillonite and hydromica type of brick clays by using simultaneous thermal analysis and dilatometry in an assessment of the suitability of brick clays to produce building elements. The plasticity coefficient and drying susceptibility were determined to discover the behavior of brick clays. Fired products' characteristics were studied by performing water absorption and compressive strength tests. All the methods were employed in the construction of the firing curves in a tunnel kiln. The results could increase the degree of certainty to lead the production process towards obtaining the desired features of brick elements.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Construction and Building Materials",
title = "The study of thermal behavior of montmorillonite and hydromica brick clays in predicting tunnel kiln firing curve",
pages = "879-872",
volume = "150",
doi = "10.1016/j.conbuildmat.2017.06.068"
}

Vasić, M., Pezo, L., Zdravković, J., Backalić, Z.,& Radojević, Z.. (2017). The study of thermal behavior of montmorillonite and hydromica brick clays in predicting tunnel kiln firing curve. in Construction and Building Materials
Elsevier Sci Ltd, Oxford., 150, 872-879.
https://doi.org/10.1016/j.conbuildmat.2017.06.068

Vasić M, Pezo L, Zdravković J, Backalić Z, Radojević Z. The study of thermal behavior of montmorillonite and hydromica brick clays in predicting tunnel kiln firing curve. in Construction and Building Materials. 2017;150:872-879.
doi:10.1016/j.conbuildmat.2017.06.068 .

Vasić, Milica, Pezo, Lato, Zdravković, Jelena, Backalić, Z., Radojević, Zagorka, "The study of thermal behavior of montmorillonite and hydromica brick clays in predicting tunnel kiln firing curve" in Construction and Building Materials, 150 (2017):872-879,
https://doi.org/10.1016/j.conbuildmat.2017.06.068 . .

TY  - JOUR
AU  - Arsenović, Milica
AU  - Pezo, Lato
AU  - Stanković, Slavka
AU  - Radojević, Zagorka
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5756
AB  - Chemical composition and XRD qualitative analysis were used to calculate mineral contents of 139 brick clay raw materials using LPNORM. The second order polynomial models (SOP) for all the samples, which express the relation between mineral contents and the characteristics of fired laboratory products, did not fit to experimental data satisfactorily, due to low coefficients of determination (r(2)). In order to improve the models, the samples are divided into four groups in factor space (four quadrants), according to their mineral content similarity, using principal component analysis (PCA). Predictive models of compressive strength (CS), water absorption (WA), firing shrinkage (FS), weight loss during firing (WLF) and volume mass of cubes (VMC) are obtained for each of the groups. Second order polynomial (SOP) models are developed, and the influence of certain minerals to brick clay bricks quality within the groups is discussed. Developed models were able to predict the final quality of products in a wide range of mineral content and temperature treatment data, showing coefficient of determination (r(2)) in range between 0.704-0.995. In order to estimate the adequacy of these models, the results were applied to the experimental data and compared according to additional statistical tests, so the next values are determined: coefficients of determination, reduced chi-square (chi(2)), mean bias error (MBE), mean percent error (MPE) and root mean square error (RMSE).
PB  - Elsevier Science Bv, Amsterdam
T2  - Applied Clay Science
T1  - Factor space differentiation of brick clays according to mineral content: Prediction of final brick product quality
EP  - 114
SP  - 108
VL  - 115
DO  - 10.1016/j.clay.2015.07.030
ER  - 

@article{
author = "Arsenović, Milica and Pezo, Lato and Stanković, Slavka and Radojević, Zagorka",
year = "2015",
abstract = "Chemical composition and XRD qualitative analysis were used to calculate mineral contents of 139 brick clay raw materials using LPNORM. The second order polynomial models (SOP) for all the samples, which express the relation between mineral contents and the characteristics of fired laboratory products, did not fit to experimental data satisfactorily, due to low coefficients of determination (r(2)). In order to improve the models, the samples are divided into four groups in factor space (four quadrants), according to their mineral content similarity, using principal component analysis (PCA). Predictive models of compressive strength (CS), water absorption (WA), firing shrinkage (FS), weight loss during firing (WLF) and volume mass of cubes (VMC) are obtained for each of the groups. Second order polynomial (SOP) models are developed, and the influence of certain minerals to brick clay bricks quality within the groups is discussed. Developed models were able to predict the final quality of products in a wide range of mineral content and temperature treatment data, showing coefficient of determination (r(2)) in range between 0.704-0.995. In order to estimate the adequacy of these models, the results were applied to the experimental data and compared according to additional statistical tests, so the next values are determined: coefficients of determination, reduced chi-square (chi(2)), mean bias error (MBE), mean percent error (MPE) and root mean square error (RMSE).",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Applied Clay Science",
title = "Factor space differentiation of brick clays according to mineral content: Prediction of final brick product quality",
pages = "114-108",
volume = "115",
doi = "10.1016/j.clay.2015.07.030"
}

Arsenović, M., Pezo, L., Stanković, S.,& Radojević, Z.. (2015). Factor space differentiation of brick clays according to mineral content: Prediction of final brick product quality. in Applied Clay Science
Elsevier Science Bv, Amsterdam., 115, 108-114.
https://doi.org/10.1016/j.clay.2015.07.030

Arsenović M, Pezo L, Stanković S, Radojević Z. Factor space differentiation of brick clays according to mineral content: Prediction of final brick product quality. in Applied Clay Science. 2015;115:108-114.
doi:10.1016/j.clay.2015.07.030 .

Arsenović, Milica, Pezo, Lato, Stanković, Slavka, Radojević, Zagorka, "Factor space differentiation of brick clays according to mineral content: Prediction of final brick product quality" in Applied Clay Science, 115 (2015):108-114,
https://doi.org/10.1016/j.clay.2015.07.030 . .

TY  - JOUR
AU  - Aćimović-Pavlović, Zagorka
AU  - Terzić, Anja
AU  - Andrić, Ljubiša
AU  - Pavlović, Marko
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5755
AB  - This study presents the results of an investigation of high-temperature materials refractory coatings based on different refractory fillers including talc, cordierite, zircon and mullite applied in the lost-foam casting process. Design and optimization of a coating composition with controlled rheological properties and synthesis were achieved by applying different coating components, suspension agents and fillers and by altering the coating-production procedure. A morphological and microstructural analysis of the fillers was carried out with scanning electron microscopy. An X-ray diffraction analysis was applied to determine and monitor the phase-composition changes of the refractory fillers. The particle size and shape were assessed with the PC software application package OZARIA 2.5. To assess the effects of the applications of individual refractory coatings, a detailed investigation of the structural and mechanical properties of the mouldings obtained was performed. Highlight was placed on revealing and analyzing surface and volume defects present on the mouldings. Radiographic moulding tests were carried out with an X-ray device, SAIFORT type-S200. The attained results are essential for the synthesis of the refractory coatings based on high-temperature fillers and their applications in the lost-foam casting process for manufacturing the mouldings with in-advance-set properties.
PB  - Inst Za Kovinske Materiale I In Tehnologie, Ljubjana
T2  - Materiali in tehnologije
T1  - Comparison of refractory coatings based on talc, cordierite, zircon and mullite fillers for lost-foam casting
EP  - 164
IS  - 1
SP  - 157
VL  - 49
UR  - https://hdl.handle.net/21.15107/rcub_rims_277
ER  - 

@article{
author = "Aćimović-Pavlović, Zagorka and Terzić, Anja and Andrić, Ljubiša and Pavlović, Marko",
year = "2015",
abstract = "This study presents the results of an investigation of high-temperature materials refractory coatings based on different refractory fillers including talc, cordierite, zircon and mullite applied in the lost-foam casting process. Design and optimization of a coating composition with controlled rheological properties and synthesis were achieved by applying different coating components, suspension agents and fillers and by altering the coating-production procedure. A morphological and microstructural analysis of the fillers was carried out with scanning electron microscopy. An X-ray diffraction analysis was applied to determine and monitor the phase-composition changes of the refractory fillers. The particle size and shape were assessed with the PC software application package OZARIA 2.5. To assess the effects of the applications of individual refractory coatings, a detailed investigation of the structural and mechanical properties of the mouldings obtained was performed. Highlight was placed on revealing and analyzing surface and volume defects present on the mouldings. Radiographic moulding tests were carried out with an X-ray device, SAIFORT type-S200. The attained results are essential for the synthesis of the refractory coatings based on high-temperature fillers and their applications in the lost-foam casting process for manufacturing the mouldings with in-advance-set properties.",
publisher = "Inst Za Kovinske Materiale I In Tehnologie, Ljubjana",
journal = "Materiali in tehnologije",
title = "Comparison of refractory coatings based on talc, cordierite, zircon and mullite fillers for lost-foam casting",
pages = "164-157",
number = "1",
volume = "49",
url = "https://hdl.handle.net/21.15107/rcub_rims_277"
}

Aćimović-Pavlović, Z., Terzić, A., Andrić, L.,& Pavlović, M.. (2015). Comparison of refractory coatings based on talc, cordierite, zircon and mullite fillers for lost-foam casting. in Materiali in tehnologije
Inst Za Kovinske Materiale I In Tehnologie, Ljubjana., 49(1), 157-164.
https://hdl.handle.net/21.15107/rcub_rims_277

Aćimović-Pavlović Z, Terzić A, Andrić L, Pavlović M. Comparison of refractory coatings based on talc, cordierite, zircon and mullite fillers for lost-foam casting. in Materiali in tehnologije. 2015;49(1):157-164.
https://hdl.handle.net/21.15107/rcub_rims_277 .

