Electrospun Poly(styrene) Fibers as a Protection for the First- and the Second-Generation Grubbs' Catalyst
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Radović, Ivana M.Stojanović, Dušica
Kojović, Aleksandar
Petrović, Miloš
Uskoković, Petar
Radojević, Vesna
Aleksić, Radoslav
Article (Published version)
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The study presents a novel method for protection of the first- and the second-generation Grubbs' catalyst, by incorporation in poly(styrene) fibers through electrospinning technique. Both catalysts are sensitive to the presence of the amine hardeners in the epoxy-based self-healing composites and require protection from deactivation to retain their ability to promote polymerization reaction of the healing agent. Comparison of healing efficiencies of both catalysts suggested that poly(styrene) fibers offer better protection and dispersion for the first-generation Grubbs' catalyst, although all the samples exhibited high-healing efficiency. Difference in stereoselectivity between two catalysts was also indicated. [GRAPHICS] .
Keywords:
Electrospun fibers / Grubbs' catalyst / impact behavior / self-healingSource:
Polymer-Plastics Technology and Engineering, 2017, 56, 11, 1188-1195Publisher:
- Taylor & Francis Inc, Philadelphia
Funding / projects:
- Predefined functional properties polymer composite materials processes and equipment development (RS-MESTD-Technological Development (TD or TR)-34011)
- Synthesis, processing and applications of nanostructured multifunctional materials with defined properties (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45019)
DOI: 10.1080/03602559.2016.1260734
ISSN: 0360-2559
WoS: 000404904900005
Scopus: 2-s2.0-85017190111
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Radović, Ivana M. AU - Stojanović, Dušica AU - Kojović, Aleksandar AU - Petrović, Miloš AU - Uskoković, Petar AU - Radojević, Vesna AU - Aleksić, Radoslav PY - 2017 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3719 AB - The study presents a novel method for protection of the first- and the second-generation Grubbs' catalyst, by incorporation in poly(styrene) fibers through electrospinning technique. Both catalysts are sensitive to the presence of the amine hardeners in the epoxy-based self-healing composites and require protection from deactivation to retain their ability to promote polymerization reaction of the healing agent. Comparison of healing efficiencies of both catalysts suggested that poly(styrene) fibers offer better protection and dispersion for the first-generation Grubbs' catalyst, although all the samples exhibited high-healing efficiency. Difference in stereoselectivity between two catalysts was also indicated. [GRAPHICS] . PB - Taylor & Francis Inc, Philadelphia T2 - Polymer-Plastics Technology and Engineering T1 - Electrospun Poly(styrene) Fibers as a Protection for the First- and the Second-Generation Grubbs' Catalyst EP - 1195 IS - 11 SP - 1188 VL - 56 DO - 10.1080/03602559.2016.1260734 ER -
@article{ author = "Radović, Ivana M. and Stojanović, Dušica and Kojović, Aleksandar and Petrović, Miloš and Uskoković, Petar and Radojević, Vesna and Aleksić, Radoslav", year = "2017", abstract = "The study presents a novel method for protection of the first- and the second-generation Grubbs' catalyst, by incorporation in poly(styrene) fibers through electrospinning technique. Both catalysts are sensitive to the presence of the amine hardeners in the epoxy-based self-healing composites and require protection from deactivation to retain their ability to promote polymerization reaction of the healing agent. Comparison of healing efficiencies of both catalysts suggested that poly(styrene) fibers offer better protection and dispersion for the first-generation Grubbs' catalyst, although all the samples exhibited high-healing efficiency. Difference in stereoselectivity between two catalysts was also indicated. [GRAPHICS] .", publisher = "Taylor & Francis Inc, Philadelphia", journal = "Polymer-Plastics Technology and Engineering", title = "Electrospun Poly(styrene) Fibers as a Protection for the First- and the Second-Generation Grubbs' Catalyst", pages = "1195-1188", number = "11", volume = "56", doi = "10.1080/03602559.2016.1260734" }
Radović, I. M., Stojanović, D., Kojović, A., Petrović, M., Uskoković, P., Radojević, V.,& Aleksić, R.. (2017). Electrospun Poly(styrene) Fibers as a Protection for the First- and the Second-Generation Grubbs' Catalyst. in Polymer-Plastics Technology and Engineering Taylor & Francis Inc, Philadelphia., 56(11), 1188-1195. https://doi.org/10.1080/03602559.2016.1260734
Radović IM, Stojanović D, Kojović A, Petrović M, Uskoković P, Radojević V, Aleksić R. Electrospun Poly(styrene) Fibers as a Protection for the First- and the Second-Generation Grubbs' Catalyst. in Polymer-Plastics Technology and Engineering. 2017;56(11):1188-1195. doi:10.1080/03602559.2016.1260734 .
Radović, Ivana M., Stojanović, Dušica, Kojović, Aleksandar, Petrović, Miloš, Uskoković, Petar, Radojević, Vesna, Aleksić, Radoslav, "Electrospun Poly(styrene) Fibers as a Protection for the First- and the Second-Generation Grubbs' Catalyst" in Polymer-Plastics Technology and Engineering, 56, no. 11 (2017):1188-1195, https://doi.org/10.1080/03602559.2016.1260734 . .