Thermodynamic modeling of vapor-liquid equilibria and excess properties of the binary systems containing diethers and n-alkanes by cubic equation of state
dc.creator | Šerbanović, Slobodan P. | |
dc.creator | Grgurić, Ivona R. | |
dc.creator | Kijevčanin, Mirjana | |
dc.creator | Tasić, AZ | |
dc.creator | Đorđević, Bojan D. | |
dc.date.accessioned | 2021-03-10T10:18:09Z | |
dc.date.available | 2021-03-10T10:18:09Z | |
dc.date.issued | 2004 | |
dc.identifier.issn | 0256-1115 | |
dc.identifier.uri | http://TechnoRep.tmf.bg.ac.rs/handle/123456789/703 | |
dc.description.abstract | A comparison of the performances of two different approaches of cubic equations of state models, based on a classical van der Waals and mixing rules incorporating the G(E) equation, was carried out for correlation of Vapor-Liquid Equilibria (VLE), H-E and c(P)(E) data alone, and simultaneous correlation of VLE+H-E, VLE+c(P)(E), H-E+c(P)(E) and VLE+H-E+c(P)(E) data for the diethers (1,4-dioxane or 1,3-dioxolane) with n-alkane systems. For all calculations the Peng-Robinson-Stryjek-Vera cubic equation of state (PRSV CEOS) was used. A family of mixing rules for the PRSV CEOS based on the Modified van der Waals one-fluid mixing rule (MvdW1) and two well-known CEOS/GE mixing rules (MHV1 and MHV2), was considered. The NRTL equation, as the G(E) model with linear or reciprocal temperature dependent parameters, was incorporated in the CEOS/G(E) models. The results obtained by the CEOS/G(E) models exhibit significant improvement in comparison to the MvdW1 models. | en |
dc.publisher | Korean Institute Chemical Engineers, Seoul | |
dc.rights | restrictedAccess | |
dc.source | Korean Journal of Chemical Engineering | |
dc.subject | cubic equation of state | en |
dc.subject | thermodynamic properties | en |
dc.subject | diether | en |
dc.subject | n-alkane | en |
dc.subject | simultaneous correlation | en |
dc.title | Thermodynamic modeling of vapor-liquid equilibria and excess properties of the binary systems containing diethers and n-alkanes by cubic equation of state | en |
dc.type | article | |
dc.rights.license | ARR | |
dc.citation.epage | 866 | |
dc.citation.issue | 4 | |
dc.citation.other | 21(4): 858-866 | |
dc.citation.rank | M22 | |
dc.citation.spage | 858 | |
dc.citation.volume | 21 | |
dc.identifier.doi | 10.1007/BF02705531 | |
dc.identifier.scopus | 2-s2.0-7944236149 | |
dc.identifier.wos | 000223325700016 | |
dc.type.version | publishedVersion |