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Electrochemically deposited iridium-oxide: Estimation of intrinsic activity and stability in oxygen evolution in acid solution
(Journal of Electroanalytical Chemistry, 2021)
Hydrated iridiumoxyhydroxide (IrOx) films were electrochemically deposited from an alkaline oxalic solution at constant anodic potentials and by applying a potential cycling protocol, in both cases with variation of the ...
Oxygen reduction on iron. Part III. An analysis of the rotating disk-ring electrode measurements in near neutral solutions
(Elsevier Science Sa, Lausanne, 1989)
The kinetics of oxygen reduction were studied on iron in borate and bicarbonate buffered solutions, pH 9.8, using the rotating disk-ring method. Under these conditions O2 reduction occurs both on the oxidized surface and ...
Mass transfer effect in electrochemical oxidation of methanol at platinum electrocatalysts
(Elsevier Science Sa, Lausanne, 2004)
The influence of the mass transfer on the electrochemical oxidation of methanol was investigated at a rotating disk electrode with smooth polycrystalline Pt and high area carbon supported Pt (Pt/C) as the electrocatalysts. ...
Experimental study of zinc morphology in alkaline electrolyte at low direct and pulsating overpotentials
(Elsevier Sequoia SA, 2000)
A possible mechanism of the formation of spongy zinc electrodeposits is considered. The confirmation of the proposed semiquantitative mathematical model is performed in zinc electrodeposition onto copper wire from a 0.1 M ...
Application of the general theory of disperse deposits formation in an investigation of mechanism of zinc electrodeposition from the alkaline electrolytes
(Elsevier, 2017)
In this study, mechanism of electrodeposition of zinc from the alkaline electrolytes has been investigated using the general theory of disperse deposits formation. The exchange current densities in the range 18.4-88 mA ...
A new insight into the mechanism of lead electrodeposition: Ohmic-diffusion control of the electrodeposition process
(Elsevier, 2013)
A new insight into the mechanism of lead electrodeposition from nitrate solutions is presented by analysis of the polarization characteristics and by scanning electron microscopic (SEM) analysis of the surface morphology ...
Ru layers electrodeposited onto highly stable Ti2AlC substrates as cathodes for hydrogen evolution in sulfuric acid solutions
(Elsevier, 2016)
In this work, the hydrogen evolution reaction (HER) was studied on Ru coated Ti2AlC electrodes in 1.0 mol dm(-3) H2SO4 at 25 degrees C. Ti2AlC was found to be a highly stable substrate in sulfuric acid solutions due to the ...
Challenges in determining the electrochemically active surface area of Ni-oxides in the oxygen evolution reaction
(Elsevier B.V., 2022)
Thin films of Ni-oxy-hydroxides of different composition and thickness were electrochemically grown on Ni foil electrode: hydrated α-phase, anhydrous β-phase, and two mixed α- and β-phase electrodeposited by potential ...
The kinetics of the hydrogen evolution reaction on zinc in EDTA solutions in the pH 3-10 range
(Elsevier Science Sa, Lausanne, 2003)
Polarization curves of the hydrogen evolution reaction on zinc were obtained in Ethylenediaminetetraacetic acid (EDTA) solutions of different total molar concentrations (0.05, 0.10, 0.15 and 0.20 mol dm(-3)), the pH values ...
Palladium-copper bimetallic surfaces as electrocatalysts for the ethanol oxidation in an alkaline medium
(Elsevier B.V., 2023)
Two types of Cu-modified Pd catalysts supported on high area carbon were prepared: Pd nanoparticles modified with a sub-monolayer of underpotentially deposited Cu (Cu@Pd/C) and Pd-Cu alloy nanoparticles (Pd-Cu/C), and ...