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Polarization curves in the ohmic controlled electrodeposition of metals
(Oxford : Pergamon-Elsevier Science Ltd, 2009)
The conditions under which ohmic controlled metal electrodeposition occurs are discussed using a simple mathematical model. it is shown that ohmic controlled electrodeposition can be operative if the value of the exchange ...
Hydrogen evolution in acid solution at Pd electrodeposited onto Ti2AlC
(Pergamon-Elsevier Science Ltd, Oxford, 2017)
The hydrogen evolution reaction (HER) was studied in 0.5 M H2SO4 at 25 degrees C on Pd electrodeposited onto Ti2AlC substrate, as an excellent substrate due to its high conductivity and high stability in concentrated ...
The effect of the electrode surface roughness at low level of coarseness on the polarization characteristics of electrochemical processes
(Pergamon-Elsevier Science Ltd, Oxford, 2010)
In this study, it is considered: (a) the effect of the exchange current density to the limiting diffusion current density ratio (J(0)/J(L)) at low level of surface coarseness on the polarization characteristics of the ...
Ni-Sn coatings as cathodes for hydrogen evolution in alkaline solutions
(Pergamon-Elsevier Science Ltd, Oxford, 2013)
In this work the hydrogen evolution reaction (HER) at Ni-Sn alloy coatings, deposited onto Ni 40 mesh at different current densities from the bath containing 0.1 mol dm(-3) SnCl2 + 0.3 mol dm(-3) NiCl2 in the pyrophosphate-glycine ...
Incorporation of Pt, Ru and Pt-Ru nanoparticles into ordered mesoporous carbons for efficient oxygen reduction reaction in alkaline media
(Electrochimica Acta, 2015)
Ordered mesoporous carbon, volume-doped up to 3w.% with Pt, Ru and Pt-Ru nanoparticles was synthesized by evaporation-induced self-assembly method, under acidic conditions. The content of incorporated metal was determined ...
The origin of high activity of Pt-Au surfaces in the formic acid oxidation
(Pergamon-Elsevier Science Ltd, Oxford, 2009)
We have investigated the oxidation of HCOOH on Au-modified Pt (Au"Pt) and Pt-modified Au (Pt")/Au) electrodes to establish the role of the ensemble and the electronic effect in the catalysis of this reaction. The surfaces ...
Kinetics of the hydrogen evolution reaction on Fe-Mo film deposited on mild steel support in alkaline solution
(Pergamon-Elsevier Science Ltd, Oxford, 2005)
The mechanism and kinetics of the hydrogen evolution reaction were studied. in 1.0 mol dm(-3) NaOH solution on Fe-Mo alloy electrodes prepared by electrodeposition at constant current densities from a pyrophosphate bath. ...
Synthesis and characterization of MoOx-Pt/C and TiOx-Pt/C nano-catalysts for oxygen reduction
(Pergamon-Elsevier Science Ltd, Oxford, 2009)
The oxygen reduction reaction (ORR) was studied at carbon supported MoOx-Pt/C and TiOx-Pt nanocatalysts in 0.5 mol dm(-3) HClO4 solution, at 25 degrees C. The MoOx-Pt/C and TiOx-Pt/C catalysts were prepared by the polyole ...
HCOOH oxidation on thin Pd layers on Au: Self-poisoning by the subsequent reaction of the reaction product
(Pergamon-Elsevier Science Ltd, Oxford, 2013)
The oxidation of HCOOH has been investigated on thin Pd layers ranging from 1 to 17 ML equivalents electrodeposited on polycrystalline Au substrate (Pd"Au). The results are compared to those on Pd black. Potentiodynamic ...
Carbon cryogel as support of platinum nano-sized electrocatalyst for the hydrogen oxidation reaction
(Electrochimica Acta, 2006)
The kinetics of hydrogen oxidation reaction was studied in perchloric acid solution on carbon-supported Pt nanoparticles using the rotating disk electrode technique. Carbon cryogel and commercial carbon black. Vulcan XC-72 ...