Aćimović-Pavlović, Zagorka, Terzić, Anja, Andrić, Ljubiša, Pavlović, Marko, "Comparison of refractory coatings based on talc, cordierite, zircon and mullite fillers for lost-foam casting" in Materiali in tehnologije, 49, no. 1 (2015):157-164,
https://hdl.handle.net/21.15107/rcub_rims_277 .

TY  - JOUR
AU  - Arsenović, Milica
AU  - Stanković, Slavka
AU  - Radojević, Zagorka
AU  - Pezo, Lato
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5800
AB  - Factors influencing final clay brick properties are numerous, since the raw materials are highly heterogeneous. The chemometric approach is rarely used in analysis in this field, although it could significantly improve understanding of the overall system behavior and the quality of products. Principal component analysis (PCA) was used on a group of 139 samples collected in Serbia to discriminate groups of samples according to similarity of chemical composition and fired laboratory products properties. The focus of this study was to determine the importance of parameters that describe clay brick production and quality, depending on final usage of raw material in the clay brick industry. A fuzzy synthetic evaluation, using a membership trapezoidal function with defined optimal interval values for different types of heavy clay products, is chosen for the study. The optimal sample's chemical composition and firing temperature were chosen by the fuzzy synthetic evaluation, regarding the kind of the heavy clay product.
PB  - Expert Fachmedien GmbH
T2  - InterCeram: International Ceramic Review
T1  - The effects of chemical composition and firing temperature in heavy clay brick production - Chemometric approach
EP  - 29
IS  - 1-2
SP  - 26
VL  - 63
DO  - 10.1007/bf03401031
ER  - 

@article{
author = "Arsenović, Milica and Stanković, Slavka and Radojević, Zagorka and Pezo, Lato",
year = "2014",
abstract = "Factors influencing final clay brick properties are numerous, since the raw materials are highly heterogeneous. The chemometric approach is rarely used in analysis in this field, although it could significantly improve understanding of the overall system behavior and the quality of products. Principal component analysis (PCA) was used on a group of 139 samples collected in Serbia to discriminate groups of samples according to similarity of chemical composition and fired laboratory products properties. The focus of this study was to determine the importance of parameters that describe clay brick production and quality, depending on final usage of raw material in the clay brick industry. A fuzzy synthetic evaluation, using a membership trapezoidal function with defined optimal interval values for different types of heavy clay products, is chosen for the study. The optimal sample's chemical composition and firing temperature were chosen by the fuzzy synthetic evaluation, regarding the kind of the heavy clay product.",
publisher = "Expert Fachmedien GmbH",
journal = "InterCeram: International Ceramic Review",
title = "The effects of chemical composition and firing temperature in heavy clay brick production - Chemometric approach",
pages = "29-26",
number = "1-2",
volume = "63",
doi = "10.1007/bf03401031"
}

Arsenović, M., Stanković, S., Radojević, Z.,& Pezo, L.. (2014). The effects of chemical composition and firing temperature in heavy clay brick production - Chemometric approach. in InterCeram: International Ceramic Review
Expert Fachmedien GmbH., 63(1-2), 26-29.
https://doi.org/10.1007/bf03401031

Arsenović M, Stanković S, Radojević Z, Pezo L. The effects of chemical composition and firing temperature in heavy clay brick production - Chemometric approach. in InterCeram: International Ceramic Review. 2014;63(1-2):26-29.
doi:10.1007/bf03401031 .

Arsenović, Milica, Stanković, Slavka, Radojević, Zagorka, Pezo, Lato, "The effects of chemical composition and firing temperature in heavy clay brick production - Chemometric approach" in InterCeram: International Ceramic Review, 63, no. 1-2 (2014):26-29,
https://doi.org/10.1007/bf03401031 . .

TY  - JOUR
AU  - Prstić, Aurel
AU  - Aćimović-Pavlović, Zagorka
AU  - Terzić, Anja
AU  - Pavlović, Ljubica
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5790
AB  - Refractory coatings based on different refractory fillers (talc, cordierite, zircon and mullite) for application in Lost Foam casting process were investigated. Design and optimization of the coatings composition with controlled, rheological properties included, and consequently synthesis were achieved by application of different coating components, namely different suspension agents and fillers and by alteration of the coating production procedure. Morphologic and microstructural analysis of fillers was carried out by means of scanning electronic microscope. X-ray diffraction analysis by means of X-ray diffractometer was applied in determination and monitoring the phase composition changes of the refractory fillers. An analysis of the particle size and shape was carried out by means of the PC software application package OZARIA 2.5. To assess the effects of application of individual refractory coatings, a detailed investigation of structural and mechanical properties of the moldings obtained was performed. Highlight was placed on revealing and analyzing surface and volume defects present on moldings. Radiographic molding tests were carried out by means of the X-ray device SAIFORT type-S200. Attained results are essential for the synthesis of refractory coatings based on high-temperature fillers and their applications in Lost Foam casting process for manufacturing of moldings with in-advance-set properties.
PB  - Polska Akad Nauk, Polish Acad Sciences, Inst Metall & Mater Sci Pas, Warszawa
T2  - Archives of Metallurgy and Materials
T1  - Synthesis and characterization of new refractory coatings based on talc, cordierite, zircon and mullite fillers for lost foam casting process
EP  - 95
IS  - 1
SP  - 89
VL  - 59
DO  - 10.2478/amm-2014-0015
ER  - 

@article{
author = "Prstić, Aurel and Aćimović-Pavlović, Zagorka and Terzić, Anja and Pavlović, Ljubica",
year = "2014",
abstract = "Refractory coatings based on different refractory fillers (talc, cordierite, zircon and mullite) for application in Lost Foam casting process were investigated. Design and optimization of the coatings composition with controlled, rheological properties included, and consequently synthesis were achieved by application of different coating components, namely different suspension agents and fillers and by alteration of the coating production procedure. Morphologic and microstructural analysis of fillers was carried out by means of scanning electronic microscope. X-ray diffraction analysis by means of X-ray diffractometer was applied in determination and monitoring the phase composition changes of the refractory fillers. An analysis of the particle size and shape was carried out by means of the PC software application package OZARIA 2.5. To assess the effects of application of individual refractory coatings, a detailed investigation of structural and mechanical properties of the moldings obtained was performed. Highlight was placed on revealing and analyzing surface and volume defects present on moldings. Radiographic molding tests were carried out by means of the X-ray device SAIFORT type-S200. Attained results are essential for the synthesis of refractory coatings based on high-temperature fillers and their applications in Lost Foam casting process for manufacturing of moldings with in-advance-set properties.",
publisher = "Polska Akad Nauk, Polish Acad Sciences, Inst Metall & Mater Sci Pas, Warszawa",
journal = "Archives of Metallurgy and Materials",
title = "Synthesis and characterization of new refractory coatings based on talc, cordierite, zircon and mullite fillers for lost foam casting process",
pages = "95-89",
number = "1",
volume = "59",
doi = "10.2478/amm-2014-0015"
}

Prstić, A., Aćimović-Pavlović, Z., Terzić, A.,& Pavlović, L.. (2014). Synthesis and characterization of new refractory coatings based on talc, cordierite, zircon and mullite fillers for lost foam casting process. in Archives of Metallurgy and Materials
Polska Akad Nauk, Polish Acad Sciences, Inst Metall & Mater Sci Pas, Warszawa., 59(1), 89-95.
https://doi.org/10.2478/amm-2014-0015

Prstić A, Aćimović-Pavlović Z, Terzić A, Pavlović L. Synthesis and characterization of new refractory coatings based on talc, cordierite, zircon and mullite fillers for lost foam casting process. in Archives of Metallurgy and Materials. 2014;59(1):89-95.
doi:10.2478/amm-2014-0015 .

Prstić, Aurel, Aćimović-Pavlović, Zagorka, Terzić, Anja, Pavlović, Ljubica, "Synthesis and characterization of new refractory coatings based on talc, cordierite, zircon and mullite fillers for lost foam casting process" in Archives of Metallurgy and Materials, 59, no. 1 (2014):89-95,
https://doi.org/10.2478/amm-2014-0015 . .

