Waste Lard Methanolysis Catalyzed by KOH at Moderate Temperatures
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2016
Authors
Stojković, IvanBanković-Ilić, Ivana B.
Velicković, Ana V.
Avramović, Jelena M.
Stamenković, Olivera S.
Povrenović, Dragan
Veljković, Vlada B.
Article (Published version)
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Show full item recordAbstract
The KOH-catalyzed methanolysis of waste lard from piglet roasting in a moderate temperature range was investigated in order to establish the reaction kinetics. For comparison, lard and thermally treated lard were also included in the study. All three reactions occurred via a pseudo-homogeneous regime where the chemical reaction controlled the overall process kinetics. A simple kinetic model comprising the irreversible pseudo-first-order reaction was demonstrated for all three fatty feedstocks. The reaction rate constant increases with raising the fatty acid unsaturation degree. The final products satisfied the EN 14214 biodiesel standard specifications.
Keywords:
Biodiesel / Methanolysis / Reaction kinetics / Waste lardSource:
Chemical Engineering & Technology, 2016, 39, 4, 741-750Publisher:
- Wiley-VCH Verlag Gmbh, Weinheim
Funding / projects:
- Nanostructured Functional and Composite Materials in Catalytic and Sorption Processes (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45001)
DOI: 10.1002/ceat.201400705
ISSN: 0930-7516
WoS: 000372958300018
Scopus: 2-s2.0-84962248369
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Tehnološko-metalurški fakultetTY - JOUR AU - Stojković, Ivan AU - Banković-Ilić, Ivana B. AU - Velicković, Ana V. AU - Avramović, Jelena M. AU - Stamenković, Olivera S. AU - Povrenović, Dragan AU - Veljković, Vlada B. PY - 2016 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3424 AB - The KOH-catalyzed methanolysis of waste lard from piglet roasting in a moderate temperature range was investigated in order to establish the reaction kinetics. For comparison, lard and thermally treated lard were also included in the study. All three reactions occurred via a pseudo-homogeneous regime where the chemical reaction controlled the overall process kinetics. A simple kinetic model comprising the irreversible pseudo-first-order reaction was demonstrated for all three fatty feedstocks. The reaction rate constant increases with raising the fatty acid unsaturation degree. The final products satisfied the EN 14214 biodiesel standard specifications. PB - Wiley-VCH Verlag Gmbh, Weinheim T2 - Chemical Engineering & Technology T1 - Waste Lard Methanolysis Catalyzed by KOH at Moderate Temperatures EP - 750 IS - 4 SP - 741 VL - 39 DO - 10.1002/ceat.201400705 ER -
@article{ author = "Stojković, Ivan and Banković-Ilić, Ivana B. and Velicković, Ana V. and Avramović, Jelena M. and Stamenković, Olivera S. and Povrenović, Dragan and Veljković, Vlada B.", year = "2016", abstract = "The KOH-catalyzed methanolysis of waste lard from piglet roasting in a moderate temperature range was investigated in order to establish the reaction kinetics. For comparison, lard and thermally treated lard were also included in the study. All three reactions occurred via a pseudo-homogeneous regime where the chemical reaction controlled the overall process kinetics. A simple kinetic model comprising the irreversible pseudo-first-order reaction was demonstrated for all three fatty feedstocks. The reaction rate constant increases with raising the fatty acid unsaturation degree. The final products satisfied the EN 14214 biodiesel standard specifications.", publisher = "Wiley-VCH Verlag Gmbh, Weinheim", journal = "Chemical Engineering & Technology", title = "Waste Lard Methanolysis Catalyzed by KOH at Moderate Temperatures", pages = "750-741", number = "4", volume = "39", doi = "10.1002/ceat.201400705" }
Stojković, I., Banković-Ilić, I. B., Velicković, A. V., Avramović, J. M., Stamenković, O. S., Povrenović, D.,& Veljković, V. B.. (2016). Waste Lard Methanolysis Catalyzed by KOH at Moderate Temperatures. in Chemical Engineering & Technology Wiley-VCH Verlag Gmbh, Weinheim., 39(4), 741-750. https://doi.org/10.1002/ceat.201400705
Stojković I, Banković-Ilić IB, Velicković AV, Avramović JM, Stamenković OS, Povrenović D, Veljković VB. Waste Lard Methanolysis Catalyzed by KOH at Moderate Temperatures. in Chemical Engineering & Technology. 2016;39(4):741-750. doi:10.1002/ceat.201400705 .
Stojković, Ivan, Banković-Ilić, Ivana B., Velicković, Ana V., Avramović, Jelena M., Stamenković, Olivera S., Povrenović, Dragan, Veljković, Vlada B., "Waste Lard Methanolysis Catalyzed by KOH at Moderate Temperatures" in Chemical Engineering & Technology, 39, no. 4 (2016):741-750, https://doi.org/10.1002/ceat.201400705 . .