Ciprofloxacin removal using sepiolite-based adsorbents
Аутори
Marjanović, VesnaJanković-Častvan, Ivona
Lazarević, Slavica
Radovanović, Željko
Janaćković, Đorđe
Petrović, Rada
Конференцијски прилог (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Ciprofloxacin (CIP) as a broad-spectrum quinolone antibiotic is extensively used in daily life and can be detected in municipal and pharmaceutical wastewaters, as well as natural waters. In this study, natural mineral sepiolite (SEP), SEP modified with hexadecyltrimethylammonium-bromide (HDAB) and SEP composites with graphene oxide (GO) were used as adsorbents for the removal of CIP from aqueous solutions. The composites were prepared at a mass ratio SEP to GO of 2 : 1, using SEP and SEP modified by [3-(2-aminoethylamino)propyl]trimethoxy-silane (APT). Thermogravimetric analysis, X-ray diffraction and nitrogen adsorption-desorption were used to characterize the obtained adsorbents. The adsorption of CIP was investigated at the pH value close to pH of natural waters. The concentration of CIP in aqueous solution was determined by UV-Vis spectroscopy. GO showed the highest adsorption capacity (~ 150 mg/g). The capacity of SEP was about 60 mg/g, while the SEP modification with HDAB has led... to a decrease in the adsorption capacity (~ 35 mg/g). The composite SEP/GO showed the higher adsorption capacity (~ 110 mg/g) than the composite SEP-APT/GO (~ 40 mg/g). The capacity of the composite SEP/GO was higher than of mixture of SEP and GO, which indicated a certain degree of GO exfoliation and intecalation of sepiolie particles, as it was shown by X-ray diffraction. Equilibrium data for all adsorbents, except for HDAB modified sepiolite, fitted well to the Langmuir isotherm model.
Кључне речи:
Adsorption, Ciprofloxacin, Sepiolite, Graphene oxideИзвор:
2nd International Conference on Advanced Production and Processing, Book of abstracts, 2022, 218-Издавач:
- University of Novi Sad, Faculty of Technology Novi Sad
Финансирање / пројекти:
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200287 (Иновациони центар Технолошко-металуршког факултета у Београду доо) (RS-MESTD-inst-2020-200287)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200135 (Универзитет у Београду, Технолошко-металуршки факултет) (RS-MESTD-inst-2020-200135)
Колекције
Институција/група
Tehnološko-metalurški fakultetTY - CONF AU - Marjanović, Vesna AU - Janković-Častvan, Ivona AU - Lazarević, Slavica AU - Radovanović, Željko AU - Janaćković, Đorđe AU - Petrović, Rada PY - 2022 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5920 AB - Ciprofloxacin (CIP) as a broad-spectrum quinolone antibiotic is extensively used in daily life and can be detected in municipal and pharmaceutical wastewaters, as well as natural waters. In this study, natural mineral sepiolite (SEP), SEP modified with hexadecyltrimethylammonium-bromide (HDAB) and SEP composites with graphene oxide (GO) were used as adsorbents for the removal of CIP from aqueous solutions. The composites were prepared at a mass ratio SEP to GO of 2 : 1, using SEP and SEP modified by [3-(2-aminoethylamino)propyl]trimethoxy-silane (APT). Thermogravimetric analysis, X-ray diffraction and nitrogen adsorption-desorption were used to characterize the obtained adsorbents. The adsorption of CIP was investigated at the pH value close to pH of natural waters. The concentration of CIP in aqueous solution was determined by UV-Vis spectroscopy. GO showed the highest adsorption capacity (~ 150 mg/g). The capacity of SEP was about 60 mg/g, while the SEP modification with HDAB has led to a decrease in the adsorption capacity (~ 35 mg/g). The composite SEP/GO showed the higher adsorption capacity (~ 110 mg/g) than the composite SEP-APT/GO (~ 40 mg/g). The capacity of the composite SEP/GO was higher than of mixture of SEP and GO, which indicated a certain degree of GO exfoliation and intecalation of sepiolie particles, as it was shown by X-ray diffraction. Equilibrium data for all adsorbents, except for HDAB modified sepiolite, fitted well to the Langmuir isotherm model. PB - University of Novi Sad, Faculty of Technology Novi Sad C3 - 2nd International Conference on Advanced Production and Processing, Book of abstracts T1 - Ciprofloxacin removal using sepiolite-based adsorbents SP - 218 SP - 218 UR - https://hdl.handle.net/21.15107/rcub_technorep_5920 ER -
@conference{ author = "Marjanović, Vesna and Janković-Častvan, Ivona and Lazarević, Slavica and Radovanović, Željko and Janaćković, Đorđe and Petrović, Rada", year = "2022", abstract = "Ciprofloxacin (CIP) as a broad-spectrum quinolone antibiotic is extensively used in daily life and can be detected in municipal and pharmaceutical wastewaters, as well as natural waters. In this study, natural mineral sepiolite (SEP), SEP modified with hexadecyltrimethylammonium-bromide (HDAB) and SEP composites with graphene oxide (GO) were used as adsorbents for the removal of CIP from aqueous solutions. The composites were prepared at a mass ratio SEP to GO of 2 : 1, using SEP and SEP modified by [3-(2-aminoethylamino)propyl]trimethoxy-silane (APT). Thermogravimetric analysis, X-ray diffraction and nitrogen adsorption-desorption were used to characterize the obtained adsorbents. The adsorption of CIP was investigated at the pH value close to pH of natural waters. The concentration of CIP in aqueous solution was determined by UV-Vis spectroscopy. GO showed the highest adsorption capacity (~ 150 mg/g). The capacity of SEP was about 60 mg/g, while the SEP modification with HDAB has led to a decrease in the adsorption capacity (~ 35 mg/g). The composite SEP/GO showed the higher adsorption capacity (~ 110 mg/g) than the composite SEP-APT/GO (~ 40 mg/g). The capacity of the composite SEP/GO was higher than of mixture of SEP and GO, which indicated a certain degree of GO exfoliation and intecalation of sepiolie particles, as it was shown by X-ray diffraction. Equilibrium data for all adsorbents, except for HDAB modified sepiolite, fitted well to the Langmuir isotherm model.", publisher = "University of Novi Sad, Faculty of Technology Novi Sad", journal = "2nd International Conference on Advanced Production and Processing, Book of abstracts", title = "Ciprofloxacin removal using sepiolite-based adsorbents", pages = "218-218", url = "https://hdl.handle.net/21.15107/rcub_technorep_5920" }
Marjanović, V., Janković-Častvan, I., Lazarević, S., Radovanović, Ž., Janaćković, Đ.,& Petrović, R.. (2022). Ciprofloxacin removal using sepiolite-based adsorbents. in 2nd International Conference on Advanced Production and Processing, Book of abstracts University of Novi Sad, Faculty of Technology Novi Sad., 218. https://hdl.handle.net/21.15107/rcub_technorep_5920
Marjanović V, Janković-Častvan I, Lazarević S, Radovanović Ž, Janaćković Đ, Petrović R. Ciprofloxacin removal using sepiolite-based adsorbents. in 2nd International Conference on Advanced Production and Processing, Book of abstracts. 2022;:218. https://hdl.handle.net/21.15107/rcub_technorep_5920 .
Marjanović, Vesna, Janković-Častvan, Ivona, Lazarević, Slavica, Radovanović, Željko, Janaćković, Đorđe, Petrović, Rada, "Ciprofloxacin removal using sepiolite-based adsorbents" in 2nd International Conference on Advanced Production and Processing, Book of abstracts (2022):218, https://hdl.handle.net/21.15107/rcub_technorep_5920 .