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On the possibility of the preparation open framework manganese phosphate
(Elsevier Inc., 1996)
Manganese(ll)/phosphate/organic template hydrothermal reactions were investigated with the aim of preparing novel crystalline porous materials. Ethylenediamine, isopropylamine, and piperidine were explored as organics that ...
On the possibility of incorporating Mn(II) and Cr(III) in SAPO-34 in the presence of isopropylamine as a template
(Butterworth-Heinemann, 1993)
Hydrothermal synthesis of SAPO materials using isopropylamine (i-PrNH2) as the template leads to the formation of MnAPSO-34 if Mn(II) is present. In the presence of Cr(III), the synthesis yields SAPO-34 containing ...
A Kinetic Study of the System Phthalocyanine-Copper(II) Chloride-Sulfuric Acid
(Elsevier, 1990)
In solutions of phthalocyanine, H2Pc, (c = 1–3 × 10−5 mol dm−3) and copper(II) chloride (c ≈ 10−3 mol dm−3) in sulfuric acid (c = 16–18 mol dm−3), two pseudo first-order reactions take place: (1) decomposition of H2Pc; (2) ...
Preparation and Properties of Sodalite-Type Aluminophosphates Containing Silicon, Cobalt and Zinc
(CSIRO PUBLISHING, 1991)
The SAPO, MeAPO and MeSAPO microporous materials (Me=Co2+ and/or 2n2+) having a sodalite structure have been obtained hydrothermally at 200°C in the presence of tetramethylammonium ion as the template. The SAPO and MeSAPO ...
A novel open framework zincophosphate: Synthesis and characterization
(Elsevier Science Inc., 1995)
The crystallization of a reactive zincophosphate gel (which may contain Co(ll) component) in the presence of sodium cations at ambient temperature and pressure yielded products (abbreviated ZnPO-HEX or CoZnPO-HEX) with a ...
A CoAPO-34 derived from a triclinic precursor prepared in the presence of HF
(Elsevier Science Inc., 1997)
The fluoride route of synthesis of AIPO,-34 is also successful in the preparation of its cobalt modified product (CoAPO-34). The triclinic precursor of CoAPO-34 has been synthesized in the presence of HF and piperidine. ...
Retention behavior of some amides in reversed- and normal-phase thin-layer chromatography
(Springer Heidelberg, Heidelberg, 1992)
The retention behavior and separation ability of reversed- and normal-phase TLC with, polar and nonpolar mobile phases, has been studied by measuring the retentions of a series of amides. The retention behavior and separation ...
The structure of CoSAPO-34, containing i-propylamine as a template
(Butterworth-Heinemann, 1991)
The crystal structure of a cobalt silicoaluminophosphate, CoSAPO-34, is reported. The crystals belong to the rhombohedral R3 space group with unit cell parameters a = 13.797(7) and c = 14.898(7) A. The final R index was ...
CoAPO-21, a cobalt-doped aluminophosphate related to AlPO4-21
(IUCr/Wiley, 1991)
Co0.12A15.88P6024(OH)2.C2HIoN2.2H2 O, Mr
= 867"7, monoclinic, P2~/n, a = 8.992 (3), b =
17-760~i c=8.359(4) A, fl=105.39(4) ° , U =
1287.0 Z = 2, Dx = 2.24 g cm -3, a = 0.895 (5) A,
/.~ = 14.7 cm-1 F(000) = 871.4, R = ...
Preparation of Two Cobalt-Substituted Zincophosphate Molecular Sieves
(Marcel Dekker, Inc., 1997)
Two different open-framework cobalt-zincophosphate phases crystallise from the same reaction mixture at ambient conditions depending on the preparative procedure. One of them is a sodalite analogue containing up 70 8 wt.% ...