TY  - JOUR
AU  - Vasić, Miloš
AU  - Grbavčić, Željko
AU  - Radojević, Zagorka
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5769
AB  - Drying plays an important role in the production of clay tiles. In the present article, drying process is analyzed taking experimental data for several masonry clays obtained from different clay tile manufacturers and published data for different clay slabs. Calculation methods and computer programs designed for the calculation of the effective diffusion coefficient are developed. The first calculation method represents the analytical solution of the Crank equation, while the second one represents the analytical solution of the Efremov equation with boundary conditions in the form of the flux. Unlike other materials, clay tiles exhibit shrinkage during the drying process. For this reason, a shrinkage correction is included in both calculation methods. Four models (Al, A2, B1 and B2) for predicting the drying behavior are obtained as the result of the calculation cited programs. It is shown that the calculated effective diffusion coefficient determined by the designed computer programs, using experimentally obtained and selected published data sets have similar values to those of the same coefficient reported in the literature. Based on the mathematically determined prognostic values of the effective diffusion coefficient, it was concluded that there is more than 90% agreement between the experimentally recorded and the calculated drying curves.
PB  - Elsevier Science Sa, Lausanne
T2  - Chemical Engineering and Processing-Process Intensification
T1  - Determination of the moisture diffusivity coefficient and mathematical modeling of drying
EP  - 44
SP  - 33
VL  - 76
DO  - 10.1016/j.cep.2013.12.003
ER  - 

@article{
author = "Vasić, Miloš and Grbavčić, Željko and Radojević, Zagorka",
year = "2014",
abstract = "Drying plays an important role in the production of clay tiles. In the present article, drying process is analyzed taking experimental data for several masonry clays obtained from different clay tile manufacturers and published data for different clay slabs. Calculation methods and computer programs designed for the calculation of the effective diffusion coefficient are developed. The first calculation method represents the analytical solution of the Crank equation, while the second one represents the analytical solution of the Efremov equation with boundary conditions in the form of the flux. Unlike other materials, clay tiles exhibit shrinkage during the drying process. For this reason, a shrinkage correction is included in both calculation methods. Four models (Al, A2, B1 and B2) for predicting the drying behavior are obtained as the result of the calculation cited programs. It is shown that the calculated effective diffusion coefficient determined by the designed computer programs, using experimentally obtained and selected published data sets have similar values to those of the same coefficient reported in the literature. Based on the mathematically determined prognostic values of the effective diffusion coefficient, it was concluded that there is more than 90% agreement between the experimentally recorded and the calculated drying curves.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Chemical Engineering and Processing-Process Intensification",
title = "Determination of the moisture diffusivity coefficient and mathematical modeling of drying",
pages = "44-33",
volume = "76",
doi = "10.1016/j.cep.2013.12.003"
}

Vasić, M., Grbavčić, Ž.,& Radojević, Z.. (2014). Determination of the moisture diffusivity coefficient and mathematical modeling of drying. in Chemical Engineering and Processing-Process Intensification
Elsevier Science Sa, Lausanne., 76, 33-44.
https://doi.org/10.1016/j.cep.2013.12.003

Vasić M, Grbavčić Ž, Radojević Z. Determination of the moisture diffusivity coefficient and mathematical modeling of drying. in Chemical Engineering and Processing-Process Intensification. 2014;76:33-44.
doi:10.1016/j.cep.2013.12.003 .

Vasić, Miloš, Grbavčić, Željko, Radojević, Zagorka, "Determination of the moisture diffusivity coefficient and mathematical modeling of drying" in Chemical Engineering and Processing-Process Intensification, 76 (2014):33-44,
https://doi.org/10.1016/j.cep.2013.12.003 . .

TY  - JOUR
AU  - Andrić, Ljubiša
AU  - Terzić, Anja
AU  - Aćimović-Pavlović, Zagorka
AU  - Pavlović, Ljubica
AU  - Petrov, Milan
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5767
AB  - Mica and talc have wide areas of application as a raw material in a number of industrial branches. Mechanically activated mica has specific applications such as: capacitors, insulators, and pearlescent pigments. Talc is widely used as either a basic raw material or as filler. This paper presents a comparative analysis of mechanically activated samples of mica and talc in ultra-centrifugal mechano-activator "Retsch ZM-1". The following mechano-activator parameters were variable: number of rotor revolutions (rpm); sieve mesh size (mu m); current intensity (A). In addition, the following parameters were monitored: duration of mechanical activation, t (min); circumferential rotor speed, v (m/s); capacity of mechano-activator, Q (kg/h); and specific energy consumption, W-e (kW h/t). It was observed that effect of mechanical activation of mica and talc increased with an increase of the load and rotor revolution of ultra-centrifugal mechano-activator. Both mica and talc were successfully treated by mechanical activation procedure. In the processing of mica, mechanical activation is suggested to be applied as a post-treatment, and in the talc processing as a pre-treatment, as the high quality talc is obtained by means of hydrometallurgical concentration method.
PB  - Elsevier Sci Ltd, Oxford
T2  - Composites Part B-Engineering
T1  - Comparative kinetic study of mechanical activation process of mica and talc for industrial application
EP  - 190
SP  - 181
VL  - 59
DO  - 10.1016/j.compositesb.2013.12.003
ER  - 

@article{
author = "Andrić, Ljubiša and Terzić, Anja and Aćimović-Pavlović, Zagorka and Pavlović, Ljubica and Petrov, Milan",
year = "2014",
abstract = "Mica and talc have wide areas of application as a raw material in a number of industrial branches. Mechanically activated mica has specific applications such as: capacitors, insulators, and pearlescent pigments. Talc is widely used as either a basic raw material or as filler. This paper presents a comparative analysis of mechanically activated samples of mica and talc in ultra-centrifugal mechano-activator "Retsch ZM-1". The following mechano-activator parameters were variable: number of rotor revolutions (rpm); sieve mesh size (mu m); current intensity (A). In addition, the following parameters were monitored: duration of mechanical activation, t (min); circumferential rotor speed, v (m/s); capacity of mechano-activator, Q (kg/h); and specific energy consumption, W-e (kW h/t). It was observed that effect of mechanical activation of mica and talc increased with an increase of the load and rotor revolution of ultra-centrifugal mechano-activator. Both mica and talc were successfully treated by mechanical activation procedure. In the processing of mica, mechanical activation is suggested to be applied as a post-treatment, and in the talc processing as a pre-treatment, as the high quality talc is obtained by means of hydrometallurgical concentration method.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Composites Part B-Engineering",
title = "Comparative kinetic study of mechanical activation process of mica and talc for industrial application",
pages = "190-181",
volume = "59",
doi = "10.1016/j.compositesb.2013.12.003"
}

Andrić, L., Terzić, A., Aćimović-Pavlović, Z., Pavlović, L.,& Petrov, M.. (2014). Comparative kinetic study of mechanical activation process of mica and talc for industrial application. in Composites Part B-Engineering
Elsevier Sci Ltd, Oxford., 59, 181-190.
https://doi.org/10.1016/j.compositesb.2013.12.003

Andrić L, Terzić A, Aćimović-Pavlović Z, Pavlović L, Petrov M. Comparative kinetic study of mechanical activation process of mica and talc for industrial application. in Composites Part B-Engineering. 2014;59:181-190.
doi:10.1016/j.compositesb.2013.12.003 .

Andrić, Ljubiša, Terzić, Anja, Aćimović-Pavlović, Zagorka, Pavlović, Ljubica, Petrov, Milan, "Comparative kinetic study of mechanical activation process of mica and talc for industrial application" in Composites Part B-Engineering, 59 (2014):181-190,
https://doi.org/10.1016/j.compositesb.2013.12.003 . .

TY  - JOUR
AU  - Andrić, Ljubiša
AU  - Terzić, Anja
AU  - Aćimović-Pavlović, Zagorka
AU  - Pavlović, Ljubica
AU  - Petrov, Milan
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5764
AB  - The efficiency of talc mechanical activation by means of two different mechano-activators centrifugal and attrition mill is investigated in this study and the comparative analysis of the characteristics of obtained talc powders is presented. A new approach for obtaining high-grade talc concentrate with low Fe2O3 content is achieved through effect of mechanical activation of talc accompanied by hydrometallurgical process. The applied mechanical activation process conditions of ultra-centrifugal mill were defined by number of rotor revolutions, sieve mesh size, and current intensity. These operating parameters of the ultra-centrifugal mill were variable. Ultra fine grinding of talc in attrition mill (attritor) was carried out in various time intervals - from 5 to 15 min. The following technological parameters of the mechanical activation were monitored: time of mechanical activation, circumferential rotor speed, capacity of ultra-centrifugal mill, and specific energy consumption. The investigation was based on a kinetic model. The structure and behavior of activated samples were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) analysis, and differential thermal analysis (DTA).
PB  - Oficyna Wydawnicza Politechniki Wroclawskiej, Wroclaw
T2  - Physicochemical Problems of Mineral Processing
T1  - Comparative analysis of process parameters of talc mechanical activation in centrifugal and attrition mill
EP  - 452
IS  - 2
SP  - 433
VL  - 50
DO  - 10.5277/ppmp140202
ER  - 

@article{
author = "Andrić, Ljubiša and Terzić, Anja and Aćimović-Pavlović, Zagorka and Pavlović, Ljubica and Petrov, Milan",
year = "2014",
abstract = "The efficiency of talc mechanical activation by means of two different mechano-activators centrifugal and attrition mill is investigated in this study and the comparative analysis of the characteristics of obtained talc powders is presented. A new approach for obtaining high-grade talc concentrate with low Fe2O3 content is achieved through effect of mechanical activation of talc accompanied by hydrometallurgical process. The applied mechanical activation process conditions of ultra-centrifugal mill were defined by number of rotor revolutions, sieve mesh size, and current intensity. These operating parameters of the ultra-centrifugal mill were variable. Ultra fine grinding of talc in attrition mill (attritor) was carried out in various time intervals - from 5 to 15 min. The following technological parameters of the mechanical activation were monitored: time of mechanical activation, circumferential rotor speed, capacity of ultra-centrifugal mill, and specific energy consumption. The investigation was based on a kinetic model. The structure and behavior of activated samples were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) analysis, and differential thermal analysis (DTA).",
publisher = "Oficyna Wydawnicza Politechniki Wroclawskiej, Wroclaw",
journal = "Physicochemical Problems of Mineral Processing",
title = "Comparative analysis of process parameters of talc mechanical activation in centrifugal and attrition mill",
pages = "452-433",
number = "2",
volume = "50",
doi = "10.5277/ppmp140202"
}

Andrić, L., Terzić, A., Aćimović-Pavlović, Z., Pavlović, L.,& Petrov, M.. (2014). Comparative analysis of process parameters of talc mechanical activation in centrifugal and attrition mill. in Physicochemical Problems of Mineral Processing
Oficyna Wydawnicza Politechniki Wroclawskiej, Wroclaw., 50(2), 433-452.
https://doi.org/10.5277/ppmp140202

Andrić L, Terzić A, Aćimović-Pavlović Z, Pavlović L, Petrov M. Comparative analysis of process parameters of talc mechanical activation in centrifugal and attrition mill. in Physicochemical Problems of Mineral Processing. 2014;50(2):433-452.
doi:10.5277/ppmp140202 .

