dc.creator | Đokić, Veljko | |
dc.creator | Marinković, Aleksandar | |
dc.creator | Petrović, Rada | |
dc.creator | Ersen, Ovidiu | |
dc.creator | Zafeiratos, Spyridon | |
dc.creator | Mitrić, Miodrag | |
dc.creator | Ophus, Colin | |
dc.creator | Radmilović, Velimir R. | |
dc.creator | Janaćković, Đorđe | |
dc.date.accessioned | 2021-03-10T14:20:55Z | |
dc.date.available | 2021-03-10T14:20:55Z | |
dc.date.issued | 2020 | |
dc.identifier.issn | 1944-8244 | |
dc.identifier.uri | http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4470 | |
dc.description.abstract | The controllable synthesis of rutile TiO2 single crystal particles with the preferential orientation of {111} facets still remains a scientific and technological challenge. Here, we developed a facile route for fabrication of rutile TiO2 nanorod crystals (RTiO(2)NRs) having high ratios of oxidative {111} to reductive {110} surfaces. RTiO(2)NRs were synthesized using a peroxo-titanium complex (PTC) approach, which was controlled by changing the Ti/H2O2 ratio. The thus obtained RTiO(2)NRs revealed a high tendency to agglomerate through orientation-dependent attachment along the {110} facets. This resulted in an increased {111}/{110} surface ratio and led to a markedly improved photocatalytic activity of RTiO2NR aggregates. The reported findings illustrate the rich potential of the herein proposed facile and energy-efficient synthesis of nanostructured rutile TiO2-based photocatalysts. | en |
dc.publisher | Amer Chemical Soc, Washington | |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200135/RS// | |
dc.relation | Serbian Academy of Sciences and Arts [F-141] | |
dc.relation | Office of Science, Office of Basic Energy Sciences, of the U.S. Department of EnergyUnited States Department of Energy (DOE) [DE-AC02-05CH11231] | |
dc.rights | restrictedAccess | |
dc.source | ACS Applied Materials & Interfaces | |
dc.subject | TiO2 | en |
dc.subject | Rutile nanorods | en |
dc.subject | Photocatalysis | en |
dc.subject | Orientation-dependent attachment | en |
dc.subject | Self-assembly | en |
dc.title | Highly Active Rutile TiO2 Nanocrystalline Photocatalysts | en |
dc.type | article | |
dc.rights.license | ARR | |
dc.citation.epage | 33068 | |
dc.citation.issue | 29 | |
dc.citation.other | 12(29): 33058-33068 | |
dc.citation.rank | M21 | |
dc.citation.spage | 33058 | |
dc.citation.volume | 12 | |
dc.identifier.doi | 10.1021/acsami.0c03150 | |
dc.identifier.pmid | 32602695 | |
dc.identifier.scopus | 2-s2.0-85088492685 | |
dc.identifier.wos | 000555417200085 | |
dc.type.version | publishedVersion | |