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Electrochemical determination of sildenafil citrate as standard, in tablets and spiked with human serum at gold and cystein modified gold electrode
(Elsevier Science Sa, Lausanne, 2016)
Nonmedical use of sildenafil citrate (SC) requires new methods for drug determination in human serum and in tablets. SC as standard and in Sildena (R) tablets is determined by square wave voltammetry (SWV) in 0.1 M H2SO4 ...
Use of carbon paste electrode and modified by gold nanoparticles for selected macrolide antibiotics determination as standard and in pharmaceutical preparations
(Elsevier B.V., 2020)
In this work, carbon paste electrode (CPE) and carbon paste electrode modified with gold nanoparticics (AuNPs/CPE) were employed with rapid direct anodic square wave voltammetry (SWV) for macrolide antibiotics erythromycin ...
Structural characteristics of bright copper surfaces
(Journal of Electroanalytical Chemistry, 2001)
In this work, the structures of copper surfaces polished mechanically and polished both mechanically and electrochemically, as well as copper coatings obtained in the presence of basic and top brightening addition agents ...
Electrochemically deposited iridium-oxide: Estimation of intrinsic activity and stability in oxygen evolution in acid solution
(Journal of Electroanalytical Chemistry, 2021)
Hydrated iridiumoxyhydroxide (IrOx) films were electrochemically deposited from an alkaline oxalic solution at constant anodic potentials and by applying a potential cycling protocol, in both cases with variation of the ...
Oxygen reduction on iron. Part III. An analysis of the rotating disk-ring electrode measurements in near neutral solutions
(Elsevier Science Sa, Lausanne, 1989)
The kinetics of oxygen reduction were studied on iron in borate and bicarbonate buffered solutions, pH 9.8, using the rotating disk-ring method. Under these conditions O2 reduction occurs both on the oxidized surface and ...
Experimental study of zinc morphology in alkaline electrolyte at low direct and pulsating overpotentials
(Elsevier Sequoia SA, 2000)
A possible mechanism of the formation of spongy zinc electrodeposits is considered. The confirmation of the proposed semiquantitative mathematical model is performed in zinc electrodeposition onto copper wire from a 0.1 M ...
Application of the general theory of disperse deposits formation in an investigation of mechanism of zinc electrodeposition from the alkaline electrolytes
(Elsevier, 2017)
In this study, mechanism of electrodeposition of zinc from the alkaline electrolytes has been investigated using the general theory of disperse deposits formation. The exchange current densities in the range 18.4-88 mA ...
Challenges in determining the electrochemically active surface area of Ni-oxides in the oxygen evolution reaction
(Elsevier B.V., 2022)
Thin films of Ni-oxy-hydroxides of different composition and thickness were electrochemically grown on Ni foil electrode: hydrated α-phase, anhydrous β-phase, and two mixed α- and β-phase electrodeposited by potential ...
Ru layers electrodeposited onto highly stable Ti2AlC substrates as cathodes for hydrogen evolution in sulfuric acid solutions
(Elsevier, 2016)
In this work, the hydrogen evolution reaction (HER) was studied on Ru coated Ti2AlC electrodes in 1.0 mol dm(-3) H2SO4 at 25 degrees C. Ti2AlC was found to be a highly stable substrate in sulfuric acid solutions due to the ...
Mass transfer effect in electrochemical oxidation of methanol at platinum electrocatalysts
(Elsevier Science Sa, Lausanne, 2004)
The influence of the mass transfer on the electrochemical oxidation of methanol was investigated at a rotating disk electrode with smooth polycrystalline Pt and high area carbon supported Pt (Pt/C) as the electrocatalysts. ...