Andrić, Ljubiša, Terzić, Anja, Aćimović-Pavlović, Zagorka, Pavlović, Ljubica, Petrov, Milan, "Comparative analysis of process parameters of talc mechanical activation in centrifugal and attrition mill" in Physicochemical Problems of Mineral Processing, 50, no. 2 (2014):433-452,
https://doi.org/10.5277/ppmp140202 . .

TY  - JOUR
AU  - Prstić, Aurel
AU  - Acimović-Pavlović, Zagorka
AU  - Terzić, Anja
AU  - Pavlović, Ljubica
AU  - Grujić, Snežana
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2769
AB  - In this study, new refractory coatings based on synthesized cordierite for the casting applications were developed. The investigation included starting raw materials characterization, synthesis of the cordierite, design of the refractory coating as final product, and its application testing. The obtained results pointed out that coating suspension sediment stability was crucial quality parameter. Design and optimization of the coatings composition, with controlled rheological properties included, were achieved by application of different coating components, namely different suspension agents and by alteration of the coating production procedure. Cordierite, used as filler, was obtained by means of synthesis in the solid-state reaction on the basis of talc, kaolin, and alumina. The investigation showed that the application of these particular types of water/alcohol-based coatings has positive influence on surface quality and structural and mechanical properties of the castings of aluminum alloys obtained by casting into sand molds by means of evaporable models method, that is, evaporate pattern casting process.
PB  - Wiley, Hoboken
T2  - International Journal of Applied Ceramic Technology
T1  - Development of New Cordierite-Based Refractory Coatings for Casting Applications
EP  - 331
IS  - 2
SP  - 321
VL  - 11
DO  - 10.1111/ijac.12010
ER  - 

@article{
author = "Prstić, Aurel and Acimović-Pavlović, Zagorka and Terzić, Anja and Pavlović, Ljubica and Grujić, Snežana",
year = "2014",
abstract = "In this study, new refractory coatings based on synthesized cordierite for the casting applications were developed. The investigation included starting raw materials characterization, synthesis of the cordierite, design of the refractory coating as final product, and its application testing. The obtained results pointed out that coating suspension sediment stability was crucial quality parameter. Design and optimization of the coatings composition, with controlled rheological properties included, were achieved by application of different coating components, namely different suspension agents and by alteration of the coating production procedure. Cordierite, used as filler, was obtained by means of synthesis in the solid-state reaction on the basis of talc, kaolin, and alumina. The investigation showed that the application of these particular types of water/alcohol-based coatings has positive influence on surface quality and structural and mechanical properties of the castings of aluminum alloys obtained by casting into sand molds by means of evaporable models method, that is, evaporate pattern casting process.",
publisher = "Wiley, Hoboken",
journal = "International Journal of Applied Ceramic Technology",
title = "Development of New Cordierite-Based Refractory Coatings for Casting Applications",
pages = "331-321",
number = "2",
volume = "11",
doi = "10.1111/ijac.12010"
}

Prstić, A., Acimović-Pavlović, Z., Terzić, A., Pavlović, L.,& Grujić, S.. (2014). Development of New Cordierite-Based Refractory Coatings for Casting Applications. in International Journal of Applied Ceramic Technology
Wiley, Hoboken., 11(2), 321-331.
https://doi.org/10.1111/ijac.12010

Prstić A, Acimović-Pavlović Z, Terzić A, Pavlović L, Grujić S. Development of New Cordierite-Based Refractory Coatings for Casting Applications. in International Journal of Applied Ceramic Technology. 2014;11(2):321-331.
doi:10.1111/ijac.12010 .

Prstić, Aurel, Acimović-Pavlović, Zagorka, Terzić, Anja, Pavlović, Ljubica, Grujić, Snežana, "Development of New Cordierite-Based Refractory Coatings for Casting Applications" in International Journal of Applied Ceramic Technology, 11, no. 2 (2014):321-331,
https://doi.org/10.1111/ijac.12010 . .

TY  - JOUR
AU  - Aćimović, Zagorka
AU  - Terzić, Anja
AU  - Andrić, Ljubiša
AU  - Pavlović, Ljubica
AU  - Pavlović, Marko
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5717
AB  - Various possibilities for developing new mullite-based refractory linings that can be applied in a casting process were investigated and are presented in this paper. An optimization of the refractory-lining composition design with the controlled rheological properties was achieved by applying different lining components and altering the lining-production procedure. Mullite was used as a high-temperature filler. A mullite sample was tested with the following methods: X-ray diffraction analysis, differential thermal analysis and scanning-electron microscopy. The particle shape and particle size were analyzed with the program package for an image analysis called OZARIA 2.5. It was proved that an application of this type of lining has a positive effect on the surface quality, structural and mechanical properties of the castings of Fe-C alloys obtained by casting into sand molds, according to the method of expandable patterns (the EPC casting process).
PB  - Inst Za Kovinske Materiale I In Tehnologie, Ljubjana
T2  - Materiali in tehnologije
T1  - Synthesizing a new type of mullite lining
EP  - 780
IS  - 6
SP  - 777
VL  - 47
UR  - https://hdl.handle.net/21.15107/rcub_rims_214
ER  - 

@article{
author = "Aćimović, Zagorka and Terzić, Anja and Andrić, Ljubiša and Pavlović, Ljubica and Pavlović, Marko",
year = "2013",
abstract = "Various possibilities for developing new mullite-based refractory linings that can be applied in a casting process were investigated and are presented in this paper. An optimization of the refractory-lining composition design with the controlled rheological properties was achieved by applying different lining components and altering the lining-production procedure. Mullite was used as a high-temperature filler. A mullite sample was tested with the following methods: X-ray diffraction analysis, differential thermal analysis and scanning-electron microscopy. The particle shape and particle size were analyzed with the program package for an image analysis called OZARIA 2.5. It was proved that an application of this type of lining has a positive effect on the surface quality, structural and mechanical properties of the castings of Fe-C alloys obtained by casting into sand molds, according to the method of expandable patterns (the EPC casting process).",
publisher = "Inst Za Kovinske Materiale I In Tehnologie, Ljubjana",
journal = "Materiali in tehnologije",
title = "Synthesizing a new type of mullite lining",
pages = "780-777",
number = "6",
volume = "47",
url = "https://hdl.handle.net/21.15107/rcub_rims_214"
}

Aćimović, Z., Terzić, A., Andrić, L., Pavlović, L.,& Pavlović, M.. (2013). Synthesizing a new type of mullite lining. in Materiali in tehnologije
Inst Za Kovinske Materiale I In Tehnologie, Ljubjana., 47(6), 777-780.
https://hdl.handle.net/21.15107/rcub_rims_214

Aćimović Z, Terzić A, Andrić L, Pavlović L, Pavlović M. Synthesizing a new type of mullite lining. in Materiali in tehnologije. 2013;47(6):777-780.
https://hdl.handle.net/21.15107/rcub_rims_214 .

Aćimović, Zagorka, Terzić, Anja, Andrić, Ljubiša, Pavlović, Ljubica, Pavlović, Marko, "Synthesizing a new type of mullite lining" in Materiali in tehnologije, 47, no. 6 (2013):777-780,
https://hdl.handle.net/21.15107/rcub_rims_214 .

TY  - JOUR
AU  - Arsenović, Milica
AU  - Pezo, Lato
AU  - Stanković, Slavka
AU  - Radojević, Zagorka
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5715
AB  - Compressive strength and water absorption of fired heavy clay products varies with firing temperatures, but not entirely according to linear function, as it is mostly reported in literature. Also, differential thermo-gravimetric curve shows many turnovers in all the samples tested, within observed temperature range (820-920 degrees C). The aim of this research was to find a cause for such behaviour. Except derivative weight (DW), compressive strength (CS) and water absorption (WA) are chosen as outputs that represent properties of the fired samples. These parameters can be calculated using second order polynomial models (SOPs), on the basis of content of major oxides and firing temperature, as shown in our previous research. Sensitivity analysis was used as the effective approach in testing changes observed in the SOP outputs, due to the variation of content of major oxides for +1% or -1% of their nominal value. This study reveals in more detail the most significant influence of inputs (SiO2, Al2O3, Fe2O3 and CaO content) over the outputs (DW, CS and WA) in every observed firing temperature. Addition or lowering of content of major oxides can both increase and decrease all the observed outputs, as revealed using sensitivity analysis.
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Sensitivity analysis of mathematical models for final product properties: Link to DTG curve
EP  - 6285
IS  - 6
SP  - 6277
VL  - 39
DO  - 10.1016/j.ceramint.2013.01.049
ER  - 

