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On the deactivation mechanism of RuO2-TiO2/Ti anodes prepared by the sol-gel procedure
(Elsevier Science Sa, Lausanne, 2005)
The deactivation process that leads to the end of titanium supported RuO2-TiO2 coating service life, for anodes prepared from RuO2 and TiO2 sols, as well as by the conventional thermal decomposition of RuCl3 and TiCl3, was ...
Capacitive properties of RuO2-coated titanium electrodes prepared by the alkoxide ink procedure
(Elsevier Science Sa, Lausanne, 2007)
The capacitive properties of titanium electrodes with an active porous RuO2 coating were investigated in H2SO4 and NaCl solution by cyclic voltammetry and electrochemical impedance spectroscopy. Electrodes with two different ...
Mass transfer effect in electrochemical oxidation of methanol at platinum electrocatalysts
(Elsevier Science Sa, Lausanne, 2004)
The influence of the mass transfer on the electrochemical oxidation of methanol was investigated at a rotating disk electrode with smooth polycrystalline Pt and high area carbon supported Pt (Pt/C) as the electrocatalysts. ...
Experimental study of zinc morphology in alkaline electrolyte at low direct and pulsating overpotentials
(Elsevier Sequoia SA, 2000)
A possible mechanism of the formation of spongy zinc electrodeposits is considered. The confirmation of the proposed semiquantitative mathematical model is performed in zinc electrodeposition onto copper wire from a 0.1 M ...
Kinetic study of formic acid oxidation on carbon-supported platinum electrocatalyst
(Elsevier Science Sa, Lausanne, 2005)
Oxidation of formic acid on the platinum catalyst supported on high area carbon was investigated by potent iodynamic and quasi-steady-state polarization measurements. It was found that the poisoning of the reaction occurred ...
The effect of hydrogen codeposition on the morphology of copper electrodeposits. 1. The concept of effective overpotential
(Elsevier, 2006)
The effect of hydrogen codeposition on the morphology of copper electrodeposits was studied. The dependences of the overall current and the volume of evolved hydrogen on the quantity of electricity used were plotted and ...
The kinetics of the hydrogen evolution reaction on zinc in EDTA solutions in the pH 3-10 range
(Elsevier Science Sa, Lausanne, 2003)
Polarization curves of the hydrogen evolution reaction on zinc were obtained in Ethylenediaminetetraacetic acid (EDTA) solutions of different total molar concentrations (0.05, 0.10, 0.15 and 0.20 mol dm(-3)), the pH values ...
Electrocatalysis by nanoparticles - Oxygen reduction on Ebonex/Pt electrode
(Elsevier, 2006)
The oxygen reduction reaction was studied in 0.5 mol dm-3 HClO4 solution on an electrode based on Ebonex-supported platinum electrocatalyst applied on rotation Au disk electrode (Au/Ebonex/Pt). Pt catalyst was prepared by ...