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FTIR spectroscopic study of possible interactions of N-tert-butylformamide with ethers
dc.creator | Jović, B. | |
dc.creator | Petrović, Slobodan | |
dc.creator | Kordić, Branko | |
dc.creator | Kovacević, M. | |
dc.date.accessioned | 2021-03-10T13:41:24Z | |
dc.date.available | 2021-03-10T13:41:24Z | |
dc.date.issued | 2018 | |
dc.identifier.issn | 0022-2860 | |
dc.identifier.uri | http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3853 | |
dc.description.abstract | IR spectroscopic investigation of intramolecular interactions of N-tert-butylformamide (NtBF) in presence of selected ethers as the O-electron donors was carried out. Following ethers were selected based on the different size of sidechain: diethyl ether (DEE), diisopropyl ether (DiPE), methyl-tert-buthyl ether (MtBE), dibutyl ether (DBE), tetrahydrofuran (THF) and tetrahydropyran (THP). Frequency shifts of carbonyl stretching vibration v(C=0) of NtBF in ether solvents were also investigated. The spectroscopic characteristics for N-H center dot center dot center dot O hydrogen bonded complexes are given. Also, the equilibrium constants for 1:1 complex formation in carbon tetrachloride, at 298 K were determined using IR measurements. Further, the wavenumbers of carbonyl stretching vibration v(C=0) were correlated with the Catalan and the linear solvation energy relationships (LSER) solvatochromic parameters. | en |
dc.publisher | Elsevier Science Bv, Amsterdam | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172013/RS// | |
dc.rights | restrictedAccess | |
dc.source | Journal of Molecular Structure | |
dc.subject | Hydrogen bonding | en |
dc.subject | N-tert-butylformamide | en |
dc.subject | Ethers | en |
dc.subject | Molecular complex | en |
dc.subject | Spectroscopy | en |
dc.title | FTIR spectroscopic study of possible interactions of N-tert-butylformamide with ethers | en |
dc.type | article | |
dc.rights.license | ARR | |
dc.citation.epage | 68 | |
dc.citation.other | 1171: 62-68 | |
dc.citation.rank | M23 | |
dc.citation.spage | 62 | |
dc.citation.volume | 1171 | |
dc.identifier.doi | 10.1016/j.molstruc.2018.05.108 | |
dc.identifier.scopus | 2-s2.0-85049318109 | |
dc.identifier.wos | 000442193700009 | |
dc.type.version | publishedVersion |