@article{
author = "Arsenović, Milica and Pezo, Lato and Stanković, Slavka and Radojević, Zagorka",
year = "2013",
abstract = "Compressive strength and water absorption of fired heavy clay products varies with firing temperatures, but not entirely according to linear function, as it is mostly reported in literature. Also, differential thermo-gravimetric curve shows many turnovers in all the samples tested, within observed temperature range (820-920 degrees C). The aim of this research was to find a cause for such behaviour. Except derivative weight (DW), compressive strength (CS) and water absorption (WA) are chosen as outputs that represent properties of the fired samples. These parameters can be calculated using second order polynomial models (SOPs), on the basis of content of major oxides and firing temperature, as shown in our previous research. Sensitivity analysis was used as the effective approach in testing changes observed in the SOP outputs, due to the variation of content of major oxides for +1% or -1% of their nominal value. This study reveals in more detail the most significant influence of inputs (SiO2, Al2O3, Fe2O3 and CaO content) over the outputs (DW, CS and WA) in every observed firing temperature. Addition or lowering of content of major oxides can both increase and decrease all the observed outputs, as revealed using sensitivity analysis.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Sensitivity analysis of mathematical models for final product properties: Link to DTG curve",
pages = "6285-6277",
number = "6",
volume = "39",
doi = "10.1016/j.ceramint.2013.01.049"
}

Arsenović, M., Pezo, L., Stanković, S.,& Radojević, Z.. (2013). Sensitivity analysis of mathematical models for final product properties: Link to DTG curve. in Ceramics International
Elsevier Sci Ltd, Oxford., 39(6), 6277-6285.
https://doi.org/10.1016/j.ceramint.2013.01.049

Arsenović M, Pezo L, Stanković S, Radojević Z. Sensitivity analysis of mathematical models for final product properties: Link to DTG curve. in Ceramics International. 2013;39(6):6277-6285.
doi:10.1016/j.ceramint.2013.01.049 .

Arsenović, Milica, Pezo, Lato, Stanković, Slavka, Radojević, Zagorka, "Sensitivity analysis of mathematical models for final product properties: Link to DTG curve" in Ceramics International, 39, no. 6 (2013):6277-6285,
https://doi.org/10.1016/j.ceramint.2013.01.049 . .

TY  - JOUR
AU  - Arsenović, Milica
AU  - Stanković, Slavka
AU  - Radojević, Zagorka
AU  - Pezo, Lato
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5711
AB  - Many factors influence final clay brick properties, since the raw materials used are highly heterogeneous. Statistical analysis is rarely used, according to literature, but it would improve understanding of the overall system behavior and the quality of products. In this study, analysis of variance (ANOVA) showed that the most important parameters influencing compressive strength (CS) were the quadratic terms of firing temperature, CaO and SiO2 content in developed second order polynomial (SOP) models. Water absorption (WA) was mostly influenced by quadratic terms of CaO and SiO2. The most influential interchange terms in all the models were SiO2 x CaO, SiO2 x Na2O, Fe2O3 x Na2O, CaO x Na2O and CaO x K2O. Developed SOP models, which connected the influence of major oxides content and firing temperature on CS and WA, showed the highest r(2) values (0.926-0.967) obtained in the literature so far, for these naturally occurring heavy clay raw materials. Developed models were able to predict CS and WA in a wide range of chemical composition and temperature treatment data. The implementation of the SOP model is simple using the set of equations in a spreadsheet. The focus of this study was to determine the optimal composition and firing temperature, depending on final usage of the raw material in heavy clay brick industry. The study was conducted using fuzzy synthetic evaluation, through membership trapezoidal function, with pre-defined optimal interval values for every group of heavy clay products. The optimal samples chemical composition and firing temperature were chosen regarding the kind of the heavy clay product (I-solid bricks, II-hollow blocks and ceiling elements, and III-roof tiles).
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Prediction and fuzzy synthetic optimization of process parameters in heavy clay brick production
EP  - 2022
IS  - 2
SP  - 2013
VL  - 39
DO  - 10.1016/j.ceramint.2012.08.053
ER  - 

@article{
author = "Arsenović, Milica and Stanković, Slavka and Radojević, Zagorka and Pezo, Lato",
year = "2013",
abstract = "Many factors influence final clay brick properties, since the raw materials used are highly heterogeneous. Statistical analysis is rarely used, according to literature, but it would improve understanding of the overall system behavior and the quality of products. In this study, analysis of variance (ANOVA) showed that the most important parameters influencing compressive strength (CS) were the quadratic terms of firing temperature, CaO and SiO2 content in developed second order polynomial (SOP) models. Water absorption (WA) was mostly influenced by quadratic terms of CaO and SiO2. The most influential interchange terms in all the models were SiO2 x CaO, SiO2 x Na2O, Fe2O3 x Na2O, CaO x Na2O and CaO x K2O. Developed SOP models, which connected the influence of major oxides content and firing temperature on CS and WA, showed the highest r(2) values (0.926-0.967) obtained in the literature so far, for these naturally occurring heavy clay raw materials. Developed models were able to predict CS and WA in a wide range of chemical composition and temperature treatment data. The implementation of the SOP model is simple using the set of equations in a spreadsheet. The focus of this study was to determine the optimal composition and firing temperature, depending on final usage of the raw material in heavy clay brick industry. The study was conducted using fuzzy synthetic evaluation, through membership trapezoidal function, with pre-defined optimal interval values for every group of heavy clay products. The optimal samples chemical composition and firing temperature were chosen regarding the kind of the heavy clay product (I-solid bricks, II-hollow blocks and ceiling elements, and III-roof tiles).",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Prediction and fuzzy synthetic optimization of process parameters in heavy clay brick production",
pages = "2022-2013",
number = "2",
volume = "39",
doi = "10.1016/j.ceramint.2012.08.053"
}

Arsenović, M., Stanković, S., Radojević, Z.,& Pezo, L.. (2013). Prediction and fuzzy synthetic optimization of process parameters in heavy clay brick production. in Ceramics International
Elsevier Sci Ltd, Oxford., 39(2), 2013-2022.
https://doi.org/10.1016/j.ceramint.2012.08.053

Arsenović M, Stanković S, Radojević Z, Pezo L. Prediction and fuzzy synthetic optimization of process parameters in heavy clay brick production. in Ceramics International. 2013;39(2):2013-2022.
doi:10.1016/j.ceramint.2012.08.053 .

Arsenović, Milica, Stanković, Slavka, Radojević, Zagorka, Pezo, Lato, "Prediction and fuzzy synthetic optimization of process parameters in heavy clay brick production" in Ceramics International, 39, no. 2 (2013):2013-2022,
https://doi.org/10.1016/j.ceramint.2012.08.053 . .

TY  - JOUR
AU  - Arsenović, Milica
AU  - Stanković, Slavka
AU  - Pezo, Lato
AU  - Mančić, Lidija
AU  - Radojević, Zagorka
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5708
AB  - Loess clays are commonly used to produce bricks. Heavy clays, taken at location near Zrenjanin, Serbia, are used as a representative raw material in this study. The sample, containing about 28% of clay sized particles, is enriched using two more plastic heavy clays from neighboring locations. Chemical and mineralogical content of clays is determined, as well as particle size distribution. Optimization of the processing parameters during the bricks production, i. e. temperature (900–1100 °C), and concentration of 2 clays combined addition (both in the range of 0–10%), is done based on the following independent parameters: compressive strength (CS), water absorption (WA), firing shrinkage (FS), weight loss during firing (WLF) and apparent density expressed as volume mass of cubes (VMC). Developed models showed r2 values in the range of 0.822–0.998, and they were able to accurately predict CS, WA, FS, WLF and VMC in a wide range of processing parameters. The optimum conditions are determined by the response surface method (RSM), coupled with the fuzzy synthetic evaluation (FSE) algorithm, using membership trapezoidal function, with defined optimal interval values, depending on a final usage of the raw material in heavy clay brick industry.
PB  - Elsevier
T2  - Ceramics International
T1  - Optimization of the production process through response surface method: Bricks made of loess
EP  - 3075
IS  - 3
SP  - 3065
VL  - 39
DO  - 10.1016/j.ceramint.2012.09.086
UR  - https://hdl.handle.net/21.15107/rcub_dais_341
ER  - 

@article{
author = "Arsenović, Milica and Stanković, Slavka and Pezo, Lato and Mančić, Lidija and Radojević, Zagorka",
year = "2013",
abstract = "Loess clays are commonly used to produce bricks. Heavy clays, taken at location near Zrenjanin, Serbia, are used as a representative raw material in this study. The sample, containing about 28% of clay sized particles, is enriched using two more plastic heavy clays from neighboring locations. Chemical and mineralogical content of clays is determined, as well as particle size distribution. Optimization of the processing parameters during the bricks production, i. e. temperature (900–1100 °C), and concentration of 2 clays combined addition (both in the range of 0–10%), is done based on the following independent parameters: compressive strength (CS), water absorption (WA), firing shrinkage (FS), weight loss during firing (WLF) and apparent density expressed as volume mass of cubes (VMC). Developed models showed r2 values in the range of 0.822–0.998, and they were able to accurately predict CS, WA, FS, WLF and VMC in a wide range of processing parameters. The optimum conditions are determined by the response surface method (RSM), coupled with the fuzzy synthetic evaluation (FSE) algorithm, using membership trapezoidal function, with defined optimal interval values, depending on a final usage of the raw material in heavy clay brick industry.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "Optimization of the production process through response surface method: Bricks made of loess",
pages = "3075-3065",
number = "3",
volume = "39",
doi = "10.1016/j.ceramint.2012.09.086",
url = "https://hdl.handle.net/21.15107/rcub_dais_341"
}

Arsenović, M., Stanković, S., Pezo, L., Mančić, L.,& Radojević, Z.. (2013). Optimization of the production process through response surface method: Bricks made of loess. in Ceramics International
Elsevier., 39(3), 3065-3075.
https://doi.org/10.1016/j.ceramint.2012.09.086
https://hdl.handle.net/21.15107/rcub_dais_341

Arsenović M, Stanković S, Pezo L, Mančić L, Radojević Z. Optimization of the production process through response surface method: Bricks made of loess. in Ceramics International. 2013;39(3):3065-3075.
doi:10.1016/j.ceramint.2012.09.086
https://hdl.handle.net/21.15107/rcub_dais_341 .

