Methanol Sensing by a Luminescent Zinc(II)-Based Metal−Organic Framework
dc.creator | Durini, Sara | |
dc.creator | Ilić, Nebojša | |
dc.creator | Ramazanova, Kyzgaldak | |
dc.creator | Grell, Toni | |
dc.creator | Lönnecke, Peter | |
dc.creator | Hey-Hawkins, Evamarie | |
dc.date.accessioned | 2023-02-24T12:28:37Z | |
dc.date.available | 2023-02-24T12:28:37Z | |
dc.date.issued | 2019 | |
dc.identifier.issn | 2192-6506 | |
dc.identifier.uri | http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5907 | |
dc.description.abstract | A luminescent zinc-based metal-organic framework (MOF; 1) was synthesized from a highly conjugated tridentate ligand, 1,3,5-tris[(1E)-2′-(4′′-benzoic acid)vinyl]benzene. X-ray single crystal analysis reveals the organization of 1 in a three-dimensional porous framework. Thermogravimetric analysis shows that 1 has a good thermal stability, and resists decomposition up to 420 °C. The removal of the solvent molecules from the cavities leads to a temporary loss of crystallinity, which can be regained by heating the MOF in diethylformamide, the solvent used for the synthesis, as shown by powder X-ray diffraction. In addition, 1 shows luminescent features influenced by the chemical environment, making it suitable as optical sensor. Detection of methanol with a turn-on effect was possible in low concentration in mixtures with water (50 μL/3 mL and 10 μL/3 mL) and as vapor. | sr |
dc.language.iso | en | sr |
dc.publisher | Wiley-VCH Verlag | sr |
dc.rights | restrictedAccess | sr |
dc.source | ChemPlusChem | sr |
dc.subject | luminescence | sr |
dc.subject | metal-organic frameworks | sr |
dc.subject | methanol | sr |
dc.subject | sensors | sr |
dc.subject | zinc | sr |
dc.title | Methanol Sensing by a Luminescent Zinc(II)-Based Metal−Organic Framework | sr |
dc.type | article | sr |
dc.rights.license | ARR | sr |
dc.citation.epage | 313 | |
dc.citation.issue | 3 | |
dc.citation.rank | M22 | |
dc.citation.spage | 307 | |
dc.citation.volume | 84 | |
dc.identifier.doi | 10.1002/cplu.201900109 | |
dc.identifier.scopus | 2-s2.0-85063626904 | |
dc.identifier.wos | 000462768700012 | |
dc.type.version | publishedVersion | sr |