The application of zeolite nanopowder for the construction of the dense composite polymer membranes for carbon dioxide separation
Authorized Users Only
2012
Authors
Nedeljković, DragutinStajčić, Aleksandar
Grujić, Aleksandar
Stajić-Trošić, Jasna
Zrilić, Milorad
Stevanović, Jasmina
Drmanić, Saša
Article (Published version)
Metadata
Show full item recordAbstract
The main task of the work is to construct the polymeric membrane that could be used for the waste gases treatment. For this purpose, membrane must have high permeability for the carbon dioxide and low permeability of the other gases commonly present in waste gases (hydrogen, oxygen, nitrogen and methane). The constructed membranes were of a dense type, based on a solubility/diffusivity mechanism. In this paper, feasibility of the application of poly(ethyleneoxid)-copoly(phtalamide) was tested. In order to enchase the permeability of carbon dioxide, four different zeolites were added, and in order to improve mechanical stability two different additives were tested. Three zeolites were with the 3-dimensional pores (ZSM5; Faujasite Linde type A) and one was with the 1-dimensional pores (Linde type L). As an additive, n-tetradecyldimethylamonium bromide - n-C14TMABr was tested. The aim of an additive was to provide good wetting of a highly electrically charged zeolite particle by the hydro...phobic polymer chains. The other examined additive was dimethylaminopyridine (DMAP) which should improve the solubility of carbon dioxide due to its alkali properties. The best results in carbon dioxide/hydrogen selectivity and permeability were obtained with the membrane constructed with PEBAX 1657 and surface treated zeolite.
Keywords:
Mixed matrix membrane / Zeolite / Carbon dioxide separation / Polymer matrix / Membrane selectivitySource:
Digest Journal of Nanomaterials and Biostructures, 2012, 7, 1, 269-278Publisher:
- Inst Materials Physics, Bucharest
Funding / projects:
- Predefined functional properties polymer composite materials processes and equipment development (RS-MESTD-Technological Development (TD or TR)-34011)
- Synthesis, processing and applications of nanostructured multifunctional materials with defined properties (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45019)
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Nedeljković, Dragutin AU - Stajčić, Aleksandar AU - Grujić, Aleksandar AU - Stajić-Trošić, Jasna AU - Zrilić, Milorad AU - Stevanović, Jasmina AU - Drmanić, Saša PY - 2012 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1983 AB - The main task of the work is to construct the polymeric membrane that could be used for the waste gases treatment. For this purpose, membrane must have high permeability for the carbon dioxide and low permeability of the other gases commonly present in waste gases (hydrogen, oxygen, nitrogen and methane). The constructed membranes were of a dense type, based on a solubility/diffusivity mechanism. In this paper, feasibility of the application of poly(ethyleneoxid)-copoly(phtalamide) was tested. In order to enchase the permeability of carbon dioxide, four different zeolites were added, and in order to improve mechanical stability two different additives were tested. Three zeolites were with the 3-dimensional pores (ZSM5; Faujasite Linde type A) and one was with the 1-dimensional pores (Linde type L). As an additive, n-tetradecyldimethylamonium bromide - n-C14TMABr was tested. The aim of an additive was to provide good wetting of a highly electrically charged zeolite particle by the hydrophobic polymer chains. The other examined additive was dimethylaminopyridine (DMAP) which should improve the solubility of carbon dioxide due to its alkali properties. The best results in carbon dioxide/hydrogen selectivity and permeability were obtained with the membrane constructed with PEBAX 1657 and surface treated zeolite. PB - Inst Materials Physics, Bucharest T2 - Digest Journal of Nanomaterials and Biostructures T1 - The application of zeolite nanopowder for the construction of the dense composite polymer membranes for carbon dioxide separation EP - 278 IS - 1 SP - 269 VL - 7 UR - https://hdl.handle.net/21.15107/rcub_technorep_1983 ER -
@article{ author = "Nedeljković, Dragutin and Stajčić, Aleksandar and Grujić, Aleksandar and Stajić-Trošić, Jasna and Zrilić, Milorad and Stevanović, Jasmina and Drmanić, Saša", year = "2012", abstract = "The main task of the work is to construct the polymeric membrane that could be used for the waste gases treatment. For this purpose, membrane must have high permeability for the carbon dioxide and low permeability of the other gases commonly present in waste gases (hydrogen, oxygen, nitrogen and methane). The constructed membranes were of a dense type, based on a solubility/diffusivity mechanism. In this paper, feasibility of the application of poly(ethyleneoxid)-copoly(phtalamide) was tested. In order to enchase the permeability of carbon dioxide, four different zeolites were added, and in order to improve mechanical stability two different additives were tested. Three zeolites were with the 3-dimensional pores (ZSM5; Faujasite Linde type A) and one was with the 1-dimensional pores (Linde type L). As an additive, n-tetradecyldimethylamonium bromide - n-C14TMABr was tested. The aim of an additive was to provide good wetting of a highly electrically charged zeolite particle by the hydrophobic polymer chains. The other examined additive was dimethylaminopyridine (DMAP) which should improve the solubility of carbon dioxide due to its alkali properties. The best results in carbon dioxide/hydrogen selectivity and permeability were obtained with the membrane constructed with PEBAX 1657 and surface treated zeolite.", publisher = "Inst Materials Physics, Bucharest", journal = "Digest Journal of Nanomaterials and Biostructures", title = "The application of zeolite nanopowder for the construction of the dense composite polymer membranes for carbon dioxide separation", pages = "278-269", number = "1", volume = "7", url = "https://hdl.handle.net/21.15107/rcub_technorep_1983" }
Nedeljković, D., Stajčić, A., Grujić, A., Stajić-Trošić, J., Zrilić, M., Stevanović, J.,& Drmanić, S.. (2012). The application of zeolite nanopowder for the construction of the dense composite polymer membranes for carbon dioxide separation. in Digest Journal of Nanomaterials and Biostructures Inst Materials Physics, Bucharest., 7(1), 269-278. https://hdl.handle.net/21.15107/rcub_technorep_1983
Nedeljković D, Stajčić A, Grujić A, Stajić-Trošić J, Zrilić M, Stevanović J, Drmanić S. The application of zeolite nanopowder for the construction of the dense composite polymer membranes for carbon dioxide separation. in Digest Journal of Nanomaterials and Biostructures. 2012;7(1):269-278. https://hdl.handle.net/21.15107/rcub_technorep_1983 .
Nedeljković, Dragutin, Stajčić, Aleksandar, Grujić, Aleksandar, Stajić-Trošić, Jasna, Zrilić, Milorad, Stevanović, Jasmina, Drmanić, Saša, "The application of zeolite nanopowder for the construction of the dense composite polymer membranes for carbon dioxide separation" in Digest Journal of Nanomaterials and Biostructures, 7, no. 1 (2012):269-278, https://hdl.handle.net/21.15107/rcub_technorep_1983 .