Cubic equation of state models for the liquid excess heat capacity calculations. I. Mixing rules
Апстракт
Binary liquid excess heat capacities, c(p)(E), were calculated by the PRSV EOS coupled with the van der Waals one fluid (vdW), the modified van der Waals one fluid (Schwartzentruber-Renon)(SR) and the Orbey-Sandler modification of the Huron-Vidal mixing rule (HVOS). The HVOS mixing rule is used with the NRTL excess free energy model. In all the EOS models (PRSV-VdW, PRSV-SR and PRSV-HVOS), the binary parameters were assumed to be a linear function of temperature. The benzene-ii-heptane binary system was chosen as the test sf stem to check the capabilities of the investigated EOS models for the estimation of the excess heat capacity c(p)(E).
Кључне речи:
excess heat capacity / cubic equation of state / mixing ruleИзвор:
Journal of the Serbian Chemical Society, 1998, 63, 4, 237-249Издавач:
- Serbian Chemical Society, Belgrade
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Kijevčanin, Mirjana AU - Đorđević, Bojan D. AU - Veselinović, Petar S. AU - Šerbanović, Slobodan P. PY - 1998 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/168 AB - Binary liquid excess heat capacities, c(p)(E), were calculated by the PRSV EOS coupled with the van der Waals one fluid (vdW), the modified van der Waals one fluid (Schwartzentruber-Renon)(SR) and the Orbey-Sandler modification of the Huron-Vidal mixing rule (HVOS). The HVOS mixing rule is used with the NRTL excess free energy model. In all the EOS models (PRSV-VdW, PRSV-SR and PRSV-HVOS), the binary parameters were assumed to be a linear function of temperature. The benzene-ii-heptane binary system was chosen as the test sf stem to check the capabilities of the investigated EOS models for the estimation of the excess heat capacity c(p)(E). PB - Serbian Chemical Society, Belgrade T2 - Journal of the Serbian Chemical Society T1 - Cubic equation of state models for the liquid excess heat capacity calculations. I. Mixing rules EP - 249 IS - 4 SP - 237 VL - 63 UR - https://hdl.handle.net/21.15107/rcub_technorep_168 ER -
@article{ author = "Kijevčanin, Mirjana and Đorđević, Bojan D. and Veselinović, Petar S. and Šerbanović, Slobodan P.", year = "1998", abstract = "Binary liquid excess heat capacities, c(p)(E), were calculated by the PRSV EOS coupled with the van der Waals one fluid (vdW), the modified van der Waals one fluid (Schwartzentruber-Renon)(SR) and the Orbey-Sandler modification of the Huron-Vidal mixing rule (HVOS). The HVOS mixing rule is used with the NRTL excess free energy model. In all the EOS models (PRSV-VdW, PRSV-SR and PRSV-HVOS), the binary parameters were assumed to be a linear function of temperature. The benzene-ii-heptane binary system was chosen as the test sf stem to check the capabilities of the investigated EOS models for the estimation of the excess heat capacity c(p)(E).", publisher = "Serbian Chemical Society, Belgrade", journal = "Journal of the Serbian Chemical Society", title = "Cubic equation of state models for the liquid excess heat capacity calculations. I. Mixing rules", pages = "249-237", number = "4", volume = "63", url = "https://hdl.handle.net/21.15107/rcub_technorep_168" }
Kijevčanin, M., Đorđević, B. D., Veselinović, P. S.,& Šerbanović, S. P.. (1998). Cubic equation of state models for the liquid excess heat capacity calculations. I. Mixing rules. in Journal of the Serbian Chemical Society Serbian Chemical Society, Belgrade., 63(4), 237-249. https://hdl.handle.net/21.15107/rcub_technorep_168
Kijevčanin M, Đorđević BD, Veselinović PS, Šerbanović SP. Cubic equation of state models for the liquid excess heat capacity calculations. I. Mixing rules. in Journal of the Serbian Chemical Society. 1998;63(4):237-249. https://hdl.handle.net/21.15107/rcub_technorep_168 .
Kijevčanin, Mirjana, Đorđević, Bojan D., Veselinović, Petar S., Šerbanović, Slobodan P., "Cubic equation of state models for the liquid excess heat capacity calculations. I. Mixing rules" in Journal of the Serbian Chemical Society, 63, no. 4 (1998):237-249, https://hdl.handle.net/21.15107/rcub_technorep_168 .