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A Kinetic Study of the System Phthalocyanine-Copper(II) Chloride-Sulfuric Acid
(Elsevier, 1990)
In solutions of phthalocyanine, H2Pc, (c = 1–3 × 10−5 mol dm−3) and copper(II) chloride (c ≈ 10−3 mol dm−3) in sulfuric acid (c = 16–18 mol dm−3), two pseudo first-order reactions take place: (1) decomposition of H2Pc; (2) ...
Preparation and Properties of Sodalite-Type Aluminophosphates Containing Silicon, Cobalt and Zinc
(CSIRO PUBLISHING, 1991)
The SAPO, MeAPO and MeSAPO microporous materials (Me=Co2+ and/or 2n2+) having a sodalite structure have been obtained hydrothermally at 200°C in the presence of tetramethylammonium ion as the template. The SAPO and MeSAPO ...
Electron microscopy observations of deformation twinning in a precipitation hardened copper-titanium alloy
(Elsevier Science Ltd., 1996)
On the possibility of the preparation open framework manganese phosphate
(Elsevier Inc., 1996)
Manganese(ll)/phosphate/organic template hydrothermal reactions were investigated with the aim of preparing novel crystalline porous materials. Ethylenediamine, isopropylamine, and piperidine were explored as organics that ...
On the formation of CoAPSO-44
(Butterworth-Heinemann, 1992)
Hydrothermal synthesis of CoAPSO-44 in the presence of cyclohexylamine (CHA) as the template is generally accompanied by the formation of an unknown phase, “Co(APSO)N.” Electronic spectroscopy indicates that CO(APSO)N ...
Resistance parameters and water quench test as criteria of thermal shock behaviour of alumina based refractories
(Taylor & Francis Ltd, Abingdon, 1999)
The materials investigated were five alumina based commercial refractories with different contents of Al2O3 + TiO2 from 28 to 78%. Thermal (k thermal conductivity, alpha coefficient of thermal expansion) and mechanical (E ...
CoAPO-21, a cobalt-doped aluminophosphate related to AlPO4-21
(IUCr/Wiley, 1991)
Co0.12A15.88P6024(OH)2.C2HIoN2.2H2 O, Mr
= 867"7, monoclinic, P2~/n, a = 8.992 (3), b =
17-760~i c=8.359(4) A, fl=105.39(4) ° , U =
1287.0 Z = 2, Dx = 2.24 g cm -3, a = 0.895 (5) A,
/.~ = 14.7 cm-1 F(000) = 871.4, R = ...
On the possibility of incorporating Mn(II) and Cr(III) in SAPO-34 in the presence of isopropylamine as a template
(Butterworth-Heinemann, 1993)
Hydrothermal synthesis of SAPO materials using isopropylamine (i-PrNH2) as the template leads to the formation of MnAPSO-34 if Mn(II) is present. In the presence of Cr(III), the synthesis yields SAPO-34 containing ...
Preparation of Two Cobalt-Substituted Zincophosphate Molecular Sieves
(Marcel Dekker, Inc., 1997)
Two different open-framework cobalt-zincophosphate phases crystallise from the same reaction mixture at ambient conditions depending on the preparative procedure. One of them is a sodalite analogue containing up 70 8 wt.% ...
A novel open framework zincophosphate: Synthesis and characterization
(Elsevier Science Inc., 1995)
The crystallization of a reactive zincophosphate gel (which may contain Co(ll) component) in the presence of sodium cations at ambient temperature and pressure yielded products (abbreviated ZnPO-HEX or CoZnPO-HEX) with a ...