Isomorphous element substitution in the chabazite-like aluminophosphate framework
Abstract
Thermal investigations and Fenske-Hall SCF MO calculations have been used for studying isomorphous element substitution in the chabazite-like aluminophosphate framework prepared in the presence of tetraethylammonium hydroxide as a template. The thermal measurements show that the temperature at which the template removal occurs increases as the element varies in the Si-Zn-Mn-Co series. The Fenske-Hall SCF MO calculations on model segments of the framework indicate that the trend can be related to an appropriate decrease in basicity of the oxygen atom directly bound to the element.
Source:
ACH - Models in Chemistry, 1998, 135, 1-2, 101-108Publisher:
- Akademiai Kiado Zrt, Budapest
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Rajić, Nevenka AU - Stojaković, Đorđe AU - Tusar, Nataa Novak PY - 1998 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/184 AB - Thermal investigations and Fenske-Hall SCF MO calculations have been used for studying isomorphous element substitution in the chabazite-like aluminophosphate framework prepared in the presence of tetraethylammonium hydroxide as a template. The thermal measurements show that the temperature at which the template removal occurs increases as the element varies in the Si-Zn-Mn-Co series. The Fenske-Hall SCF MO calculations on model segments of the framework indicate that the trend can be related to an appropriate decrease in basicity of the oxygen atom directly bound to the element. PB - Akademiai Kiado Zrt, Budapest T2 - ACH - Models in Chemistry T1 - Isomorphous element substitution in the chabazite-like aluminophosphate framework EP - 108 IS - 1-2 SP - 101 VL - 135 UR - https://hdl.handle.net/21.15107/rcub_technorep_184 ER -
@article{ author = "Rajić, Nevenka and Stojaković, Đorđe and Tusar, Nataa Novak", year = "1998", abstract = "Thermal investigations and Fenske-Hall SCF MO calculations have been used for studying isomorphous element substitution in the chabazite-like aluminophosphate framework prepared in the presence of tetraethylammonium hydroxide as a template. The thermal measurements show that the temperature at which the template removal occurs increases as the element varies in the Si-Zn-Mn-Co series. The Fenske-Hall SCF MO calculations on model segments of the framework indicate that the trend can be related to an appropriate decrease in basicity of the oxygen atom directly bound to the element.", publisher = "Akademiai Kiado Zrt, Budapest", journal = "ACH - Models in Chemistry", title = "Isomorphous element substitution in the chabazite-like aluminophosphate framework", pages = "108-101", number = "1-2", volume = "135", url = "https://hdl.handle.net/21.15107/rcub_technorep_184" }
Rajić, N., Stojaković, Đ.,& Tusar, N. N.. (1998). Isomorphous element substitution in the chabazite-like aluminophosphate framework. in ACH - Models in Chemistry Akademiai Kiado Zrt, Budapest., 135(1-2), 101-108. https://hdl.handle.net/21.15107/rcub_technorep_184
Rajić N, Stojaković Đ, Tusar NN. Isomorphous element substitution in the chabazite-like aluminophosphate framework. in ACH - Models in Chemistry. 1998;135(1-2):101-108. https://hdl.handle.net/21.15107/rcub_technorep_184 .
Rajić, Nevenka, Stojaković, Đorđe, Tusar, Nataa Novak, "Isomorphous element substitution in the chabazite-like aluminophosphate framework" in ACH - Models in Chemistry, 135, no. 1-2 (1998):101-108, https://hdl.handle.net/21.15107/rcub_technorep_184 .