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On the kinetics of the hydrogen evolution reaction on nickel in alkaline solution - Part I. The mechanism
(Elsevier S.A., 2001)
The mechanism and kinetics of the hydrogen evolution reaction (her) were studied in 1.0 mol dm(-3) NaOH at 393.0 K. It was found that a combination of classical steady-state voltammetry and impedance spectroscopy can help ...
On the deactivation mechanism of RuO2-TiO2/Ti anodes prepared by the sol-gel procedure
(Elsevier Science Sa, Lausanne, 2005)
The deactivation process that leads to the end of titanium supported RuO2-TiO2 coating service life, for anodes prepared from RuO2 and TiO2 sols, as well as by the conventional thermal decomposition of RuCl3 and TiCl3, was ...
An electrochemical illustration of the mathematical modelling of chlorine impact and acidification in electrochemical tumour treatment and its application on an agar-agar gel system
(Elsevier, 2003)
Electrochemical treatment (EchT) of tumours, which is also known as electrochemical therapy, implies that tumour tissue is treated with a direct current through the use of electrodes. This was shown earlier when the major ...
Capacitive properties of RuO2-coated titanium electrodes prepared by the alkoxide ink procedure
(Elsevier Science Sa, Lausanne, 2007)
The capacitive properties of titanium electrodes with an active porous RuO2 coating were investigated in H2SO4 and NaCl solution by cyclic voltammetry and electrochemical impedance spectroscopy. Electrodes with two different ...
A comparative study of the electrochemical properties of carbon nanotubes and carbon black
(Elsevier Science Sa, Lausanne, 2009)
Two samples of commercial multi-walled carbon nanotubes (Sigma-Aldrich and Sun Nanotech) and a sample of carbon black (Vulcan XC-72R) were investigated in raw state and after the activation in nitric and sulfuric acid by ...
The effect of hydrogen co-deposition on the morphology of copper electrodeposits. II. Correlation between the properties of electrolytic solutions and the quantity of evolved hydrogen
(Elsevier, 2008)
Formation of irregular deposits by electrodeposition from acid sulfate solutions of various H2SO4 concentrations was examined by the determination of the average current efficiency of hydrogen evolution and by the scanning ...
On the kinetics of the hydrogen evolution reaction on nickel in alkaline solution - Part II. Effect of temperature
(Elsevier S.A., 2001)
The effect of temperature on the kinetics of the hydrogen evolution reaction (her) on nickel in 1.0 mol dm (-3) NaOH solution was studied. In this article, four sets of experiments were done in a non-isothermal cell. In ...
Rate expression for electrochemical oxidation of methanol on a direct methanol fuel cell anode
(Elsevier, 2005)
The kinetics of methanol oxidation at PtRu catalyst was investigated on a membrane electrode assembly (MEA) in a cyclone flow cell. Catalyst characterisation was done by means of cyclic voltammetry and CO stripping. The ...
Oscillatory behavior in the electrochemical oxidation of formic acid on Pt(100): rotation and temperature effects
(Elsevier Science Sa, Lausanne, 2001)
We investigated the oscillatory behavior in the kinetics of formic acid electrooxidation on Pt(100) in 1 mM HClO4 solution. We studied the effect of different experimental parameters on the oscillatory behavior, viz. defined ...
Adsorption of oxygen containing species and their effect on oxygen reduction on Pt3Co electrode
(Elsevier Science Sa, Lausanne, 2003)
A rotating Pt3Co, thermally prepared alloy disc is used to study electrochemical oxygen reduction in alkaline solutions of different pH. In all solutions two Tafel regions are found: at low current densities partial ...