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FTIR spectroscopic study of hydrogen bonding and solvent induced frequency shifts of N-tert-butylacetamide
dc.creator | Jović, Branislav | |
dc.creator | Nikolić, Aleksandar | |
dc.creator | Petrović, Slobodan | |
dc.date.accessioned | 2021-03-10T12:10:05Z | |
dc.date.available | 2021-03-10T12:10:05Z | |
dc.date.issued | 2013 | |
dc.identifier.issn | 0022-2860 | |
dc.identifier.uri | http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2438 | |
dc.description.abstract | This paper reports the results of FTIR study of N-tert-butylacetamide in carbon tetrachloride solution and in presence of seven different molecules as H acceptors. The spectroscopic characteristics for N-H center dot center dot center dot O hydrogen bonded complexes are given. Also, the equilibrium constants for 1:1 complex formation, at 25 degrees C were determined by using IR measurements. Frequency shifts of carbonyl stretching vibration nu(C=O) of N-tert-butylacetamide in the same organic H acceptors was also investigated. The wavenumbers of carbonyl stretching vibration nu(C=O) were correlated with the solvent acceptor number (AN) and the linear solvation energy relationships (LSERs). | en |
dc.publisher | Elsevier Science Bv, Amsterdam | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172013/RS// | |
dc.rights | restrictedAccess | |
dc.source | Journal of Molecular Structure | |
dc.subject | Hydrogen bonding | en |
dc.subject | N-tert-butylacetamide | en |
dc.subject | Solvent effect | en |
dc.title | FTIR spectroscopic study of hydrogen bonding and solvent induced frequency shifts of N-tert-butylacetamide | en |
dc.type | article | |
dc.rights.license | ARR | |
dc.citation.epage | 143 | |
dc.citation.other | 1044: 140-143 | |
dc.citation.rank | M23 | |
dc.citation.spage | 140 | |
dc.citation.volume | 1044 | |
dc.identifier.doi | 10.1016/j.molstruc.2012.10.009 | |
dc.identifier.scopus | 2-s2.0-84878289211 | |
dc.identifier.wos | 000320635200023 | |
dc.type.version | publishedVersion |