ABA type block copolymers of poly(monobutyl itaconate) and poly(monocyclohexyl itaconate) with poly(dimethylsiloxane): Synthesis and characterization
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2000
Authors
Cvetkovska, MKoseva, S
Buzarovska, A
Baysal, BM
Yasar, B
Karal-Yilmaz, O
Popović, Ivanka
Katsikas, Lynne
Article (Published version)
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Monoesters of itaconic acid (monobutyl itaconate and monocyclohexyl itaconate) were synthesized and used as monomers. Poly(monobutyl itaconate) (PMBI) and poly(monocyclohexyl itaconate) (PMCHI) were prepared by free radical polymerization of these monomers using tert-butyl hydroperoxide as initiator. Subsequently, ABA type block copolymers where the A block is PMBI or PMCHI and the B block is poly(dimethyl siloxane) (PDMS) were synthesized by free radical polymerization using a macroinitiator (diperoxycarbamate) containing PDMS units. The structural formulae of the products were confirmed by spectral analysis. The molecular weights of the products are not high. Therefore the mechanical and physical properties are rather poor. However, porous structures of copolymers are observed by means of SEM.
Source:
Macromolecular Chemistry and Physics, 2000, 201, 6, 685-693Publisher:
- Wiley-VCH Verlag Gmbh, Weinheim
DOI: 10.1002/(sici)1521-3935(20000301)201:6685::aid-macp6853.3.co;2-9
ISSN: 1022-1352
WoS: 000086608900010
Scopus: 2-s2.0-0012656447
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Cvetkovska, M AU - Koseva, S AU - Buzarovska, A AU - Baysal, BM AU - Yasar, B AU - Karal-Yilmaz, O AU - Popović, Ivanka AU - Katsikas, Lynne PY - 2000 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/278 AB - Monoesters of itaconic acid (monobutyl itaconate and monocyclohexyl itaconate) were synthesized and used as monomers. Poly(monobutyl itaconate) (PMBI) and poly(monocyclohexyl itaconate) (PMCHI) were prepared by free radical polymerization of these monomers using tert-butyl hydroperoxide as initiator. Subsequently, ABA type block copolymers where the A block is PMBI or PMCHI and the B block is poly(dimethyl siloxane) (PDMS) were synthesized by free radical polymerization using a macroinitiator (diperoxycarbamate) containing PDMS units. The structural formulae of the products were confirmed by spectral analysis. The molecular weights of the products are not high. Therefore the mechanical and physical properties are rather poor. However, porous structures of copolymers are observed by means of SEM. PB - Wiley-VCH Verlag Gmbh, Weinheim T2 - Macromolecular Chemistry and Physics T1 - ABA type block copolymers of poly(monobutyl itaconate) and poly(monocyclohexyl itaconate) with poly(dimethylsiloxane): Synthesis and characterization EP - 693 IS - 6 SP - 685 VL - 201 DO - 10.1002/(sici)1521-3935(20000301)201:6685::aid-macp6853.3.co;2-9 ER -
@article{ author = "Cvetkovska, M and Koseva, S and Buzarovska, A and Baysal, BM and Yasar, B and Karal-Yilmaz, O and Popović, Ivanka and Katsikas, Lynne", year = "2000", abstract = "Monoesters of itaconic acid (monobutyl itaconate and monocyclohexyl itaconate) were synthesized and used as monomers. Poly(monobutyl itaconate) (PMBI) and poly(monocyclohexyl itaconate) (PMCHI) were prepared by free radical polymerization of these monomers using tert-butyl hydroperoxide as initiator. Subsequently, ABA type block copolymers where the A block is PMBI or PMCHI and the B block is poly(dimethyl siloxane) (PDMS) were synthesized by free radical polymerization using a macroinitiator (diperoxycarbamate) containing PDMS units. The structural formulae of the products were confirmed by spectral analysis. The molecular weights of the products are not high. Therefore the mechanical and physical properties are rather poor. However, porous structures of copolymers are observed by means of SEM.", publisher = "Wiley-VCH Verlag Gmbh, Weinheim", journal = "Macromolecular Chemistry and Physics", title = "ABA type block copolymers of poly(monobutyl itaconate) and poly(monocyclohexyl itaconate) with poly(dimethylsiloxane): Synthesis and characterization", pages = "693-685", number = "6", volume = "201", doi = "10.1002/(sici)1521-3935(20000301)201:6685::aid-macp6853.3.co;2-9" }
Cvetkovska, M., Koseva, S., Buzarovska, A., Baysal, B., Yasar, B., Karal-Yilmaz, O., Popović, I.,& Katsikas, L.. (2000). ABA type block copolymers of poly(monobutyl itaconate) and poly(monocyclohexyl itaconate) with poly(dimethylsiloxane): Synthesis and characterization. in Macromolecular Chemistry and Physics Wiley-VCH Verlag Gmbh, Weinheim., 201(6), 685-693. https://doi.org/10.1002/(sici)1521-3935(20000301)201:6685::aid-macp6853.3.co;2-9
Cvetkovska M, Koseva S, Buzarovska A, Baysal B, Yasar B, Karal-Yilmaz O, Popović I, Katsikas L. ABA type block copolymers of poly(monobutyl itaconate) and poly(monocyclohexyl itaconate) with poly(dimethylsiloxane): Synthesis and characterization. in Macromolecular Chemistry and Physics. 2000;201(6):685-693. doi:10.1002/(sici)1521-3935(20000301)201:6685::aid-macp6853.3.co;2-9 .
Cvetkovska, M, Koseva, S, Buzarovska, A, Baysal, BM, Yasar, B, Karal-Yilmaz, O, Popović, Ivanka, Katsikas, Lynne, "ABA type block copolymers of poly(monobutyl itaconate) and poly(monocyclohexyl itaconate) with poly(dimethylsiloxane): Synthesis and characterization" in Macromolecular Chemistry and Physics, 201, no. 6 (2000):685-693, https://doi.org/10.1002/(sici)1521-3935(20000301)201:6685::aid-macp6853.3.co;2-9 . .