Arsenović, Milica, Stanković, Slavka, Pezo, Lato, Mančić, Lidija, Radojević, Zagorka, "Optimization of the production process through response surface method: Bricks made of loess" in Ceramics International, 39, no. 3 (2013):3065-3075,
https://doi.org/10.1016/j.ceramint.2012.09.086 .,
https://hdl.handle.net/21.15107/rcub_dais_341 .

TY  - JOUR
AU  - Arsenović, Milica V.
AU  - Pezo, Lato L.
AU  - Radojević, Zagorka M.
AU  - Stanković, Slavka M.
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5090
AB  - This study is focused on the behavior of five new deposits of heavy clays from Serbia, with the aim to evaluate their potential suitability as raw materials in rough ceramic applications. The Pfefferkorn plasticity coefficient (PC) and drying susceptibility using Bigot’s curve were measured for each raw sample. Thermodilatometric analysis (TDA) showed the behaviour of dry products during firing. Samples groups were fired in the range of 850°C - 1000°C. Water absorption capacity (WAC) and compressive strength (CS) were done in order to characterize clays after firing. Linear regression models were used to fit the results. Mathematical tools were used to determine statistical difference of major oxides content, shaping moist and compressive strength of dry laboratory products, using post-hoc Tukey`s HSD test. The chemical and mineralogical compositions of samples do not differ considerably, but their possible application does. All studied clays seem to be easily adaptable to a correct brick making process.
PB  - Association of the Chemical Engineers of Serbia
T2  - Hemijska industrija
T1  - Serbian heavy clays behavior: Application in rough ceramics
EP  - 822
IS  - 5
SP  - 811
VL  - 67
DO  - 10.2298/HEMIND121123006A
ER  - 

@article{
author = "Arsenović, Milica V. and Pezo, Lato L. and Radojević, Zagorka M. and Stanković, Slavka M.",
year = "2013",
abstract = "This study is focused on the behavior of five new deposits of heavy clays from Serbia, with the aim to evaluate their potential suitability as raw materials in rough ceramic applications. The Pfefferkorn plasticity coefficient (PC) and drying susceptibility using Bigot’s curve were measured for each raw sample. Thermodilatometric analysis (TDA) showed the behaviour of dry products during firing. Samples groups were fired in the range of 850°C - 1000°C. Water absorption capacity (WAC) and compressive strength (CS) were done in order to characterize clays after firing. Linear regression models were used to fit the results. Mathematical tools were used to determine statistical difference of major oxides content, shaping moist and compressive strength of dry laboratory products, using post-hoc Tukey`s HSD test. The chemical and mineralogical compositions of samples do not differ considerably, but their possible application does. All studied clays seem to be easily adaptable to a correct brick making process.",
publisher = "Association of the Chemical Engineers of Serbia",
journal = "Hemijska industrija",
title = "Serbian heavy clays behavior: Application in rough ceramics",
pages = "822-811",
number = "5",
volume = "67",
doi = "10.2298/HEMIND121123006A"
}

Arsenović, M. V., Pezo, L. L., Radojević, Z. M.,& Stanković, S. M.. (2013). Serbian heavy clays behavior: Application in rough ceramics. in Hemijska industrija
Association of the Chemical Engineers of Serbia., 67(5), 811-822.
https://doi.org/10.2298/HEMIND121123006A

Arsenović MV, Pezo LL, Radojević ZM, Stanković SM. Serbian heavy clays behavior: Application in rough ceramics. in Hemijska industrija. 2013;67(5):811-822.
doi:10.2298/HEMIND121123006A .

Arsenović, Milica V., Pezo, Lato L., Radojević, Zagorka M., Stanković, Slavka M., "Serbian heavy clays behavior: Application in rough ceramics" in Hemijska industrija, 67, no. 5 (2013):811-822,
https://doi.org/10.2298/HEMIND121123006A . .

TY  - JOUR
AU  - Andrić, Ljubiša
AU  - Terzić, Anja
AU  - Aćimović-Pavlović, Zagorka
AU  - Trumić, Milan
AU  - Petrov, Milan
AU  - Pavlović, Ljubica
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5087
AB  - This paper presents results of the research of micronization grinding of dry mica in a planetary ball mill. Investigation was conducted in order to improve the quality and to obtain clearly defined properties and characteristics of mica powder. The micronization grinding of dry mica was performed in four time periods: 30, 60, 120, and 360 minutes. The micronized powder was investigated by means of differential thermal and thermogravimetric analyses, analysis of the degree of micronization, the specific surface area analysis, and X-ray diffraction analysis. The achieved results pointed out that dry mica micronization grinding which exceeds 360 minutes is recommended for this type of mill. However, it was also shown that the micronized mica produced by means of planetary ball mill after extra long periods of micronization grinding can pass into amorphous state.
PB  - Hindawi Publishing Corporation
T2  - Advances in Materials Science and Engineering
T1  - A Kinetic Study of Micronization Grinding of Dry Mica in a Planetary Ball Mill
SP  - 543857
VL  - 2013
DO  - 10.1155/2013/543857
ER  - 

@article{
author = "Andrić, Ljubiša and Terzić, Anja and Aćimović-Pavlović, Zagorka and Trumić, Milan and Petrov, Milan and Pavlović, Ljubica",
year = "2013",
abstract = "This paper presents results of the research of micronization grinding of dry mica in a planetary ball mill. Investigation was conducted in order to improve the quality and to obtain clearly defined properties and characteristics of mica powder. The micronization grinding of dry mica was performed in four time periods: 30, 60, 120, and 360 minutes. The micronized powder was investigated by means of differential thermal and thermogravimetric analyses, analysis of the degree of micronization, the specific surface area analysis, and X-ray diffraction analysis. The achieved results pointed out that dry mica micronization grinding which exceeds 360 minutes is recommended for this type of mill. However, it was also shown that the micronized mica produced by means of planetary ball mill after extra long periods of micronization grinding can pass into amorphous state.",
publisher = "Hindawi Publishing Corporation",
journal = "Advances in Materials Science and Engineering",
title = "A Kinetic Study of Micronization Grinding of Dry Mica in a Planetary Ball Mill",
pages = "543857",
volume = "2013",
doi = "10.1155/2013/543857"
}

Andrić, L., Terzić, A., Aćimović-Pavlović, Z., Trumić, M., Petrov, M.,& Pavlović, L.. (2013). A Kinetic Study of Micronization Grinding of Dry Mica in a Planetary Ball Mill. in Advances in Materials Science and Engineering
Hindawi Publishing Corporation., 2013, 543857.
https://doi.org/10.1155/2013/543857

Andrić L, Terzić A, Aćimović-Pavlović Z, Trumić M, Petrov M, Pavlović L. A Kinetic Study of Micronization Grinding of Dry Mica in a Planetary Ball Mill. in Advances in Materials Science and Engineering. 2013;2013:543857.
doi:10.1155/2013/543857 .

Andrić, Ljubiša, Terzić, Anja, Aćimović-Pavlović, Zagorka, Trumić, Milan, Petrov, Milan, Pavlović, Ljubica, "A Kinetic Study of Micronization Grinding of Dry Mica in a Planetary Ball Mill" in Advances in Materials Science and Engineering, 2013 (2013):543857,
https://doi.org/10.1155/2013/543857 . .

