Mechanochemical preparation and characterization of CaO·ZnO used as catalyst for biodiesel synthesis
Само за регистроване кориснике
2012
Аутори
Kesić, ŽeljkaLukić, Ivana
Brkić, Dragana
Rogan, Jelena
Zdujić, Miodrag
Liu, Hui
Skala, Dejan
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
In this study, the synthesis of biodiesel or fatty acid methyl esters (FAME) from sunflower oil and methanol using CaO center dot ZnO catalyst was investigated. Catalyst was synthesized by ball milling of Ca(OH)(2) and ZnO powder mixture with the addition of water (BMH), as well as solely by ball milling of mentioned powders (BM) and subsequent calcination at 700 degrees C in air atmosphere. For comparison, the CaO center dot ZnO mixed oxide was also prepared using usual coprecipitation procedure (CP) followed by calcination at 700 degrees C of the formed calcium zinc hydroxide hydrate. The BMH, BM and CP catalysts were characterized by X-ray diffraction (XRD), thermogravimetric analysis (TGA), infrared spectroscopy (FTIR), particle size distribution measurement and scanning electron microscopy (SEM and SEM-EDS). In addition, specific surface area (BET), solubility in methanol at 60 degrees C and alkalinity (Hammett indicator method) were also determined. The activity of BMH, BM and CP... catalysts for biodiesel synthesis were tested at 60 degrees C and 1 bar, using molar ratio of sunflower oil to methanol of 1:10 and with 2 wt% of catalyst based on oil weight.
Кључне речи:
Biodiesel / Heterogeneous catalyst / Methanolysis / CaO / ZnOИзвор:
Applied Catalysis A-General, 2012, 427-428, 58-65Издавач:
- Elsevier, Amsterdam
Финансирање / пројекти:
- Наноструктурни функционални и композитни материјали у каталитичким и сорпционим процесима (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45001)
DOI: 10.1016/j.apcata.2012.03.032
ISSN: 0926-860X
WoS: 000304692000008
Scopus: 2-s2.0-84860517577
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Kesić, Željka AU - Lukić, Ivana AU - Brkić, Dragana AU - Rogan, Jelena AU - Zdujić, Miodrag AU - Liu, Hui AU - Skala, Dejan PY - 2012 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2129 AB - In this study, the synthesis of biodiesel or fatty acid methyl esters (FAME) from sunflower oil and methanol using CaO center dot ZnO catalyst was investigated. Catalyst was synthesized by ball milling of Ca(OH)(2) and ZnO powder mixture with the addition of water (BMH), as well as solely by ball milling of mentioned powders (BM) and subsequent calcination at 700 degrees C in air atmosphere. For comparison, the CaO center dot ZnO mixed oxide was also prepared using usual coprecipitation procedure (CP) followed by calcination at 700 degrees C of the formed calcium zinc hydroxide hydrate. The BMH, BM and CP catalysts were characterized by X-ray diffraction (XRD), thermogravimetric analysis (TGA), infrared spectroscopy (FTIR), particle size distribution measurement and scanning electron microscopy (SEM and SEM-EDS). In addition, specific surface area (BET), solubility in methanol at 60 degrees C and alkalinity (Hammett indicator method) were also determined. The activity of BMH, BM and CP catalysts for biodiesel synthesis were tested at 60 degrees C and 1 bar, using molar ratio of sunflower oil to methanol of 1:10 and with 2 wt% of catalyst based on oil weight. PB - Elsevier, Amsterdam T2 - Applied Catalysis A-General T1 - Mechanochemical preparation and characterization of CaO·ZnO used as catalyst for biodiesel synthesis EP - 65 SP - 58 VL - 427-428 DO - 10.1016/j.apcata.2012.03.032 ER -
@article{ author = "Kesić, Željka and Lukić, Ivana and Brkić, Dragana and Rogan, Jelena and Zdujić, Miodrag and Liu, Hui and Skala, Dejan", year = "2012", abstract = "In this study, the synthesis of biodiesel or fatty acid methyl esters (FAME) from sunflower oil and methanol using CaO center dot ZnO catalyst was investigated. Catalyst was synthesized by ball milling of Ca(OH)(2) and ZnO powder mixture with the addition of water (BMH), as well as solely by ball milling of mentioned powders (BM) and subsequent calcination at 700 degrees C in air atmosphere. For comparison, the CaO center dot ZnO mixed oxide was also prepared using usual coprecipitation procedure (CP) followed by calcination at 700 degrees C of the formed calcium zinc hydroxide hydrate. The BMH, BM and CP catalysts were characterized by X-ray diffraction (XRD), thermogravimetric analysis (TGA), infrared spectroscopy (FTIR), particle size distribution measurement and scanning electron microscopy (SEM and SEM-EDS). In addition, specific surface area (BET), solubility in methanol at 60 degrees C and alkalinity (Hammett indicator method) were also determined. The activity of BMH, BM and CP catalysts for biodiesel synthesis were tested at 60 degrees C and 1 bar, using molar ratio of sunflower oil to methanol of 1:10 and with 2 wt% of catalyst based on oil weight.", publisher = "Elsevier, Amsterdam", journal = "Applied Catalysis A-General", title = "Mechanochemical preparation and characterization of CaO·ZnO used as catalyst for biodiesel synthesis", pages = "65-58", volume = "427-428", doi = "10.1016/j.apcata.2012.03.032" }
Kesić, Ž., Lukić, I., Brkić, D., Rogan, J., Zdujić, M., Liu, H.,& Skala, D.. (2012). Mechanochemical preparation and characterization of CaO·ZnO used as catalyst for biodiesel synthesis. in Applied Catalysis A-General Elsevier, Amsterdam., 427-428, 58-65. https://doi.org/10.1016/j.apcata.2012.03.032
Kesić Ž, Lukić I, Brkić D, Rogan J, Zdujić M, Liu H, Skala D. Mechanochemical preparation and characterization of CaO·ZnO used as catalyst for biodiesel synthesis. in Applied Catalysis A-General. 2012;427-428:58-65. doi:10.1016/j.apcata.2012.03.032 .
Kesić, Željka, Lukić, Ivana, Brkić, Dragana, Rogan, Jelena, Zdujić, Miodrag, Liu, Hui, Skala, Dejan, "Mechanochemical preparation and characterization of CaO·ZnO used as catalyst for biodiesel synthesis" in Applied Catalysis A-General, 427-428 (2012):58-65, https://doi.org/10.1016/j.apcata.2012.03.032 . .