New inorganic-organic hybrid: Synthesis and structural characterization of an alumino(oxalato)phosphate
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2003
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A new 3-D alumino(oxalato)phosphate, [H3NCH(CH3)CH2NH3](2)[Al4P6O20(OH)(4)(C2O4)(H2O)], consists of aluminophosphate layers which are pillared by oxalate anions. It contains a hybrid 12-membered channel where guest species, diprotonated 1,2-diaminopropane and water molecules, are found. The layers are composed of AlO6, AlO4, and PO4 polyhedra giving double chains, which are interconnected through Al-O-P-O-Al bridges. Oxalate ions are quadridentately bonded by participating in the coordination of AlO6 and by bridging the aluminophosphate layers. The guest species strongly interact with the alumino(oxalato)phosphate layers which is evidenced by solid-state NMR spectroscopy. Crystal data are: triclinic, space group P (1) over bar, a = 8.611(1) Angstrom, b = 9.096(1) Angstrom, c = 11.371(1) Angstrom, alpha = 104.811(1)degrees, beta = 111.368(1)degrees, and gamma = 94.248(1)degrees, V = 787.9(1) Angstrom(3), and R = 0.041.
Izvor:
Chemistry of Materials, 2003, 15, 8, 1734-1738Izdavač:
- Amer Chemical Soc, Washington
DOI: 10.1021/cm021343u
ISSN: 0897-4756
WoS: 000182381300024
Scopus: 2-s2.0-0037461235
Institucija/grupa
Tehnološko-metalurški fakultetTY - JOUR AU - Rajić, Nevenka AU - Zabukovec-Logar, Nataša AU - Mali, Gregor AU - Kaučič, Venčeslav PY - 2003 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/563 AB - A new 3-D alumino(oxalato)phosphate, [H3NCH(CH3)CH2NH3](2)[Al4P6O20(OH)(4)(C2O4)(H2O)], consists of aluminophosphate layers which are pillared by oxalate anions. It contains a hybrid 12-membered channel where guest species, diprotonated 1,2-diaminopropane and water molecules, are found. The layers are composed of AlO6, AlO4, and PO4 polyhedra giving double chains, which are interconnected through Al-O-P-O-Al bridges. Oxalate ions are quadridentately bonded by participating in the coordination of AlO6 and by bridging the aluminophosphate layers. The guest species strongly interact with the alumino(oxalato)phosphate layers which is evidenced by solid-state NMR spectroscopy. Crystal data are: triclinic, space group P (1) over bar, a = 8.611(1) Angstrom, b = 9.096(1) Angstrom, c = 11.371(1) Angstrom, alpha = 104.811(1)degrees, beta = 111.368(1)degrees, and gamma = 94.248(1)degrees, V = 787.9(1) Angstrom(3), and R = 0.041. PB - Amer Chemical Soc, Washington T2 - Chemistry of Materials T1 - New inorganic-organic hybrid: Synthesis and structural characterization of an alumino(oxalato)phosphate EP - 1738 IS - 8 SP - 1734 VL - 15 DO - 10.1021/cm021343u ER -
@article{ author = "Rajić, Nevenka and Zabukovec-Logar, Nataša and Mali, Gregor and Kaučič, Venčeslav", year = "2003", abstract = "A new 3-D alumino(oxalato)phosphate, [H3NCH(CH3)CH2NH3](2)[Al4P6O20(OH)(4)(C2O4)(H2O)], consists of aluminophosphate layers which are pillared by oxalate anions. It contains a hybrid 12-membered channel where guest species, diprotonated 1,2-diaminopropane and water molecules, are found. The layers are composed of AlO6, AlO4, and PO4 polyhedra giving double chains, which are interconnected through Al-O-P-O-Al bridges. Oxalate ions are quadridentately bonded by participating in the coordination of AlO6 and by bridging the aluminophosphate layers. The guest species strongly interact with the alumino(oxalato)phosphate layers which is evidenced by solid-state NMR spectroscopy. Crystal data are: triclinic, space group P (1) over bar, a = 8.611(1) Angstrom, b = 9.096(1) Angstrom, c = 11.371(1) Angstrom, alpha = 104.811(1)degrees, beta = 111.368(1)degrees, and gamma = 94.248(1)degrees, V = 787.9(1) Angstrom(3), and R = 0.041.", publisher = "Amer Chemical Soc, Washington", journal = "Chemistry of Materials", title = "New inorganic-organic hybrid: Synthesis and structural characterization of an alumino(oxalato)phosphate", pages = "1738-1734", number = "8", volume = "15", doi = "10.1021/cm021343u" }
Rajić, N., Zabukovec-Logar, N., Mali, G.,& Kaučič, V.. (2003). New inorganic-organic hybrid: Synthesis and structural characterization of an alumino(oxalato)phosphate. in Chemistry of Materials Amer Chemical Soc, Washington., 15(8), 1734-1738. https://doi.org/10.1021/cm021343u
Rajić N, Zabukovec-Logar N, Mali G, Kaučič V. New inorganic-organic hybrid: Synthesis and structural characterization of an alumino(oxalato)phosphate. in Chemistry of Materials. 2003;15(8):1734-1738. doi:10.1021/cm021343u .
Rajić, Nevenka, Zabukovec-Logar, Nataša, Mali, Gregor, Kaučič, Venčeslav, "New inorganic-organic hybrid: Synthesis and structural characterization of an alumino(oxalato)phosphate" in Chemistry of Materials, 15, no. 8 (2003):1734-1738, https://doi.org/10.1021/cm021343u . .