TY  - JOUR
AU  - Ćosić, Milena
AU  - Acimović-Pavlović, Zagorka
AU  - Terzić, Anja
AU  - Dojčinović, Marina
AU  - Pavlović, Ljubica
PY  - 2012
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2164
AB  - The aim of this study was to investigate the influence of various process parameters on the microstructure of composite materials based on alloys All 8Wt%Si with the addition of 10Wt%SiC. The effect of stirring speed (1000 and 1500 rpm), stirring time 15 min and casting temperature 565 degrees C on the structural and mechanical properties are discussed. It was found that applying the stirring speed of 1500 rpm in semisolid state the best distribution of SiC particles in the matrix was achieved, which gave satisfying mechanical properties. In order to evaluate the quality of obtained composites and their possible application in the practice, tests were carried out under conditions of cavitation. Cavitation damage to the composite samples was determined using modified vibratory cavitation equipment. Mass loss and surface analysis of composite samples during the experiment were used as an indicator the level of cavitation damage. The results showed very good cavitation resistance which gives the possibility of using these materials in condition where cavitation resistance is needed.
PB  - Modtech Publishing House, Iasi
T2  - Modtech 2012: New Face of T M C R, Vols I and II
T1  - The possibility of obtaining. Composite al18wt%si/sic by compocasting process
EP  - 252
SP  - 249
UR  - https://hdl.handle.net/21.15107/rcub_technorep_2164
ER  - 

@article{
author = "Ćosić, Milena and Acimović-Pavlović, Zagorka and Terzić, Anja and Dojčinović, Marina and Pavlović, Ljubica",
year = "2012",
abstract = "The aim of this study was to investigate the influence of various process parameters on the microstructure of composite materials based on alloys All 8Wt%Si with the addition of 10Wt%SiC. The effect of stirring speed (1000 and 1500 rpm), stirring time 15 min and casting temperature 565 degrees C on the structural and mechanical properties are discussed. It was found that applying the stirring speed of 1500 rpm in semisolid state the best distribution of SiC particles in the matrix was achieved, which gave satisfying mechanical properties. In order to evaluate the quality of obtained composites and their possible application in the practice, tests were carried out under conditions of cavitation. Cavitation damage to the composite samples was determined using modified vibratory cavitation equipment. Mass loss and surface analysis of composite samples during the experiment were used as an indicator the level of cavitation damage. The results showed very good cavitation resistance which gives the possibility of using these materials in condition where cavitation resistance is needed.",
publisher = "Modtech Publishing House, Iasi",
journal = "Modtech 2012: New Face of T M C R, Vols I and II",
title = "The possibility of obtaining. Composite al18wt%si/sic by compocasting process",
pages = "252-249",
url = "https://hdl.handle.net/21.15107/rcub_technorep_2164"
}

Ćosić, M., Acimović-Pavlović, Z., Terzić, A., Dojčinović, M.,& Pavlović, L.. (2012). The possibility of obtaining. Composite al18wt%si/sic by compocasting process. in Modtech 2012: New Face of T M C R, Vols I and II
Modtech Publishing House, Iasi., 249-252.
https://hdl.handle.net/21.15107/rcub_technorep_2164

Ćosić M, Acimović-Pavlović Z, Terzić A, Dojčinović M, Pavlović L. The possibility of obtaining. Composite al18wt%si/sic by compocasting process. in Modtech 2012: New Face of T M C R, Vols I and II. 2012;:249-252.
https://hdl.handle.net/21.15107/rcub_technorep_2164 .

Ćosić, Milena, Acimović-Pavlović, Zagorka, Terzić, Anja, Dojčinović, Marina, Pavlović, Ljubica, "The possibility of obtaining. Composite al18wt%si/sic by compocasting process" in Modtech 2012: New Face of T M C R, Vols I and II (2012):249-252,
https://hdl.handle.net/21.15107/rcub_technorep_2164 .

TY  - JOUR
AU  - Prstić, Aurel
AU  - Aćimović-Pavlović, Zagorka
AU  - Andrić, Ljubiša
AU  - Stojanović, Jovica
AU  - Terzić, Anja
PY  - 2012
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5748
AB  - U ovom radu je istraživana mogućnost dobijanja novih vatrostalnih premaza na bazi cirkona koji bi imali primenu u livarstvu. Optimizacija sastava premaza kontrolisana reološkim svojstvima postignuta je primenom različitih komponenata premaza, naročito primenom novog veziva na bazi suspenzije i variranjem načina spravljanja premaza. Čestice cirkonskoh praha veličine 25×10-6 m su korišćene kao ispuna. Uzorak cirkona ispitivan je pomoću sledećih metoda: difrakcija X-zraka, diferencijalna termalna analiza i mikroskopija. Oblik i veličina zrna su analizirani pomoću računarskog programa za analizu slike OZARIA 2.5. Pokazano je da primena ovih premaza na bazi vode i alkohola ima pozitivan uticaj na kvalitet površine, tj. na strukturne i mehaničke karakteristike odlivaka livenog gvožđa koji su dobijeni metodom livenja u peščane kalupe i pomoću isparljivih modela (Lost Foam metoda livenja).
AB  - In this work, a possibility to develop a new zircon-based refractory coating for casting applications was investigated. Optimization of the coating composition with controlled rheological properties was attained by application of different coating components, particularly by application of a new suspension agent and by alteration of coating production procedure. Zircon powder with particle size of 25×10-6 m was used as filler. The zircon sample was investigated by means of X-ray diffraction analysis, diffraction thermal analysis and polarized microscopy. The shape and grain size were analyzed using OZARIA 2.5 software. It was shown that application of this type of water-alcohol-based coating had a positive influence on surface quality, structural and mechanical properties of the castings of cast iron obtained by pouring into sand molds by means of the expandable patterns method (Lost Foam casting process).
PB  - Savez hemijskih inženjera, Beograd
T2  - Chemical Industry and Chemical Engineering Quarterly / CICEQ
T1  - Premazi na bazi cirkona sa primenom u Lost Foam procesu livenja
T1  - Zircon-based coating for the applications in Lost Foam casting process
EP  - 593
IS  - 4
SP  - 587
VL  - 18
DO  - 10.2298/CICEQ111122034P
ER  - 

@article{
author = "Prstić, Aurel and Aćimović-Pavlović, Zagorka and Andrić, Ljubiša and Stojanović, Jovica and Terzić, Anja",
year = "2012",
abstract = "U ovom radu je istraživana mogućnost dobijanja novih vatrostalnih premaza na bazi cirkona koji bi imali primenu u livarstvu. Optimizacija sastava premaza kontrolisana reološkim svojstvima postignuta je primenom različitih komponenata premaza, naročito primenom novog veziva na bazi suspenzije i variranjem načina spravljanja premaza. Čestice cirkonskoh praha veličine 25×10-6 m su korišćene kao ispuna. Uzorak cirkona ispitivan je pomoću sledećih metoda: difrakcija X-zraka, diferencijalna termalna analiza i mikroskopija. Oblik i veličina zrna su analizirani pomoću računarskog programa za analizu slike OZARIA 2.5. Pokazano je da primena ovih premaza na bazi vode i alkohola ima pozitivan uticaj na kvalitet površine, tj. na strukturne i mehaničke karakteristike odlivaka livenog gvožđa koji su dobijeni metodom livenja u peščane kalupe i pomoću isparljivih modela (Lost Foam metoda livenja)., In this work, a possibility to develop a new zircon-based refractory coating for casting applications was investigated. Optimization of the coating composition with controlled rheological properties was attained by application of different coating components, particularly by application of a new suspension agent and by alteration of coating production procedure. Zircon powder with particle size of 25×10-6 m was used as filler. The zircon sample was investigated by means of X-ray diffraction analysis, diffraction thermal analysis and polarized microscopy. The shape and grain size were analyzed using OZARIA 2.5 software. It was shown that application of this type of water-alcohol-based coating had a positive influence on surface quality, structural and mechanical properties of the castings of cast iron obtained by pouring into sand molds by means of the expandable patterns method (Lost Foam casting process).",
publisher = "Savez hemijskih inženjera, Beograd",
journal = "Chemical Industry and Chemical Engineering Quarterly / CICEQ",
title = "Premazi na bazi cirkona sa primenom u Lost Foam procesu livenja, Zircon-based coating for the applications in Lost Foam casting process",
pages = "593-587",
number = "4",
volume = "18",
doi = "10.2298/CICEQ111122034P"
}

Prstić, A., Aćimović-Pavlović, Z., Andrić, L., Stojanović, J.,& Terzić, A.. (2012). Premazi na bazi cirkona sa primenom u Lost Foam procesu livenja. in Chemical Industry and Chemical Engineering Quarterly / CICEQ
Savez hemijskih inženjera, Beograd., 18(4), 587-593.
https://doi.org/10.2298/CICEQ111122034P

Prstić A, Aćimović-Pavlović Z, Andrić L, Stojanović J, Terzić A. Premazi na bazi cirkona sa primenom u Lost Foam procesu livenja. in Chemical Industry and Chemical Engineering Quarterly / CICEQ. 2012;18(4):587-593.
doi:10.2298/CICEQ111122034P .

Prstić, Aurel, Aćimović-Pavlović, Zagorka, Andrić, Ljubiša, Stojanović, Jovica, Terzić, Anja, "Premazi na bazi cirkona sa primenom u Lost Foam procesu livenja" in Chemical Industry and Chemical Engineering Quarterly / CICEQ, 18, no. 4 (2012):587-593,
https://doi.org/10.2298/CICEQ111122034P . .

