Reinvestigation of Sr2 [Cu(OH)6]
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
During an investigation of the SrO-CuO-P2O5-H 2O system, single crystals of distrontium hexa-hydroxido-cuprate(II), Sr2 [Cu(OH) 6], were obtained by the hydro-thermal method. The blue prismatic crystals of Sr2 [Cu(OH) 6] adopt the same structure type as Ba2 [Cu(OH) 6], Sr 2 [Zn(OH) 6] and Ba2 [Zn(OH) 6]. The Cu atoms, located at (0, 0, 1/2 ) (site symmetry ), form /mutually isolated and highly elongated Cu(OH) 6 octa-hedra, which are inter-connected to slightly distorted Sr(OH) 6 trigonal prisms, forming a layered structure. The location of H atoms from difference Fourier maps and their refinement allowed the precise determination of a three-dimensional hydrogen-bonding network in which all hy-drox-ide O atoms are involved. In addition, the hydrogen-bonding topologies in Sr2 [Cu(OH) 6] and other similar hexa-hydroxido-metallates with the general formulae M1[M2(OH) 6], M12 [M2(OH) 6] and M13 [M2(OH) 6] were analysed in detail.
Izvor:
Acta Crystallographica Section C: Crystal Structure Communications, 2009, 65, 8, i48-i51Izdavač:
- International Union of Crystallography
Finansiranje / projekti:
- Strukturna i funkcionalna hemija nekih prelaznih i postprelaznih elemenata (RS-MESTD-MPN2006-2010-142030)
DOI: 10.1107/S0108270109021519
ISSN: 0108-2701
WoS: 000268483200002
Scopus: 2-s2.0-68649118364
Institucija/grupa
Tehnološko-metalurški fakultetTY - JOUR AU - Šutović, Sabina AU - Karanović, Ljiljana AU - Poleti, Dejan PY - 2009 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5547 AB - During an investigation of the SrO-CuO-P2O5-H 2O system, single crystals of distrontium hexa-hydroxido-cuprate(II), Sr2 [Cu(OH) 6], were obtained by the hydro-thermal method. The blue prismatic crystals of Sr2 [Cu(OH) 6] adopt the same structure type as Ba2 [Cu(OH) 6], Sr 2 [Zn(OH) 6] and Ba2 [Zn(OH) 6]. The Cu atoms, located at (0, 0, 1/2 ) (site symmetry ), form /mutually isolated and highly elongated Cu(OH) 6 octa-hedra, which are inter-connected to slightly distorted Sr(OH) 6 trigonal prisms, forming a layered structure. The location of H atoms from difference Fourier maps and their refinement allowed the precise determination of a three-dimensional hydrogen-bonding network in which all hy-drox-ide O atoms are involved. In addition, the hydrogen-bonding topologies in Sr2 [Cu(OH) 6] and other similar hexa-hydroxido-metallates with the general formulae M1[M2(OH) 6], M12 [M2(OH) 6] and M13 [M2(OH) 6] were analysed in detail. PB - International Union of Crystallography T2 - Acta Crystallographica Section C: Crystal Structure Communications T1 - Reinvestigation of Sr2 [Cu(OH)6] EP - i51 IS - 8 SP - i48 VL - 65 DO - 10.1107/S0108270109021519 ER -
@article{ author = "Šutović, Sabina and Karanović, Ljiljana and Poleti, Dejan", year = "2009", abstract = "During an investigation of the SrO-CuO-P2O5-H 2O system, single crystals of distrontium hexa-hydroxido-cuprate(II), Sr2 [Cu(OH) 6], were obtained by the hydro-thermal method. The blue prismatic crystals of Sr2 [Cu(OH) 6] adopt the same structure type as Ba2 [Cu(OH) 6], Sr 2 [Zn(OH) 6] and Ba2 [Zn(OH) 6]. The Cu atoms, located at (0, 0, 1/2 ) (site symmetry ), form /mutually isolated and highly elongated Cu(OH) 6 octa-hedra, which are inter-connected to slightly distorted Sr(OH) 6 trigonal prisms, forming a layered structure. The location of H atoms from difference Fourier maps and their refinement allowed the precise determination of a three-dimensional hydrogen-bonding network in which all hy-drox-ide O atoms are involved. In addition, the hydrogen-bonding topologies in Sr2 [Cu(OH) 6] and other similar hexa-hydroxido-metallates with the general formulae M1[M2(OH) 6], M12 [M2(OH) 6] and M13 [M2(OH) 6] were analysed in detail.", publisher = "International Union of Crystallography", journal = "Acta Crystallographica Section C: Crystal Structure Communications", title = "Reinvestigation of Sr2 [Cu(OH)6]", pages = "i51-i48", number = "8", volume = "65", doi = "10.1107/S0108270109021519" }
Šutović, S., Karanović, L.,& Poleti, D.. (2009). Reinvestigation of Sr2 [Cu(OH)6]. in Acta Crystallographica Section C: Crystal Structure Communications International Union of Crystallography., 65(8), i48-i51. https://doi.org/10.1107/S0108270109021519
Šutović S, Karanović L, Poleti D. Reinvestigation of Sr2 [Cu(OH)6]. in Acta Crystallographica Section C: Crystal Structure Communications. 2009;65(8):i48-i51. doi:10.1107/S0108270109021519 .
Šutović, Sabina, Karanović, Ljiljana, Poleti, Dejan, "Reinvestigation of Sr2 [Cu(OH)6]" in Acta Crystallographica Section C: Crystal Structure Communications, 65, no. 8 (2009):i48-i51, https://doi.org/10.1107/S0108270109021519 . .