Thermodynamic properties of binary system eugenol + 4- propylguaiacol in wide ranges of temperature and pressure
Само за регистроване кориснике
2022
Конференцијски прилог (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The negative consequences of the use of fossil fuels, as well as the unsustainability of meeting ever-increasing energy requirements with limited reserves of fossil fuels, have led to the intensification of research in the field of renewable energy sources. Thermo-chemical conversion of biomass results in bio-oil with low energy density due to high oxygen content which can be upgraded by hydrodeoxygenation process (HDO). HDO consists of a number of reactions that can overlap so the process management requires knowledge on the thermodynamic properties of all compounds present in the biomass valorization process.
Eugenol is promising biomass-derived platform chemical that, depending on used catalyst and reaction conditions, can be converted into a variety of important products including 4-propylguaiacol. Densities of eugenol and 4-propylguaiacol were measured at temperatures (293.15 – 413.15) K and pressures up to 60 MPa. The obtained results were correlated using the modified Tammann-...Tait equation, which enabled the calculation of the valuable derived thermodynamic properties, such as the isothermal compressibility, the isobaric thermal expansivity, the internal pressure and the difference between isobaric and isochoric heat capacity. Densities of the binary mixtures eugenol + 4-propylguaiacol were measured at atmospheric pressure and temperatures (288.15 – 343.15) K to examine the influence of interactions between the studied
components on the thermodynamic properties of their mixtures.
Кључне речи:
density / biomass valorisation / eugenol / 4-propylguaiacol / modellingИзвор:
32nd European Symposium on Applied Thermodynamics 2022, 17-20. July 2022, Graz, Austria, 2022, 184-Издавач:
- Graz : Graz University of Technology
Финансирање / пројекти:
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200135 (Универзитет у Београду, Технолошко-металуршки факултет) (RS-MESTD-inst-2020-200135)
Институција/група
Tehnološko-metalurški fakultetTY - CONF AU - Ivaniš, Gorica AU - Radović, Ivona AU - Kijevčanin, Mirjana PY - 2022 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7397 AB - The negative consequences of the use of fossil fuels, as well as the unsustainability of meeting ever-increasing energy requirements with limited reserves of fossil fuels, have led to the intensification of research in the field of renewable energy sources. Thermo-chemical conversion of biomass results in bio-oil with low energy density due to high oxygen content which can be upgraded by hydrodeoxygenation process (HDO). HDO consists of a number of reactions that can overlap so the process management requires knowledge on the thermodynamic properties of all compounds present in the biomass valorization process. Eugenol is promising biomass-derived platform chemical that, depending on used catalyst and reaction conditions, can be converted into a variety of important products including 4-propylguaiacol. Densities of eugenol and 4-propylguaiacol were measured at temperatures (293.15 – 413.15) K and pressures up to 60 MPa. The obtained results were correlated using the modified Tammann-Tait equation, which enabled the calculation of the valuable derived thermodynamic properties, such as the isothermal compressibility, the isobaric thermal expansivity, the internal pressure and the difference between isobaric and isochoric heat capacity. Densities of the binary mixtures eugenol + 4-propylguaiacol were measured at atmospheric pressure and temperatures (288.15 – 343.15) K to examine the influence of interactions between the studied components on the thermodynamic properties of their mixtures. PB - Graz : Graz University of Technology C3 - 32nd European Symposium on Applied Thermodynamics 2022, 17-20. July 2022, Graz, Austria T1 - Thermodynamic properties of binary system eugenol + 4- propylguaiacol in wide ranges of temperature and pressure SP - 184 UR - https://hdl.handle.net/21.15107/rcub_technorep_7397 ER -
@conference{ author = "Ivaniš, Gorica and Radović, Ivona and Kijevčanin, Mirjana", year = "2022", abstract = "The negative consequences of the use of fossil fuels, as well as the unsustainability of meeting ever-increasing energy requirements with limited reserves of fossil fuels, have led to the intensification of research in the field of renewable energy sources. Thermo-chemical conversion of biomass results in bio-oil with low energy density due to high oxygen content which can be upgraded by hydrodeoxygenation process (HDO). HDO consists of a number of reactions that can overlap so the process management requires knowledge on the thermodynamic properties of all compounds present in the biomass valorization process. Eugenol is promising biomass-derived platform chemical that, depending on used catalyst and reaction conditions, can be converted into a variety of important products including 4-propylguaiacol. Densities of eugenol and 4-propylguaiacol were measured at temperatures (293.15 – 413.15) K and pressures up to 60 MPa. The obtained results were correlated using the modified Tammann-Tait equation, which enabled the calculation of the valuable derived thermodynamic properties, such as the isothermal compressibility, the isobaric thermal expansivity, the internal pressure and the difference between isobaric and isochoric heat capacity. Densities of the binary mixtures eugenol + 4-propylguaiacol were measured at atmospheric pressure and temperatures (288.15 – 343.15) K to examine the influence of interactions between the studied components on the thermodynamic properties of their mixtures.", publisher = "Graz : Graz University of Technology", journal = "32nd European Symposium on Applied Thermodynamics 2022, 17-20. July 2022, Graz, Austria", title = "Thermodynamic properties of binary system eugenol + 4- propylguaiacol in wide ranges of temperature and pressure", pages = "184", url = "https://hdl.handle.net/21.15107/rcub_technorep_7397" }
Ivaniš, G., Radović, I.,& Kijevčanin, M.. (2022). Thermodynamic properties of binary system eugenol + 4- propylguaiacol in wide ranges of temperature and pressure. in 32nd European Symposium on Applied Thermodynamics 2022, 17-20. July 2022, Graz, Austria Graz : Graz University of Technology., 184. https://hdl.handle.net/21.15107/rcub_technorep_7397
Ivaniš G, Radović I, Kijevčanin M. Thermodynamic properties of binary system eugenol + 4- propylguaiacol in wide ranges of temperature and pressure. in 32nd European Symposium on Applied Thermodynamics 2022, 17-20. July 2022, Graz, Austria. 2022;:184. https://hdl.handle.net/21.15107/rcub_technorep_7397 .
Ivaniš, Gorica, Radović, Ivona, Kijevčanin, Mirjana, "Thermodynamic properties of binary system eugenol + 4- propylguaiacol in wide ranges of temperature and pressure" in 32nd European Symposium on Applied Thermodynamics 2022, 17-20. July 2022, Graz, Austria (2022):184, https://hdl.handle.net/21.15107/rcub_technorep_7397 .