TY  - JOUR
AU  - Terzić, Anja
AU  - Radojević, Zagorka
AU  - Miličić, Ljiljana
AU  - Pavlović, Ljubica
AU  - Aćimović, Zagorka
PY  - 2012
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5697
AB  - Odlaganje letećeg pepela dobijenog u procesu sagorevanja uglja u termo-elektranama predstavlja veliki rizik za prirodnu sredinu zbog mogućnosti luženja opasnih čestica kao što su toksični metali. Takođe, opasnost od izluživanja je prisutna čak i kada je leteći pepeo ugrađen u konstukcioni kompozit. Leteći pepeli sa različitih deponija su upotrebljeni za spravljanje uzoraka različitih kompozita (malter, beton ili opeka) pri čemu na pepelu nije sproveden nikakav fizički ili termički pred-tretman. Ispitivano je luženje potencijalno toksičnih elemenata prisutnih u proizvodima na bazi letećeg pepela. Praćeno je izluživanje i mogući uticaj na prirodnu sredinu 11 potencijalno opasnih elemenata: Pb, Cd, Zn, Cu, Ni, Cr, Hg, As, Ba, Sb i Se. Sprovedeno je detaljno istraživanje fizičko-hemijskih svojstava letećeg pepela, sa posebnim naglaskom na ispitivanju hemijskog sastava i prisutnosti elemenata u tragovima. Fizičko-hemijska svojstva pepela su ispitivana sledećim metodama: X-ray fluorescenicija, difrakciona termička analiza i X-ray difrakciona metoda. Skenirajući elektronski mikroskop je primenjen u mikrostukturnoj analizi. Rezultati su pokazali da se većina elemenata lakše izlužuje iz pepela nego kompozita spravljenih na bazi pepela. Izluživanje svih ispitivanih toksičnih elemenata je bilo u dozvoljenim granicama što znači da se ispitivani leteći pepeo može upotrebiti u proizvodnji konstrukcionih materijala.
AB  - The disposal of fly ash generated in coal based power-plants may pose a significant risk to the environment due to the possible leaching of hazardous pollutants, such as toxic metals. Also, there is a risk of leaching even when fly ash is built in the construction composites. Fly ashes from various landfills were applied in several composite samples (mortar, concrete and brick) without any physical or thermal pre-treatment. The leachability of the potentially toxic pollutants from the fly ash based products was investigated. The leaching behaviour and potential environmental impact of 11 potentially hazardous elements was tracked: Pb, Cd, Zn, Cu, Ni, Cr, Hg, As, Ba, Sb and Se. A detailed study of physico-chemical characteristics of the fly ash, with an accent on trace elements and the chemical composition investigation is included. Physicochemical properties of fly ash were investigated by means of X-ray fluorescence, differential thermal analysis and X-ray diffraction methods. Scanning electron microscopy was used in microstructure analysis. The results show that most of the elements are more easily leachable from the fly ash in comparison to the fly ash based composites. The leaching of investigated pollutants is within allowed range thus investigated fly ashes can be reused in construction materials production.
PB  - Savez hemijskih inženjera, Beograd
T2  - Chemical Industry and Chemical Engineering Quarterly / CICEQ
T1  - Luženje potencijalno toksičnih elemenata iz kompozita na bazi otpadnih sirovina
T1  - Leaching of the potentially toxic pollutants from composites based on waste raw material
EP  - 383
IS  - 3
SP  - 373
VL  - 18
DO  - 10.2298/CICEQ111128013T
ER  - 

@article{
author = "Terzić, Anja and Radojević, Zagorka and Miličić, Ljiljana and Pavlović, Ljubica and Aćimović, Zagorka",
year = "2012",
abstract = "Odlaganje letećeg pepela dobijenog u procesu sagorevanja uglja u termo-elektranama predstavlja veliki rizik za prirodnu sredinu zbog mogućnosti luženja opasnih čestica kao što su toksični metali. Takođe, opasnost od izluživanja je prisutna čak i kada je leteći pepeo ugrađen u konstukcioni kompozit. Leteći pepeli sa različitih deponija su upotrebljeni za spravljanje uzoraka različitih kompozita (malter, beton ili opeka) pri čemu na pepelu nije sproveden nikakav fizički ili termički pred-tretman. Ispitivano je luženje potencijalno toksičnih elemenata prisutnih u proizvodima na bazi letećeg pepela. Praćeno je izluživanje i mogući uticaj na prirodnu sredinu 11 potencijalno opasnih elemenata: Pb, Cd, Zn, Cu, Ni, Cr, Hg, As, Ba, Sb i Se. Sprovedeno je detaljno istraživanje fizičko-hemijskih svojstava letećeg pepela, sa posebnim naglaskom na ispitivanju hemijskog sastava i prisutnosti elemenata u tragovima. Fizičko-hemijska svojstva pepela su ispitivana sledećim metodama: X-ray fluorescenicija, difrakciona termička analiza i X-ray difrakciona metoda. Skenirajući elektronski mikroskop je primenjen u mikrostukturnoj analizi. Rezultati su pokazali da se većina elemenata lakše izlužuje iz pepela nego kompozita spravljenih na bazi pepela. Izluživanje svih ispitivanih toksičnih elemenata je bilo u dozvoljenim granicama što znači da se ispitivani leteći pepeo može upotrebiti u proizvodnji konstrukcionih materijala., The disposal of fly ash generated in coal based power-plants may pose a significant risk to the environment due to the possible leaching of hazardous pollutants, such as toxic metals. Also, there is a risk of leaching even when fly ash is built in the construction composites. Fly ashes from various landfills were applied in several composite samples (mortar, concrete and brick) without any physical or thermal pre-treatment. The leachability of the potentially toxic pollutants from the fly ash based products was investigated. The leaching behaviour and potential environmental impact of 11 potentially hazardous elements was tracked: Pb, Cd, Zn, Cu, Ni, Cr, Hg, As, Ba, Sb and Se. A detailed study of physico-chemical characteristics of the fly ash, with an accent on trace elements and the chemical composition investigation is included. Physicochemical properties of fly ash were investigated by means of X-ray fluorescence, differential thermal analysis and X-ray diffraction methods. Scanning electron microscopy was used in microstructure analysis. The results show that most of the elements are more easily leachable from the fly ash in comparison to the fly ash based composites. The leaching of investigated pollutants is within allowed range thus investigated fly ashes can be reused in construction materials production.",
publisher = "Savez hemijskih inženjera, Beograd",
journal = "Chemical Industry and Chemical Engineering Quarterly / CICEQ",
title = "Luženje potencijalno toksičnih elemenata iz kompozita na bazi otpadnih sirovina, Leaching of the potentially toxic pollutants from composites based on waste raw material",
pages = "383-373",
number = "3",
volume = "18",
doi = "10.2298/CICEQ111128013T"
}

Terzić, A., Radojević, Z., Miličić, L., Pavlović, L.,& Aćimović, Z.. (2012). Luženje potencijalno toksičnih elemenata iz kompozita na bazi otpadnih sirovina. in Chemical Industry and Chemical Engineering Quarterly / CICEQ
Savez hemijskih inženjera, Beograd., 18(3), 373-383.
https://doi.org/10.2298/CICEQ111128013T

Terzić A, Radojević Z, Miličić L, Pavlović L, Aćimović Z. Luženje potencijalno toksičnih elemenata iz kompozita na bazi otpadnih sirovina. in Chemical Industry and Chemical Engineering Quarterly / CICEQ. 2012;18(3):373-383.
doi:10.2298/CICEQ111128013T .

Terzić, Anja, Radojević, Zagorka, Miličić, Ljiljana, Pavlović, Ljubica, Aćimović, Zagorka, "Luženje potencijalno toksičnih elemenata iz kompozita na bazi otpadnih sirovina" in Chemical Industry and Chemical Engineering Quarterly / CICEQ, 18, no. 3 (2012):373-383,
https://doi.org/10.2298/CICEQ111128013T . .

TY  - JOUR
AU  - Arsenović, Milica
AU  - Radojević, Zagorka
AU  - Stanković, Slavka
PY  - 2012
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5736
AB  - The aim of this study was to test utilization possibilities of industrial sludge in masonry industry, as well as risk of toxic elements leaching potential. Sludge is generated in a hot-dip galvanizing process after waste water neutralization. This waste is considered to be hazardous due to the presence of toxic elements, which can be fixed within heavy clay matrix after thermal treatment. Relatively large amounts of toxic metals were found in used raw materials, but their leachability reduces to a negligible level after firing at 1020 degrees C. The results show that sludge can be used to produce eco-friendly bricks.
PB  - Elsevier Sci Ltd, Oxford
T2  - Construction and Building Materials
T1  - Removal of toxic metals from industrial sludge by fixing in brick structure
EP  - 14
SP  - 7
VL  - 37
DO  - 10.1016/j.conbuildmat.2012.07.002
ER  - 

@article{
author = "Arsenović, Milica and Radojević, Zagorka and Stanković, Slavka",
year = "2012",
abstract = "The aim of this study was to test utilization possibilities of industrial sludge in masonry industry, as well as risk of toxic elements leaching potential. Sludge is generated in a hot-dip galvanizing process after waste water neutralization. This waste is considered to be hazardous due to the presence of toxic elements, which can be fixed within heavy clay matrix after thermal treatment. Relatively large amounts of toxic metals were found in used raw materials, but their leachability reduces to a negligible level after firing at 1020 degrees C. The results show that sludge can be used to produce eco-friendly bricks.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Construction and Building Materials",
title = "Removal of toxic metals from industrial sludge by fixing in brick structure",
pages = "14-7",
volume = "37",
doi = "10.1016/j.conbuildmat.2012.07.002"
}

Arsenović, M., Radojević, Z.,& Stanković, S.. (2012). Removal of toxic metals from industrial sludge by fixing in brick structure. in Construction and Building Materials
Elsevier Sci Ltd, Oxford., 37, 7-14.
https://doi.org/10.1016/j.conbuildmat.2012.07.002

Arsenović M, Radojević Z, Stanković S. Removal of toxic metals from industrial sludge by fixing in brick structure. in Construction and Building Materials. 2012;37:7-14.
doi:10.1016/j.conbuildmat.2012.07.002 .

Arsenović, Milica, Radojević, Zagorka, Stanković, Slavka, "Removal of toxic metals from industrial sludge by fixing in brick structure" in Construction and Building Materials, 37 (2012):7-14,
https://doi.org/10.1016/j.conbuildmat.2012.07.002 . .