Glycidyl esters synthesis catalysed by ion-exchange resins
Апстракт
Ion-exchange resins not previously used for this purpose were employed to study the synthesis of glycidyl esters. The reaction was carried out both with free acids and their sodium salts. The model reaction was the synthesis of glycidyl stearate. Crude glycidyl stearate was afforded in yields greater than 90% in a nonaquous, but not anhydrous system with GC purity above 99%. The phase-transfer catalytic (PTC) mechanism is proposed for the investigated reaction.
Кључне речи:
Glycidyl stearate / Ion-exchange resins / Phase transfer catalysisИзвор:
Journal of the Serbian Chemical Society, 1996, 61, 7, 517-522Издавач:
- Serbian Chemical Society, Belgrade
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Mijin, Dušan AU - Ostrić, I.D. AU - Mišić-Vuković, Milica PY - 1996 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/80 AB - Ion-exchange resins not previously used for this purpose were employed to study the synthesis of glycidyl esters. The reaction was carried out both with free acids and their sodium salts. The model reaction was the synthesis of glycidyl stearate. Crude glycidyl stearate was afforded in yields greater than 90% in a nonaquous, but not anhydrous system with GC purity above 99%. The phase-transfer catalytic (PTC) mechanism is proposed for the investigated reaction. PB - Serbian Chemical Society, Belgrade T2 - Journal of the Serbian Chemical Society T1 - Glycidyl esters synthesis catalysed by ion-exchange resins EP - 522 IS - 7 SP - 517 VL - 61 UR - https://hdl.handle.net/21.15107/rcub_technorep_80 ER -
@article{ author = "Mijin, Dušan and Ostrić, I.D. and Mišić-Vuković, Milica", year = "1996", abstract = "Ion-exchange resins not previously used for this purpose were employed to study the synthesis of glycidyl esters. The reaction was carried out both with free acids and their sodium salts. The model reaction was the synthesis of glycidyl stearate. Crude glycidyl stearate was afforded in yields greater than 90% in a nonaquous, but not anhydrous system with GC purity above 99%. The phase-transfer catalytic (PTC) mechanism is proposed for the investigated reaction.", publisher = "Serbian Chemical Society, Belgrade", journal = "Journal of the Serbian Chemical Society", title = "Glycidyl esters synthesis catalysed by ion-exchange resins", pages = "522-517", number = "7", volume = "61", url = "https://hdl.handle.net/21.15107/rcub_technorep_80" }
Mijin, D., Ostrić, I.D.,& Mišić-Vuković, M.. (1996). Glycidyl esters synthesis catalysed by ion-exchange resins. in Journal of the Serbian Chemical Society Serbian Chemical Society, Belgrade., 61(7), 517-522. https://hdl.handle.net/21.15107/rcub_technorep_80
Mijin D, Ostrić I, Mišić-Vuković M. Glycidyl esters synthesis catalysed by ion-exchange resins. in Journal of the Serbian Chemical Society. 1996;61(7):517-522. https://hdl.handle.net/21.15107/rcub_technorep_80 .
Mijin, Dušan, Ostrić, I.D., Mišić-Vuković, Milica, "Glycidyl esters synthesis catalysed by ion-exchange resins" in Journal of the Serbian Chemical Society, 61, no. 7 (1996):517-522, https://hdl.handle.net/21.15107/rcub_technorep_80 .