Osmotic and activity coefficients of {yK(2)SO(4)+(1-y)Mg(NO3)(2)}(aq) at the temperature T = 298.15 K
Abstract
'The osmotic coefficients of the mixed electrolyte solution {yK(2)SO(4) + (1 - y)Mg(NO3)(2)}(aq) have been measured by the isopiestic method, at the temperature T = 298.15 K. The activity coefficients of K2SO4 and Mg(NO3)(2) were calculated by Scatchard's neutral-electrolyte method and by Fitter and Kim's treatment for mixed electrolyte solutions. The results are used for calculation of the excess Gibbs energy as a function of ionic strength and ionic-strength fraction of K2SO4, and also as a test of Zdanovskii's rule of linearity.
Keywords:
osmotic coefficients / activity coefficientsSource:
Journal of Chemical Thermodynamics, 1998, 30, 7, 847-853Publisher:
- Academic Press Ltd, London
DOI: 10.1006/jcht.1998.0351
ISSN: 0021-9614
WoS: 000075081500006
Scopus: 2-s2.0-0012391922
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Todorović, M. AU - Ninković, Rozalija AU - Miladinović, Jelena PY - 1998 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/215 AB - 'The osmotic coefficients of the mixed electrolyte solution {yK(2)SO(4) + (1 - y)Mg(NO3)(2)}(aq) have been measured by the isopiestic method, at the temperature T = 298.15 K. The activity coefficients of K2SO4 and Mg(NO3)(2) were calculated by Scatchard's neutral-electrolyte method and by Fitter and Kim's treatment for mixed electrolyte solutions. The results are used for calculation of the excess Gibbs energy as a function of ionic strength and ionic-strength fraction of K2SO4, and also as a test of Zdanovskii's rule of linearity. PB - Academic Press Ltd, London T2 - Journal of Chemical Thermodynamics T1 - Osmotic and activity coefficients of {yK(2)SO(4)+(1-y)Mg(NO3)(2)}(aq) at the temperature T = 298.15 K EP - 853 IS - 7 SP - 847 VL - 30 DO - 10.1006/jcht.1998.0351 ER -
@article{ author = "Todorović, M. and Ninković, Rozalija and Miladinović, Jelena", year = "1998", abstract = "'The osmotic coefficients of the mixed electrolyte solution {yK(2)SO(4) + (1 - y)Mg(NO3)(2)}(aq) have been measured by the isopiestic method, at the temperature T = 298.15 K. The activity coefficients of K2SO4 and Mg(NO3)(2) were calculated by Scatchard's neutral-electrolyte method and by Fitter and Kim's treatment for mixed electrolyte solutions. The results are used for calculation of the excess Gibbs energy as a function of ionic strength and ionic-strength fraction of K2SO4, and also as a test of Zdanovskii's rule of linearity.", publisher = "Academic Press Ltd, London", journal = "Journal of Chemical Thermodynamics", title = "Osmotic and activity coefficients of {yK(2)SO(4)+(1-y)Mg(NO3)(2)}(aq) at the temperature T = 298.15 K", pages = "853-847", number = "7", volume = "30", doi = "10.1006/jcht.1998.0351" }
Todorović, M., Ninković, R.,& Miladinović, J.. (1998). Osmotic and activity coefficients of {yK(2)SO(4)+(1-y)Mg(NO3)(2)}(aq) at the temperature T = 298.15 K. in Journal of Chemical Thermodynamics Academic Press Ltd, London., 30(7), 847-853. https://doi.org/10.1006/jcht.1998.0351
Todorović M, Ninković R, Miladinović J. Osmotic and activity coefficients of {yK(2)SO(4)+(1-y)Mg(NO3)(2)}(aq) at the temperature T = 298.15 K. in Journal of Chemical Thermodynamics. 1998;30(7):847-853. doi:10.1006/jcht.1998.0351 .
Todorović, M., Ninković, Rozalija, Miladinović, Jelena, "Osmotic and activity coefficients of {yK(2)SO(4)+(1-y)Mg(NO3)(2)}(aq) at the temperature T = 298.15 K" in Journal of Chemical Thermodynamics, 30, no. 7 (1998):847-853, https://doi.org/10.1006/jcht.1998.0351 . .