dc.creator | Milovanović, Jelena | |
dc.creator | Rajić, Nevenka | |
dc.creator | Romero, Antonio A. | |
dc.creator | Li, Hangkong | |
dc.creator | Shih, Kaimin | |
dc.creator | Tschentscher, Roman | |
dc.creator | Luque, Rafael | |
dc.date.accessioned | 2021-03-10T13:00:49Z | |
dc.date.available | 2021-03-10T13:00:49Z | |
dc.date.issued | 2016 | |
dc.identifier.issn | 2168-0485 | |
dc.identifier.uri | http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3233 | |
dc.description.abstract | The depolymerization of biolignin (BL), eucalyptus (EL), and hardwood lignins (HL) to simple aromatics was studied by a microwave assisted approach using NiO/H-ZSM-S zeolites as catalysts. The catalysts prepared by the mechanochemical dry milling (MCDM) method contained bunsenite nano NiO particles with an average size of 67 mu m at a concentration of 1-4.8 wt % NiO. Yields and composition of the obtained bio-oils are highly dependent on lignin type as well as on the content of NiO. The highest bio-oil yield (about 20 wt %) was obtained using 3.5 wt % NiO and HL as the feedstock. A number of relevant findings based depolymerization experiments are provided which pointed to different monomeric products (mostly S-derived) that could be produced in different proportions depending on the source of investigated lignin and content of the NiO at H-ZSM-5. | en |
dc.publisher | Amer Chemical Soc, Washington | |
dc.relation | COST Action (under a STSM of Jelena Milovanovic at Universidad de Cordoba) [FP1306] | |
dc.relation | BRISK- Biofuels Research Infrastructure for Sharing Knowledge | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172018/RS// | |
dc.relation | Norwegian Research CouncilResearch Council of Norway | |
dc.relation | Consejeria de Ciencia e Innovacion, Junta de AndaluciaJunta de Andalucia [P10 FQM 6711] | |
dc.rights | restrictedAccess | |
dc.source | ACS Sustainable Chemistry & Engineering | |
dc.subject | Lignin | en |
dc.subject | Microwave | en |
dc.subject | Depolymerization | en |
dc.subject | Zeolite | en |
dc.subject | Nickel oxide | en |
dc.title | Insights into the Microwave-Assisted Mild Deconstruction of Lignin Feedstocks Using NiO-Containing ZSM-5 Zeolites | en |
dc.type | article | |
dc.rights.license | ARR | |
dc.citation.epage | 4313 | |
dc.citation.issue | 8 | |
dc.citation.other | 4(8): 4305-4313 | |
dc.citation.rank | aM21 | |
dc.citation.spage | 4305 | |
dc.citation.volume | 4 | |
dc.identifier.doi | 10.1021/acssuschemeng.6b00825 | |
dc.identifier.scopus | 2-s2.0-84980002602 | |
dc.identifier.wos | 000380869800028 | |
dc.type.version | publishedVersion | |