Comparison of two polymeric transition metal complexes with 1,4-benzenedicarboxylate ions as bridging ligands, [Co(C8H4O4)(C12H8N2)(H2O)] and [Cu(C8H4O4)(C10H9N3)] center dot H2O
dc.creator | Karanović, Ljiljana | |
dc.creator | Poleti, Dejan | |
dc.creator | Rogan, Jelena | |
dc.creator | Bogdanović, Goran A. | |
dc.creator | Spasojević-de Bire, Anne | |
dc.date.accessioned | 2021-03-10T10:00:51Z | |
dc.date.available | 2021-03-10T10:00:51Z | |
dc.date.issued | 2002 | |
dc.identifier.issn | 2053-2296 | |
dc.identifier.uri | http://TechnoRep.tmf.bg.ac.rs/handle/123456789/437 | |
dc.description.abstract | The title complexes, catena-poly[[aqua(1,10-phenanthroline- kappa(2)N,N')cobalt(II)]-mu-benzene-1,4-dicarboxylato-kappa(2)O(1):O-4], [Co(C8H4O4)(C12H8N2)(H2O)], (I), and catena-poly[[[(di-2-pyridyl-kappaN-amine)copper(II)]-mu-benzene-1,4-dicarboxylato- kappa(4)O(1), O-1' :O-4,O-4'] hydrate], [Cu(C8H4O4)(C10H9N3)].H2O, (II), take the form of zigzag chains, with the 1,4-benzenedicarboxylate ion acting as an amphimonodentate ligand in (I) and a bis-bidentate ligand in (II). The Co-II ion in (I) is five-coordinate and has a distorted trigonal-bipyramidal geometry. The Cu-II ion in (II) is in a very distorted octahedral 4+2 environment, with the octahedron elongated along the trans O-Cu-O bonds and with a trans O-Cu-O angle of only 137.22 (8)degrees. | en |
dc.publisher | Int Union Crystallography, Chester | |
dc.rights | restrictedAccess | |
dc.source | Acta Crystallographica Section C-Structural Chemistry | |
dc.title | Comparison of two polymeric transition metal complexes with 1,4-benzenedicarboxylate ions as bridging ligands, [Co(C8H4O4)(C12H8N2)(H2O)] and [Cu(C8H4O4)(C10H9N3)] center dot H2O | en |
dc.type | article | |
dc.rights.license | ARR | |
dc.citation.epage | m279 | |
dc.citation.other | 58: m275-m279 | |
dc.citation.spage | m275 | |
dc.citation.volume | 58 | |
dc.identifier.doi | 10.1107/S0108270102004341 | |
dc.identifier.pmid | 11983964 | |
dc.identifier.scopus | 2-s2.0-0036588028 | |
dc.identifier.wos | 000175316400008 | |
dc.type.version | publishedVersion |