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The origin of high activity of Pt-Au surfaces in the formic acid oxidation
(Pergamon-Elsevier Science Ltd, Oxford, 2009)
We have investigated the oxidation of HCOOH on Au-modified Pt (Au"Pt) and Pt-modified Au (Pt")/Au) electrodes to establish the role of the ensemble and the electronic effect in the catalysis of this reaction. The surfaces ...
Kinetics of the hydrogen evolution reaction on Fe-Mo film deposited on mild steel support in alkaline solution
(Pergamon-Elsevier Science Ltd, Oxford, 2005)
The mechanism and kinetics of the hydrogen evolution reaction were studied. in 1.0 mol dm(-3) NaOH solution on Fe-Mo alloy electrodes prepared by electrodeposition at constant current densities from a pyrophosphate bath. ...
Carbon cryogel as support of platinum nano-sized electrocatalyst for the hydrogen oxidation reaction
(Electrochimica Acta, 2006)
The kinetics of hydrogen oxidation reaction was studied in perchloric acid solution on carbon-supported Pt nanoparticles using the rotating disk electrode technique. Carbon cryogel and commercial carbon black. Vulcan XC-72 ...
The electrochemical behavior of erythromycin A on a gold electrode
(Pergamon-Elsevier Science Ltd, Oxford, 2008)
The reactivity of erythromycin (pure) was investigated on a gold electrode in neutral electrolyte by cyclic voltammetry. The resulting structural changes were observed with HPLC and FTIR spectroscopy by analyzing the bulk ...
Physical and mathematical models of an inert macroelectrode modified with active hemispherical microelectrodes
(Pergamon-Elsevier Science Ltd, Oxford, 2007)
The physical model of an inert electrode partially activated with hemispherical microelectrodes was formed by the deposition of silver grains on a graphite substrate. It is shown that the process on the microelectrodes can ...
Study of the kinetics and the influence of Bi-irr, on formic acid oxidation at Pt2RU3/C
(Pergamon-Elsevier Science Ltd, Oxford, 2007)
Electrochemical oxidation of HCOOH in H2SO4 and HCIO4 solutions was examined on thin film Pt2RU3/C electrode. XRD pattern revealed that Pt2RU3 alloy consisted of the solid solution of Ru in Pt and the small amount of Ru ...
Studies on electrochemical oxidation of azithromycin and Hemomycin (R) at gold electrode in neutral electrolyte
(Pergamon-Elsevier Science Ltd, Oxford, 2006)
The aim of the present study was to examine the oxidative properties and an assay of azithromycin and Hemomycin (R) at a gold electrode in neutral electrolyte using cyclic linear sweep voltammetry. The maximum value of the ...
The properties of carbon-supported hydrous ruthenium oxide obtained from RuOxHy sol
(Pergamon-Elsevier Science Ltd, Oxford, 2003)
Preparation of RuOxHy/carbon black nanocomposite material was performed by the impregnation method starting from RuOxHy sol as a precursor. Black Pearls 2000(R) (BP) and Vulcan(R) XC-72 R (XC) were used as supporting ...
Polypyrrole as possible electrode materials for the aqueous-based rechargeable zinc batteries
(Pergamon-Elsevier Science Ltd, Oxford, 2008)
Polypyrrole (PPy) thin film electrode was galvanostatically synthesized and characterized in 0.1 M HCI on graphite electrode as cathode materials for the aqueous-based rechargeable zinc batteries. The charge/discharge ...
Methanol electrooxidation on supported Pt and PtRu catalysts in acid and alkaline solutions
(Pergamon-Elsevier Science Ltd, Oxford, 2002)
The kinetics of methanol oxidation on supported 47.5 wt.% Pt and 54 wt.% Pt-Ru (with nominal Pt:Ru ratios of 2:3) catalysts are measured in 0.5 M H2SO4 and 0.1 NaOH at 295 and 333 K using thin-film rotating disk electrode ...