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Effects of solid poly (ethylene glycols) addition to the solutions of aniline or N,N-dimethylaniline with water: Experimental measurements and modelling
dc.creator | Soldatović, Danijela | |
dc.creator | Grozdanić, Nikola | |
dc.creator | Višak, Zoran P. | |
dc.creator | Radović, Ivona | |
dc.creator | Kijevčanin, Mirjana | |
dc.date.accessioned | 2021-03-10T13:13:38Z | |
dc.date.available | 2021-03-10T13:13:38Z | |
dc.date.issued | 2016 | |
dc.identifier.issn | 0352-5139 | |
dc.identifier.uri | http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3429 | |
dc.description.abstract | In this work, the liquid-liquid and solid-liquid phase behaviour of ten aqueous pseudo-binary and three binary systems containing polyethylene glycol (PEG) 2050, polyethylene glycol 35000, aniline, N,N-dimethylaniline and water, in the temperature range 298.15-350.15 K and at ambient pressure of 0.1 MPa, was studied. The obtained temperature-composition phase diagrams showed that the only functional co-solvent was PEG2050 for aniline in water, while PEG35000 even showed a clear anti-solvent effect in the N,N-dimethylaniline aqueous system. The experimental solid-liquid equilibria (SLE) data have been correlated by the non-random two-liquid (NRTL) model, and the correlation results are in accordance with the experimental results. | en |
dc.publisher | Srpsko hemijsko društvo, Beograd | |
dc.relation | Research Fund of Ministry of Science and Environmental Protection, Serbia | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172063/RS// | |
dc.rights | openAccess | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.source | Journal of the Serbian Chemical Society | |
dc.subject | solid-liquid equilibria | en |
dc.subject | liquid-liquid equilibria | en |
dc.subject | NRTL model | en |
dc.subject | polyethylene glycol | en |
dc.subject | aniline | en |
dc.subject | N,N-dimethylaniline | en |
dc.title | Effects of solid poly (ethylene glycols) addition to the solutions of aniline or N,N-dimethylaniline with water: Experimental measurements and modelling | en |
dc.type | article | |
dc.rights.license | BY-NC-ND | |
dc.citation.epage | 798 | |
dc.citation.issue | 7 | |
dc.citation.other | 81(7): 789-798 | |
dc.citation.rank | M23 | |
dc.citation.spage | 789 | |
dc.citation.volume | 81 | |
dc.identifier.doi | 10.2298/JSC160317058S | |
dc.identifier.fulltext | http://TechnoRep.tmf.bg.ac.rs/bitstream/id/9592/0352-51391600058S.pdf | |
dc.identifier.scopus | 2-s2.0-84982732362 | |
dc.identifier.wos | 000382175400006 | |
dc.type.version | publishedVersion |