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Palladium-copper bimetallic surfaces as electrocatalysts for the ethanol oxidation in an alkaline medium
(Elsevier B.V., 2023)
Two types of Cu-modified Pd catalysts supported on high area carbon were prepared: Pd nanoparticles modified with a sub-monolayer of underpotentially deposited Cu (Cu@Pd/C) and Pd-Cu alloy nanoparticles (Pd-Cu/C), and ...
A new insight into the mechanism of lead electrodeposition: Ohmic-diffusion control of the electrodeposition process
(Elsevier, 2013)
A new insight into the mechanism of lead electrodeposition from nitrate solutions is presented by analysis of the polarization characteristics and by scanning electron microscopic (SEM) analysis of the surface morphology ...
Ru layers electrodeposited onto highly stable Ti2AlC substrates as cathodes for hydrogen evolution in sulfuric acid solutions
(Elsevier, 2016)
In this work, the hydrogen evolution reaction (HER) was studied on Ru coated Ti2AlC electrodes in 1.0 mol dm(-3) H2SO4 at 25 degrees C. Ti2AlC was found to be a highly stable substrate in sulfuric acid solutions due to the ...
Determination of kinetic parameters for the hydrogen evolution reaction on the electrodeposited Ni-MoO2 composite coating in alkaline solution
(Elsevier Science Sa, Lausanne, 2012)
As a result of research on the non-noble metal-based composite electrocatalysts for the hydrogen evolution reaction (HER), the Ni-MoO2 composite coating was produced by electrodeposition from an NH4Cl and NiCl2 containing ...
The kinetics of the hydrogen evolution reaction on zinc in EDTA solutions in the pH 3-10 range
(Elsevier Science Sa, Lausanne, 2003)
Polarization curves of the hydrogen evolution reaction on zinc were obtained in Ethylenediaminetetraacetic acid (EDTA) solutions of different total molar concentrations (0.05, 0.10, 0.15 and 0.20 mol dm(-3)), the pH values ...
Experimental study of zinc morphology in alkaline electrolyte at low direct and pulsating overpotentials
(Elsevier Sequoia SA, 2000)
A possible mechanism of the formation of spongy zinc electrodeposits is considered. The confirmation of the proposed semiquantitative mathematical model is performed in zinc electrodeposition onto copper wire from a 0.1 M ...
Challenges in determining the electrochemically active surface area of Ni-oxides in the oxygen evolution reaction
(Elsevier B.V., 2022)
Thin films of Ni-oxy-hydroxides of different composition and thickness were electrochemically grown on Ni foil electrode: hydrated α-phase, anhydrous β-phase, and two mixed α- and β-phase electrodeposited by potential ...
Kinetic study of formic acid oxidation on carbon-supported platinum electrocatalyst
(Elsevier Science Sa, Lausanne, 2005)
Oxidation of formic acid on the platinum catalyst supported on high area carbon was investigated by potent iodynamic and quasi-steady-state polarization measurements. It was found that the poisoning of the reaction occurred ...
Oxygen reduction on iron. Part VII. Temperature dependence of oxygen reduction on passivated iron in alkaline solutions
(Elsevier Science Sa, Lausanne, 1995)
The temperature dependence of the kinetics of O2 reduction was studied on passivated Fe in NaOH solutions having a concentration ranging from 0.010 to 1.0 mol dm-3 and in the temperature range from 2 to 42 °C. The apparent ...
Oxygen reduction on iron. Part III. An analysis of the rotating disk-ring electrode measurements in near neutral solutions
(Elsevier Science Sa, Lausanne, 1989)
The kinetics of oxygen reduction were studied on iron in borate and bicarbonate buffered solutions, pH 9.8, using the rotating disk-ring method. Under these conditions O2 reduction occurs both on the oxidized surface and ...